{"title":"Dissolution of Primary Carbides and Formation and Healing of Kirkendall Voids in Bearing Steel under Pulsed Electric Current","authors":"Zhongxue Wang, Tao Zhang, Mengcheng Zhou, Mingkui Zhang, Jinchao Ma, Xinfang Zhang, Jingdong Guo, Jide Liu, Yizhou Zhou","doi":"10.1002/srin.202400400","DOIUrl":"https://doi.org/10.1002/srin.202400400","url":null,"abstract":"<p>The alloying elements in 8Cr4Mo4V bearing steel tend to form large primary carbides with carbon, which not only causes element segregation but also becomes the primary source of fatigue crack initiation, thereby decreasing the material's usability and machinability. Owing to the excellent thermal stability of primary carbides, traditional homogenization annealing requires high temperatures, which is both time- and energy-intensive. Excessively high heat treatment temperatures can also result in “overburning” of the sample. Herein, primary carbides are rapidly dissolved at low temperatures using pulsed electric current treatment. The additional free energy introduced by the pulsed electric current lowers the thermodynamic barrier for carbide dissolution. During the second-phase dissolution process, the unbalanced diffusion of elements may cause the formation of Kirkendall voids. Due to the difference in electrical conductivity between the voids and the matrix, the pulsed electric current generates thermal compressive stress on the voids, promoting rapid atom migration to these voids and accelerating their healing. This pulse-current treatment technology offers a novel method for the rapid dissolution of carbides in alloys at low temperatures and for the rapid healing of related voids.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Angelo Perrone, Pasquale Cavaliere, Behzad Sadeghi, Leandro Dijon, Aleksandra Laska
{"title":"Optimization of Hydrogen Utilization and Process Efficiency in the Direct Reduction of Iron Oxide Pellets: A Comprehensive Analysis of Processing Parameters and Pellet Composition","authors":"Angelo Perrone, Pasquale Cavaliere, Behzad Sadeghi, Leandro Dijon, Aleksandra Laska","doi":"10.1002/srin.202400565","DOIUrl":"https://doi.org/10.1002/srin.202400565","url":null,"abstract":"<p>The article deals with the H<sub>2</sub> consumption for different processing conditions and the composition of the processed pellets during the direct reduction process. The experiments are carried out at 600–1300 °C, with gas pressures of 1–5 bar, gas flow rates of 1–5 L min<sup>−1</sup>, and basicity indices of 0 to 2.15. Pellets with different compositions of TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, CaO, and SiO<sub>2</sub> are analyzed. The gas flow rate is crucial, with 0–10 L min<sup>−1</sup> leading to an H2 consumption of 0–5.1 kg H<sub>2</sub>/kg pellet. The gas pressure (0–10 bar) increases the H<sub>2</sub> consumption from 0 to 5.1 kg H<sub>2</sub>/kg pellet. Higher temperatures (600–1300 °C) reduce H<sub>2</sub> consumption from 5.1 to 0 kg H<sub>2</sub>/kg pellet, most efficiently at 950–1050 °C, where it decreases from 0.22 to 0.10 kg H<sub>2</sub>/kg pellet. An increase in TiO<sub>2</sub> content from 0% to 0.92% lowers H<sub>2</sub> consumption from 0.22 to 0.10 kg H<sub>2</sub>/kg pellet, while a higher Fe content (61–67.5%) also reduces it. An increase in SiO<sub>2</sub> content from 0% to 3% increases H<sub>2</sub> consumption from 0 to 5.1 kg H<sub>2</sub>/kg pellet. Porosity structure influences H<sub>2</sub> consumption, with the average pore size decreasing from 2.83 to 0.436 mm with increasing TiO<sub>2</sub> content, suggesting that micropores increase H<sub>2</sub> consumption and macropores decrease it.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/srin.202400565","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microstructure and Precipitation of a Cu–Ni Alloyed Medium-Mn Duplex Low-Density Steel Prepared by Near-Rapid Solidification","authors":"Mingxiang Liu, Song Liu, Changjiang Song","doi":"10.1002/srin.202400623","DOIUrl":"https://doi.org/10.1002/srin.202400623","url":null,"abstract":"<p>A Cu–Ni-alloyed medium-Mn duplex low-density steel with a composition of Fe–9Mn–5.5Al–0.3C–3Ni–1.5Cu (wt%) is prepared by near-rapid solidification. The microstructure features of the alloy under as-cast, cold-rolling, and heat treatments are studied. The effect of Cu- and Ni-alloying elements on the microstructure and precipitates is discussed. In the results, it is shown that martensite and nanoscale precipitates are found in the microstructure of near-rapid solidification. The enrichment of Cu is found at the phase boundaries of austenite and ferrite. A large number of annealing twins are present in the microstructure of cold-rolled and annealed alloy. In the first principles and thermodynamic calculations, it is shown that Ni element is capable to shorten the nucleation incubation time of Cu precipitates. In addition, the interface segregation of Ni and Al elements reduces the adhesion work of Cu particles with the matrix. Both Cu and Ni elements increase the stacking fault energy of the alloy, which is increased from 37.3 to 44.2 mJ m<sup>−2</sup>. The contributions of precipitation strengthening and twinning strengthening to the strength of the alloy are 72 and 86 MPa, respectively, while the dominant contribution of dislocation hardening to the strength is 326 MPa.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 3","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuhang Zhu, Guocheng Ren, Cainian Jing, Tao Lin, Yingming Tu
