Elumalai Vengadesan , Benjamin Eanest Jebasingh , T Arunkumar , B Prabhu
{"title":"Development and corrosive sensitivity of sustainable aluminium hybrid reinforced composites for latent heat energy storage systems","authors":"Elumalai Vengadesan , Benjamin Eanest Jebasingh , T Arunkumar , B Prabhu","doi":"10.1016/j.susmat.2025.e01533","DOIUrl":"10.1016/j.susmat.2025.e01533","url":null,"abstract":"<div><div>The development of corrosion-resistant materials under alkaline environments is envisioned for better sustainable environment. While latent heat energy storage systems (LHES) using alkaline inorganic phase change materials are crucial, corrosion significantly impacts component lifespan, posing challenges to commercialization and reliability. This study develops sustainable aluminium hybrid reinforced composites (AHRC) via 3R principles of waste management strategy and examines their corrosive sensitivity considering the effects of (i) varying concentrations of Tungsten carbide (WC) and Red mud (RMD) reinforcements (ii) exposure to a 0.2 M concentrated aqueous sodium hydroxide, and (iii) process temperatures of RT, 40 and 60 °C. The AHRCs are stir-casted, and designated as AHRC<sub>WR1</sub>, AHRC<sub>WR2</sub>, and AHRC<sub>WR3</sub>. The microstructural and hardness characteristics of the specimens are examined. Tafel, and EIS studies are performed to assess corrosion characteristics of the AHRCs. Dynamic corrosion studies are conducted for 30 days to assess weight loss and layer formed. Moreover, life cycle assessment (LCA) is conducted via “Cradle to Grave” approach. The static and dynamic corrosion study results are merely comparable. The AHRC<sub>WR2</sub> composite exhibiting hardness (61.85 BHN), demonstrates better corrosion resistance, outperforming the base alloy by 81.15 %, 37.75 %, and 42.60 % at room temperature, 40 °C and 60 °C, respectively. The corroded composite specimens form a compact corrosion product layer, enhancing durability. The LCA results emphasize that the produced composite reveals better energy consumption (334.32 MJ/kg) and CO₂ emissions (39.37 kg CO₂/kg). The findings support the development of a sustainable corrosion-resistant composite material for LHES applications in alkaline environments, aligning with SDGs 7, 9, and 12.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01533"},"PeriodicalIF":8.6,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144685964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dawei Gao , Haixiang Wang , Jiajun Tang, Chao Ye, Lili Wang
{"title":"Charge-excited enhanced piezoelectric-triboelectric hybrid nanogenerator for high-efficiency energy harvesting and applications","authors":"Dawei Gao , Haixiang Wang , Jiajun Tang, Chao Ye, Lili Wang","doi":"10.1016/j.susmat.2025.e01539","DOIUrl":"10.1016/j.susmat.2025.e01539","url":null,"abstract":"<div><div>Triboelectric Nanogenerator (TENG) is an energy-harvesting device based on the triboelectric effect and electrostatic induction, capable of extracting energy from the environment. It offers advantages such as a simple device structure, sustainability, and high efficiency in harvesting low-frequency mechanical energy. To address the low output charge density of traditional piezoelectric-triboelectric hybrid nanogenerator (PT-NG), this study proposes a charge excitation-enhanced PT-NG for improved performance. This innovative design enhances output performance by optimizing charge accumulation and transfer processes, enabling efficient energy capture even in weak vibration environments. In this study, silk fibroin film was prepared via electrospinning as the positive triboelectric layer, while a bead-like P-PVDF/MoS<sub>2</sub> composite film served as the negative triboelectric layer. Leveraging the triboelectric series difference and interfacial effects, these two functional films were assembled to successfully construct a PT-NG. However, low output charge density limits its practical application. To enhance the triboelectric output, a charge excitation-enhanced PT-NG was proposed. Experimental results demonstrated that, under working conditions of 2 Hz frequency and 3 N mechanical force, the voltage output reached 35 V under excitation, the excited current output was 3 μA, and the peak instantaneous power density reached 1 W/m<sup>2</sup>. Even under weak vibrations, the device achieved high power output, with the current increasing by 50 % compared to the non-excited PT-NG. Additionally, the potential applications of this device were systematically explored, including powering electronic devices, environmental energy harvesting, and wireless alarm systems, providing a novel technological pathway for the development of self-powered systems. This integrated strategy significantly enhances energy conversion efficiency for self-powered systems.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01539"},"PeriodicalIF":8.6,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144685853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Farideh Pahlavan , Zhiyang Liu , Mohmmadjavad Kazemi , Elham H. Fini
{"title":"Enhancing sustainability via chemistry-informed design of bituminous composites: Unveiling the underlying molecular level mechanisms of moisture-induced damages","authors":"Farideh Pahlavan , Zhiyang Liu , Mohmmadjavad Kazemi , Elham H. Fini","doi":"10.1016/j.susmat.2025.e01520","DOIUrl":"10.1016/j.susmat.2025.e01520","url":null,"abstract":"<div><div>Moisture-induced damage at the asphalt binder–aggregate interface is a major factor in the premature failure of asphalt mixtures when exposed to moisture. While studies often relate moisture damage to aggregate types and compositions, this paper highlights the role of asphalt binder's acid value as a major contributing factor to moisture damage. While polar alkane acids in asphalt can improve adhesion in dry conditions, their high acid content exacerbates water-induced degradation at asphalt binder–aggregate interface. This study investigates the molecular-level mechanisms underlying moisture susceptibility, focusing on the role of asphalt's acid value in influencing desorption and water retention at the asphalt–aggregate interface. A combination of laboratory experiments, including contact angle measurements and moisture-induced shear-thinning index (MISTI) tests, and computational methods such as molecular dynamics (MD) simulations and density functional theory (DFT) calculations was employed. Experimental results revealed that binders with higher acid content exhibit increased moisture susceptibility, with contact angles as high as 155° for high-acid binders, a 2.65 % increase compared to neat asphalt binder. MISTI values also showed greater deviation from unity for high-acid binders, indicating weakened interfacial adhesion. MD simulations identified a critical acid content threshold of 8 %, beyond which hexadecenoic acid accumulates at the silica-water interface, forming micelles and disrupting adhesion. DFT calculations quantified the adsorption energy of hexadecenoic acid on silica as −36.7 kcal/mol, significantly higher than most asphalt components (−20.8 kcal/mol), further driving acid migration to interface, hence weakening the interface resistance to moisture damage. These findings emphasize the importance of chemistry-informed design of asphalt mixtures to optimize interfacial binding when exposed to moisture. By minimizing acid value in asphalt, particularly when using modifiers and rejuvenators, the durability of asphalt pavements can be significantly enhanced, reducing moisture-induced damage and promoting sustainable construction practices.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01520"},"PeriodicalIF":8.6,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144595643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Green synthesized gum Arabic nano-biopolymer encapsulating Saraca asoca leaf essential oil accelerates wound healing","authors":"Soumya Ranjan Jena , Ganeswar Dalei , Subhraseema Das , Anwesha Pradhan , Sajan Sahoo , Darshni Mohanty , Swagatika Biswal , Debasis Jena , Luna Samanta","doi":"10.1016/j.susmat.2025.e01532","DOIUrl":"10.1016/j.susmat.2025.e01532","url":null,"abstract":"<div><div>Plant essential oils (EO) has demonstrated remarkable bio-efficacies throughout. Yet, they are highly prone to environmental stimuli leading to their degradation. Nanoencapsulation has blossomed as a promising technology to preserve the inherent bioactivities of the EOs. Thus, in this study, EO of <em>Saraca asoca</em> leaves have been encapsulated in gum Arabic (GA) biopolymer. The leaf EO was accomplished by the ultrasound-assisted hydrodistillation method. The synthesis of nano-GA and EO-encapsulated GA nanoparticles was followed <em>via</em> the green route using <em>A. marmelos</em> leaf extract. The pristine GA nanoparticles demonstrated a mean diameter of 175.2 nm which further increased with increase in EO content. The encapsulation of EO onto the GA nanoparticles slightly enhanced their thermal stability. The <em>in vitro</em> EO release profiles in SGF and SIF