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Mo2C-Mo3N2 Heterojunction Encapsulated Within N-Doped Carbon Cage for Enhanced Selective Hydrogenation of CO2 to CO. 氮掺杂碳笼内包裹Mo2C-Mo3N2异质结增强CO2选择性加氢制CO
IF 12.1 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202508722
Pengze Zhang, Chong Yao, Peng Zhang, Qingtao Wang, Xiaonian Li, Mingyuan Zhu
{"title":"Mo<sub>2</sub>C-Mo<sub>3</sub>N<sub>2</sub> Heterojunction Encapsulated Within N-Doped Carbon Cage for Enhanced Selective Hydrogenation of CO<sub>2</sub> to CO.","authors":"Pengze Zhang, Chong Yao, Peng Zhang, Qingtao Wang, Xiaonian Li, Mingyuan Zhu","doi":"10.1002/smll.202508722","DOIUrl":"https://doi.org/10.1002/smll.202508722","url":null,"abstract":"<p><p>The reverse water gas shift reaction (RWGS) can convert CO<sub>2</sub> into CO, but the low activity and the inexpensive catalysts inhibit the industrialization process. As a potential material for the RWGS reaction, Mo<sub>2</sub>C faces the challenges of high dispersibility and synthesis efficiency. Here, the Mo<sub>3</sub>N<sub>2</sub>-Mo<sub>2</sub>C heterojunction encaged in N-doped carbon matrix is synthesized using in situ carbonization method, which exhibits high activity under mild temperature. The CO<sub>2</sub> conversion is 38.3%, the selectivity of CO is 99.1% upon 410 °C. The Space Time Yield is 17333.6 mgCO g<sub>cat</sub> <sup>-1</sup>h<sup>-1</sup> (619.06 mmol g<sub>cat</sub> <sup>-1</sup> h<sup>-1</sup>) under 450 °C, and WHSV = 240 000 mL g<sub>cat</sub> <sup>-1</sup> h<sup>-1</sup>, which is superior than traditional catalysts such as Cu-Zn-Al and noble metal catalysts. The catalyst shows 99.9% selectivity of CO, and maintaining equilibrium conversion for 200 h under 500 °C. The structure-performance relationship studies indicate the synergistic effect of Mo<sub>2</sub>C-Mo<sub>3</sub>N<sub>2</sub> heterojunction active sites enhances H<sub>2</sub> adsorption and dissociation significantly, which boosting the H assisted CO<sub>2</sub> reduction reaction. Moreover, the N-doped carbon cage confined environment greatly boosts the catalyst stability. This work provides a simple and feasible strategy for the synthesis of highly dispersed Mo<sub>2</sub>C-Mo<sub>3</sub>N<sub>2</sub> heterojunction active site for CO<sub>2</sub> hydrogenation reaction, and a way to boost the H<sub>2</sub> activation capacity of Mo<sub>2</sub>C catalyst.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e08722"},"PeriodicalIF":12.1,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145224636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low‐Spin‐Induced Optimization of Intermediate Adsorption in Selenium‐Incorporated Layered Double Hydroxides for Enhanced Electrochemical Water Splitting 低自旋诱导优化含硒层状双氢氧化物的中间吸附,以增强电化学水分解
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202508466
Yutong Wang, Yilin Liang, Dawei Chu, Jiacen An, Dong‐Feng Chai, Wenzhi Zhang, Yue Li, Guohua Dong, Dongxuan Guo
{"title":"Low‐Spin‐Induced Optimization of Intermediate Adsorption in Selenium‐Incorporated Layered Double Hydroxides for Enhanced Electrochemical Water Splitting","authors":"Yutong Wang, Yilin Liang, Dawei Chu, Jiacen An, Dong‐Feng Chai, Wenzhi Zhang, Yue Li, Guohua Dong, Dongxuan Guo","doi":"10.1002/smll.202508466","DOIUrl":"https://doi.org/10.1002/smll.202508466","url":null,"abstract":"The rational manipulation of spin configurations in cobalt‐based electrocatalysts offers a viable strategy for optimizing oxygen and hydrogen evolution activities. Nevertheless, the