V. Shaternik, A. Shapovalov, O. Suvorov, E. V. Zubov
{"title":"Charge Transport with Many-Electron Processes in Tunnel Junctions with Hybrid Barriers","authors":"V. Shaternik, A. Shapovalov, O. Suvorov, E. V. Zubov","doi":"10.1109/NAP.2018.8914992","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914992","url":null,"abstract":"We propose to realize MoRe/Si(W) /MoRe hybrid junctions by using self-organization effects for the creation of quantum dots (tungsten clusters) in the semiconductor barriers consisting of a mixture of silicon and silicon oxide. Current-voltage characteristics of the MoRe/Si(W)/MoRe samples have been measured in a wide voltage range from −900 to 900 mV at temperatures from 4.2 K to 77 K. At low temperatures and for a comparatively small W content in the hybrid barrier, the heterostructures demonstrate current-voltage curves of an unusual shape. Single or several current peaks caused by electron tunneling through the allowed states in the barrier have been observed in the transport characteristics. With increasing temperature, superconducting fluctuations in the MoRe electrodes become unimportant, and the current-voltage curve of a heterostructure follows the Ohm's law. At last, we present theoretical description of the charge transport in such inhomogeneous systems with account of many-electron processes.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115499892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Karakurkchi, N. Sakhnenko, M. Ved’, I. Parsadanov, S. Menshov
{"title":"Nanostructured Oxide-Metal Catalysts for Intra-Cylinder Catalysis","authors":"A. Karakurkchi, N. Sakhnenko, M. Ved’, I. Parsadanov, S. Menshov","doi":"10.1109/NAP.2018.8914840","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914840","url":null,"abstract":"The paper discusses the preparation of cobalt and manganese oxide catalytic systems on cast piston aluminum alloy for intra-cylinder catalysis. It has been considered the features of the conversion coatings formation on silumin by plasma electrolytic oxidizing in alkaline electrolytes based on potassium pyrophosphate. The effect of the electrolyte components and processing conditions on the composition and the morphology of the surface layers has been studied. Plasma electrolytic oxidizing of internal combustion engines pistons allows the formation of alumina matrix containing manganese and cobalt oxides which evinces high catalytic properties. Manganese-containing oxide system demonstrates the highest fuel economy at 3–4 %. When using a piston with a cobalt oxides coating, toxic gas emissions are reduced: NOxwithin 10 % and CO - of 15–18 %. The proposed systems can find application in intra cylinder catalysis technologies in order to reduce the toxicity of gas emissions of engines and increase their fuel efficiency.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"1020 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123120088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Pogorielov, V. Deineka, O. Oleshko, Irina Liubchak, K. Dědková, R. Vasyliev, Dimitri Zubov, A. Kalinkevich, O. Kalinkevich
{"title":"Development of Chitosan Hemostatic Sponges with Different Solvents and Tranexamic Acid","authors":"M. Pogorielov, V. Deineka, O. Oleshko, Irina Liubchak, K. Dědková, R. Vasyliev, Dimitri Zubov, A. Kalinkevich, O. Kalinkevich","doi":"10.1109/NAP.2018.8914877","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914877","url":null,"abstract":"Blood loss during surgery and combat trauma are still main complications leading patient death. Topical hemostasis in case of diffuse bleeding over past 2 decades have resulted in low mortality and morbidity rates but relatively high cost limited their application in low- and middle-income countries, that stimulate investigation of effective and low cost materials. In recent paper chitosan sponges with different solvents (acetic, ascorbic, lactic and oxalic acids) with/without tranexamic acid were made as a hemostatic sponges. SEM and Degradation test used for physical characterization and Cell Toxicity test and Blood Clotting Test - for biological evaluation. Based on structural features and in-vitro studies, chitosan-acetate sponge with TXA is the best choice for development of high efficient hemostatic materials.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121020492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. Lavrynenko, Yu.S. Shchukin, N. Dudchenko, O. B. Brik
