Reviews in Inorganic Chemistry最新文献_第7页

Metal-Organic Frameworks as bio- and heterogeneous catalyst supports for biodiesel production 金属有机框架作为生物柴油生产的生物和多相催化剂支持

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-12-08 DOI: 10.1515/revic-2022-0014

Yetzin Rodríguez Mejía, Fernando Romero Romero, Murali Venkata Basavanag Unnamatla, Maria Fernanda Ballesteros Rivas, Victor Varela Guerrero

{"title":"Metal-Organic Frameworks as bio- and heterogeneous catalyst supports for biodiesel production","authors":"Yetzin Rodríguez Mejía, Fernando Romero Romero, Murali Venkata Basavanag Unnamatla, Maria Fernanda Ballesteros Rivas, Victor Varela Guerrero","doi":"10.1515/revic-2022-0014","DOIUrl":"https://doi.org/10.1515/revic-2022-0014","url":null,"abstract":"Abstract As biodiesel (BD)/Fatty Acid Alkyl Esters (FAAE) is derived from vegetable oils and animal fats, it is a cost-effective alternative fuel that could complement diesel. The BD is processed from different catalytic routes of esterification and transesterification through homogeneous (alkaline and acid), heterogeneous and enzymatic catalysis. However, heterogeneous catalysts and biocatalysts play an essential role towards a sustainable alternative to homogeneous catalysts applied in biodiesel production. The main drawback is the supporting material. To overcome this, currently, Metal-Organic Frameworks (MOFs) have gained significant interest as supports for catalysts due to their extremely high surface area and numerous binding sites. This review focuses on the advantages of using various MOFs structures as supports for heterogeneous catalysts and biocatalysts for the eco-friendly biodiesel production process. The characteristics of these materials and their fabrication synthesis are briefly discussed. Moreover, we address in a general way basic items ranging from biodiesel synthesis to applied catalysts, giving great importance to the enzymatic part, mainly to the catalytic mechanism in esterification/transesterification reactions. We provide a summary with recommendations based on the limiting factors.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"43 1","pages":"323 - 355"},"PeriodicalIF":4.1,"publicationDate":"2022-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45547198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

A review on the chemistry of novel platinum chelates based on azo-azomethine ligands 新型偶氮甲亚胺铂螯合物的化学研究进展

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-11-04 DOI: 10.1515/revic-2022-0027

Paritosh Mandal, J. L. Pratihar

引用次数: 0

Recent reports on vanadium based coordination polymers and MOFs 钒基配位聚合物和MOFs的最新报道

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-10-24 DOI: 10.1515/revic-2022-0021

Samik Gupta

引用次数: 0

Iron metabolism: pathways and proteins in homeostasis 铁代谢：稳态中的途径和蛋白质

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-10-24 DOI: 10.1515/revic-2022-0031

E. Arora, Vibha Sharma

引用次数: 0

Chemistry of azo-imine based palladium complexes: a brief review 偶氮亚胺基钯配合物的化学研究进展

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-10-03 DOI: 10.1515/revic-2022-0017

Paritosh Mandal, J. L. Pratihar

引用次数: 0

Main group cyanides: from hydrogen cyanide to cyanido-complexes 主要氰化物：从氰化氢到氰化物络合物

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-09-21 DOI: 10.1515/revic-2021-0044

A. Schulz, Jonas Surkau

引用次数: 1

Real scenario of metal ion sensor: is conjugated polymer helpful to detect hazardous metal ion 金属离子传感器的真实场景:是有助于检测有害金属离子的共轭聚合物

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-09-21 DOI: 10.1515/revic-2022-0006