{"title":"Effect of Partition Temperature on Microstructure and Mechanical Properties of Cold-Rolled Medium-Manganese Steel","authors":"Yuhang Zhu, Guocheng Ren, Cainian Jing, Tao Lin, Yingming Tu","doi":"10.1002/srin.202400562","DOIUrl":"https://doi.org/10.1002/srin.202400562","url":null,"abstract":"<p>The influence of different heat-treatment conditions on the microstructure evolution and mechanical properties of cold-rolled Fe–7.69Mn–2.76Al–0.12C (wt%) steel is investigated using various techniques, including scanning electron microscopy, transmission electron microscopy (TEM), and X-ray diffraction. In the results, it is shown that the stability of austenite is significantly affected by different partitioning temperatures. It is found that factors such as dislocation density, temperature, and grain size collectively influence partitioning behavior. In the observations, it is revealed that when the partitioning temperature is raised from 120 to 180 °C, the dislocation density of the face centered cubic phase within the test steel decreases from 10.38 × 10<sup>16</sup> to 7.67 × 10<sup>16</sup> m<sup>−2</sup>. Additionally, within specimens exhibiting higher dislocation densities, carbon element diffusion is more uniform. During the experiment, the poor stability of the austenite is found to be susceptible to stress-inducing the phase of the martensitic transformation, and the type of the martensite transformation affects the deformation process and the performance of submission behavior. In the observations under TEM, a phenomenon where variations in dislocation density within individual austenite grains may lead to differing stability across grain regions is revealed, thereby triggering localized martensitic phase transformations.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 3","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Precipitation Refinement via Aging Time Modification for Enhancing Wear Resistance in Ti–V–Nb Microalloyed High-Manganese Steels","authors":"Hongli Cao, Xin Chen, Delei Mu, Tongtao Wei, Hongxing Guo, Sida Chen, Xiaomin Huang, Zulai Li, Quan Shan","doi":"10.1002/srin.202400397","DOIUrl":"https://doi.org/10.1002/srin.202400397","url":null,"abstract":"<p>It is imperative to ensure an even distribution of refined precipitates to enhance wear resistance. Herein, different heat treatments are to control the size and distribution of precipitates. The treatments include water quenching at 1100 °C followed by aging at 400 °C for 24, 60, and 84 h, designated as AT24, AT60, and AT84, respectively. The microstructure, mechanical properties, and impact wear properties of high-manganese steel are investigated under solution and aging conditions using scanning electron microscopy, field-emission scanning electron microscopy, tensile testing, and impact abrasive wear testing. Notably, the absence of nanoscale precipitates largely accounts for the poor wear resistance of as-casting steel, whereas the strengthening effect of larger micrometer-sized precipitates is insufficient. After the solution and aging treatment, nanosized precipitates continuously form within the matrix, conducive to the formation of the deeper work-hardening layer, thereby improving the wear resistance. The fine micrometer-sized precipitates and evenly distributed nanoscale precipitates in AT60 actively contribute to toughness. Additionally, these precipitates interact with slip dislocations, providing stronger strengthening via the Orowan looping mechanism. The wear mechanisms of steel can be transformed from wide, deep pits to shallow grooves and microcutting by extending the aging time.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis of Flow Pattern and Bubble Behavior in Slab Continuous Casting with Mold Electromagnetic Stirring","authors":"Haibiao Lu, Qiao Cheng, Yunbo Zhong, Changgui Cheng, WeiLi Ren, Zhongming Ren, Zuosheng Lei","doi":"10.1002/srin.202400591","DOIUrl":"https://doi.org/10.1002/srin.202400591","url":null,"abstract":"<p>The electromagnetic stirring (EMS) and argon blowing are the widely recognized and extensively employed technologies to control the flow pattern in slab continuous casting, and their interaction is directly linked to the final product. To investigate the flow pattern, bubble characteristics under mold EMS and argon blowing, a mathematical model coupling the electromagnetic field, two-phase flow is constructed. The population balance model (PBM) under the Eulerian frame is applied to describe the bubbles breakage and coalescence. The results show that the flow regime under the interaction of argon blowing and EMS transfers from bubble ascending flow to intermediate flow to horizontal recirculation flow as EMS current increases, and the large argon flow rate could suppress the formation of horizontal recirculation flow. Meanwhile, EMS can promote the coalescence of bubbles, with the increasing EMS current, the bubble numbers decrease first and then increase, and the bubble mean diameter increases first and then decreases. For obtaining the horizontal recirculation flow, the suitable argon flow rate and EMS current should be matched suitably.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 3","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pengyan Zhang, Yi Yang, Zhenyi Huang, Qiang Yue, Ke Zhang
