主要氰化物：从氰化氢到氰化物络合物

IF 4.1 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Reviews in Inorganic Chemistry Pub Date : 2022-09-21 DOI:10.1515/revic-2021-0044

A. Schulz, Jonas Surkau

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引用次数: 1

摘要

摘要几乎所有的主族元素都存在同质氰化物化合物。当碱金属和碱土金属形成氰化物盐时，较轻的主族元素的氰化物主要以共价化合物的形式出现。本文综述了主要族元素氰化物和氰化物配合物的研究现状。包括有关合成的信息以及应用、特殊物质性质、键长、光谱特性和计算。氰化物化学主要从无机化学领域介绍，但也讨论了化学生物学和天体物理学方面与氰基化合物的关系。

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Main group cyanides: from hydrogen cyanide to cyanido-complexes

Abstract Homoleptic cyanide compounds exist of almost all main group elements. While the alkali metals and alkaline earth metals form cyanide salts, the cyanides of the lighter main group elements occur mainly as covalent compounds. This review gives an overview of the status quo of main group element cyanides and cyanido complexes. Information about syntheses are included as well as applications, special substance properties, bond lengths, spectroscopic characteristics and computations. Cyanide chemistry is presented mainly from the field of inorganic chemistry, but aspects of chemical biology and astrophysics are also discussed in relation to cyano compounds.

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来源期刊

Reviews in Inorganic Chemistry 化学-分析化学

CiteScore

7.30

自引率

4.90%

发文量

审稿时长

1 months

期刊介绍： Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids