ACS Omega最新文献

{"title":"Innovative Approach to Sustainable Fertilizer Production: Leveraging Electrically Assisted Conversion of Sewage Sludge for Nutrient Recovery.","authors":"Gerardine G Botte, Dayana Donneys-Victoria, Christian E Alvarez-Pugliese, Jedidian Adjei, Selin Sahin, Nathan W Wilson, Kayleigh Millerick, Amy Hardberger, Ariel L Furst, Nicole Hu, Andrew J Medford","doi":"10.1021/acsomega.4c07926","DOIUrl":"10.1021/acsomega.4c07926","url":null,"abstract":"<p><p>Efforts addressing sludge management, food security, and resource recovery have led to novel approaches in these areas. Electrically assisted conversion of sludge stands out as a promising technology for sewage sludge valorization, producing nitrogen and phosphorus-based fertilizers. The adoption of this technology, which could lead to a fertilizer circular economy, holds the potential to catalyze a transformative change in wastewater treatment facilities toward process intensification, innovation, and sustainability. This paper provides insights into the economic aspects of the technology, policy considerations, and challenges involved in realizing the potential of electrified processes for sludge valorization. To demonstrate the impact of the technology, a case study for its implementation in the United States assuming the municipal wastewater treatment plants market is discussed. It was found that electrically assisted sludge conversion could enable the recovery of nitrogen and phosphorus from waste, representing up to 9% of the nitrogen and 32% of the phosphorus consumption of the U.S. for fertilizer use. This technology also enables full electrification and modularization of the process, thereby presenting significant economic and environmental opportunities.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49692-49706"},"PeriodicalIF":3.7,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656355/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Innovative Approach to Sustainable Fertilizer Production: Leveraging Electrically Assisted Conversion of Sewage Sludge for Nutrient Recovery","authors":"Gerardine G. Botte*,&nbsp;Dayana Donneys-Victoria,&nbsp;Christian E. Alvarez-Pugliese,&nbsp;Jedidian Adjei,&nbsp;Selin Sahin,&nbsp;Nathan W. Wilson,&nbsp;Kayleigh Millerick,&nbsp;Amy Hardberger,&nbsp;Ariel L. Furst,&nbsp;Nicole Hu and Andrew J. Medford,&nbsp;","doi":"10.1021/acsomega.4c0792610.1021/acsomega.4c07926","DOIUrl":"https://doi.org/10.1021/acsomega.4c07926https://doi.org/10.1021/acsomega.4c07926","url":null,"abstract":"<p >Efforts addressing sludge management, food security, and resource recovery have led to novel approaches in these areas. Electrically assisted conversion of sludge stands out as a promising technology for sewage sludge valorization, producing nitrogen and phosphorus-based fertilizers. The adoption of this technology, which could lead to a fertilizer circular economy, holds the potential to catalyze a transformative change in wastewater treatment facilities toward process intensification, innovation, and sustainability. This paper provides insights into the economic aspects of the technology, policy considerations, and challenges involved in realizing the potential of electrified processes for sludge valorization. To demonstrate the impact of the technology, a case study for its implementation in the United States assuming the municipal wastewater treatment plants market is discussed. It was found that electrically assisted sludge conversion could enable the recovery of nitrogen and phosphorus from waste, representing up to 9% of the nitrogen and 32% of the phosphorus consumption of the U.S. for fertilizer use. This technology also enables full electrification and modularization of the process, thereby presenting significant economic and environmental opportunities.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49692–49706 49692–49706"},"PeriodicalIF":3.7,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c07926","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142842279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fast and Facile Synthesis of Cobalt-Doped ZIF-8 and Fe₃O₄/MCC/Cobalt-Doped ZIF-8 for the Photodegradation of Organic Dyes under Visible Light.","authors":"Amin Mehrehjedy, Piyush Kumar, Zachary Ahmad, Penelope Jankoski, Anuraj S Kshirsagar, Jason D Azoulay, Xuyang He, Mahesh K Gangishetty, Tristan D Clemons, Xiaodan Gu, Wujian Miao, Song Guo","doi":"10.1021/acsomega.4c06142","DOIUrl":"10.1021/acsomega.4c06142","url":null,"abstract":"<p><p>Co-doped ZIF-8 as a water-stable visible light photocatalyst was prepared by using a one-pot, fast, cost-effective, and environmentally friendly method. The band structure of ZIF-8 was tuned through the incorporation of different percentages of cobalt to attain an optimal band gap (<i>E</i> _g) that enables the activation of ZIF-8 under visible light and minimizes the recombination of photogenerated charge carriers. A magnetic composite of Co-doped ZIF-8 was also synthesized to facilitate