Reviews in Inorganic Chemistry最新文献

{"title":"Advances in synthesis and anticancer applications of organo-tellurium compounds","authors":"Fadhil Farhood M. Al-joborae, Sawsan S. Al-Rawi, Ahmad H. Ibrahim, Abbas Washeel Salman, Muhammad Adnan Iqbal","doi":"10.1515/revic-2024-0039","DOIUrl":"https://doi.org/10.1515/revic-2024-0039","url":null,"abstract":"The present review deeply delves the major methods for the synthesis of organotellurium compounds along with their biological significance. Elaboration of various precursors (ligands) including Schiff bases, naphthoquinones, amino acids, <jats:italic>β</jats:italic>-hydroxy alkylated compounds, <jats:italic>β</jats:italic>-phenyltelluro alcohols, <jats:italic>β</jats:italic>-aryltelluro amines, <jats:italic>β</jats:italic>-aryl-chalcogenium azides, chalcogenobiotin, benzenesulfonamide, carbonic anhydrase, and Sulpha compounds has been briefly described. Furthermore, the article investigates their possible biological uses, specifically as antioxidant and anticancer agents while comparing their effectiveness with their respective ligands and with the standard medications in terms IC<jats:sub>50</jats:sub> values. All types of details are haunted to make the information a priceless resource for researchers who wish to probe deeper into and examine the diverse roles that organotellurium complexes play in biological settings.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A comprehensive overview of fabrication of biogenic multifunctional metal/metal oxide nanoparticles and applications","authors":"Rafi Ullah, Muhammad Siraj, Farishta Zarshan, Banzeer Ahsan Abbasi, Tabassum Yaseen, Abdul Waris, Javed Iqbal","doi":"10.1515/revic-2024-0031","DOIUrl":"https://doi.org/10.1515/revic-2024-0031","url":null,"abstract":"The re-evaluation of animals, plants, and microorganisms for green synthesis has revolutionized the fabrication of metallic nanoparticles (MNPs). Green synthesis provides more biocompatibility compared to chemically synthesized MNPs, which make them ideal for diverse biological applications, especially in biomedicine. Various organisms have been extensively studied for green synthesis. Interestingly, angiosperms, algae, and animal-derived biomaterials like chitin and silk have shown a prominent role in synthesizing these nanoparticles. Moreover, bacteria, viruses, and fungi serve as sources of reducing agents, further expanding green synthesis possibilities. Despite progress, research on natural reducing agents remains relatively limited, with only a few exceptions such as tea and neem plants receiving attention. Green-synthesized nanoparticles have diverse applications in various fields. In biomedicine, they enable drug delivery, targeted therapies, and bio-imaging due to their enhanced biocompatibility. Some MNPs also exhibit potent antimicrobial properties, aiding in disease control and eco-friendly disinfection. Furthermore, green nanoparticles contribute to environmental remediation by purifying water and serve as sensitive biosensors for diagnostics and environmental monitoring. This review will provide the recent progress and advancements in the field of green synthesis (GS) of nanoparticles. It will also analyze the key characteristics and evaluate the advantages and disadvantages of GS compared to chemical synthesis.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comparative analysis of dye degradation methods: unveiling the most effective and environmentally sustainable approaches, a critical review","authors":"Fakhr Un Nisa, Khalida Naseem, Asad Aziz, Warda Hassan, Nimra Fatima, Jawayria Najeeb, Shafiq Ur Rehman, Awais Khalid, Mohammad Ehtisham Khan","doi":"10.1515/revic-2024-0042","DOIUrl":"https://doi.org/10.1515/revic-2024-0042","url":null,"abstract":"The constant increase in population and as a result increase in industrial activities in many areas, such as textiles, cosmetics, leather, polymers, and food processing leads to the contamination of water sources with different dyes. Thus, the removal of dyes from contaminated water sources to make water reusable is the utmost requirement of the time in order to get environmental sustainability. The reason of removal is that many dyes and pollutants present in dyeing wastewater from industries have detrimental impacts on plants, wildlife, and humans. To lessen the negative effects of dye wastewater on the environment and living beings, it should be processed first to remove un-wanted components before being released in the water sources. However, due to some drawbacks of dye removal technologies, it is challenging to settle on a single solution that addresses the current dye effluent problem to make water clean. In the current work, we tried our best to elaborate different methods adopted for the treatment of dyes polluted wastewater with respect to their implementation along with drawbacks and advantages.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of doping of metal salts on polymers and their applications in various fields","authors":"Dyari Mustafa Mamand, Nazk Mohammed Aziz, Rebaz Anwar Omer","doi":"10.1515/revic-2024-0034","DOIUrl":"https://doi.org/10.1515/revic-2024-0034","url":null,"abstract":"Transition metal compounds (TMCs) provide the benefits of vast reserves, affordability, non-toxicity, and environmental friendliness, making them highly sought-after in recent times. Integrating transition metal salts into polymers may result in substantial enhancements in optical and electrical characteristics, making them appealing for many applications. Transition metal ions may display a range of electronic transitions, which enables the adjustment of absorption and emission spectra. This characteristic has significant value in applications such as light-emitting devices (LEDs) and sensors. The photoluminescence of polymers may be improved by the addition of transition metal salts, which results in light emission that is both more brilliant and more efficient. On the other hand, this is advantageous for screens and optoelectronic devices. The presence of transition metal salts in polymers may help to improve their optical stability, hence lowering the probability that the polymers will degrade or change color over time. When it comes to the performance of optical devices over the long run, this is quite essential. Elevating the electrical conductivity of polymers is possible via the use of transition metal salts. This is very helpful in the process of developing conductive polymers for use in applications such as electronic fabrics, organic solar cells, and flexible electronic devices. Transition metal salts can affect the electrical band structure of polymers, which enables the band gap of the material to be tuned. This is very necessary in order to maximize the amount of light that is absorbed by photovoltaic devices. Through having all these benefits, we conducted a review to find out the effects on polymeric materials.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review of coordination compounds: structure, stability, and biological significance","authors":"Kwestan N. Aziz, Karzan Mahmood Ahmed, Rebaz A. Omer, Aryan F. Qader, Eman I. Abdulkareem","doi":"10.1515/revic-2024-0035","DOIUrl":"https://doi.org/10.1515/revic-2024-0035","url":null,"abstract":"Coordination compounds are molecules that contain one or more metal centers bound to ligands. Ligands can be atoms, ions, or molecules that transfer electrons to the metal. These compounds can be charged or neutral. When charged, neighboring counter-ions help stabilize the complex. The metal ion is located at the center of a complex ion, surrounded by other molecules or ions known as ligands. Ligands can be thought of as covalently bonded to the core ion through coordination. Understanding coordination theory in chemistry provides insight into the geometric shape of complexes and the structure of coordination compounds, which consist of a central atom or molecule connected to surrounding atoms or compounds. Inorganic coordination compounds exhibit different properties and are used in synthesizing organic molecules. The coordination of chemicals is vital for the survival of living organisms. Metal complexes are also essential for various biological processes, with many enzymes, known as metalloenzymes, being composed of metal complexes. These metal complexes occur naturally.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review of organometallic compounds as versatile sensors in environmental, medical, and industrial applications","authors":"Peshang Khdir Omer, Eman Ibraheem Abdulkareem, Rebaz Anwar Omer, Rzgar Faruq Rashid","doi":"10.1515/revic-2024-0055","DOIUrl":"https://doi.org/10.1515/revic-2024-0055","url":null,"abstract":"Sensing technology is gaining attention and continuously advancing, making it a recommended element of individualized healthcare management. This is due to the powers exhibited by organometallic compounds, which are further enhanced by the field of bioengineering. Organometallic compounds have a wide range of biological activity and find uses in industrial and material science fields. Their unique ability to specifically target and overcome constraints faced by traditional counterparts makes them potential contenders for sensor technology. These compounds are highly sensitive to changes in their environment, allowing them to be utilized as sensors for detecting various chemicals or conditions. Additionally, the versatility of organometallic compounds enables their integration into different sensor platforms, making them suitable for environmental monitoring, medical diagnostics, and industrial quality control. This article provides a comprehensive summary of recent advancements in the design and synthesis of organometallic compounds, with a specific emphasis on their potential use as sensors. It also discusses the changes made to the structure, the processes used for functionalization, the incorporation of microfluidics, and the resulting impact on the materials’ sensing capabilities. These biologically derived methods align with sustainability goals and enhance the affordability, applicability, and effectiveness of sensing.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review: evaluating methods for analyzing kidney stones and investigating the influence of major and trace elements on their formation","authors":"Fidan Suleman Muhammed, Musher Ismael Salih, Rebaz Anwar Omer, Aryan Fathulla Qader, Rzgar Faruq RashidIman, Eman Ibrahim Abdulkareem","doi":"10.1515/revic-2024-0045","DOIUrl":"https://doi.org/10.1515/revic-2024-0045","url":null,"abstract":"Kidney stone disease is a global concern, and its prevalence is increasing. The objective of this review is to provide a thorough analysis of the many analytical techniques used in the study of kidney stones and to investigate the significance of major and trace components in the development of kidney stone formation. The samples included organic (uric acid) and inorganic (calcium oxalate and carbonate apatite). To study kidney stone analysis methods like XRD, FTIR, SEM, and ICP-MS, a systematic literature review was conducted. The quantities and effects of main (calcium, oxalate, phosphate) and trace (magnesium, zinc, copper) elements in kidney stone development were also examined. The review shows that XRD and FTIR are best for evaluating kidney stone crystalline structure and content, whereas SEM gives rich morphological insights. Its trace element detection sensitivity makes ICP-MS unique. Calcium oxalate and calcium phosphate, the most common components, affect kidney stone development. Trace elements like magnesium prevent stone formation, whereas zinc and copper may encourage crystallisation. Results revealed significantly higher calcium levels in inorganic components compared to organic ones. Uric acid stones exhibited lower element content except for copper and selenium, likely originating from the liver. Carbonate apatite stones showed higher element concentrations, particularly magnesium, compared to calcium oxalate stones. Principal component analysis (PCA) identified three principal components, explaining 91.91 % of the variance. These components reflected specific co-precipitation processes of elements, with distinct distributions among different stone types. This variability in element content among stone types could serve as valuable guidance for patient dietary considerations.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring inorganic phosphors: basics, types, fabrications and their luminescence properties for LED/WLED/displays","authors":"Junaid Ur Rahman, Shahab Khan, Vicky Jain, Asha Rajiv, Shivakrishna Dasi, Khaled Fahmi Fawy, Pardeep Kumar Jindal, Reddi Sivaranjani","doi":"10.1515/revic-2024-0044","DOIUrl":"https://doi.org/10.1515/revic-2024-0044","url":null,"abstract":"The utilization of phosphors in lighting and display applications has garnered significant attention due to their unique luminescent properties and versatile crystal structures. This review article comprehensively examines recent advances in the synthesis, characterization, and applications of nitride and sulfide phosphors. This article addresses various phosphor crystal structures, including perovskite, garnet, nitride sulfide, fabrications strategies, and their impact on the optical and electronic properties. Furthermore, the review highlights the role of doping and activator ions in tailoring the emission characteristics of nitride and sulfide phosphors, enabling precise control over color rendering and efficiency. Additionally, the article also discusses emerging trends in phosphor technology, such as the development of novel synthesis methods and the integration of phosphors into next-generation lighting and display devices. The basic properties of phosphor materials like CRI, CIE chromaticity coordinates, quantum efficiencies are well discussed. Overall, this article provides valuable insights into the current state of research and future directions in the field of phosphors offering potential avenues for further advancements in lighting and display technologies.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent trends in medicinal applications of mercury based organometallic and coordination compounds","authors":"Fozia Maqsood, Sawsan S. Al-Rawi, Ahmad H. Ibrahim, Faisal Jamil, Ayesha Zafar, Muhammad Adnan Iqbal, Umar Sohail Shoukat, Mohammad Asad, Sami Ullah Zia, Farhan Ahmad, Muhammad Atif","doi":"10.1515/revic-2024-0033","DOIUrl":"https://doi.org/10.1515/revic-2024-0033","url":null,"abstract":"Metal-based drugs are finding new medical applications, particularly in antibacterial therapies. Compounds such as Prontosil and ciprofloxacin, as well as its derivatives such as beta-lactam drugs, aminoglycosides, vancomycin, fosfomycin, as well as tetracyclines, play critical roles in the prevention of bacterial and fungal infections. The increasing prevalence of microbial resistance is prompting the use of metal complexes to tackle fungal and bacterial strains. Mercury-based complexes, which are known for their unusual characteristics and reactivity, have received a lot of interest in the field of medicine recently. Additionally, Schiff base complexes are widely used as antifungal, antibacterial, and anticancer drugs, as well as in dye manufacturing. This article discusses current advances in the use of mercury compounds for combating fungus and bacteria, offering information on their efficacy and future applications.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142203611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient removal of Cr(VI) ions from industrial wastewater using carbon-based adsorbents functionalized with boronic acid","authors":"Sonali R. Dhokpande, Satyajit M. Deshmukh, Ajinkya Khandekar, Amaya Sankhe","doi":"10.1515/revic-2024-0051","DOIUrl":"https://doi.org/10.1515/revic-2024-0051","url":null,"abstract":"The adsorption of potentially toxic element ions from contaminated water sources has garnered significant attention due to its critical role in environmental remediation and ensuring safe drinking water. Potentially toxic element ions can be removed from water using conventional adsorbents such as activated zeolites; however, these materials have low absorption and slow kinetics. To solve these issues, carbon-based adsorbents that exhibit easy synthesis, high porosity, designability, and stability have been proposed. In this study, a carbon-based adsorbent, named Magnetic Nitrogen-Doped Carbon (M-NC), and graphene oxide were developed for the selective removal of potentially toxic element ions. To increase the potential for HM immobilization, sulfide-modified biochar was created via a process called simultaneous carbon layer encapsulation. A theoretical physicochemical and thermodynamic investigation of the adsorption of potentially toxic elements s Zn<jats:sup>2+</jats:sup>, Cd<jats:sup>2+</jats:sup>, Ni<jats:sup>2+</jats:sup>, Ag<jats:sup>2+</jats:sup>, Pb<jats:sup>2+</jats:sup> and Cu<jats:sup>2+</jats:sup> on carbon-based adsorbents was performed with statistical physics fundaments. The biochar with large surface areas is used to remove potentially toxic element ions, one of the most important potentially toxic element pollutants, from aqueous solutions. The capacity of the adsorbent for removing potentially toxic element ions was studied using Langmuir adsorption isotherm under ultrasound-assisted conditions. The MNCs can be applied to the Langmuir model and pseudo-second-order kinetics. It is possible to use the Langmuir and second-order kinetic equations to accurately explain the adsorption method. Thermodynamic limitations were also envisioned because sorption is exothermic when it happens spontaneously. A homogeneous statistical physics adsorption model was used to describe and analyze the experimental potentially toxic element removal isotherms at 30 °C and pH<jats:sub>5</jats:sub> utilizing adsorbents produced by pyrolysis of biomasses (broccoli stalks). The findings show the proposed adsorbent, with an efficiency of 98.7 % and even reaching 99.3 % in certain cases, making it a standout choice for potentially toxic element removal applications. This research holds significance in advancing the understanding of environmentally sustainable potentially toxic element removal processes, particularly in the context of biomass-derived adsorbents, offering potential solutions for water purification and environmental remediation.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}