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Optimising Venturi flume oxygen transfer efficiency using uncertainty-aware decision trees. 利用不确定性感知决策树优化文丘里水槽氧传递效率。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-12-01 DOI: 10.2166/wst.2024.393
Nand Kumar Tiwari, Dinesh Panwar
{"title":"Optimising Venturi flume oxygen transfer efficiency using uncertainty-aware decision trees.","authors":"Nand Kumar Tiwari, Dinesh Panwar","doi":"10.2166/wst.2024.393","DOIUrl":"https://doi.org/10.2166/wst.2024.393","url":null,"abstract":"<p><p>This study optimizes standard oxygen transfer efficiency (SOTE) in Venturi flumes investigating the impact of key parameters such as discharge per unit width (<i>q</i>), throat width (<i>W</i>), throat length (<i>F</i>), upstream entrance width (<i>E</i>), and gauge readings (<i>H<sub>a</sub></i> and <i>H<sub>b</sub></i>). To achieve this, a comprehensive experimental dataset was analyzed using multiple linear regression (MLR), multiple nonlinear regression (MNLR), gradient boosting machine (GBM), extreme gradient boosting (XRT), random forest (RF), M5 (pruned and unpruned), random tree (RT), and reduced error pruning (REP). Model performance was evaluated based on key metrics: correlation coefficient (CC), root mean square error (RMSE), and mean absolute error (MAE). Among the proposed models, M5_Unprun emerged as the top performer, exhibiting the highest CC (0.9455), the lowest RMSE (0.1918), and the lowest MAE (0.0030). GBM followed closely with a CC value of 0.9372, an RMSE value of 0.2067, and an MAE value of 0.0006. Uncertainty analysis further solidified the superior performance of M5_Unpruned (0.7522) and GBM (0.8055), with narrower prediction bands compared to other models, including MLR, which exhibited the widest band (1.4320). One-way analysis of variance confirmed the reliability and robustness of the proposed models. Sensitivity, correlation, and SHapley Additive exPlanations analyses identified <i>W</i> and <i>H<sub>b</sub></i> as the most influencing factors.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 12","pages":"3210-3240"},"PeriodicalIF":2.5,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142903261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of thermal pretreatment on the anaerobic digestion characteristics of fruit waste liquids. 热预处理对水果废液厌氧消化特性的影响。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-12-01 Epub Date: 2024-11-28 DOI: 10.2166/wst.2024.388
Haoran Sun, Hua Wang, Xinmin Zhang, Weihua Cheng, Xuyang Li
{"title":"Effects of thermal pretreatment on the anaerobic digestion characteristics of fruit waste liquids.","authors":"Haoran Sun, Hua Wang, Xinmin Zhang, Weihua Cheng, Xuyang Li","doi":"10.2166/wst.2024.388","DOIUrl":"https://doi.org/10.2166/wst.2024.388","url":null,"abstract":"<p><p>Fruit waste is one of the main components of municipal waste. To study its potential and characteristics in anaerobic digestion, this study took fruit waste and its waste liquid as raw materials, investigate the influence of thermal pretreatment on the anaerobic digestion characteristics under 35 ± 17 °C. The anaerobic digestion materials were fruit waste liquid (group A1), fruit waste liquid after thermal pretreatment (group A2), fruit slurry (group A3), and the material of A2 and A3 mixed with municipal sludge (groups A4 and A5) has also been involved. The results showed that the thermal pretreatment is in favor of increasing the total gas production rate, which the waste liquid after thermal pretreatment (A2) was the highest one with 767.09 mL/gVS which 6.51% higher than A1; while it has not obviously influence on the total hydrogen production rate of waste liquid; the addition of municipal sludge increased the total methane production rate of fruit waste or its liquid. After thermal pretreatment, the pH of fruit waste was 0.37 lower than initial pH; VFAs and SCOD content were both increased, which are benefit for anaerobic digestion. In addition, the experimental data were verified by the modified Gompertz model.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 11","pages":"3041-3051"},"PeriodicalIF":2.5,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142824453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Navigating the definition of urban flooding: A conceptual and systematic review of the literature. 导航城市洪水的定义:对文献的概念和系统回顾。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-10-23 DOI: 10.2166/wst.2024.351
