{"title":"Electrospun PEO/Chitosan Nanofibers Templated with Gold Nanoparticles Prepared with Laser and Wet Synthesis","authors":"V. Nirwan, A. Al-Kattan, A. Kabashin, Amir Fahmia","doi":"10.1109/NAP.2018.8914938","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914938","url":null,"abstract":"Hybrid nanofibers are emerging as one of the solutions to unite two modalities (organic and in-organic) widely found in nature, rarely engineered at small length scale; due to restrictions like wide array of physical, chemical properties, range of processing environments; these modalities feature seldom in applications. Hybrid nanofibers enables overcoming these restrictions by combining many dissimilar modalities thereby, incorporating functionalities of those dissimilar modalities into a single structure. Therefore, efficiently fabricating a multifunctional hybrid system with applications not limited by processing environments or range of properties. Additionally, multifunctionality, porosity, high surface to volume ratio provide hybrid nanofibers as an alternative for wide biomedical as well as other applications like filtration, tissue engineering among others. Electrospinning enables fabrication of nonwoven nanofibers ranging from few hundred nanometers to microns. Functional modalities like nanoparticles, dendrimers, proteins could be fabricated in polymer matrix. One such process being used here employs Poly (ethylene oxide), chitosan as matrix with gold nanoparticles as functional elements. The gold nanoparticles have been synthesized by laser ablation and by Turkevich's method [1]. With continuation to previous study the fibers have been prepared and analyzed with higher concentration of chitosan and then electrospun to produce nanofibers averaging 300 nm. With potential such as high contrast for biological imaging, induced hyperthermia and drug loading modalities. The fibers were then characterized to distinguish them from pristine fibers. Various techniques used includes TGA, DSC, FTIR.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"532 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132314388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. P. Tkach, I. Cheshko, M. Vasyukhno, L. Odnodvorets, S. Protsenko
{"title":"Strain Properties of Film Systems Based on Fe and Pd as Sensitive Elements of Flexible Electronics","authors":"O. P. Tkach, I. Cheshko, M. Vasyukhno, L. Odnodvorets, S. Protsenko","doi":"10.1109/NAP.2018.8915021","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915021","url":null,"abstract":"On the basis of strain properties study at the room temperatures, it was established that the transition from elastic to quasi-elastic deformation in Pd/Fe samples is on the range 0,3-0,4%, and shifts toward large deformations in multilayes. For two-layer samples and multilayers based on Pd and Fe with layer thickness from 5 to 40 nm, a size dependence of the strain coefficient is obtained, the value of which from 6 to 13 units.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130097084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Goncharov, A. Yunda, A. Pogrebnjak, I. Shelest, V. Buranich, V. Loboda
{"title":"Influence of RF-magnetron Sputtering System Parameters on the Process of Thin Films Nanostructure Formation","authors":"A. Goncharov, A. Yunda, A. Pogrebnjak, I. Shelest, V. Buranich, V. Loboda","doi":"10.1109/NAP.2018.8914825","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914825","url":null,"abstract":"Effect of a radio-frequency magnetron sputtering system parameters on the process of thin films structure formation was analyzed. Dependence of energy delivered to the growing film by bombarding ions on the magnetron parameters and configuration was studied. Main parameters determining this energy are plasma potential, substrate ion current density, substrate bias and deposition rate. It was shown, that energetic conditions sufficiently influence on the structure formation of textured coatings. The influence of discharge gap distance and substrate bias potential on formation of hafnium diboride films structure was studied.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134223301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microwave Assisted Formation of the Chitosan/Hydroxyapatite Scaffold for Bone Tissue Regeneration","authors":"L. Sukhodub, M. Kumeda, V. Gapon, L. Sukhodub","doi":"10.1109/NAP.2018.8914971","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914971","url":null,"abstract":"Polymer-hydroxyapatite composites are an attractive biomaterial for bone and tooth implants. Compared with conventional methods, microwave synthesis is a fast, simple and efficient method to prepare nanosized biomaterials. In this work chitosan-hydroxyapatite (CS-HA) composite were obtained under MW radiation. With increasing MW power, the average size of the HA crystallites, formed in the presence of chitosan, decreases from 31 nm (300 W) to 24 (800 W). With in creasing micro wavepower, the swelling degree of sample sincreases from 40 to 55% and porosity decreases from 28 to 18%. A similar dependence iso bserved with a nincreasein the alginate polymercontent.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127587042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Grishchenko, B. Blyzniuk, V. Diyuk, O. Boldyrieva, Vladyslav V. Lisnyak, O. Mischanchuk
{"title":"Adsorption Characteristics of Nanoporous Activated Carbon Tailored with Acidic Treatment","authors":"L. Grishchenko, B. Blyzniuk, V. Diyuk, O. Boldyrieva, Vladyslav V. Lisnyak, O. Mischanchuk","doi":"10.1109/NAP.2018.8915164","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915164","url":null,"abstract":"The adsorption remediation behavior of nanoporous activated carbon (NAC) was studied towards toluene, heptane, water, and 2-propanol. Besides, NACs tailored with acidic treatment were prepared and selected as catalysts to examine their potential in the reaction of 2-propanol dehydration to propylene. It was shown that depending on the used modification method, the surface layers of carbons contain from 0.30 up to 0.98 mmol/g of SO3H groups. Thermal stability, adsorption of 2-propanol and catalytic behavior of the resulted samples were characterized. Thermoprogrammed desorption studies presented the positive correlation of catalytic efficiency with the temperature range of desorption of 2-propanol and propylene. The lowest temperatures at the desorption maxima had the sample of NAC modified with the sulfonated poly(α-methylstyrene). It showed the highest catalytic performance and relatively low temperatures and could completely dehydrate alcohol at 140 °C, while the pristine NAC has no catalytic activity for 2-propanol dehydration at that temperature.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"63 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134457316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. Khomenko, I. Berezovskaya, I. Stoyanova, N. Efryushina, V. Dotsenko, N. Poletaev, M. E. Khlebnikova
{"title":"Synthesis and Luminescence Study of Mn-doped Nanosized Al2O3","authors":"O. Khomenko, I. Berezovskaya, I. Stoyanova, N. Efryushina, V. Dotsenko, N. Poletaev, M. E. Khlebnikova","doi":"10.1109/NAP.2018.8915033","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915033","url":null,"abstract":"Mn<sup>3</sup>+-doped Al<inf>2</inf>O<inf>3</inf>was obtained by combustion method. It was found that the resulting powder, with particle sizes of 10–70 nm, consists of a mixture of transition aluminas <tex>$(delta^{*}, delta, theta)$</tex>, among which <tex>$delta^{*}$</tex> -polymorph is dominant. The presence of Mn<sup>3</sup>+ ions results in a wide absorption band in the 400–620 nm region, but no emission of these ions was observed, probably due to a strong Jahn-Teller effect. It is shown that a part of Mn impurity ions exists in the oxidation state +2 and occupies tetrahedral positions in the <tex>$delta^{star}-mathrm{A}1_{2}mathrm{O}_{3}$</tex>, causing a broad emission band with a maximum at 520 nm.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"107 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124226848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. I. Dobrozhan, G. Kopach, R. Mygushchenko, G. Khrypunov, M. M. Harchenko, Olesia V. Polezhaeva
{"title":"Study Solid Solutions in CdS/CdTe Thin Films Heterosystems Obtaine by DC Magnetron Sputtering","authors":"A. I. Dobrozhan, G. Kopach, R. Mygushchenko, G. Khrypunov, M. M. Harchenko, Olesia V. Polezhaeva","doi":"10.1109/NAP.2018.8915293","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915293","url":null,"abstract":"The influence of physical and technological condensation mode by direct current magnetron sputtering on the crystal structure and optical properties of grown CdS and CdTe films, CdS/CdTe thin films heterosystems was investigated. Traditional chloride treatment of thin-film CdS/CdTe heterosystem leads to recrystallization of CdTe basic layer and its wurtzite-sphalerite phase transition. After Cl treatment a bandgap in CdTe increases up to 1.5 eV, For CdS/CdTe heterosystem a decrease of a bandgap to 1.45 eV is observed which is determined by formation of solid solutions of $mathrm{CdS}_{mathrm{x}}mathrm{Te}_{mathrm{1-x}}$ at the interphase boundary of CdS/CdTe. The value of the stoichiometric parameter $mathrm{x}=0,1pm 0,01$ was calculated using the optical researches data.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"140 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124415955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Z. Tsybrii, M. Vuichyk, K. Svezhentsova, F. Sizov, I. Korotash, E. Rudenko, D. Polotskiy
{"title":"Nanostructured Functional Film Coatings Formed by Helicon-Arc Ion-Plasma Method on the Polymeric Substrates","authors":"Z. Tsybrii, M. Vuichyk, K. Svezhentsova, F. Sizov, I. Korotash, E. Rudenko, D. Polotskiy","doi":"10.1109/NAP.2018.8915365","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915365","url":null,"abstract":"The technology of low-temperature ion-plasma formation of nanostructured aluminum nitride films on various substrates, including Mylar and Teflon flexible thermolabile polymeric films, was developed. The study of structural and optical characteristics of such nanostructured coatings has shown the possibility to use them as functional films with selective transmissions and barriers in infrared (IR) spectral region. Due to high thermal conductivity and specific optical properties (the Restrahlen band at the wavelengths 10.3-17.9 microns and good transparency in visible and sub-THz spectral regions) AIN thin polycrystalline films on polymeric substrates can be attractive for making IR radiation blocking filters from the background at 300 K and to improve performance of sub-THz low-temperature detectors in ground-based telescopes.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124430208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Boychuk, V. Kotsyubynsky, K. Bandura, S. Fedorchenko
{"title":"Nickel-Iron Spinel/Reduced Graphene Oxide Nanocomposites: Structural and Mossbauer Studies","authors":"V. Boychuk, V. Kotsyubynsky, K. Bandura, S. Fedorchenko","doi":"10.1109/NAP.2018.8915082","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915082","url":null,"abstract":"Ultrafine nickel ferrite and nickel ferrite/ reduced graphene oxide (rGO) nanocomposite have been synthesized by hydrothermal method. Structural and magnetic properties of the obtained materials have been studied. XRD studies revealed that the joint hydrothermal synthesis of nickel ferrite and graphene oxide reduction leads to decreasing of ferrite particles to 8–9 nm. Normalized pair distance distribution functions and the most probable particle sizes were studied by SAXS method. The distribution of Fe3+ and Ni2+ cations between tetrahedral and octahedral sublattices was analyzed and transitions magnetic ordered state - spin glass like state - superparamagnetic state for ultrafine nickel ferrite were observed by Mossbauer spectroscopy.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115113088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}