intermediate spin (IS) configuration of Co<jats:sup>2+</jats:sup> sites, featuring partially occupied d orbitals, triggers suboptimal adsorption with oxygenated species. In this work, selenium incorporation into CoCr layered double hydroxides (LDH) is demonstrated to induce spin‐state transition, activating inert sites and stabilizing the low‐spin (LS) Co<jats:sup>2+</jats:sup> configuration. The low spin‐state materials exhibit superior electrocatalytic activity, requiring overpotentials of merely 284.0 and 130.0 mV for oxygen and hydrogen evolution reactions, respectively, at 10 mA cm<jats:sup>−2</jats:sup>, while maintaining excellent durability over 168 h. The lowered e<jats:sub>g</jats:sub> occupancy in low‐spin Co<jats:sup>2+</jats:sup> results in electronic asymmetry and enhances electron density at the metal center. This electronic configuration facilitates robust Co 3d‐O 2p orbital hybridization, which enhances the adsorption of oxygenated intermediates by elevating the d‐band center toward the Fermi level, optimizing adsorption energetics. Moreover, low‐spin Co<jats:sup>2+</jats:sup>’s paired d‐orbital electron configuration minimizes high‐energy antibonding e<jats:sub>g</jats:sub> orbital occupancy, enhancing crystal lattice stability. Overall, this work establishes that spin state modulation in transition metals significantly lowers reaction energy barriers, offering a promising strategy for developing high‐performance electrocatalysts.","PeriodicalId":228,"journal":{"name":"Small","volume":"74 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145215765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tantalum-Doped Tin Oxide Films with Post-Annealing in H2 Strategy Enabling Improved Performance of Indium-Free Perovskite Solar Cells H2后退火掺杂钽氧化锡膜提高无铟钙钛矿太阳能电池性能
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202508172
Buchao Chen, Lingen Yao, Chuan Li, Weiyan Wang, Jing Zhuang, Jing Zhang, Huahang Lai, Zhizhong Yuan
{"title":"Tantalum-Doped Tin Oxide Films with Post-Annealing in H2 Strategy Enabling Improved Performance of Indium-Free Perovskite Solar Cells","authors":"Buchao Chen, Lingen Yao, Chuan Li, Weiyan Wang, Jing Zhuang, Jing Zhang, Huahang Lai, Zhizhong Yuan","doi":"10.1002/smll.202508172","DOIUrl":"https://doi.org/10.1002/smll.202508172","url":null,"abstract":"Indium tin oxide (ITO) films are widely used as transparent electrodes in perovskite solar cells (PSCs). However, the limited supply and high cost of rare indium pose challenges to the sustainable development of PSCs. In this study, sputtered tantalum-doped tin oxide (TTO) films with post-annealing in H<sub>2</sub> (TTO-H<sub>2</sub>), are proposed as an attractive alternative to ITO electrodes in PSCs. It is demonstrated that TTO films post-annealed in H<sub>2</sub> atmosphere exhibited lower sheet resistance of 91.8 Ω sq<sup>−1</sup>, with a higher carrier concentration of 6.51 × 10<sup>20</sup> cm<sup>−3</sup>, and a higher mobility of 6.96 cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup>, compared to TTO films post-annealed in O<sub>2</sub> and N<sub>2</sub> atmospheres. The mechanism behind the improvement in electrical characteristics is revealed. Indium-free inverted PSCs using TTO-H<sub>2</sub> bottom electrodes are constructed. High-quality TTO-H<sub>2</sub>/MeO-2PACZ/perovskite interface is demonstrated with advantages of higher built-in electric field, lower defect state density, and improved carrier transport ability, compared to the