偶氮亚胺基钯配合物的化学研究进展

IF 4.1 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Reviews in Inorganic Chemistry Pub Date : 2022-10-03 DOI:10.1515/revic-2022-0017

Paritosh Mandal, J. L. Pratihar

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引用次数: 0

摘要

摘要本文综述了含多齿偶氮亚胺配体的钯配合物的结构多样性、合成方法、氧化还原性等有趣性质、生物活性及其在C - N偶联反应、C - C交叉偶联反应(如Suzuki和Heck)和不同有机转化催化活性方面的进一步应用。详细的文献调查显示，目前还没有关于偶氮-偶氮甲醚基钯配合物的简要综述。因此，本文综述了以钯为中心的各种偶氮亚胺配体的合成策略和配位行为以及金属配合物的一些重要性质的研究。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Chemistry of azo-imine based palladium complexes: a brief review

Abstract This paper provides a general overview of palladium complexes incorporating numerous multidentate azo-imine ligands, their structural diversity, synthetic protocol, interesting properties such as redox properties, biological activity and their further application on C – N coupling reactions, C – C cross-coupling reactions (e.g., Suzuki and Heck) and catalytic activity on different organic transformations. A detailed literature survey revealed that no brief review has yet been published on the azo-azomethine-based palladium complex. Therefore, the present review incorporates the research undertaken on the synthetic strategies and coordinating behaviour of various azo-imine ligands with palladium metal centre and a few important properties of metal complexes.

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来源期刊

Reviews in Inorganic Chemistry 化学-分析化学

CiteScore

7.30

自引率

4.90%

发文量

审稿时长

1 months

期刊介绍： Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids