Optical Materials最新文献_第2页

Linear and nonlinear optical properties of DNA in suspensions 悬浮液中DNA的线性和非线性光学性质

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-06 DOI: 10.1016/j.optmat.2025.117223

Arturo Ramirez , Lipi Patel , Andres Morin , Jesus Poblano , Rebecca Sipen , Chhandak Basu , Anna Bezryadina

引用次数: 0

Enhancement upconversion luminescence of In2O3: Er3+, Yb3+ phosphors by Al3+ ions doping Al3+离子掺杂增强In2O3: Er3+， Yb3+荧光粉的上转换发光

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-05 DOI: 10.1016/j.optmat.2025.117224

Daobin Zhu , Junshan Hu , Keyu Guo , Yuxiang Wu , Changchun Ding , Rangrang Fan , Tong Liu , Wei Jin , Yongtao Liu

{"title":"Enhancement upconversion luminescence of In2O3: Er3+, Yb3+ phosphors by Al3+ ions doping","authors":"Daobin Zhu , Junshan Hu , Keyu Guo , Yuxiang Wu , Changchun Ding , Rangrang Fan , Tong Liu , Wei Jin , Yongtao Liu","doi":"10.1016/j.optmat.2025.117224","DOIUrl":"10.1016/j.optmat.2025.117224","url":null,"abstract":"<div><div>The In2O3: 4 % Er3+, 10 % Yb3+, x % Al3+ (x = 0, 1, 2, 5) phosphor were prepared by high temperature solid phase method. At 980 nm laser excitation, the emission peaks near 552 nm and 661 nm correspond to the 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2 transitions of the Er3+ ion. With the doping of Al3+ ions, the luminescence intensity of the phosphor increased significantly. In addition, the upconversion luminescence intensity is the highest when 2 % Al3+ ions are doped. The mechanism of upconversion luminescence was investigated by power dependence, UV–Vis–NIR absorption spectrum, photoluminescence excitation spectrum and down-conversion luminescence spectrum. In addition, the temperature sensing of phosphor in the temperature range of 298 K–598 K was studied by fluorescence intensity ratio technique. The phosphors showed maximum absolute and relative sensitivity of 0.067 K-1 and 1.13 % K−1, respectively.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117224"},"PeriodicalIF":3.8,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ce3+-doped chalcogenide glass fibre for laser beyond 4 microns wavelength: Glass material-integrity 用于波长超过4微米激光的Ce3+掺杂硫系玻璃纤维：玻璃材料的完整性

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-04 DOI: 10.1016/j.optmat.2025.117219

Shweta Chahal , Boyu Xiao , Jessica Grant , David Furniss , Mark Farries , Sendy Phang , Nigel Neate , Lorelei Robertson , Martin Roe , Emma Barney , Angela B. Seddon

{"title":"Ce3+-doped chalcogenide glass fibre for laser beyond 4 microns wavelength: Glass material-integrity","authors":"Shweta Chahal , Boyu Xiao , Jessica Grant , David Furniss , Mark Farries , Sendy Phang , Nigel Neate , Lorelei Robertson , Martin Roe , Emma Barney , Angela B. Seddon","doi":"10.1016/j.optmat.2025.117219","DOIUrl":"10.1016/j.optmat.2025.117219","url":null,"abstract":"<div><div>The 4-μm wavelength barrier encountered for mid-infrared fibre lasing based on heavy metal fluoride glasses has been overcome. We reported, in 2021, the first continuous wave, mid-infrared fibre laser operating beyond 4 μm at room temperature in a fibre with a Ce3+-doped selenide-chalcogenide core. Defects, such as crystallites in the core glass, could cause unwanted light-scattering, diminishing fibre laser efficiency. It is important to identify such optical loss mechanisms and eradicate them. Here, we report on investigating the material nano-structure of a chalcogenide-glass lasing fibre which exhibits 7 mW laser power output; the fibre has a Ce3+-doped core (8.5 μm diameter), concentrically surrounded by an inner- and outer-cladding, where both cladding-glasses are nominally the same composition. High resolution transmission electron microscopy and electron diffraction show that the core, inner-cladding and outer-cladding of the lasing fibre are internally nano-crystallite-free and amorphous. However, the external outer surface of the last 10 m of fibre drawn, of the total 100 m, contains monoclinic GeSe2 crystallites adjacent to discrete, small (<0.5 mm) wrinkled defects. The final length of fibre is drawn from the final part of the glass fibreoptic preform. The glass preform has as its outermost component an extruded chalcogenide glass tube. It is the last part of the tube which spends the longest time at high temperature inside the extruder during tube manufacture, encouraging heterogeneous nucleation at the tube outer-surface in contact with the extruder. These heterogeneous nuclei subsequently nucleate crystal growth during fibre-drawing in the outermost fibre surface.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117219"},"PeriodicalIF":3.8,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermal-enhanced upconversion luminescence and optical temperature sensing properties based on the Stark sublevels of Er3+ ion in CaGdGaO4:Yb3+,Er3+ 基于CaGdGaO4:Yb3+，Er3+中Er3+离子Stark亚能级的热增强上转换发光和光学感温特性

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-03 DOI: 10.1016/j.optmat.2025.117221

Jiaqi Zhao, Hong Wang, Ruiyang Wang, Qingyun Liu, Yao Fu, Mingming Xing, Ying Tian

{"title":"Thermal-enhanced upconversion luminescence and optical temperature sensing properties based on the Stark sublevels of Er3+ ion in CaGdGaO4:Yb3+,Er3+","authors":"Jiaqi Zhao, Hong Wang, Ruiyang Wang, Qingyun Liu, Yao Fu, Mingming Xing, Ying Tian","doi":"10.1016/j.optmat.2025.117221","DOIUrl":"10.1016/j.optmat.2025.117221","url":null,"abstract":"<div><div>Accurate optical thermometry with thermally enhanced fluorescence is urgently desired for non-invasive and high sensitivity temperature determination in high temperature operating environment. Here we explore thermally enhanced upconversion luminescence (UCL) and thermal sensing properties of Er3+/Yb3+ doped CaGdGaO4 (CGGO) phosphors under near-infrared excitation. The UCL spectra exhibit multiple sharp peaks from 2H11/2, 4S3/2, and 4F9/2 levels of Er3+ ions, arising from the electronic transitions between crystal-field Stark sublevels. The emission color of samples is tuned from green to red successfully by introducing Yb3+ dopants and adjusting different excitation wavelengths. The UCL intensity is greatly enhanced with the increase of temperature, which benefits from the thermally enhanced phonon-assisted effect. By using the fluorescence intensity ratio technique, temperature sensing performances are evaluated based on thermally coupled energy levels (TCELs) involving Stark sublevels of Er3+ over a wide temperature range of 303–573 K. The maximum relative sensitivity of 2H11/2(1) and 4S3/2(2) levels reaches up to 1.55 % K−1 at 303 K, which is higher than that of the traditional TCELs of 2H11/2/4S3/2. The optical thermometer CGGO:Er3+,Yb3+ shows a high repeatability of 99 % and minimum temperature resolution of 0.28 K. Our findings demonstrate that CGGO:Yb3+,Er3+ phosphors with thermal enhancement UCL can be used as candidates for non-contact and high sensitivity optical thermometry.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117221"},"PeriodicalIF":3.8,"publicationDate":"2025-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144230649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cr2C MXene quantum dots for selective detection of mercury ions 用于选择性检测汞离子的Cr2C MXene量子点

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-02 DOI: 10.1016/j.optmat.2025.117218

Madhushree R, Kalathiparambil Rajendra Pai Sunajadevi, Dephan Pinheiro

{"title":"Cr2C MXene quantum dots for selective detection of mercury ions","authors":"Madhushree R, Kalathiparambil Rajendra Pai Sunajadevi, Dephan Pinheiro","doi":"10.1016/j.optmat.2025.117218","DOIUrl":"10.1016/j.optmat.2025.117218","url":null,"abstract":"<div><div>Mercury (Hg), a highly toxic environmental contaminant that presents significant ecological and health risks, even at low concentrations. There is an urgent need for precise and sensitive methods for detecting Hg2+ ions in the environment. In recent years, a new class of 2D layered materials, MXene, has gained enormous attention due to their unique properties, such as high surface area, oxidation resistance, thermal and chemical stability, electrical and thermal conductivity. This study presents the synthesis and characterization of Cr2C MXene quantum dots (MQDs) derived from Cr2CTx nanolayered MXene sheets via the probe-sonication method. The Cr2C-MQDs were characterized using XRD, FTIR, SEM-EDS mapping, and Zeta potential analysis. The vibrant green fluorescence material, Cr2C-MQDs, was investigated for Hg2+ detection, which exhibited high selectivity and stability with a limit of detection of 30.7 nM. The sensing mechanism is attributed to the strong affinity of Cr2C MXene quantum dots for Hg2+ ions.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117218"},"PeriodicalIF":3.8,"publicationDate":"2025-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144203516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation on the highly fluorescent IRMOF-3/thiol-ene polymer and its ligand-based composite with 76 % quantum yield 高荧光IRMOF-3/巯基聚合物及其量子产率76%的配体基复合材料的研究