catalyst recycling and reusability through the application of an external magnetic field. Surface modification of magnetic Fe₃O₄ nanoparticles with microcrystalline cellulose (MCC) was used to reduce the level of agglomeration. The photocatalytic activities of Co-doped ZIF-8 (Co-ZIF-8) and Fe₃O₄/MCC/Co-ZIF-8 were evaluated for the photodegradation of methylene blue (MB) under visible light irradiation from a 20 W LED source. Co-ZIF-8 showed considerably higher photocatalytic activity than pure ZIF-8, confirming the success of the doping strategy. Both Co20%-ZIF-8 and Fe₃O₄/MCC/Co20%-ZIF-8 exhibited similar and remarkable photocatalytic activity under visible light (achieving 97% MB removal). The mechanism of photodegradation of MB by Fe₃O₄/MCC/Co20%-ZIF-8 was studied, revealing a first-order degradation kinetics (<i>k</i> = 13.78 × 10^-3 min^-1), with peroxide and hole species as the predominant active reagents. The magnetic composite successfully displayed recyclability and reusability over multiple cycles with negligible reduction in MB photodegradation efficiency.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49239-49248"},"PeriodicalIF":3.7,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656232/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fast and Facile Synthesis of Cobalt-Doped ZIF-8 and Fe3O4/MCC/Cobalt-Doped ZIF-8 for the Photodegradation of Organic Dyes under Visible Light","authors":"Amin Mehrehjedy,&nbsp;Piyush Kumar,&nbsp;Zachary Ahmad,&nbsp;Penelope Jankoski,&nbsp;Anuraj S. Kshirsagar,&nbsp;Jason D. Azoulay,&nbsp;Xuyang He,&nbsp;Mahesh K. Gangishetty,&nbsp;Tristan D. Clemons,&nbsp;Xiaodan Gu,&nbsp;Wujian Miao and Song Guo*,&nbsp;","doi":"10.1021/acsomega.4c0614210.1021/acsomega.4c06142","DOIUrl":"https://doi.org/10.1021/acsomega.4c06142https://doi.org/10.1021/acsomega.4c06142","url":null,"abstract":"<p >Co-doped ZIF-8 as a water-stable visible light photocatalyst was prepared by using a one-pot, fast, cost-effective, and environmentally friendly method. The band structure of ZIF-8 was tuned through the incorporation of different percentages of cobalt to attain an optimal band gap (<i>E</i>_g) that enables the activation of ZIF-8 under visible light and minimizes the recombination of photogenerated charge carriers. A magnetic composite of Co-doped ZIF-8 was also synthesized to facilitate catalyst recycling and reusability through the application of an external magnetic field. Surface modification of magnetic Fe₃O₄ nanoparticles with microcrystalline cellulose (MCC) was used to reduce the level of agglomeration. The photocatalytic activities of Co-doped ZIF-8 (Co-ZIF-8) and Fe₃O₄/MCC/Co-ZIF-8 were evaluated for the photodegradation of methylene blue (MB) under visible light irradiation from a 20 W LED source. Co-ZIF-8 showed considerably higher photocatalytic activity than pure ZIF-8, confirming the success of the doping strategy. Both Co20%-ZIF-8 and Fe₃O₄/MCC/Co20%-ZIF-8 exhibited similar and remarkable photocatalytic activity under visible light (achieving 97% MB removal). The mechanism of photodegradation of MB by Fe₃O₄/MCC/Co20%-ZIF-8 was studied, revealing a first-order degradation kinetics (<i>k</i> = 13.78 × 10^–3 min^–1), with peroxide and hole species as the predominant active reagents. The magnetic composite successfully displayed recyclability and reusability over multiple cycles with negligible reduction in MB photodegradation efficiency.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49239–49248 49239–49248"},"PeriodicalIF":3.7,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c06142","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142842186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structure-Based QSAR Modeling of RET Kinase Inhibitors from 49 Different 5,6-Fused Bicyclic Heteroaromatic Cores to Patent-Driven Validation","authors":"Sumin Jin,&nbsp;Surendra Kumar and Mi-hyun Kim*,&nbsp;","doi":"10.1021/acsomega.4c0784310.1021/acsomega.4c07843","DOIUrl":"https://doi.org/10.1021/acsomega.4c07843https://doi.org/10.1021/acsomega.4c07843","url":null,"abstract":"<p >RET receptor tyrosine kinase is crucial for nerve and tissue development but can be an important oncogenic driver. This study focuses on exploring the design principles of potent RET inhibitors through molecular docking and 3D-QSAR modeling of 5,6-fused bicyclic heteroaromatic derivatives. First of all, RET inhibitors of 49 different bicyclic substructures were collected from five different data sources and selected through molecular docking simulations. QSAR models were built from the 3399 conformers of 952 RET inhibitors using the partial least-squares method and statistically evaluated. The optimal QSAR model exhibited high predictive performance, with <i>R</i>² (of training data) and <i>Q</i>² (of test data) values of 0.801 and 0.794, respectively, effectively predicting known inhibitors. The optimal model was doubly verified by patent-filed RET inhibitors as the out-of-set data to demonstrate acceptable residual analysis results. Moreover, feature importance analysis of the QSAR model outlined the impact of substituent characteristics on the inhibitory activity within the 5,6-fused bicyclic heteroaromatic core structures. Furthermore, the relationship between structure and inhibitory activity was successfully applied to the RET screening of known clinical and nonclinical kinase inhibitors to afford accurate off-target prediction.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49662–49673 49662–49673"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c07843","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142850099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Formulation of Polymer-Augmented Surfactant-Based Oil-Water Microemulsions for Application in Enhanced Oil Recovery.","authors":"Debanjan Ray, Lavisha Jangid, Dinesh Joshi, Shubham Prakash, Keka Ojha, Ofer Manor, Ajay Mandal","doi":"10.1021/acsomega.4c09829","DOIUrl":"10.1021/acsomega.4c09829","url":null,"abstract":"<p><p>This research explores the development of engineered oil-water microemulsions stabilized by a synergistic combination of polymer and surfactant to enhance stability and interfacial properties for improved enhanced oil recovery (EOR). Conventional surfactant-stabilized emulsions often suffer from phase instability and limited wettability alteration during water flooding and chemical injection, hindering the EOR efficiency. In contrast, our formulations incorporating polymers significantly increase the emulsion viscosity and resilience to temperature fluctuations, resulting in enhanced phase stability. Experimental investigations reveal that while the water-microemulsion interfacial tension (IFT) increases with salinity, the oil-microemulsion IFT decreases substantially, achieving an optimal IFT of 4.43 × 10^-4 mN/m at balanced salinity levels. The microemulsions exhibit remarkable stability across varying temperatures, successfully transitioning between Winsor type II and III phases, which is critical for effective EOR applications. Notably, the addition of polymers enhances the viscosity of the surfactant-stabilized emulsion from 50 mPa·s at a shear rate of 10 s^-1 to 300 mPa·s, significantly improving emulsion stability, as confirmed by measured zeta potential values of -31.1 mV for the surfactant system and -33.2 mV for the polymer-augmented surfactant system. These enhancements contribute to improved sweep efficiency during the oil recovery processes. Furthermore, the microemulsions effectively alter the sandstone wettability from oil-wet to water-wet, promoting better oil displacement. Core flooding experiments demonstrate that injecting one pore volume of the polymer-augmented surfactant-stabilized microemulsion results in an additional 20.58% oil recovery compared with conventional water flooding.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"50024-50040"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656390/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phase Change Materials for Energy Storage Applications from PEG and PBAT with AlN and CNT as Fillers.","authors":"Eyob Wondu, Wondu Lee, Minsu Kim, Dabin Park, Jooheon Kim","doi":"10.1021/acsomega.4c07480","DOIUrl":"10.1021/acsomega.4c07480","url":null,"abstract":"<p><p>This study investigates the fabrication of phase change material-poly(butylene adipate-<i>co</i>-terephthalate) (PCM-PBAT) composites through melt blending techniques, focusing on the impact of isophorone diisocyanate (IPDI) treatment on carbon nanotubes (CNTs) and (3-aminopropyl)triethoxysilane (APTES) treatment on aluminum nitride (AlN) particles. Analysis of mechanical properties highlights an enhancement in tensile strength with APTES-treated AlN particles, while dynamic mechanical analysis (DMA) reveals an increase in stiffness. Laser flash analysis (LFA) investigation demonstrates a significant increase, up to 325%, in thermal conductivity compared to PCM-PBAT composites without filler. Moreover, the fabricated composites exhibit enhanced latent heat storage capabilities, with the PCM-PBAT composite containing 30% filler (20PCM-PBAT-30F) showing promising latent heat values. These findings underscore the efficacy of selecting an appropriate PCM-PBAT ratio and surface functionalization of the filler particles in enhancing the latent heat storage and thermal and mechanical properties of the polymer composites, suggesting their potential application across diverse fields.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49557-49565"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656395/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Internal State of Vesicles Affects Higher Order State of Vesicle Assembly and Interaction.","authors":"Silvia Holler, Federica Casiraghi, Martin Michael Hanczyc","doi":"10.1021/acsomega.4c06037","DOIUrl":"10.1021/acsomega.4c06037","url":null,"abstract":"<p><p>Dynamic soft matter systems composed of functionalized vesicles and liposomes are typically produced and then manipulated through external means, including the addition of exogenous molecules. In biology, natural cells possess greater autonomy, as their internal states are continuously updated, enabling them to effect higher order properties of the system. Therefore, a conceptual and technical gap exists between the natural and artificial systems. We engineered functionalized vesicles to form multicore aggregates capable of self-assembly due to the presence of complementary ssDNA strands. A dynamic process was then triggered through an exogenously triggered on-demand release of an endogenously produced displacer molecule, resulting in multicore aggregate disassembly. This approach explores how internal states of vesicles can affect the external organization, demonstrating a very simple programmable strategy for assembly and then endogenous disassembly. This framework supports the exploration of larger and more complex multicore entities, opening a path toward community behavior and a higher degree of autonomy.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49316-49322"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656350/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photocatalytic Estrogen Degradation by the Composite of Tin Oxide Fine Particles and Graphene-like Carbon Nitride.","authors":"Yuzuki Amino, Ayar Al-Zubaidi, Yosuke Ishii, Shinji Kawasaki","doi":"10.1021/acsomega.4c03390","DOIUrl":"10.1021/acsomega.4c03390","url":null,"abstract":"<p><p>This study investigates whether 17β-estradiol (E2), a natural estrogen and one of the endocrine-disrupting chemicals responsible for water pollution, can be oxidatively decomposed under simulated solar light using a composite of tin oxide nanoparticles and graphene-like carbon nitride (g-CN) as a photocatalyst. The composite photocatalyst was prepared by heating a mixture of urea and tin acetate. FT-IR measurements revealed that g-CN possesses structural units similar to g-C₃N₄, a well-studied graphite-like carbon nitride. However, unlike g-C₃N₄, sharp diffraction lines were not observed in the XRD diffraction pattern of g-CN, indicating lower crystallinity. Elemental analysis showed that g-CN is slightly nitrogen-rich compared to g-C₃N₄, and UV-vis measurements indicated that the band gap of g-CN is slightly smaller than that of g-C₃N₄. The presence of tin in the composite of tin oxide and g-CN was clearly confirmed by XPS, although no sharp diffraction peaks were observed in the XRD patterns, suggesting the presence of microcrystals. Furthermore, FE-SEM observations did not reveal large tin oxide crystals, although EDS mapping indicated the presence of tin oxide. It was found that the prepared tin oxide and g-CN composites function effectively as photocatalysts for degrading E2 under simulated solar light. The degradation rate constant was evaluated to be <i>k</i> = 3.34 (0.14) × 10^-2 min^-1. Peroxide ion radicals were detected in ESR measurements from the irradiated solution, suggesting that peroxide ion radicals are generated through oxygen photoreduction as the counter-reaction of the oxidative decomposition of E2.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49064-49070"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11656215/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Internal State of Vesicles Affects Higher Order State of Vesicle Assembly and Interaction","authors":"Silvia Holler,&nbsp;Federica Casiraghi and Martin Michael Hanczyc*,&nbsp;","doi":"10.1021/acsomega.4c0603710.1021/acsomega.4c06037","DOIUrl":"https://doi.org/10.1021/acsomega.4c06037https://doi.org/10.1021/acsomega.4c06037","url":null,"abstract":"<p >Dynamic soft matter systems composed of functionalized vesicles and liposomes are typically produced and then manipulated through external means, including the addition of exogenous molecules. In biology, natural cells possess greater autonomy, as their internal states are continuously updated, enabling them to effect higher order properties of the system. Therefore, a conceptual and technical gap exists between the natural and artificial systems. We engineered functionalized vesicles to form multicore aggregates capable of self-assembly due to the presence of complementary ssDNA strands. A dynamic process was then triggered through an exogenously triggered on-demand release of an endogenously produced displacer molecule, resulting in multicore aggregate disassembly. This approach explores how internal states of vesicles can affect the external organization, demonstrating a very simple programmable strategy for assembly and then endogenous disassembly. This framework supports the exploration of larger and more complex multicore entities, opening a path toward community behavior and a higher degree of autonomy.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 50","pages":"49316–49322 49316–49322"},"PeriodicalIF":3.7,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c06037","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142849856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}