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Reviews in Inorganic Chemistry最新文献

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Newfangled progressions in the charge transport layers impacting the stability and efficiency of perovskite solar cells 影响钙钛矿太阳能电池稳定性和效率的电荷传输层的新进展
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-07-07 DOI: 10.1515/revic-2021-0004
S. Jaffri, K. Ahmad
{"title":"Newfangled progressions in the charge transport layers impacting the stability and efficiency of perovskite solar cells","authors":"S. Jaffri, K. Ahmad","doi":"10.1515/revic-2021-0004","DOIUrl":"https://doi.org/10.1515/revic-2021-0004","url":null,"abstract":"Abstract Organic-inorganic lead halide perovskite solar cells have rapidly emerged as a newfangled material for solar energy harnessing. Perovskite solar cells have succeeded in gaining a power conversion efficiency of 25% in the last year, further enhancement in the efficiency is anticipated due to advanced engineering of the different components making up the complete cell architecture with enhanced performance, stability and efficiency. Significant components of perovskite solar cell configurational architecture are the electron transport layer, active perovskite absorber layer, hole transport layer and counter electrode. Considering the profound role of transport layers in charge mobility, current review has particularly elucidated the advancements in the charge transport layers. The time duration of the review is from 2010 to 2021. However, the special focus has been laid on the recent articles. The influence of different organic and inorganic materials used for development of transport layers influencing the cell performance have been summarized. Materials used for transport layers have been modified by utilization of myriad of engineered substances through doping and surface functionalization strategies but every method have been marked by posing serious challenges towards the stability and efficiency of the cell and thus, hindering its commercialization. The review also provides an elucidation of the mechanical challenges and abatement strategies. These strategies are associated with the charge transport layers for enhancement of cell functionality.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"137 - 159"},"PeriodicalIF":4.1,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48280585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Recent reports on Pyridoxal derived Schiff base complexes 吡哆醇衍生席夫碱配合物的研究进展
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-06-17 DOI: 10.1515/revic-2020-0026
Samik Gupta
{"title":"Recent reports on Pyridoxal derived Schiff base complexes","authors":"Samik Gupta","doi":"10.1515/revic-2020-0026","DOIUrl":"https://doi.org/10.1515/revic-2020-0026","url":null,"abstract":"Abstract Pyridoxal and Pyridoxal 5-phosphate are two among the six aqua soluble vitamers of vitamin B6. They can form Schiff bases readily due to the presence of aldehyde group. Schiff bases can offer diverse coordination possibilities for many transition metals as has been found in a large volume of research till now. The coordination complexes thus formed gives insight into the active core structure and enzymatic activities of vit B6 containing enzymes. Apart from that, these complexes have been found useful as catalysts for synthesis of fine chemicals, as sensors and for their diverse biological activities.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"161 - 177"},"PeriodicalIF":4.1,"publicationDate":"2021-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46472283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
NO, CO and H2S based pharmaceuticals in the mission of vision (eye health): a comprehensive review 基于NO、CO和H2S的药物在视觉（眼睛健康）任务中的作用：综述
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-06-08 DOI: 10.1515/revic-2021-0009
J. Mir, R. Maurya, Mohd. Washid Khan
{"title":"NO, CO and H2S based pharmaceuticals in the mission of vision (eye health): a comprehensive review","authors":"J. Mir, R. Maurya, Mohd. Washid Khan","doi":"10.1515/revic-2021-0009","DOIUrl":"https://doi.org/10.1515/revic-2021-0009","url":null,"abstract":"Abstract A set of well defined signaling molecules responsible for normal functioning of human physiology including nitric oxide along with carbon monoxide and hydrogen sulphide are referred as “gasotransmitters”. Due to their involvement in almost every system of a human body, the care of highly sensitive organs using these molecules as drugs represents highly fascinating area of research. In connection with these interesting aspects, the applied aspects of these gaseous molecules in maintaining healthy eye and vision have been targeted in this review. Several examples of eye-droppers including NORMs like latanoprost and nipradiol, CORMs like CORM-3 and CORM-A1, and Hydrogen sulfide releasing system like GYY4137 have been discussed in this context. Therefore the relation of these trio-gasotransmitters with the ophthalmic homeostasis on one hand, and de-infecting role on the other hand has been mainly highlighted. Some molecular systems capable of mimicking gasotransmitter action have also been introduced in connection with the titled theme.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"179 - 195"},"PeriodicalIF":4.1,"publicationDate":"2021-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49655134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Removal of decidedly lethal metal arsenic from water using metal organic frameworks: a critical review 使用金属有机框架从水中去除致命的金属砷：一项重要综述
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-05-26 DOI: 10.1515/revic-2021-0005
Khalil Ahmad, Habib-ur-Rehman Shah, Muhammad Ashfaq, H. Nawaz
{"title":"Removal of decidedly lethal metal arsenic from water using metal organic frameworks: a critical review","authors":"Khalil Ahmad, Habib-ur-Rehman Shah, Muhammad Ashfaq, H. Nawaz","doi":"10.1515/revic-2021-0005","DOIUrl":"https://doi.org/10.1515/revic-2021-0005","url":null,"abstract":"Abstract Water contamination is worldwide issue, undermining whole biosphere, influencing life of a large number of individuals all over the world. Water contamination is one of the chief worldwide danger issues for death, sickness, and constant decrease of accessible drinkable water around the world. Among the others, presence of arsenic, is considered as the most widely recognized lethal contaminant in water bodies and poses a serious threat not exclusively to humans but also towards aquatic lives. Hence, steps must be taken to decrease quantity of arsenic in water to permissible limits. Recently, metal-organic frameworks (MOFs) with outstanding stability, sorption capacities, and ecofriendly performance have empowered enormous improvements in capturing substantial metal particles. MOFs have been affirmed as good performance adsorbents for arsenic removal having extended surface area and displayed remarkable results as reported in literature. In this review we look at MOFs which have been recently produced and considered for potential applications in arsenic metal expulsion. We have delivered a summary of up-to-date abilities as well as significant characteristics of MOFs used for this removal. In this review conventional and advanced materials applied to treat water by adsorptive method are also discussed briefly.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"197 - 227"},"PeriodicalIF":4.1,"publicationDate":"2021-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45221057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Bicyclic and tricyclic phosphanes with p-block substituents 具有p-嵌段取代基的双环和三环膦
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-04-27 DOI: 10.1515/revic-2020-0028
J. Bresien, K. Faust, A. Schulz
{"title":"Bicyclic and tricyclic phosphanes with p-block substituents","authors":"J. Bresien, K. Faust, A. Schulz","doi":"10.1515/revic-2020-0028","DOIUrl":"https://doi.org/10.1515/revic-2020-0028","url":null,"abstract":"Abstract This review summarises the experimental and structural knowledge on polycyclic phosphanes, with a focus on bicyclic and tricyclic phosphanes, as they have not only been the most studied in the last 25 years, but also show the greatest diversity in terms of constitutional isomerism and structural motifs. Moreover, only polycyclic phosphanes that have p-block substituents at all free valences are discussed.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"1 - 20"},"PeriodicalIF":4.1,"publicationDate":"2021-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2020-0028","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49596491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Techniques in the synthesis of organometallic compounds of Hafnium 铪金属有机化合物的合成技术
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-03-16 DOI: 10.1515/revic-2020-0027
Meeshar Shahid, Mahvish Abbasi, Munazza Yaqoob, Rosenani A. Haque, M. Iqbal
{"title":"Techniques in the synthesis of organometallic compounds of Hafnium","authors":"Meeshar Shahid, Mahvish Abbasi, Munazza Yaqoob, Rosenani A. Haque, M. Iqbal","doi":"10.1515/revic-2020-0027","DOIUrl":"https://doi.org/10.1515/revic-2020-0027","url":null,"abstract":"Abstract Hafnium is a transition metal and it is the 45th most abundant transition element present on the earth. Hafnium has been successfully alloyed with several metals including titanium, iron, and niobium. Hafnium complexes are less active olefin polymerization catalysts. In the current review synthesis of hafnium complexes involving bonding through different linkages like “carbon, nitrogen, oxygen, carbon and oxygen, nitrogen and cobalt nitrogen and oxygen, nitrogen and phosphorus, nitrogen and sulfur, phosphorus and carbon, phosphorus and oxygen, sulfur carbon and oxygen, carbon–nitrogen and oxygen, carbon–nitrogen and phosphorus, carbon–nitrogen oxygen, sulfur and phosphorus, carbon–oxygen phosphorus and nitrogen”. The commonly used solvents for the synthesis of Hafnium complexes are tetrahydrofuran, n-hexane, and toluene, etc. These complexes were mostly reported at different temperatures ranges from −35 to 110 °C with continuous stirring, according to the nature of ligands. An overview of techniques in the synthesis of Hafnium complexes through various routes has been compiled.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"89 - 120"},"PeriodicalIF":4.1,"publicationDate":"2021-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2020-0027","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47711702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Supercapacitor electrode materials: addressing challenges in mechanism and charge storage 超级电容器电极材料:解决机制和电荷存储方面的挑战
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-03-10 DOI: 10.1515/revic-2020-0022
S. Attia, S. Mohamed, Y. F. Barakat, H. Hassan, W. A. Zoubi
{"title":"Supercapacitor electrode materials: addressing challenges in mechanism and charge storage","authors":"S. Attia, S. Mohamed, Y. F. Barakat, H. Hassan, W. A. Zoubi","doi":"10.1515/revic-2020-0022","DOIUrl":"https://doi.org/10.1515/revic-2020-0022","url":null,"abstract":"Abstract In recent years, rapid technological advances have required the development of energy-related devices. In this regard, Supercapacitors (SCs) have been reported to be one of the most potential candidates to meet the demands of human’s sustainable development owing to their unique properties such as outstanding cycling life, safe operation, low processing cost, and high power density compared to the batteries. This review describes the concise aspects of SCs including charge-storage mechanisms and scientific principles design of SCs as well as energy-related performance. In addition, the most important performance parameters of SCs, such as the operating potential window, electrolyte, and full cell voltage, are reviewed. Researches on electrode materials are crucial to SCs because they play a pivotal role in the performance of SCs. This review outlines recent research progress of carbon-based materials, transition metal oxides, sulfides, hydroxides, MXenes, and metal nitrides. Finally, we give a brief outline of SCs’ strategic direction for future growth.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"53 - 88"},"PeriodicalIF":4.1,"publicationDate":"2021-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2020-0022","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45833954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 57
Ligand isomerism in Pt(II) complexes – structural aspects 铂(II)配合物中的配体异构体-结构方面
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-03-09 DOI: 10.1515/revic-2020-0023
M. Melnik, P. Mikuš
{"title":"Ligand isomerism in Pt(II) complexes – structural aspects","authors":"M. Melnik, P. Mikuš","doi":"10.1515/revic-2020-0023","DOIUrl":"https://doi.org/10.1515/revic-2020-0023","url":null,"abstract":"Abstract This review has focused on ligand isomers in Pt(II) complexes. There are a variety of inner coordination spheres about the platinum(II) atom (PtN4, PtN2Cl2, PtP2Cl2, PtPNC2, PtPNCl2, PtP2CBr, PtP2CS), build up by mono- and bidentate ligands. The bidentate ligands create a variety of metallocyclic rings. The L–Pt–L bite angle (mean values) open in the sequence: 73.1° (PNP) < 78.7° (NC2C) < 80.4° (NC2N) < 86.4° (PC2P) < 86.7° (PNNP) < 93.0° (CC3S). There are three types of isomers: ligand, mixed – (ligand + distortion), and mixed – (ligand + cis-trans), isomers, which are rarity.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"21 - 28"},"PeriodicalIF":4.1,"publicationDate":"2021-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2020-0023","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43975472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Medicinal inorganic chemistry: an updated review on the status of metallodrugs and prominent metallodrug candidates 药用无机化学：金属药物和主要候选金属药物的最新进展
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-03-09 DOI: 10.1515/revic-2020-0030
Victor M. Miranda
{"title":"Medicinal inorganic chemistry: an updated review on the status of metallodrugs and prominent metallodrug candidates","authors":"Victor M. Miranda","doi":"10.1515/revic-2020-0030","DOIUrl":"https://doi.org/10.1515/revic-2020-0030","url":null,"abstract":"Abstract Metallodrugs correspond to a small portion of all available drugs in the market and, yet, some of them are among the most used and important drugs in modern medicine. However, medicinal inorganic chemistry remains an underestimated area within medicinal chemistry and the main reason is the mislead association of metals to toxic agents. Thus, in this review, the potential of medicinal inorganic chemistry in drug designing is highlighted through a description of the current status of metallodrugs and metallodrug candidates in advanced clinical trials. The broad spectrum of application of metal-based drugs in medicine for both therapy and diagnosis is addressed by the extensive list of examples presented herein.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"29 - 52"},"PeriodicalIF":4.1,"publicationDate":"2021-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2020-0030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45353026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Frontmatter Frontmatter
IF 4.1 3区 化学
Reviews in Inorganic Chemistry Pub Date : 2021-02-15 DOI: 10.1515/revic-2021-frontmatter1
{"title":"Frontmatter","authors":"","doi":"10.1515/revic-2021-frontmatter1","DOIUrl":"https://doi.org/10.1515/revic-2021-frontmatter1","url":null,"abstract":"","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"1 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2021-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/revic-2021-frontmatter1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45183313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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