Surface & Coatings Technology最新文献

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Microstructure and wear resistance of plasma nitrocarburized high deformed and controlled hot rolled low carbon bainitic steel
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-10 DOI: 10.1016/j.surfcoat.2025.132028
João Vitor Piovesan Dalla Nora , Vinicius Waechter Dias , Victor Velho de Castro , Célia de Fraga Malfatti , Morvan Silva Franco , Alexandre da Silva Rocha
{"title":"Microstructure and wear resistance of plasma nitrocarburized high deformed and controlled hot rolled low carbon bainitic steel","authors":"João Vitor Piovesan Dalla Nora ,&nbsp;Vinicius Waechter Dias ,&nbsp;Victor Velho de Castro ,&nbsp;Célia de Fraga Malfatti ,&nbsp;Morvan Silva Franco ,&nbsp;Alexandre da Silva Rocha","doi":"10.1016/j.surfcoat.2025.132028","DOIUrl":"10.1016/j.surfcoat.2025.132028","url":null,"abstract":"<div><div>Despite the growing industrial relevance of continuously cooled bainitic steels, the combination of plasma nitrocarburizing and HSX 130HD remains unexplored. Furthermore, no prior studies have investigated plasma treatments applied to HSX 130HD XTP® steel, which undergoes microstructural refinement through thermomechanical post-processing. This study evaluates the effects of plasma nitriding and nitrocarburizing on two bainitic steels, HSX 130HD and HSX 130HD XTP® (Xtreme Performance Technology®), with a focus on microstructural evolution, microhardness, phase formation, and wear resistance. Although both steels share the same chemical composition, the HSX 130HD XTP® variant exhibits a finer microstructure due to its thermomechanical processing. Plasma treatments were conducted using different gas mixtures, specifically N₂ (fixed at 75 vol%), H₂ (balance), and CH₄ (3 vol% and 5 vol%), at 500 °C for 6 h. The resulting microstructure, roughness, surface and profile microhardness, phase composition (determined via X-ray diffraction), friction coefficient under dry sliding, and wear resistance (evaluated through reciprocating sliding wear tests) were analyzed. The results indicate that increasing CH₄ concentration led to a reduction in white layer thickness, an increase in surface microhardness and roughness, and enhanced Fe₂-₃N phase formation for both substrates. Fe₃C formation was also observed in HSX 130HD XTP® samples treated with 5 vol% CH₄, while a lower friction coefficient was recorded for the same steel treated with 3 vol% CH₄. Although plasma nitrocarburizing proved to be effective for both steels, plasma-nitrided HSX 130HD XTP® exhibited the lowest worn volume, highlighting its superior wear resistance.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"504 ","pages":"Article 132028"},"PeriodicalIF":5.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Mo content on microstructural evolution, corrosion behavior, and friction performance of laser cladded (Fe50Mn30Co10Cr10)1−xMox coatings
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-10 DOI: 10.1016/j.surfcoat.2025.132022
Jiaye Geng , Xiaohui Yang , Guicheng Wang , Cuirong Liu , Ming Yin , Yan Li
{"title":"Effect of Mo content on microstructural evolution, corrosion behavior, and friction performance of laser cladded (Fe50Mn30Co10Cr10)1−xMox coatings","authors":"Jiaye Geng ,&nbsp;Xiaohui Yang ,&nbsp;Guicheng Wang ,&nbsp;Cuirong Liu ,&nbsp;Ming Yin ,&nbsp;Yan Li","doi":"10.1016/j.surfcoat.2025.132022","DOIUrl":"10.1016/j.surfcoat.2025.132022","url":null,"abstract":"<div><div>In this study, (Fe<sub>50</sub>Mn<sub>30</sub>Co<sub>10</sub>Cr<sub>10</sub>)<sub>1−x</sub>Mo<sub>x</sub> (x = 0, 0.1, 0.2, 0.3 at.%) high-entropy alloy (HEA) coatings were fabricated using laser cladding technology and characterized through OM, XRD, SEM, TEM, 3D optical profilometry, microhardness tests, and electrochemical measurements. The results indicate that the addition of Mo causes an initial increase, followed by a decrease, in the martensite content of the (Fe<sub>50</sub>Mn<sub>30</sub>Co<sub>10</sub>Cr<sub>10</sub>)<sub>1−x</sub>Mo<sub>x</sub> coating microstructure. The Mo content of x = 0.1 promotes HCP martensite phase formation. However, an excessive Mo content will lead to the enrichment of Mo in the IR, causing a large amount of Fe<sub>2</sub>Mo phase to start precipitating continuously with the IR as nucleation points. The addition of these Fe<sub>2</sub>Mo phases significantly enhances the average microhardness of the coating through second-phase strengthening and solid-solution strengthening. This enables the Mo<sub>0.3</sub> coating to possess the highest microhardness of 711 HV and the lowest coefficient of friction of 0.57. Moreover, the Mo<sub>0.1</sub> coating demonstrates superior corrosion resistance, as evidenced by the lowest self-corrosion current density and the broadest passivation region. This is attributed to the protective MoO<sub>3</sub>/MoO<sub>2</sub> oxide film and the low Fe<sub>2</sub>Mo precipitate content, which together lower the Cl<sup>−</sup> erosion rate. When the Mo content is x = 0.2 at.%, the (Fe<sub>50</sub>Mn<sub>30</sub>Co<sub>10</sub>Cr<sub>10</sub>)<sub>1−x</sub>Mo<sub>x</sub> HEA coating achieves the optimal balance among hardness, wear resistance and corrosion resistance.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"504 ","pages":"Article 132022"},"PeriodicalIF":5.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An investigation on corrosion resistance of laser-cladded FeCoNiCrCu high-entropy alloy coatings based on different initial powder particle sizes
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-10 DOI: 10.1016/j.surfcoat.2025.132030
Ying Wang , Yuhua Peng , Changzhe He , Shuobin Chen , Jian Yu , Cheng Nie , Mao Zhang , Pan Gong , Zhigang Hu , Bin Li , Junsheng Yang
{"title":"An investigation on corrosion resistance of laser-cladded FeCoNiCrCu high-entropy alloy coatings based on different initial powder particle sizes","authors":"Ying Wang ,&nbsp;Yuhua Peng ,&nbsp;Changzhe He ,&nbsp;Shuobin Chen ,&nbsp;Jian Yu ,&nbsp;Cheng Nie ,&nbsp;Mao Zhang ,&nbsp;Pan Gong ,&nbsp;Zhigang Hu ,&nbsp;Bin Li ,&nbsp;Junsheng Yang","doi":"10.1016/j.surfcoat.2025.132030","DOIUrl":"10.1016/j.surfcoat.2025.132030","url":null,"abstract":"<div><div>This study comprehensively investigates the corrosion mechanism of laser-cladded FeCoNiCrCu high-entropy alloy (HEA) coatings fabricated with varying initial powder particle sizes in a 3.5 % NaCl solution. Subsequent to orthogonal experimental optimization, optimal laser cladding parameters were obtained to generate fine coatings with exceptional quality. It's noteworthy that finer initial powder particles possess higher specific surface energy, promoting the formation of coatings with fewer defects. Aside from that, steady increases in corrosion current density and decreases in corrosion potential were observed with coarser initial powder particles, accompanied by lower charge transfer resistance. Corrosion preferentially initiates at surface defects, with more severe defects directly degrading corrosion resistance. The Cu accumulation at these defects generates a less extensively protective passivation film, which hinders the formation of Cr oxides. As evidently demonstrated by XPS analysis, smaller powder particles form protective films with more Cr oxides and fewer Cu oxides in comparison with those formed by larger particles. To sum up, coatings prepared from finer initial powder particle sizes display superior corrosion resistance.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132030"},"PeriodicalIF":5.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143579942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of interface roughness on the CMAS + molten salt (Na2SO4 + NaCl + NaVO3) corrosion resistance of EB-PVD thermal barrier coatings
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-08 DOI: 10.1016/j.surfcoat.2025.132026
Xiaopeng Hu , Sai Liu , Qing Liu, Yang Su, Junyao Wu, Zhihang Xie, Jinwei Guo, Wang Zhu
{"title":"Effect of interface roughness on the CMAS + molten salt (Na2SO4 + NaCl + NaVO3) corrosion resistance of EB-PVD thermal barrier coatings","authors":"Xiaopeng Hu ,&nbsp;Sai Liu ,&nbsp;Qing Liu,&nbsp;Yang Su,&nbsp;Junyao Wu,&nbsp;Zhihang Xie,&nbsp;Jinwei Guo,&nbsp;Wang Zhu","doi":"10.1016/j.surfcoat.2025.132026","DOIUrl":"10.1016/j.surfcoat.2025.132026","url":null,"abstract":"<div><div>The service life of thermal barrier coatings (TBCs) in calcium magnesium aluminosilicate (CMAS) and molten salt environments has become a key factor in determining engine reliability and safety. The effect of interface roughness (bond coating surface roughness) on the CM (CMAS + molten salt (Na<sub>2</sub>SO<sub>4</sub> + NaCl + NaVO<sub>3</sub>)) corrosion resistance of electron beam physical vapor deposition (EB-PVD) TBCs is investigated. The addition of molten salts lowers the melting point of CM, leading to more severe destructive effects compared to single CMAS corrosion. Moreover, the 1200# specimen (Ra = 2.0 μm) exhibits the best resistance to CM corrosion. The adjustment of interface roughness significantly alters the microstructure of the top-ceramic coating and induces changes in crack patterns after CM corrosion. Therefore, appropriately reducing interface roughness is key to improving the isothermal CM corrosion resistance and high-temperature CM corrosion-induced thermal shock performance of TBCs.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132026"},"PeriodicalIF":5.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence mechanisms of Y2O3 addition on the microstructure and wear resistance of laser-cladded T-800 + Si coatings on DD5 substrates