Priscila B R Alves, Ebenezer Amanguah, Devin McNally, Maria Espinoza, Hamed Ghaedi, Allison C Reilly, Marccus D Hendricks
{"title":"Navigating the definition of urban flooding: A conceptual and systematic review of the literature.","authors":"Priscila B R Alves, Ebenezer Amanguah, Devin McNally, Maria Espinoza, Hamed Ghaedi, Allison C Reilly, Marccus D Hendricks","doi":"10.2166/wst.2024.351","DOIUrl":"https://doi.org/10.2166/wst.2024.351","url":null,"abstract":"<p><p>Urban flooding is a pervasive global risk, posing a great challenge to urban planners, policymakers, and particularly communities. This paper reviews the literature to analyze how urban flooding is defined across scientific disciplines. Our objectives are to uncover the elements used to define urban flooding and evaluate how these elements can impact future research and practice. A key difficulty is the lack of a consistent, comprehensive definition that captures both physical and social dimensions of urban flooding. Current definitions often focus solely on physical aspects (e.g., rainfall, infrastructure) or social impacts, rarely integrating both. This fragmentation hinders effective flood risk management and interdisciplinary collaboration. Our contribution is a multifaceted definition incorporating spatial and social concerns, including water origins, built environment characteristics, and local community aspects. We introduce the 'Urban Water Transect' concept to illustrate the continuum of flood risk across urban zones, addressing a gap in the literature. The analysis reveals that many papers discuss flooding causes without providing an explicit definition. Urban flooding is predominantly defined based on water source, imperviousness, and drainage infrastructure. Future research should adopt an interdisciplinary perspective considering both physical and social aspects, potentially transforming urban flood risk management.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2796-2812"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Developing a universal equation to estimate the mass of dewatered wastewater sludge during biological digestion at mesophilic and thermophilic temperatures. 建立一个通用方程来估计在嗜温和嗜热温度下生物消化过程中脱水废水污泥的质量。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-08 DOI: 10.2166/wst.2024.366
Eskandar Poorasgari, Banu Örmeci
{"title":"Developing a universal equation to estimate the mass of dewatered wastewater sludge during biological digestion at mesophilic and thermophilic temperatures.","authors":"Eskandar Poorasgari, Banu Örmeci","doi":"10.2166/wst.2024.366","DOIUrl":"https://doi.org/10.2166/wst.2024.366","url":null,"abstract":"<p><p>A series of dewaterability tests were conducted on various types of sludges to establish a wholistic relationship between sludge water fractions. Sludge samples were obtained from batch and continuous sludge digesters, which were operated anaerobically and aerobically under mesophilic and thermophilic conditions. Dewaterability of the sludge samples and the distribution of water fractions were studied using centrifugation and thermal drying. Thickened waste activated sludge (T-WAS) contained 10-11 g bound water (BW)/g of total solids (TS), and it was more hydrophilic than primary and digested sludges. During anaerobic digestion, BW content fluctuated between 3.2 and 4.2 g BW/g TS. However, aerobic digestion at 55°C reduced the BW content of the mixed T-WAS + primary sludges from 3.7 to 2.1 g BW/g TS. A linear function was developed to correlate supernatant and BW mass fractions (R<sup>2</sup> = 0.995). An equation was derived from the linear function to estimate the mass of dewatered sludge based on the TS concentration of the initial wet sludge. The developed expression is applicable to different kinds of wastewater sludges. Such an expression would be helpful for the designers and operators of sludge thickening and dewatering systems that use centrifugal separation.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2894-2910"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of rubber particle inputs on nitrogen removal efficiency of bioretention systems. 橡胶颗粒输入对生物滞留系统脱氮效率的影响。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-05 DOI: 10.2166/wst.2024.363