{"title":"Magnetic Properties of Nanoparticles Formed on the Steel Surface Contacting with Aurum-Bearing Water Solutions","authors":"O. Lavrynenko, Yu.S. Shchukin, N. Dudchenko, O. B. Brik","doi":"10.1109/NAP.2018.8915372","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915372","url":null,"abstract":"the magnetic properties of the nanosized structures formed via the rotation-corrosion dispergation route in the presence of aurum aguaforms have been studied using magnetometry. The differences in the magnetic properties of the samples are in evident due to the changes of the physical-chemical conditions during synthesis procedure, especially, aurum concentration, temperature and the presence of the preliminary formed Green Rust or lepidocrocite layers on the steel surface. All samples belong to superparamagnetics, hence, they do not show the remanence magnetization and coercitivity.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121086918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
U. Yakhnevych, I. Syvorotka, O. Buryy, S. Ubizskii, M. Vakiv, D. Sugak
{"title":"OH- Absorption Spectra of Lithium Niobate Crystals Diffusion-Doped by Copper","authors":"U. Yakhnevych, I. Syvorotka, O. Buryy, S. Ubizskii, M. Vakiv, D. Sugak","doi":"10.1109/NAP.2018.8914802","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914802","url":null,"abstract":"The OH- groups absorption band depth profiles of LiNbO3 single crystals were investigated after high-temperature treatment in the presence of CuO powder. The changes of the optical absorption caused by diffusion of Cu were registered in the direction perpendicular to the direction of diffusion. The correlation of the OH- groups absorption band intensities and positions with the spatial distributions of copper ions is revealed.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116746407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"TiO2-SnO2 Nanocomposites Obtained by Hydrothermal Method","authors":"Anastasiya S. Kutuzova, T. Dontsova","doi":"10.1109/NAP.2018.8914747","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914747","url":null,"abstract":"The TiO2-SnO2nanocomposites with different ratio of components (1, 3, 5, 10 mas% of tin (IV) oxide) were obtained by simple and low-temperature hydrothermal method. The synthesized nanopowders were analyzed by means of X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and N2 adsorption-desorption method. The obtained composites are nanocrystalline with a crystallite size in the range of 5–7 nm. It was found that the synthesized nanocomposites consist of anatase and rutile-type TiO2-SnO2 solid solutions because of Sn4+ ions incorporation. It was established that the presence of tin (IV) oxide increases the specific surface area of nanocomposites. It was demonstrated, that obtained TiO2-SnO2 nanocomposites show better photocatalytic performance towards anionic dyes (congo red) than towards cationic dyes (methylene blue) and the photocatalytic activity increases with the increase of SnO2 content. Moreover, synthesized TiO2-SnO2 samples have higher adsorption and photocatalytic activity than the commercial titania powder P25 TiO2AEROXIDE® towards congo red degradation.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130682572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Nedilko, S. Hamamda, M. Nedielko, O. Alekseev, Yu.E. Grabovskyi, E. O. Reznichenko, V. Scherbatskyi, V. Boyko, V. Chornii, V. Barabash, O. Yaschenko
{"title":"Luminescent Composites on the Base of Microcrystalline Cellulose: Synthesis, Fabrication and Properties","authors":"S. Nedilko, S. Hamamda, M. Nedielko, O. Alekseev, Yu.E. Grabovskyi, E. O. Reznichenko, V. Scherbatskyi, V. Boyko, V. Chornii, V. Barabash, O. Yaschenko","doi":"10.1109/NAP.2018.8914750","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914750","url":null,"abstract":"The data on preparation, structure and morphology of cellulose-based composites, those have oxide component as filler are reported. It is shown that depending on raw materials origin and processing degree cellulose samples reveal various degree of crystallinity (in the range 64 – 77 %. Obtained composites reveal even lesser crystallinity degree ⋍ 57%. Detailed analysis of surface morphology was performed with using of scanning electronic microscopy. It was found the studied samples contains plates with sizes ~ 20 – 50 μ those consist of close-packed grains of 5–10 μ size. In the case of composites some oxide nanoparticles (sizes up to 200 nm) were incorporated into grains of microcrystalline cellulose. It was established the luminescence properties of cellulose are dependent on type of plant raw materials as well as on processing methods. These factors have influence on luminescence intensity but profile of photoluminescence bands remains practically unchanged. Under excitation in 337–532 nm spectral region the composites that contain K2Eu(PO4)(MoO4) and LaVO4:Sm are characterized by intensive visible photoluminescence. Spectra of these PL depend on excitation wavelength.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"194 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121418271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of Thermal Transport Anisotropy in Porous Silicon Systems by Raman Technique","authors":"M. Isaiev, O. Didukh, V. Lysenko, A. Belarouci","doi":"10.1109/NAP.2018.8915014","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915014","url":null,"abstract":"We have investigated the thermal transport in anisotropic nanostructured materials. Particularly, porous silicon and silicon nanowires arrays have been considered in this work. For thermal conductivity evaluation Raman technique has been applied. The thermal transport anisotropy is more pronounce in silicon nanowires array than in porous silicon. Yet, the in-plane and cross-plane thermal conductivities of porous silicon differ approximately in twice. Both values are in a good agreement with the literature.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"91 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121679084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Structure of ZnNi Coatings Modified by the YAG: Nd3+Laser Radiation","authors":"N. Valko, S. Anufric","doi":"10.1109/NAP.2018.8914859","DOIUrl":"https://doi.org/10.1109/NAP.2018.8914859","url":null,"abstract":"The work presents research results of the influence of various modes of YAG: Nd3+laser irradiation on the surface morphology, elemental and phase compositions of ZnNi coatings electrodeposited onto the steel 08kp. There are presented relationships of elemental and phase compositions from the modes of irradiation and a density power of laser irradiation. It is found that the optimal mode for modification ZnNi coatings with forming dense structure and uniform distribution of the elements on the irradiated surface, is YAG: Nd3+laser irradiation characterized by the Q-switching mode, second harmonic generation $(lambda=532 text{nm}, tau=16text{ns})$","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"144 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115959197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis Methods and Modern Direction in Modification of Nickel Cobaltite and Composite Nanoparticles with its Participation","authors":"A. Voronova, I. Ivanenko","doi":"10.1109/NAP.2018.8915243","DOIUrl":"https://doi.org/10.1109/NAP.2018.8915243","url":null,"abstract":"This paper presents an exhaustive review on the methods of synthesis, properties and modification of Ni, Co-spinels. Among many kinds of catalytic materials and composites with its participation, Ni, Co-spinel attracted great interest, especially as electrode material for electrochemical energy storage/conversion systems, due to its higher theoretical specific capacity than conventional graphite. The main advantages of nickel cobalt spinel and composite materials with its participation are high electrical resistivity and electron conductivity, high rate capability, thermodynamic stability and durability. Peculiarities of the crystal structure of spinels cause such properties. Ni, Co-spinels refer to single-phase triple oxides of the inverse spinel type with two different metal cations. Inverse spinels have considerable electrical conductivity due to the possibility of electron exchange between divalent and trivalent ions in the octahedral position. Due to the presence of such structural features, inverse spinels can be successfully used as electrocatalysts in energy storage/conversion systems. Synthesis approaches of Ni, Co-spinel and composites with its participation include hydrothermal method, microwave synthesis, coprecipitation method, dry synthesis technique and sol-gel method. Establishing a connection between methods and conditions of synthesis, as well as a comprehensive understanding of the methods used to modification the obtained samples, is an important scientific and practical task and an urgent topic for further research in this field.","PeriodicalId":239169,"journal":{"name":"2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP)","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132032746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}