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-08 DOI: 10.1016/j.surfcoat.2025.132025
Guangtai Zhang , Weijun Liu , Hongyou Bian , Wenchao Xi , Yijie Zao , Kai Zhang , Huiru Wang
{"title":"Influence mechanisms of Y2O3 addition on the microstructure and wear resistance of laser-cladded T-800 + Si coatings on DD5 substrates","authors":"Guangtai Zhang ,&nbsp;Weijun Liu ,&nbsp;Hongyou Bian ,&nbsp;Wenchao Xi ,&nbsp;Yijie Zao ,&nbsp;Kai Zhang ,&nbsp;Huiru Wang","doi":"10.1016/j.surfcoat.2025.132025","DOIUrl":"10.1016/j.surfcoat.2025.132025","url":null,"abstract":"<div><div>This study investigates the effects of adding varying contents (0, 1, and 2 wt%) of micron-sized Y₂O₃ particles on the microstructure and wear resistance of laser-cladded T-800 + Si coatings. Through BSE, EDS, EBSD, microhardness tests, and wear resistance evaluations, the influence mechanisms of Y₂O₃ addition on the precipitation behavior of Laves phases and secondary phases, grain growth, dislocation distribution, microhardness, and wear resistance were systematically elucidated. The optimal Y₂O₃ addition content was determined. The results show that with 1 wt% Y₂O₃ addition, grain refinement is most pronounced, reducing the average grain size by 12.17 % to 4.34 μm compared to the coating without Y₂O₃ (4.93 μm). The moderate Laves phase content (55.1 %) and the formation of Y₅Si₃ secondary phase particles were observed. The average KAM value increased to 0.40° with a more uniform distribution. These features, combined with grain refinement, Laves phase, Y₅Si₃ precipitation, and dislocation strengthening, resulted in the highest average microhardness (803.4 HV<sub>0.5</sub>), a 10.19 % increase compared to the coating without Y₂O₃ (729.1 HV<sub>0.5</sub>). Additionally, the dense oxide film contributed to superior wear resistance, with the wear volume loss and wear rate reduced by 34.98 %. At 2 wt% Y₂O₃, despite higher Laves phase content (67.5 %) and KAM value (0.75°), grain coarsening (4.84 μm) due to Ostwald ripening and rare-earth polarization effects weakened the strengthening mechanisms, reducing microhardness to 764.9 HV<sub>0.5</sub>. The discontinuous oxide film further compromised wear resistance, though it remained better than the coating without Y₂O₃.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132025"},"PeriodicalIF":5.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deriving of process signature correlation on measurable material loading for process optimization: A case study of thermal spray of cemented carbide coatings
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-08 DOI: 10.1016/j.surfcoat.2025.132020
J.R. Yuan, X.P. Zhu, M.K. Lei
{"title":"Deriving of process signature correlation on measurable material loading for process optimization: A case study of thermal spray of cemented carbide coatings","authors":"J.R. Yuan,&nbsp;X.P. Zhu,&nbsp;M.K. Lei","doi":"10.1016/j.surfcoat.2025.132020","DOIUrl":"10.1016/j.surfcoat.2025.132020","url":null,"abstract":"<div><div>The multiple process parameters of a product coupled with materials of design have a profound influence on its performance. To enable a practical knowledge-based method of process optimization, process signature is explored with respect to surface integrity as a pivot in the material-product-process linking, as represented by thermal spraying of WC-Ni coatings for coated products utilizing the online measurable material loading, i.e. the in-flight particle temperature and velocity. The process signature correlations, from multiple process parameters of oxygen/fuel flow rates and spray distance to multiple surface integrity parameters of coating microstructures and mechanical properties, are explored in two steps via the measurable material loading. A process-dependent correlation from process parameters to the particle temperature and velocity of in-flight particles in spray flame is firstly established by identifying a characteristic process quantity of fuel/oxygen ratio that mainly controls the flame temperature, and a characteristic processing load of combustion pressure that controls the flame flow velocity. Subsequently, a partially process-independent correlation coupled with spray distance effect is derived from the particle deposition temperature/velocity to the coating microstructures and mechanical properties. Finally, a process-independent correlation is derived as the thermal and kinetic energies of coating formation correlating to the surface integrity parameters by thermodynamic analysis with incorporated spray distance effect. The study provides a feasible methodology of process signature derivation for practical implementation in process optimization and control for advanced manufacturing development.