accorded to colonic delivery. The GA nanoparticles effectually preserved the TPC and TFC of the encapsulated <em>S. asoca</em> leaf EO. The antioxidant activity of encapsulated EO in terms of DPPH and superoxide radical scavenging was found to be higher than the pure EO. The samples exhibited good antibacterial and antiobiofilm activities against <em>E. coli</em> and <em>E. faecalis</em>. The scratch assay on 3 T3 cells revealed the wound closure was prominent in GA/ EO<sub>1:1</sub> with cellular migration of 90 % in 48 h. The <em>in vivo</em> CAM assay also pointed to the fast angiogenesis and neovascularization occurring in GA/ EO<sub>1:1</sub> in 48 h, thus highly recommending its applicability in wound healing. Furthermore, the effective skin irritation index zero confirms GA/ EO<sub>1:1</sub> as a safe candidate for transdermal application.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01532"},"PeriodicalIF":8.6,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Chemically engineered multifunctional hydrogel for potential use in biomedical applications: A report on synthesis, physicochemical characterizations, and in vitro evaluation","authors":"Prasanna Kumari Barani, Indu Yadav, Aniruddha Dan, Ankur Singh, Dhiraj Bhatia, Mukesh Dhanka","doi":"10.1016/j.susmat.2025.e01534","DOIUrl":"10.1016/j.susmat.2025.e01534","url":null,"abstract":"<div><div>Addressing the limitations of conventional polymeric hydrogels in eradicating bacterial infection and stimulating cell activity within a biological environment presents a significant challenge. However, chemically engineered biopolymers have gained significant attention in designing advanced hydrogel-based platforms due to their flexibility, tunable properties, multiple functionalities, and ability to deliver bioactive agents. In this study, a novel biopolymer conjugate has been synthesized through simple EDC/NHS chemical functionalization methods, where bioactive spermine, a bioamine, was conjugated to the polymeric backbone of gellan gum (GG). Analytical characterization confirmed the successful synthesis of the GG-S conjugate. This conjugate was further engineered into a multifunctional, injectable hydrogel by incorporating oxidized tannic acid (oTA), forming a crosslinked 3D matrix via imine bond formation or Schiff base reaction with superior physicochemical properties. Physicochemical characterization of novel hydrogel shows the desirable injectability profile, microporous morphology, swelling rate, degradation, and drug release profile. In vitro evaluations of hydrogel (GG-S-oTA) exhibit remarkable antibacterial, antioxidant, hemocompatibility, and excellent cytocompatibility, resulting in a twofold increase in cell viability compared to controls. These attributes highlight the potential of the GG–S–oTA hydrogel platform as a multifunctional biomaterial for diverse biomedical applications, effectively addressing challenges related to infection control while also promoting environmental sustainability.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01534"},"PeriodicalIF":8.6,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144655604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hong-Sheng Chu , Dong-Mei Ma , Xingming Zhao , Jun Xiang , Rongda Zhao , Fufa Wu , Tianlin Wang
{"title":"NiO@CoxSy nanostructures electrocatalysts designed for efficient alkaline water electrolysis","authors":"Hong-Sheng Chu , Dong-Mei Ma , Xingming Zhao , Jun Xiang , Rongda Zhao , Fufa Wu , Tianlin Wang","doi":"10.1016/j.susmat.2025.e01527","DOIUrl":"10.1016/j.susmat.2025.e01527","url":null,"abstract":"<div><div>Rational design of composite-structured electrocatalysts presents a promising strategy for enhancing water electrolysis efficiency. In this work, two NiO-based heterostructured electrocatalysts were rationally constructed by coupling NiO with cobalt sulfides possessing different crystalline phases, synthesized via two distinct methods. Despite sharing the same NiO substrate, the two resulting heterostructures exhibit significantly different electrocatalytic performances: NiO@Co<sub>9</sub>S<sub>8</sub> material demonstrates superior hydrogen evolution reaction (HER) activity, while the other(NiO@CoS<sub>2</sub>) exhibits enhanced oxygen evolution reaction (OER) activity. This finding reveals that the electrocatalytic behavior can be finely tuned by modulating the crystalline structure of the cobalt sulfide component, while keeping the NiO support constant. Notably, the NiO@Co<sub>9</sub>S<sub>8</sub> catalyst exhibits excellent HER performance, requiring an overpotential of only 158.8 mV at a current density of 50 mA/cm<sup>2</sup>, the corresponding Tafel slope is 142.72 mV/dec. Conversely, the NiO@CoS<sub>2</sub> electrocatalyst exhibits even stronger OER activity, achieving an overpotential of 340.2 mV at 50 mA/cm<sup>2</sup> with a Tafel slope of 178.81 mV/dec. Extended stability tests under high current density conditions over 50 h confirmed the exceptional durability of both electrocatalysts in overall water splitting applications. These results underscore NiO@CoS<sub>2</sub> and NiO@Co<sub>9</sub>S<sub>8</sub> potential as novel high-efficiency bifunctional catalysts for advanced water electrolysis systems.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01527"},"PeriodicalIF":8.6,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rui Wan , Wenting Zhao , Xia Sun , Zhenqiang Wang , Zhili Gong , Lei Guo , Riadh Marzouki , Mingwen Luo , Ao Li , Yilong Ma , Bochuan Tan
{"title":"N, S‑carbon quantum dots as a green corrosion inhibitor for brine heaters in multistage flash desalination systems","authors":"Rui Wan , Wenting Zhao , Xia Sun , Zhenqiang Wang , Zhili Gong , Lei Guo , Riadh Marzouki , Mingwen Luo , Ao Li , Yilong Ma , Bochuan Tan","doi":"10.1016/j.susmat.2025.e01531","DOIUrl":"10.1016/j.susmat.2025.e01531","url":null,"abstract":"<div><div>This study presents an eco-friendly and sustainable approach for the first time to synthesize N, S-CDs by electrochemical methods using peanut cake residue. Demonstrating their potential as a green corrosion inhibitor for brine heaters in multistage flash desalination systems. Comprehensive characterization using TEM, FTIR, XPS, AFM and SEM revealed the nanostructure and surface functionality of the materials. Electrochemical evaluation under simulated pickling conditions revealed inhibition efficiencies of 98.77 % (298 K), 98.26 % (308 K) and 97.22 % (318 K) at 100 mg/L N, S-CDs, respectively. Surface analysis confirmed the formation of a protective adsorption layer and XPS data verified the chemical bonding between N, S-CDs and the Cu-Ni alloys surface, which contributes to the stability and corrosion resistance of the material. Thermodynamic studies showed that the adsorption followed a Langmuir monolayer behavior, combining physisorption and chemisorption mechanisms.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01531"},"PeriodicalIF":8.6,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Laura Bergamonti , Marianna Potenza , Elena Michelini , Daniele Ferretti , Silvia Borsacchi , Lucia Calucci , Laura Lazzarini , Pier Paolo Lottici , Francesco Talento , Claudia Graiff
{"title":"One-part geopolymer-like binders with calcium-based solid alkaline activators and metakaolin","authors":"Laura Bergamonti , Marianna Potenza , Elena Michelini , Daniele Ferretti , Silvia Borsacchi , Lucia Calucci , Laura Lazzarini , Pier Paolo Lottici , Francesco Talento , Claudia Graiff","doi":"10.1016/j.susmat.2025.e01528","DOIUrl":"10.1016/j.susmat.2025.e01528","url":null,"abstract":"<div><div>The need to reduce greenhouse gas emissions has promoted the development of sustainable materials for the building industry to replace ordinary Portland cement (OPC).</div><div>This work focuses on the development of one-part geopolymer-like binders using calcium-based solid alkaline activators and metakaolin. The alkaline activator was prepared by mixing Ca(OH)<sub>2</sub> or CaO and Na-silicate or K-silicate, all in powders form.</div><div>XRD, FTIR, TGA/DTG and solid-state NMR analyses show the coexistence of both geopolymer gel and hydrated aluminosilicates. Microscopical investigations show that the morphology of the binders is heterogeneous with micrometric agglomerates. TEM reveals that the binders are characterized by agglomerates of nanoparticles, with abundant amorphous material and rare crystalline phases. The mechanical properties demonstrate the potential of this product as an eco-friendly alternative to OPC.</div><div>The use of powdered alkaline activators and the production process followed make the product suitable for the building industry to be used on construction sites.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01528"},"PeriodicalIF":8.6,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai Li , Haitao Cheng , Chenxuan Zhao , Lichao Jia
{"title":"Attenuating the metal‑oxygen bonds in BaCo0.4Fe0.4Zr0.1Y0.1O3-δ to achieve a high efficiency bifunctional oxygen electrode for reversible solid oxide cells","authors":"Kai Li , Haitao Cheng , Chenxuan Zhao , Lichao Jia","doi":"10.1016/j.susmat.2025.e01523","DOIUrl":"10.1016/j.susmat.2025.e01523","url":null,"abstract":"<div><div>Proton-conducting reversible solid oxide cells (P-RSOCs) have the potential to enable interconversion between power and green hydrogen at low to intermediate temperatures. However, the large-scale application of P-RSOCs is significantly hindered by inefficient oxygen reduction (ORR) and evolution reaction (OER) kinetics in air electrode at reduced temperatures. Herein, this investigation introduces a straightforward approach of doping 5 % Zn into the BaCo<sub>0.4</sub>Fe<sub>0.4</sub>Zr<sub>0.1</sub>Y<sub>0.1</sub>O<sub>3-δ</sub> (BCFZY) lattice to form Ba(Co<sub>0.4</sub>Fe<sub>0.4</sub>Zr<sub>0.1</sub>Y<sub>0.1</sub>)<sub>0.95</sub>Zn<sub>0.05</sub>O<sub>3-δ</sub> (BCFZYZ) as an exceptional efficiency and durable air electrode for P-RSOC. The introduction of Zn doping is anticipated to weaken the coulombic forces between B-site metallic ions and oxygen ions, thereby increasing the oxygen vacancies and proton defect concentration. Experimental results identify that the incorporation of Zn significantly enhances oxygen vacancies generation and hydration, and facilitates oxygen/proton surface exchange and bulk diffusion rates, thereby accelerating the ORR and OER kinetics. The BCFZYZ electrode exhibits relatively smaller polarization resistance and corresponding reaction activation energy (E<sub>a</sub> = 1.198 ev). The P-RSOCs using BCFZYZ air electrode deliver impressive bifunctional performance at 650 °C, the cell achieves a peak power density of 946 mW cm<sup>−2</sup> in fuel cell operation, and 1175 mA cm<sup>−2</sup> electrolysis current density at 1.3 V in water splitting process. Moreover, the BCFZYZ full cell maintains stable voltage for 120 h and exhibits robust stable reversibility over a 100 h cycling period. This work provides an effective design strategy to facilitate the ORR and OER kinetics of BCFZY for high performance and durable air electrode of P-RSOC.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01523"},"PeriodicalIF":8.6,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144605052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Desmond Kwayela Sama, Agnieszka Tomczyk-Nazarczuk, Katarzyna Szewczuk-Karpisz
{"title":"Modification directions of agricultural waste biochars to improve their effectiveness as amendments for degraded soils","authors":"Desmond Kwayela Sama, Agnieszka Tomczyk-Nazarczuk, Katarzyna Szewczuk-Karpisz","doi":"10.1016/j.susmat.2025.e01529","DOIUrl":"10.1016/j.susmat.2025.e01529","url":null,"abstract":"<div><div>With over 140 billion tons of agricultural waste generated yearly, its management has become a critical issue posing economic and environmental concerns. The waste conversion into biochar (BC) provides a sustainable solution, that is, a promising material for various applications such as carbon sequestration, pollution remediation, and soil regeneration. The latest research has contributed significantly to the development of innovative techniques of biochar (BC) modification that go beyond conventional pyrolytic processing of biomass. These treatments usually increase textural parameters and surface chemistry of BC, thereby enhancing its ability to bind various species. High adsorption capacity makes it an effective carrier for nutrients essential for crops or an efficient immobilizer limiting availability of toxic compounds. So far, it was noted that modified BC has a satisfied impact on soil aeration, water retention, and growth of soil microorganisms, stimulating overall agroecosystem functionality. However, its effectiveness depending on soil type is not fully understood and difficult to predict, which is why modified BC use by farmers is limited and troublesome. Taking this into account, the review indicates the effects of BC modification on particular soil types, highlighting the most beneficial ones. The authors identified poor features of pristine BC and showed the most effective treatment increasing its performance as a soil conditioner. A roadmap was also presented to optimize the use of modified BC in addressing the issues of soil degradation, climate change, and agricultural waste management, along with suggestions for new research directions and ways to integrate modified BC with sustainable practices.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01529"},"PeriodicalIF":8.6,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144605537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}