ACS NanoPub Date : 2025-07-29Epub Date: 2025-07-15DOI: 10.1021/acsnano.5c10337
Yuqi Wu, Xuan Qin, Xing Lu, Chen Ji, Yufan Ling, Jiawei Zhang, Haoliang Shi, Binbin Chu, Bin Song, Houyu Wang, Yao He
{"title":"Correction to \"Enzyme-Responsive DNA Origami-Antibody Conjugates for Targeted and Combined Therapy of Choroidal Neovascularization\".","authors":"Yuqi Wu, Xuan Qin, Xing Lu, Chen Ji, Yufan Ling, Jiawei Zhang, Haoliang Shi, Binbin Chu, Bin Song, Houyu Wang, Yao He","doi":"10.1021/acsnano.5c10337","DOIUrl":"10.1021/acsnano.5c10337","url":null,"abstract":"","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":" ","pages":"27005-27006"},"PeriodicalIF":16.0,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS NanoPub Date : 2025-07-29Epub Date: 2025-07-14DOI: 10.1021/acsnano.5c08169
Jameela Karol, Charles O Ogolla, Mohsen Sotoudeh, Manuel Dillenz, Maciej Tobis, Ellen Vollmer, Yoga T Malik, Maider Zarrabeitia, Axel Groß, Benjamin Butz, Simon Fleischmann
{"title":"Nanoconfinement Geometry of Pillared V<sub>2</sub>O<sub>5</sub> Determines Electrochemical Ion Intercalation Mechanisms, Storage Sites, and Diffusion Pathways.","authors":"Jameela Karol, Charles O Ogolla, Mohsen Sotoudeh, Manuel Dillenz, Maciej Tobis, Ellen Vollmer, Yoga T Malik, Maider Zarrabeitia, Axel Groß, Benjamin Butz, Simon Fleischmann","doi":"10.1021/acsnano.5c08169","DOIUrl":"10.1021/acsnano.5c08169","url":null,"abstract":"<p><p>Improving the electrochemical ion intercalation capacity and kinetics in layered host materials is a critical challenge to further develop lithium-ion batteries, as well as emerging cell chemistries based on ions beyond lithium. Modification of the nanoconfining interlayer space within host materials by synthetic pillaring approaches has emerged as a promising strategy; however, the resulting structural properties of host materials, host-pillar interactions as well as associated electrochemical mechanisms remain poorly understood. Herein, we systematically study a series of bilayered V<sub>2</sub>O<sub>5</sub> host materials pillared with alkyldiamines of different lengths, resulting in tunable nanoconfinement geometries with interlayer spacings in the range of 1.0-1.9 nm. The electrochemical Li<sup>+</sup> intercalation capacity is increased from approximately 1.0 to 1.5 Li<sup>+</sup> per V<sub>2</sub>O<sub>5</sub> in expanded host materials due to the stabilization of new storage sites. The intercalation kinetics improve with expansion due to a transition in Li<sup>+</sup> diffusion pathways from 1D to 2D diffusional networks. Operando X-ray diffraction reveals a transition of the intercalation mechanism from solid-solution Li<sup>+</sup> intercalation in V<sub>2</sub>O<sub>5</sub> hosts with small and medium interlayer spacings to solvent cointercalation in V<sub>2</sub>O<sub>5</sub> with the largest interlayer spacing. The work systematically demonstrates the impact of nanoconfinement geometry within bilayered V<sub>2</sub>O<sub>5</sub> on the resulting Li<sup>+</sup> intercalation metrics and mechanisms, providing insights into both the microstructure and associated electrochemistry of pillared materials.</p>","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":" ","pages":"26904-26919"},"PeriodicalIF":16.0,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pushpender Yadav, Kyeongdeuk Moon, Muhammad Shoaib, Puja Thapa, Rui Sun, Seungmin Yang, Jung-Moo Heo, Sijun Seong, John McCracken, Xiwen Gong, Jinsang Kim, Joonho Bang, Dali Sun and Seokhyoung Kim*,
Chihyun Nam, Bonho Koo, Juwon Kim, Jinkyu Chung, Jaejung Song, Danwon Lee, Sungjae Seo, Munsoo Song, Seyeon Shin, Namdong Kim, Markus Weigand, Jian Wang and Jongwoo Lim*,
{"title":"","authors":"Chihyun Nam, Bonho Koo, Juwon Kim, Jinkyu Chung, Jaejung Song, Danwon Lee, Sungjae Seo, Munsoo Song, Seyeon Shin, Namdong Kim, Markus Weigand, Jian Wang and Jongwoo Lim*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"19 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.8,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsnano.5c10738","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144715880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS NanoPub Date : 2025-07-29DOI: 10.1021/acsnano.5c07973
Ziyue Feng,Mingrui He,Zhen Li,Xiaojing Hao
{"title":"A Perspective on Spatiotemporal Engineering of Multidimensional Heterointerfaces in Perovskite Solar Cells.","authors":"Ziyue Feng,Mingrui He,Zhen Li,Xiaojing Hao","doi":"10.1021/acsnano.5c07973","DOIUrl":"https://doi.org/10.1021/acsnano.5c07973","url":null,"abstract":"Perovskite solar cells offer promising cost-to-performance characteristics but face challenges from intrinsic chemical reactivity, which induces ion migration and defect formation, particularly at interfaces where nonradiative recombination limits efficiency and stability. This perspective discusses multidimensional interface engineering as a potential approach to address these trade-offs. We systematically evaluate passivation paradigms employing low-dimensional perovskites (2D, 1D, 0D) and related materials (e.g., antiperovskites, polymers, small molecules), analyzing their impact on defect mitigation, charge dynamics, and long-term stability under operational stress. Beyond simplified models, we consider theoretical frameworks involving adsorption dynamics (GCS), interfacial thermodynamics (Guggenheim), and reaction kinetics (Marcus/Gerischer) to support the rational design of stable interfaces. Recommendations for future interface design directions are presented. This work aims to support cross-dimensional heterointerface engineering in the development of durable and efficient perovskite photovoltaics.","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"13 1","pages":""},"PeriodicalIF":17.1,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144737450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"","authors":"Hyeonjeong Kim, Hyeon Ji Kim and Youngho Eom*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"19 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":15.8,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsnano.5c03399","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144715865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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