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132020"},"PeriodicalIF":5.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Constructing correlations between ion concentration, temperature and pH: A novel strategy to improve the corrosion resistance of electroless NiP plating on AZ91D magnesium alloy
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-07 DOI: 10.1016/j.surfcoat.2025.132023
Qi Xu, Peng Zhou, Tao Zhang, Fuhui Wang
{"title":"Constructing correlations between ion concentration, temperature and pH: A novel strategy to improve the corrosion resistance of electroless NiP plating on AZ91D magnesium alloy","authors":"Qi Xu,&nbsp;Peng Zhou,&nbsp;Tao Zhang,&nbsp;Fuhui Wang","doi":"10.1016/j.surfcoat.2025.132023","DOIUrl":"10.1016/j.surfcoat.2025.132023","url":null,"abstract":"<div><div>Most of the optimization methods for electroless nickel plating solutions are based on practical experience in production. This work reports a novel indicator for guiding the optimization of electroless plating baths, NiPT/pH (<span><math><mo>lg</mo><mfenced><mfrac><mrow><mfenced><mrow><msub><mi>C</mi><msup><mi>Ni</mi><mrow><mn>2</mn><mo>+</mo></mrow></msup></msub><mo>+</mo><mn>0.3</mn><mo>∗</mo><msub><mi>C</mi><mrow><msub><mi>H</mi><mn>2</mn></msub><msubsup><mi>PO</mi><mn>2</mn><mo>−</mo></msubsup></mrow></msub></mrow></mfenced><mo>∗</mo><mi>T</mi></mrow><mi>pH</mi></mfrac></mfenced></math></span>). Compared to conventional models that solely regulate the deposition rate, the NiPT/pH system demonstrates significant advancements by elucidating the influences of various factors on the deposition process from both thermodynamic and kinetic perspectives, while simultaneously offering a more streamlined and efficient modeling approach. The SEM analysis indicated that the compactness of the Ni-P coatings increased with the increase of NiPT/pH. The electrochemical measurements confirm the enhanced corrosion resistance of the optimized coatings. The main contribution of this work is the proposition of a model that takes into account various parameters for the design and estimation of the performance of electroless nickel plating bath, which also facilitate the application of such a process to the industry.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"504 ","pages":"Article 132023"},"PeriodicalIF":5.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser cladding-spraying fabrication of Al/Ni/WC@SMP-MoS2 composite coating with enhanced anti-corrosion and self-lubricating property
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-07 DOI: 10.1016/j.surfcoat.2025.132017
Guangliang Zhang, Zhichao Ren, Jinlei Hu, Yuanyuan Hou, Hongyu Zheng
{"title":"Laser cladding-spraying fabrication of Al/Ni/WC@SMP-MoS2 composite coating with enhanced anti-corrosion and self-lubricating property","authors":"Guangliang Zhang,&nbsp;Zhichao Ren,&nbsp;Jinlei Hu,&nbsp;Yuanyuan Hou,&nbsp;Hongyu Zheng","doi":"10.1016/j.surfcoat.2025.132017","DOIUrl":"10.1016/j.surfcoat.2025.132017","url":null,"abstract":"<div><div>Aluminum alloy has many advantages and is widely used in aviation, automobile industry, machinery and other fields. However, it has the problems of low hardness, poor wear resistance and low melting point, which makes it have certain limitations in application. In this study, the morphology and properties of Al/Ni/WC cladding layer prepared by laser cladding and Al/Ni/WC @ SMP-MoS<sub>2</sub> self-lubricating and anti-wear composite coating prepared by laser cladding / spraying organic silane sol adhesive (SMP) and MoS<sub>2</sub> were tested and analyzed. The WC content increased from 4 % to 16 %, and the surface hardness of the cladding layer increased from 1031.7 HV<sub>2</sub> to 1099.7 HV<sub>2</sub>, which is about 7 times that of the matrix. The average friction coefficient of Al/Ni/WC cladding and Al/Ni/WC@SMP-MoS<sub>2</sub> composite coating is 46 % and 55 % lower than that of the matrix, respectively. The corrosion potential of Al/Ni/WC@SMP-MoS<sub>2</sub> composite coating increases to −0.8196 V, and the corrosion current density decreases by 3 orders of magnitude. These studies have important significance for promoting the application of aluminum alloy in engineering metal protection, automobile industry and other fields.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132017"},"PeriodicalIF":5.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High temperature performance of MnCo oxide coatings deposited by HiPIMS for interconnect application in Solid Oxide Cell