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-02 DOI: 10.1016/j.optmat.2025.117222

Pei Zhang , Mengmeng Li , Yibo Zheng , Linjiao Ren , Zirui Qin , Qingfang Zhang , Rubin Qi , Jitao Zhang , Liying Jiang , Dongke Li

{"title":"Investigation on the highly fluorescent IRMOF-3/thiol-ene polymer and its ligand-based composite with 76 % quantum yield","authors":"Pei Zhang , Mengmeng Li , Yibo Zheng , Linjiao Ren , Zirui Qin , Qingfang Zhang , Rubin Qi , Jitao Zhang , Liying Jiang , Dongke Li","doi":"10.1016/j.optmat.2025.117222","DOIUrl":"10.1016/j.optmat.2025.117222","url":null,"abstract":"<div><div>The isoreticular metal organic frameworks-3 (IRMOF-3)/non-stoichiometric thiol-ene (OSTE) and 2-aminoterephthalic acid (BDC-NH2)/OSTE composites were synthesized via a photo-induced click reaction. Interestingly, through polymerization with OSTE, both the fluorescence lifetime and intensity of IRMOF-3 increased. Moreover, its two lifetimes merged into one, which could be ascribed to the inhibition of the dynamic non-radiative quenching process by the OSTE network. In contrast, the ligand maintained a single lifetime with only minor changes. The dilution effect of the thiol-ene mixed solution could effectively reduce the static photo-induced electron transfer process between the ligand and toluene molecules. After the post-synthetic polymerization (PSP) treatment, the photoluminescence quantum yield (PLQY) of IRMOF-3 was increased from 7.2 % (in toluene) to 42.3 %, and that of the pure BDC-NH2 ligand was significantly enhanced from 1.8 % (in toluene) to 76.0 %. Moreover, when a commercially available 370-nm light-emitting diode (LED) chip was individually encapsulated by the two composites, it could emit intense indigo light. This rapid PSP treatment via the OSTE polymer holds promise for application in other excellent luminescent MOFs.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117222"},"PeriodicalIF":3.8,"publicationDate":"2025-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144222543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spectral characteristics of Nd3+/Yb3+:LuPO4 crystal applied to multi-wavelength emission in 1.0 μm 应用于1.0 μm多波长发射的Nd3+/Yb3+:LuPO4晶体的光谱特性

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-02 DOI: 10.1016/j.optmat.2025.117220

Hua Xu , Lijun Xu , Ziliang Zhu , Qingtang Xu , Jingyao Lu , Shijia Sun

{"title":"Spectral characteristics of Nd3+/Yb3+:LuPO4 crystal applied to multi-wavelength emission in 1.0 μm","authors":"Hua Xu , Lijun Xu , Ziliang Zhu , Qingtang Xu , Jingyao Lu , Shijia Sun","doi":"10.1016/j.optmat.2025.117220","DOIUrl":"10.1016/j.optmat.2025.117220","url":null,"abstract":"<div><div>Exploring new gain media for near-infrared multi-wavelength lasers remains a current research hotspot. In this paper, 0.8 at.% Nd3+ co-doped 0.2 at.% Yb3+:LuPO4 (Nd/Yb:LuPO4) single crystal was prepared for the first time by high-temperature solution method. The corresponding crystal structures, spectroscopic properties and energy transfer mechanism are analyzed in detail. The absorption FWHM near 803 nm were determined to be 9 nm and 10 nm, respectively, indicating that the Nd/Yb:LuPO4 crystal is quite suitable for commercial AlGaAs laser diode pumping. The emission spectral parameters of Nd3+ and Yb3+ ions in the grown crystal were calculated by RM and F-L methods. And the energy transfer process between the 4F3/2 level of Nd3+ and 2F5/2 level of Yb3+ was discussed. The co-doping of Yb3+ and Nd3+ ions successfully achieved the characteristics of multi-wavelength emission, which indicates that Nd/Yb:LuPO4 crystal is a potential candidate for multi-wavelength laser applicable in the 1.0 μm.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117220"},"PeriodicalIF":3.8,"publicationDate":"2025-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144212904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of new potential erbium/promethium Co-doped aluminum tellurite glass in active optical materials 活性光学材料中新型电位铒/钷共掺碲铝玻璃的研究

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-06-01 DOI: 10.1016/j.optmat.2025.117217

Saman Q. Mawlud

{"title":"Investigation of new potential erbium/promethium Co-doped aluminum tellurite glass in active optical materials","authors":"Saman Q. Mawlud","doi":"10.1016/j.optmat.2025.117217","DOIUrl":"10.1016/j.optmat.2025.117217","url":null,"abstract":"<div><div>The possibility of using trivalent erbium/promethium as the active ion in tellurite glass was achieved. Tellurite glass doped with ZnO–Al2O3–Pm2O3–Er2O3 synthesized by the melt-quenching technique. Glasses with varying Er2O3 doped concentrations have been produced in the temperature range of 900 °C. The glassy nature of the synthesized samples is verified by the X-ray diffraction (XRD) pattern. Furthermore, to study the synthesized glasses' spectroscopic properties, the absorption spectra are recorded in the range of 200 nm–1800 nm. The spectroscopic properties of the Er3+/Pm3+ co-doped ions were measured by the Judd-Ofelt theory. The maximum calculated values of Ωλ (λ = 2,4,6) are 6.5712, 2.29534 and 2.91274 for TZEAP2 glasses. The highest value of spectroscopic quality factor 1.3921 is obtained for the sample TZEAP1. The Judd Ofelt parameter for all the prepared glass samples are follows the trends Ω2>Ω4< Ω6. Three emission bands were detected in the visible region for the Er3+/Pm3+ ions doped to tellurite glass under the excitation of at 375 nm. These bands were at approximately around 470 nm, 500 nm and 550 nm from 2F5/2 → 4I15/2, 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 radiative transition, respectively. The highest measured cross sections for the green visible transitions 4S3/2 → 4I15/2 are 1.05X10−20 cm2. The radiative lifetime is also calculated for different Er3+ concentrations. The radiative lifetime of the 4S3/2 → 4I15/2 transition increased with an increase in the Er3+ concentration. A single exponential decay with a maximum lifetime of 1.71396 msec is detected for the TZEAP4 samples.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117217"},"PeriodicalIF":3.8,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144212895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effects of temperature on magneto-optical properties of high terbium fluoro-oxide glass 温度对高铽氟氧化物玻璃磁光性能的影响

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-05-31 DOI: 10.1016/j.optmat.2025.117215

Xiaoxiao Han, Wenpei Hu, Xiaoxin Zheng, Shuo Liu, Jing Ren, Jianzhong Zhang

引用次数: 0

Fabrication of Fe3O4/HAP/Ag as surface-enhanced Raman scattering substrate for detection of antibiotic residues in fish and aquatic ecosystems Fe3O4/HAP/Ag表面增强拉曼散射底物在鱼类和水生生态系统中抗生素残留检测的制备

IF 3.8 3区材料科学

Optical Materials Pub Date : 2025-05-30 DOI: 10.1016/j.optmat.2025.117209

Rui Wu, Yulin Wang, Xi Song, Hairan Zhang

{"title":"Fabrication of Fe3O4/HAP/Ag as surface-enhanced Raman scattering substrate for detection of antibiotic residues in fish and aquatic ecosystems","authors":"Rui Wu, Yulin Wang, Xi Song, Hairan Zhang","doi":"10.1016/j.optmat.2025.117209","DOIUrl":"10.1016/j.optmat.2025.117209","url":null,"abstract":"<div><div>Antibiotic residues in food and environment pose a serious threat to human's health and ecological system. Therefore, it is crucial and urgent challenge to fabricate Surface-Enhanced Raman Scattering (SERS) substrate with high sensitivity to detect pesticide residues. A multifunctional three-layer Fe3O4/HAP/Ag nanoparticle system was fabricated as an active SERS substrate. The active substrate was characterized by comprehensive techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), Scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), mapping, and X-ray photoelectron spectroscopy (XPS). The FHA was not only employed to detect ciprofloxacin (CIP) solution by SERS but also it was successfully applied for detection of CIP in fish body. It showed excellent linear relationship in the range of 1.0 × 10−8- 1.0 × 10−3 mol/L for CIP, with low limit of detection (7.5 × 10−9 mol/L), satisfactory enhancement factor, stability, and repeatability. A novel approach for detecting analyte in animal's body based on SERS was developed. It could be potential candidate to rapid detection of analyte for animal and it will open new perspective in application of SERS in vivo.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"166 ","pages":"Article 117209"},"PeriodicalIF":3.8,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144203518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0