reference ITO/MeO-2PACZ/perovskite interface. Thus, the prepared PSCs using TTO-H<sub>2</sub> electrodes exhibit improved photovoltaic performance compared to reference ITO-based PSCs: the open-circuit voltage (<i>V</i><sub>oc</sub>) is enhanced from 1.100 to 1.134 V; and the power conversion efficiency (PCE) is enhanced from 20.58% to 20.77% with 1% increase. This study demonstrates the indium-free PSCs with enhanced <i>V</i><sub>oc</sub> and PCE for the first time, and elucidates the underlying mechanisms, providing new insights for high-performance and low-cost PSCs.","PeriodicalId":228,"journal":{"name":"Small","volume":"8 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Precise Decoupling of Biomass Components to Engineer Hard Carbon Microcrystalline Architecture for Enhanced Sodium-Ion Storage Performance 生物质组分的精确解耦设计硬碳微晶结构以增强钠离子存储性能
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202507313
Yixiang Zhang, Zeren Zhou, Qiaoyan Lin, Qixian Zhang, Lishuang Fan
{"title":"Precise Decoupling of Biomass Components to Engineer Hard Carbon Microcrystalline Architecture for Enhanced Sodium-Ion Storage Performance","authors":"Yixiang Zhang, Zeren Zhou, Qiaoyan Lin, Qixian Zhang, Lishuang Fan","doi":"10.1002/smll.202507313","DOIUrl":"https://doi.org/10.1002/smll.202507313","url":null,"abstract":"Extensive research on biomass-derived hard carbon (HC) anodes for sodium-ion batteries has aimed to optimize sodium storage through precise manipulation of precursor structures. Existent methods, involving harsh acids or corrosive reagents, typically raise production costs, pose safety hazards, and cause unwanted carbon loss, reducing precursor utilization efficiency. To overcome these issues, this study introduces a mild, environmentally friendly, and scalable approach utilizing selective sulfonation of raw bamboo. This method enhances lignin hydrophilicity, facilitating partial delignification via solid-liquid separation. Subsequent carbonization of the cellulose-enriched precursor yields HC with thin-layered pseudo-graphitic domains, enlarged interlayer spacing, and dense closed-pore structures. The resulting anodes achieve a reversible capacity of 348 mAh g<sup>−1</sup> at 30 mA g<sup>−1</sup> with an initial Coulombic efficiency of 84.2%, excellent rate capability (241 mAh g<sup>−1</sup> at 900 mA g<sup>−1</sup>), and superior cycling stability (97.8% capacity retention after 500 cycles at 500 mA g<sup>−1</sup>). Ex situ XRD and XPS analyses further indicate an adsorption-intercalation/filling mechanism. This sustainable pretreatment not only enhances electrochemical performance but also supports efficient lignosulfonate recovery, promoting comprehensive and high-value utilization of lignocellulosic biomass in energy storage applications.","PeriodicalId":228,"journal":{"name":"Small","volume":"33 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Irradiation Accelerated Hydrolysis of Soluble Keplerate Titanium–Bismuth Oxo Clusters with Complete Surface Ligands Exchange Behavior for Direct Oxides Nanopatterning 辐照加速可溶Keplerate钛铋氧簇的水解,具有完全的表面配体交换行为,用于直接氧化物纳米图
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202507562
Hui-Fang Zhao, Zuo-Hu Zhou, Ni Zhen, Fang-Fang Liu, Si-Ming Qi, Jian Wei, Ze-Qi Yu, Ai-Bing Yang, Lei Zhang
{"title":"Irradiation Accelerated Hydrolysis of Soluble Keplerate Titanium–Bismuth Oxo Clusters with Complete Surface Ligands Exchange Behavior for Direct Oxides Nanopatterning","authors":"Hui-Fang Zhao, Zuo-Hu Zhou, Ni Zhen, Fang-Fang Liu, Si-Ming Qi, Jian Wei, Ze-Qi Yu, Ai-Bing Yang, Lei Zhang","doi":"10.1002/smll.202507562","DOIUrl":"https://doi.org/10.1002/smll.202507562","url":null,"abstract":"Controlled hydrolysis of metal oxo clusters has been first applied as a direct nanopatterning strategy for oxide materials. A heterometallic Bi<sub>4</sub>Ti<sub>12</sub> oxo cluster is constructed with Keplerian-type architecture as a molecular platform for post-synthetic reactivity studies. Detailed mass spectrometry analysis confirms its exceptional dissolution stability and complete surface alkoxy ligands exchangeability. Interestingly, spin-coated thin films of Bi<sub>4</sub>Ti<sub>12</sub> oxo clusters exhibit significant solubility contrast after ambient condition hydrolysis. Accordingly, electron-beam irradiation is applied to accelerate the cluster hydrolysis in exposed areas to enable fine lines patterning, with the hydrolysis-condensation pathways of irradiated Bi<sub>4</sub>Ti<sub>12</sub> oxo clusters being demonstrated by comparative spectroscopic analyses. Finally, 20 nm critical dimension (CD) lines can be fabricated using this method under an expose energy of 130 µCcm<sup>−</sup><sup>2</sup>. Therefore, this work not only constructs a Keplerate cluster family with interesting complete surface ligand exchange behavior, but also provides a new metal hydrolysis-driven lithography strategy for the direct patterning of metal oxide nanostructures.","PeriodicalId":228,"journal":{"name":"Small","volume":"78 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Capture and Separation of Xenon/Krypton from Off-Gas by a Radiation-Resistant Metal–Organic Framework 抗辐射金属有机骨架在废气中氙/氪的高效捕获和分离
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202508918
Thien D Duong, Jiangnan Li, Ruohan Li, Xin Lian, Yinlin Chen, Jiarui Fan, Joseph Hurd, Lixia Guo, Daniel Lee, Mark Warren, Sihai Yang
{"title":"Efficient Capture and Separation of Xenon/Krypton from Off-Gas by a Radiation-Resistant Metal–Organic Framework","authors":"Thien D Duong, Jiangnan Li, Ruohan Li, Xin Lian, Yinlin Chen, Jiarui Fan, Joseph Hurd, Lixia Guo, Daniel Lee, Mark Warren, Sihai Yang","doi":"10.1002/smll.202508918","DOIUrl":"https://doi.org/10.1002/smll.202508918","url":null,"abstract":"The capture of xenon (Xe) and krypton (Kr) from the off-gas of used nuclear fuel is of great importance to the treatment of radioactive wastes and production of high purity Xe. Solid sorbents, in particular metal–organic frameworks (MOFs), show promise in gas capture. However, the unknown radiation resistance of MOFs has limited their development. Herein, the efficient capture and separation of Xe/Kr by MFM-520, which strikes a remarkable stability toward 1750 kilogray (kGy) γ-irradiation, is reported. Under ambient conditions, dynamic breakthrough experiments confirm the efficient separation performance, yielding a Xe capacity of 66 and 0.2 mg g<sup>−1</sup> from a by-product of air separation (Xe/Kr: 20/80; v/v) and off-gas (Xe/Kr: 400/40 ppm balance in air), respectively. In situ synchrotron X-ray single crystal diffraction and solid-state nuclear magnetic resonance (ssNMR) studies reveal that the optimal micropore of MFM-520 underpins specific host-guest interactions to Xe, resulting in selective Xe capture.","PeriodicalId":228,"journal":{"name":"Small","volume":"78 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CO2-Driven Polarity Compensation Mechanism for Stabilizing High-Index Facets in KTaO3 二氧化碳驱动极性补偿机制稳定KTaO3高指数面
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202510040
Yuning Liang, Bo Gao, Yonglong Zhu, Qun Xu
{"title":"CO2-Driven Polarity Compensation Mechanism for Stabilizing High-Index Facets in KTaO3","authors":"Yuning Liang, Bo Gao, Yonglong Zhu, Qun Xu","doi":"10.1002/smll.202510040","DOIUrl":"https://doi.org/10.1002/smll.202510040","url":null,"abstract":"In ionic crystals, the simultaneous control of polarity compensation and exposure of high-crystallinity surfaces has long been a critical bottleneck for modulating their interfacial electronic and spin properties. Using the typical ionic crystal KTaO&lt;sub&gt;3&lt;/sub&gt; (KTO) as a model system, it is demonstrated that supercritical carbon dioxide (SC CO&lt;sub&gt;2&lt;/sub&gt;) treatment is an effective solution to this challenge. As the SC CO&lt;sub&gt;2&lt;/sub&gt; pressure increases from 12 to 20 MPa, the surface of KTO gradually transforms from a rough, low-index (001) facet into high-crystallinity, high-index polar facets, specifically (&lt;span data-altimg=\"/cms/asset/1a106bc5-3d0b-4587-8ae7-5418b7f898ef/smll71048-math-0001.png\"&gt;&lt;/span&gt;&lt;mjx-container ctxtmenu_counter=\"2\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"&gt;&lt;mjx-math aria-hidden=\"true\" location=\"graphic/smll71048-math-0001.png\"&gt;&lt;mjx-semantics&gt;&lt;mjx-mrow data-semantic-annotation=\"clearspeak:unit\" data-semantic-children=\"0,3,4\" data-semantic-content=\"7,5\" data-semantic- data-semantic-role=\"implicit\" data-semantic-speech=\"0 ModifyingAbove 1 With bar 1\" data-semantic-type=\"infixop\"&gt;&lt;mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"8\" data-semantic-role=\"integer\" data-semantic-type=\"number\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mn&gt;&lt;mjx-mo data-semantic-added=\"true\" data-semantic- data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"8\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" style=\"margin-left: 0.056em; margin-right: 0.056em;\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mo&gt;&lt;mjx-mrow&gt;&lt;mjx-mover data-semantic-children=\"1,2\" data-semantic- data-semantic-parent=\"8\" data-semantic-role=\"integer\" data-semantic-type=\"overscore\"&gt;&lt;mjx-over style=\"padding-bottom: 0.105em; margin-bottom: -0.544em;\"&gt;&lt;mjx-mo data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"overaccent\" data-semantic-type=\"operator\"&gt;&lt;mjx-stretchy-h style=\"width: 0.5em;\"&gt;&lt;mjx-ext&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-ext&gt;&lt;/mjx-stretchy-h&gt;&lt;/mjx-mo&gt;&lt;/mjx-over&gt;&lt;mjx-base&gt;&lt;mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"3\" data-semantic-role=\"integer\" data-semantic-type=\"number\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mn&gt;&lt;/mjx-base&gt;&lt;/mjx-mover&gt;&lt;mjx-mo data-semantic-added=\"true\" data-semantic- data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"8\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" style=\"margin-left: 0.056em; margin-right: 0.056em;\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mo&gt;&lt;mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"8\" data-semantic-role=\"integer\" data-semantic-type=\"number\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mn&gt;&lt;/mjx-mrow&gt;&lt;/mjx-mrow&gt;&lt;/mjx-semantics&gt;&lt;/mjx-math&gt;&lt;mjx-assistive-mml display=\"inline\" unselectable=\"on\"&gt;&lt;math altimg=\"urn:x-wiley:16136810:media:smll71048:smll71048-math-0001\" display=\"inline\" location=\"graphic/s","PeriodicalId":228,"journal":{"name":"Small","volume":"39 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrated Electrochromic‐Electromagnetic Shielding‐Energy Storage Smart Window Based on PEDOT@Fe3O4 Core–Shell Functional Layer 基于PEDOT@Fe3O4核壳功能层的集成电致变色-电磁屏蔽-储能智能窗口
IF 13.3 2区 材料科学
Small Pub Date : 2025-10-03 DOI: 10.1002/smll.202507963
Taolin Zhang, Siying Guan, Zhicheng Sun, Shouzheng Jiao, Zhengyu Chen, Siqiao Zhang, Yuwei Hao, Rui ma, Lu Han, Ruping Liu
{"title":"Integrated Electrochromic‐Electromagnetic Shielding‐Energy Storage Smart Window Based on PEDOT@Fe3O4 Core–Shell Functional Layer","authors":"Taolin Zhang, Siying Guan, Zhicheng Sun, Shouzheng Jiao, Zhengyu Chen, Siqiao Zhang, Yuwei Hao, Rui ma, Lu Han, Ruping Liu","doi":"10.1002/smll.202507963","DOIUrl":"https://doi.org/10.1002/smll.202507963","url":null,"abstract":"Amid intensifying energy and electromagnetic (EM)‐pollution pressures, smart windows that couple light modulation with EM protection are urgently needed. Electrochromic (EC) windows offer low power and high contrast; however, multifunctional EC devices often suffer from structural complexity and unstable interfaces, impeding integration. Here, therefore a WO<jats:sub>3</jats:sub>–PEDOT@Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> composite cathode paired with a Prussian blue (PB) anode is engineered to assemble an electromagnetic‐shielding smart window (ESSW). Specifically, the ESSW delivers 53% UV–vis modulation at 611 nm, fast switching (3.1 s coloration; 4.7 s bleaching), high coloration efficiency (104.7 cm<jats:sup>2</jats:sup> C<jats:sup>−1</jats:sup>), and durable cycling (93.4% of the initial current density after 600 cycles). Moreover, the ESSW cathode exhibits a capacitive contribution of 86.4% and an areal capacitance of 25.12 mF cm<jats:sup>−2</jats:sup> at a discharge current density of 0.2 mA cm<jats:sup>−2</jats:sup>. Owing to multiple loss pathways introduced by PEDOT@Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>, the EMI shielding effectiveness consequently rises from 15.3 dB (WO<jats:sub>3</jats:sub>‐ECD) to 31.8 dB (ESSW). Furthermore, a 10 cm × 10 cm spray‐coated prototype demonstrates scalability and, in a sunroom scenario, reduces indoor EM‐radiation intensity from 108.2 to 19.2 µW cm<jats:sup>−2</jats:sup>. Such smart windows, integrating electrochromism, energy storage, and EMI shielding, show strong application potential in aerospace, energy‐efficient buildings, and defense equipment.","PeriodicalId":228,"journal":{"name":"Small","volume":"40 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145215812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Atomic Ce-Induced Adaptive Synergism for Self-Optimized Multi-Enzymatic Nanozyme Design for Soil Amendment (Small 39/2025) 原子ce诱导的自优化多酶纳米酶土壤改进剂自适应协同设计(Small 39/2025)
IF 12.1 2区 材料科学
Small Pub Date : 2025-10-02 DOI: 10.1002/smll.70302
Qiong Li, Yongyu Cha, Yu Zhan, Xinyue Miao, Guixiang He, Pengyuan Lv, Lixiang Wang, Wei Li, Changbao Chen
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引用次数: 0
Synergistic Effect of Prolonged Oxygenation and Reactive Oxygen Species Scavenging on Diabetic Wound Healing Using an Injectable Thermoresponsive Hydrogel (Small 39/2025) 注射热反应性水凝胶对糖尿病伤口愈合的协同作用(Small 39/2025)
IF 12.1 2区 材料科学
Small Pub Date : 2025-10-02 DOI: 10.1002/smll.70298
Jiyeon Lee, Jun Kim, Jisun kim, Soo-Chang Song
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引用次数: 0
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