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-07 DOI: 10.1016/j.surfcoat.2025.132024
Théo Dejob , Mathilde Bouvier , Antoine Casadebaigt , Jaafar Ghanbaja , Fabien Rouillard , Frédéric Sanchette
{"title":"High temperature performance of MnCo oxide coatings deposited by HiPIMS for interconnect application in Solid Oxide Cell","authors":"Théo Dejob ,&nbsp;Mathilde Bouvier ,&nbsp;Antoine Casadebaigt ,&nbsp;Jaafar Ghanbaja ,&nbsp;Fabien Rouillard ,&nbsp;Frédéric Sanchette","doi":"10.1016/j.surfcoat.2025.132024","DOIUrl":"10.1016/j.surfcoat.2025.132024","url":null,"abstract":"<div><div>To decrease the volatilization rate of Cr on AISI 441 interconnect for Solid Oxide Cells (SOC) application, Mn<sub>0.5</sub>Co<sub>0.5</sub>O coatings were deposited using Reactive High Power Impulse Magnetron Sputtering (R-HiPIMS). Three different coating morphologies and preferential growth orientations were obtained by varying bias and temperature settings. All synthetized Mn<sub>0.5</sub>Co<sub>0.5</sub>O coatings reduced the volatilization rate of Cr during exposure in dry air at 800 °C for 2000 h. Moreover, the Cr retention power was influenced by the preferential growth orientation of the coating. This study suggests that the deposition parameters of R-HiPIMS can be adjusted to optimize the crystalline orientation and enhance the effectiveness of Mn<img>Co oxide coatings as barriers against chromium volatilization.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 132024"},"PeriodicalIF":5.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Friction surfacing of aluminum alloys on Ti6Al4V - Investigation of process parameters, material deposition behavior and bonding mechanisms
IF 5.3 2区 材料科学
Surface & Coatings Technology Pub Date : 2025-03-07 DOI: 10.1016/j.surfcoat.2025.131985
Marius Hoffmann , Arne Roos , Benjamin Klusemann
{"title":"Friction surfacing of aluminum alloys on Ti6Al4V - Investigation of process parameters, material deposition behavior and bonding mechanisms","authors":"Marius Hoffmann ,&nbsp;Arne Roos ,&nbsp;Benjamin Klusemann","doi":"10.1016/j.surfcoat.2025.131985","DOIUrl":"10.1016/j.surfcoat.2025.131985","url":null,"abstract":"<div><div>This study addresses a detailed investigation of friction surfacing (FS) process parameters for two materials with low metallurgical compatibility, i.e. Al and Ti, to achieve successful depositions, representing a very challenging task. The difference in suitable process parameters between two Al alloys onto Ti is highlighted. For instance, AA6082 requires higher rotational speeds than AA7050, resulting in higher process temperatures that lead to the formation of intermetallics with a thickness of about 0.3 <span><math><mi>μ</mi></math></span>m at the interface. This indicates that diffusion is the main bonding mechanism for AA6082, while mainly mechanical interlocking contributes to bonding for AA7050. Additionally, AA6082 presents slightly thicker (<span><math><mo>∼</mo></math></span>240 <span><math><mi>μ</mi></math></span>m) and wider (<span><math><mo>∼</mo></math></span>28 mm) layers than AA7050 (<span><math><mo>∼</mo></math></span>185 <span><math><mi>μ</mi></math></span>m and <span><math><mo>∼</mo></math></span>24 mm, respectively). Based on the experimental results, a new theory of material deposition is proposed for the dissimilar Al/Ti material combination, as a unique deposition behavior could be identified. The experiments show that material is deposited only in the peripheral areas of the stud, but not in the center, as typically seen in FS. Higher local process temperatures in the peripheral areas result in lower local flow stresses, which increase stud shearing and thus deposition of the plasticized stud material.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"503 ","pages":"Article 131985"},"PeriodicalIF":5.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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