Pushparani Selvakumar Umabharathi, S. Karpagam

{"title":"Real scenario of metal ion sensor: is conjugated polymer helpful to detect hazardous metal ion","authors":"Pushparani Selvakumar Umabharathi, S. Karpagam","doi":"10.1515/revic-2022-0006","DOIUrl":"https://doi.org/10.1515/revic-2022-0006","url":null,"abstract":"Abstract Metal ions from natural and anthropogenic sources cause pollution to society and the environment is major concern in the present scenario. The deposition and contamination of metal ions in soil and water affect the biogeochemical cycles. Thus, it threatens the everyday life of living and non-living organisms. Reviews on the detection of metal ions through several techniques (Analytical methods, electrochemical techniques, and sensors) and materials (Nanoparticles, carbon dots (quantum dots), polymers, chiral molecules, metal-organic framework, carbon nanotubes, etc.) are addressed separately in the present literature. This review reveals the advantages and disadvantages of the techniques and materials for metal ion sensing with crucial factors. Furthermore, it focus on the capability of conjugated polymers (CPs) as metal ion sensors able to detect/sense hazardous metal ions from environmental samples. Six different routes can synthesize this type of CPs to get specific properties and better metal ion detecting capability in vast research areas. The metal ion detection by CP is time-independent, simple, and low cost compared to other materials/techniques. This review outlines recent literature on the conjugated polymer for cation, anion, and dual ion sensors. Over the last half decades published articles on the conjugated polymer are discussed and compared.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":" ","pages":""},"PeriodicalIF":4.1,"publicationDate":"2022-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49169013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

The use of metal-organic frameworks as heterogeneous catalysts 金属-有机骨架作为非均相催化剂的应用

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-09-19 DOI: 10.1515/revic-2022-0020

V. Larina, O. Babich, Anastasia Zhikhreva, S. Ivanova, Eugene Chupakhin

引用次数: 1

Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior 具有强而长寿命激发态吸收的过渡金属配合物:从分子设计到光功率限制行为

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-08-22 DOI: 10.1515/revic-2022-0013

H. Su, Lai Hu, Senqiang Zhu, Jiapeng Lu, Jinyang Hu, Rui Liu, Hongjun Zhu

引用次数: 1

Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I) 卤代金属酸亚烯二铵材料(金属:Bi, Sb，卤素:Cl, Br, I)的结构、热、振动、光学、相变和催化性能研究进展

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2022-07-07 DOI: 10.1515/revic-2022-0012

A. Ouasri

{"title":"Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)","authors":"A. Ouasri","doi":"10.1515/revic-2022-0012","DOIUrl":"https://doi.org/10.1515/revic-2022-0012","url":null,"abstract":"Abstract This paper aims to review recent advances on synthesis, crystal structures, thermal, spectroscopic, phase transitions, optical, dielectric, and catalysis properties of hydrate and anhydrous alkylenediammonium halogenometallates materials (Metal: Bi, Sb, Halogen: Cl, Br, I). These hybrid materials present rich structural diversities based on octahedra forming infinite zero dimensional, 1-dimensional chains, 2-dimensional layers, discrete bioctahedra, and discrete tetramer units. The effect, contribution and importance of hydrogen bonding N–H … X (X: Cl, Br, I) are reviewed in terms of solid state relationship. Particularly, a comparative study is made on hydrate and anyhdrous aliphatic chlorobismuthates with alkylenediammonium +NH3(CH2) n NH3+ based on structural data and V/Z variation with (CH2) n chains (n = 2–8, 12), and variation of BiCl63− Raman frequencies modes versus (CH2) n chains (n = 3–8). Hydrate salts with (n = 3, 12) consist of isolated BiCl63− anions and two water molecules, against others ones with isolated anionic chains [BiCl52−] n or Bi2Cl104− dimers, formed by distorted octahedra BiCl63− sharing corners, vices or edges. The reviewed optical and electronic band gaps suggested interesting compounds with band gaps (1.85–2.4 eV), as suitable materials in optoelectronic properties, photoactive layer in solution-processed photovoltaics, and bio-imaging or photovoltaic applications. It was concluded that iodobismuthate salts have generally the lowest bands gap, compared to that of bromo and chlorobismuthate slats. Catalysis proprieties are reviewed n fast (RhB) degradation under dark conditions for (C4N2H7)4Bi2Cl10, (C5H9N2)BiI4, and {(H-BPA)4·[(BiI6)I13]·2I3} n , and in organic salts synthesis under solvent-free conditions. Herein NH3(CH2) n NH3BiCl5 (n = 5–7) salts were used as highly efficient catalysts, which is a novel tendency in chlorobismuthate researchs in the green chemistry field.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"43 1","pages":"247 - 280"},"PeriodicalIF":4.1,"publicationDate":"2022-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43272099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1