{"title":"Study on Microstructure and Low-Temperature Impact Toughness in Coarse Grain Heat-Affected Zone of EH460 Steel","authors":"Pengyan Zhang, Yi Yang, Zhenyi Huang, Qiang Yue, Ke Zhang","doi":"10.1002/srin.202400276","DOIUrl":"https://doi.org/10.1002/srin.202400276","url":null,"abstract":"<p>Herein, the effects of peak temperature on the microstructure and low-temperature impact toughness of coarse grain heat-affected zone (CGHAZ) of EH460 steel are investigated by Gleeble simulation welding. The low-temperature impact toughness of CGHAZ decreases with the increase of peak temperature. With the increase of peak temperature, the microstructure of CGHAZ gradually changes from bainite to a mixed structure composed of bainite, intragranular ferrite, side lath ferrite, and a small amount of grain boundary ferrite. The inclusions size decreases as the peak temperature increases. The existence of large-sized inclusions is conducive to the initiation and propagation of cracks, reducing the low-temperature impact toughness of the material.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kaiwang Chen, Lei Yuan, Qiang Gu, Guoqi Liu, Jianjun Zhi, Jingkun Yu, Hongxia Li
{"title":"Effect of Direct Current Electric Field on the Clogging Behavior of Submerged Entry Nozzle During Casting of UltraLow-Carbon Steel","authors":"Kaiwang Chen, Lei Yuan, Qiang Gu, Guoqi Liu, Jianjun Zhi, Jingkun Yu, Hongxia Li","doi":"10.1002/srin.202400395","DOIUrl":"https://doi.org/10.1002/srin.202400395","url":null,"abstract":"<p>The clogging of the submerged entry nozzle (SEN), as an important device to connect the tundish and the mold, has been widely concerned. However, until now, the clogging of the SEN cannot be eliminated during the casting. Herein, the clogging behavior of the SEN during the casting of ultralow-carbon steel is studied using an external DC electric field. The findings demonstrate that the DC electric field inhibits the growth of the clogging on the outlet and the thickness of the clogging layer is small, which ensures the integrity of the profile of the outlet. After DC treatment, the interface of the clogging is clear and the density is increased, which reduces the pollution to molten steel. At the same time, the fluctuation of the mold level is significantly improved, and the defect rate of cold rolling is effectively reduced to 30% of the original level, which is beneficial to the overall performance of the slab.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xingfu Yu, He Ma, Yong Su, Yinghua Wei, Yufeng Sun, Shuai Yang, Dongyue Zheng
{"title":"Effect of Carbide Precipitation on Hardness and Wear Resistance of H13 Steel","authors":"Xingfu Yu, He Ma, Yong Su, Yinghua Wei, Yufeng Sun, Shuai Yang, Dongyue Zheng","doi":"10.1002/srin.202400345","DOIUrl":"https://doi.org/10.1002/srin.202400345","url":null,"abstract":"<p>The carbide precipitation of H13 steel and its effect on hardness and friction and wear resistance are investigated by microstructure observation, phase analysis, and mechanical property test. Results show that the tempering hardness is mainly related to the content of secondary carbides. After solution treatment in the temperature range of 1040–1070 °C, quenching and tempering, with the increase of the solution temperature, the content of secondary carbides and hardness of H13 steel in the tempering microstructure increase first and then decrease, and both reach the maximum value when the solution temperature is 1060 °C. The change of hardness is consistent with that of the content of secondary carbides. When the solution temperature is 1040 °C, the wear mass loss of the tempered H13 steel is the least, which is 4.63 mg, indicating that its wear resistance is the best, and this is caused by the presence of more undissolved carbides in the tempering microstructure. With the increase of the solution temperature, the wear mass loss increases gradually, and the wear resistance decreases, which is mainly related to the content decrease of undissolved and secondary carbides and the content increase of residual austenite.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143113958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation of Oxidized Pellets of Vanadium Titanium Magnetite and Direct Reduction Behavior in Hydrogen-Based Shaft Furnace","authors":"Jue Tang, Mansheng Chu, Jinge Feng, Zichuan Zhao, Hongyu Tian","doi":"10.1002/srin.202400480","DOIUrl":"https://doi.org/10.1002/srin.202400480","url":null,"abstract":"<p>Herein, the optimized process parameters for the preparation of vanadium-titanium magnetite (VTM) pellets are determined, and an efficient and green utilization technology for VTM based on the integration of oxidation roasting-hydrogen-based shaft furnace direct reduction is established. The results indicate that the preferable VTM oxidized and pre-reduced pellets can be prepared by preheating at 925 °C for 18 min and roasting at 1200 °C for 25 min, followed by the reduction temperature of 1050 °C at the reduction atmosphere of 4% CO<sub>2</sub> and H<sub>2</sub>/CO = 8. The corresponding compressive strength of the preheated and roasted pellets is 516 N per pellet and 2028 N per pellet, respectively. In addition, the LTD<sub>+6.3</sub> and LTD<sub>UP</sub> of roasted pellets are 80.86% and 93.90%, and the corresponding reducibility index, reduction swelling index, and the reduction sticking index are 0.0428, 2.32%, and 2.50%, respectively. All of which meet the production requirements of hydrogen-based shaft furnace.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"96 2","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143113845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}