Tuanping Hu, Wenyi Li, Jiaqing Xiong, Jiajia Zhou, Qianhe Xia
{"title":"Influence of rubber particle inputs on nitrogen removal efficiency of bioretention systems.","authors":"Tuanping Hu, Wenyi Li, Jiaqing Xiong, Jiajia Zhou, Qianhe Xia","doi":"10.2166/wst.2024.363","DOIUrl":"https://doi.org/10.2166/wst.2024.363","url":null,"abstract":"<p><p>Bioretention systems effectively capture rubber particles and other microplastics in stormwater runoff. However, it is uncertain whether long-term particle accumulation affects pollutant removal efficacy. This study investigated the impact of various concentrations of ethylene-propylene-diene-monomer (EPDM) particles (0, 50, 100, and 400 mg/L) on bioretention system nitrogen removal performance. The input of EPDM during short-duration (2 h) rainfall favored the removal of nitrogen, and the total nitrogen effluent concentration of the bioretention system with EPDM was reduced by 0.59-1.52 mg/L compared with that of the system without EPDM. In addition, the input of EPDM reduced the negative effects of drought. During long-duration (24 h) rainfall, higher concentrations of EPDM led to lower nitrate-nitrogen concentrations in the effluent. The bioretention system with EPDM required less time for nitrate-nitrogen removal to reach 50% than that without EPDM input. Microbial community analysis showed that EPDM increased the relative total abundance of denitrifying bacteria (such as <i>Dechloromonas</i>, <i>Zoogloea</i>, <i>Ramlibacter</i>, and <i>Aeromonas</i>) by 7.25-10.26%, which improved the denitrification capacity of the system.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2734-2746"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetic study of mineral oil removal from wastewater by the sono-electrochemical process. 超声电化学法去除废水中矿物油的动力学研究。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-11 DOI: 10.2166/wst.2024.370
Hana Posavcic, Katarina Licht, Ivan Halkijevic, Domagoj Nakic
{"title":"Kinetic study of mineral oil removal from wastewater by the sono-electrochemical process.","authors":"Hana Posavcic, Katarina Licht, Ivan Halkijevic, Domagoj Nakic","doi":"10.2166/wst.2024.370","DOIUrl":"https://doi.org/10.2166/wst.2024.370","url":null,"abstract":"<p><p>Chemical kinetics can be a useful tool for determining the optimal operating time of electrochemical processes. The main objective of the study was to determine the mineral oil removal rate by sono-electrochemical treatment. In this study, zero-, first-, and second-order kinetic models were used to determine the reaction rate of mineral oil removal with the sono-electrochemical process. The reaction rate experiments were conducted under the following optimal conditions: 8 min of treatment time, a current density of 53.1 A/m<sup>2</sup>, and a flow rate of 0.23 L/s. It was found that the changes in mineral oil concentrations follow second-order kinetics with a coefficient of determination of 0.9732. The mineral oil removal efficiency was 94.4%. This study concludes that sono-electrochemical process could be a promising technology for the removal of mineral oil from wastewater, and that the mineral oil removal rate can be determined by chemical kinetics. The results obtained may be useful for the optimization of the sono-EC process and reactor design.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2911-2917"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A new strategy for greenhouse gas emission reduction in the anaerobic/anoxic/oxic biological treatment process using exogenous N-acyl-homoserine lactones, a quorum-sensing signaling molecules. 利用外源n -酰基同丝氨酸内酯这一群体感应信号分子在厌氧/缺氧/缺氧生物处理过程中减少温室气体排放的新策略
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-11 DOI: 10.2166/wst.2024.369
Wenjiao Sang, Zhenxue Ge, Qian Zhang, Fangmao Gan, Nianhong Wan, Lei Zou
{"title":"A new strategy for greenhouse gas emission reduction in the anaerobic/anoxic/oxic biological treatment process using exogenous N-acyl-homoserine lactones, a quorum-sensing signaling molecules.","authors":"Wenjiao Sang, Zhenxue Ge, Qian Zhang, Fangmao Gan, Nianhong Wan, Lei Zou","doi":"10.2166/wst.2024.369","DOIUrl":"https://doi.org/10.2166/wst.2024.369","url":null,"abstract":"<p><p>In this study, the impact of exogenous N-acyl-homoserine lactones (AHLs) on greenhouse gas (GHG) emissions in anaerobic/anoxic/oxic (A/A/O) systems was analyzed by manipulating the type and dosage of AHLs. The mechanism behind AHLs' effects on GHG emissions was explored through changes in microbial community structure. Findings revealed that N-octanoyl-homoserine lactone (C8-HSL) and high-dose N-dodecanoyl-homoserine lactone (C12-HSL) increased GHG emissions, while low-dose C12-HSL decreased them. Moreover, C8-HSL and high-dose C12-HSL promoted methane (CH<sub>4</sub>) and nitrous oxide (N<sub>2</sub>O) production by affecting sludge particle size. Bacterial community analysis highlighted <i>Acinetobacter</i> and <i>Flavobacterium</i>'s roles in N<sub>2</sub>O emissions and acetate methanogens in methane synthesis. Metabolic pathway analysis showed that the acetic acid (CH<sub>3</sub>COOH) methanogenic pathway was the main methanogenic pathway; C8-HSL and C12-HSL influenced methane emission by affecting the methanogenic pathway and N<sub>2</sub>O emission by changing nitrous oxide reductase (<i>Nos</i>) abundance. This research underscores AHL-based quorum sensing's potential in mitigating GHG emissions during activated sludge wastewater treatment, offering insights into their application and impact on key microbial activities. Limitations include the absence of methane emission reduction by signaling molecules and the need for further investigation into their effects on sludge accumulation.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2764-2783"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of reference libraries for the detection of tire-derived microplastics (TMPs). 轮胎衍生微塑料(TMPs)检测参考文库的比较。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-13 DOI: 10.2166/wst.2024.378
Hiroshi Sakai, Zizheng Sun, Masami Yanagihara
{"title":"Comparison of reference libraries for the detection of tire-derived microplastics (TMPs).","authors":"Hiroshi Sakai, Zizheng Sun, Masami Yanagihara","doi":"10.2166/wst.2024.378","DOIUrl":"10.2166/wst.2024.378","url":null,"abstract":"<p><p>Introducing microplastics (MPs) into the marine environment is a global problem. Tire-derived microplastics (TMPs) are estimated to account for 60% of all secondary MPs dispersed in aquatic environments. To effectively detect TMPs in environmental samples using micro-Fourier transform infrared (μFTIR) spectroscopy, a high-quality reference library is essential. However, the use of conventional diamond crystals in FTIR presents challenges for the detection of materials containing carbon black, such as rubber and tires. In addition, there is a discrepancy between spectra from standard libraries and spectra from environmental samples, which makes detection difficult. In order to overcome these problems in the detection of TMPs by μFTIR, we developed four reference libraries to improve the detection, and 'The 26 tire wear library' was found to be the best among these four. Furthermore, a comparison of these new libraries revealed the following requirements to improve TMP detection: (i) the reference spectra must be acquired under the same setup used for material observation including prism material, (ii) tires, not rubber, must be used as reference materials, and (iii) tire wear samples must be prepared to replicate the actual generation conditions on roads.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2784-2795"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microbe-plant-nanoparticle interactions: role in bioremediation of petroleum hydrocarbons. 微生物-植物-纳米颗粒的相互作用:在石油烃生物修复中的作用。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-04 DOI: 10.2166/wst.2024.362
Augustine A Unimke, Onyemaechi Okezie, Sa'adatu E Mohammed, Augusta O Mmuoegbulam, Saidu Abdullahi, Utibe A Ofon, Denis M Olim, Hamza Badamasi, Abdulsalam I Galadima, Opeyemi K Fatunla, Aminu Abdullahi, Sharhabil M Yahaya, Muhammad M Ibrahim, Abba B Muhammad, Naseer I Durumin Iya, Olushola S Ayanda
{"title":"Microbe-plant-nanoparticle interactions: role in bioremediation of petroleum hydrocarbons.","authors":"Augustine A Unimke, Onyemaechi Okezie, Sa'adatu E Mohammed, Augusta O Mmuoegbulam, Saidu Abdullahi, Utibe A Ofon, Denis M Olim, Hamza Badamasi, Abdulsalam I Galadima, Opeyemi K Fatunla, Aminu Abdullahi, Sharhabil M Yahaya, Muhammad M Ibrahim, Abba B Muhammad, Naseer I Durumin Iya, Olushola S Ayanda","doi":"10.2166/wst.2024.362","DOIUrl":"https://doi.org/10.2166/wst.2024.362","url":null,"abstract":"<p><p>Petroleum hydrocarbons (PHCs) are organic substances that occur naturally on earth. PHCs have emerged as one of the most prevalent and detrimental contaminants in regions comprising soil and water resources. The limitations of conventional physicochemical and biological remediation solutions could be solved by combining remediation techniques. An effective, affordable, and environmentally benign method of reducing petroleum toxins is provided by the advanced idea of bioremediation, which has evolved into nanobioremediation. Environments contaminated with PHCs have been restored through microbe-plant-nanoparticle (NP)-mediated remediation, this review emphasizes how various metallic NPs interact with microbes and plants changing both their activity and that of enzymes, therefore accelerating the remediation process. This work further examines the challenges and possible uses of nanobioremediation, as well as the application of novel technologies in the interactions between bacteria, plants, and NPs for the bioremediation of PHCs. Furthermore, it has been shown that the use of plant-based, microbe-based, microbe-plant-based, and microbe-plant-NP-based techniques to remediate contaminated soils or water bodies is economical and environmentally beneficial. Microbial consortia have been reported as the treasure houses for the cleaning and recovery of hydrocarbon-contaminated environments, and the development of technologies for bioremediation requires an understanding of hydrocarbon degradation mechanisms.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2870-2893"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phytomediated synthesis of WO3 nanoparticles using Solanum lycopersicum fruit extract for enhanced photocatalytic activity of 2,4-dichlorophenol. 利用番茄茄果实提取物植物介导合成WO3纳米颗粒增强2,4-二氯酚的光催化活性。
IF 2.5 4区 环境科学与生态学
Water Science and Technology Pub Date : 2024-11-01 Epub Date: 2024-11-06 DOI: 10.2166/wst.2024.365
S Natchathra, G Indramahalakshmi, Balasubramani Kavitha
{"title":"Phytomediated synthesis of WO<sub>3</sub> nanoparticles using <i>Solanum lycopersicum</i> fruit extract for enhanced photocatalytic activity of 2,4-dichlorophenol.","authors":"S Natchathra, G Indramahalakshmi, Balasubramani Kavitha","doi":"10.2166/wst.2024.365","DOIUrl":"https://doi.org/10.2166/wst.2024.365","url":null,"abstract":"<p><p>In the present study, bio-citric acid/tungsten oxide (WO<sub>3</sub>) (BCAWO) nanoparticles (NPs) were prepared by using <i>Solanum lycopersicum</i> fruit extract as a reducing as well as a capping agent. The photocatalysts were characterized by UV-vis diffuse reflectance spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), high-resolution transmission electron microscopy, and photoluminescence spectroscopy techniques. Diffraction peaks in the XRD spectrum were identified as the crystal planes of crystalline tungsten oxide. The BCAWO had an average size of 23.14 nm. For W-O bonds, the Fourier transform infrared spectrum displays the vibrational peak at 671.23 cm<sup>-1</sup>. A prominent absorption band was observed at 268 nm, indicating the 1.2 eV bandgap. Under xenon (Xe) lamp irradiation, the synthesized BCAWO nanoparticles showed notable photocatalytic degradation of 2,4-dichlorophenol (2,4-DCP), with a degradation rate of 96%. With BCAWO concentrations of 2.5 g/L, pH of 4, reaction period of 180 min, and 2,4 DCP concentration of 10 mg/L, the degradation of 2,4-DCP had the highest efficacy, 96%. The degradation of phenols in wastewater may be facilitated by using the green WO<sub>3</sub> nanoparticles as a photocatalyst, according to the results.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 10","pages":"2918-2933"},"PeriodicalIF":2.5,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142751780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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