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Bilayer structure niobium oxide/titanium oxide film with improved electrochromism
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-29 DOI: 10.1016/j.optmat.2024.116505
Hui Wang , Lei Chen , Xiangfei Wei , Hongquan Zhao , Bo Zhang
{"title":"Bilayer structure niobium oxide/titanium oxide film with improved electrochromism","authors":"Hui Wang ,&nbsp;Lei Chen ,&nbsp;Xiangfei Wei ,&nbsp;Hongquan Zhao ,&nbsp;Bo Zhang","doi":"10.1016/j.optmat.2024.116505","DOIUrl":"10.1016/j.optmat.2024.116505","url":null,"abstract":"<div><div>A combination of simple hydrothermal and electrodeposition techniques is proposed for the synthesis of niobium oxide/titanium oxide (Nb<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub>) bilayer films, which can improve the electrochromic performance for niobium oxide (Nb<sub>2</sub>O<sub>5</sub>)-based materials, including response time, cycle stability, coloration efficiency and optical properties. The structure, morphology, electrochemical and electrochromic performance of the Nb<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub> film are improved via the systematic study of TiO<sub>2</sub> electrodeposition period. X-ray diffraction shows that TiO<sub>2</sub> is amorphous and Nb<sub>2</sub>O<sub>5</sub> is orthogonal. The vibration modes and structural properties are studied by the Raman spectroscopy. The chemical compositions, elemental states, and surface features are studied via the X-ray photoelectron spectroscopy. The effects of TiO<sub>2</sub> electrodeposition periods on the morphology of Nb<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub> films are analyzed by the field emission scanning electron microscopy. These results show that NTO-20 film has high efficiency Li<sup>+</sup> reaction kinetics, which shows remarkable electrochromic properties, including wide transmittance modulation (76.94 %), good reversibility (98.15 %), large coloration efficiency (91.6 cm<sup>2</sup>/C) and high cycle stability. For the electrochromic device with NTO-20 film, it shows conspicuous transmittance modulation (69.1 %) and excellent cycle stability. Thus, Nb<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub> bilayer films have important research value in the field of electrochromism.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116505"},"PeriodicalIF":3.8,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of physical properties of Mn doped lead phosphate glasses
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-29 DOI: 10.1016/j.optmat.2024.116503
Zeineb Seboui , Sana Hraiech , Ahmed Hichem Hamzaoui
{"title":"Investigation of physical properties of Mn doped lead phosphate glasses","authors":"Zeineb Seboui ,&nbsp;Sana Hraiech ,&nbsp;Ahmed Hichem Hamzaoui","doi":"10.1016/j.optmat.2024.116503","DOIUrl":"10.1016/j.optmat.2024.116503","url":null,"abstract":"<div><div>Mn doped lead phosphate glasses (MnLPG) as (40-x)%P<sub>2</sub>O<sub>5</sub>-40 % PbO-16.5%Na<sub>2</sub>O-3.5%Al<sub>2</sub>O<sub>3</sub>-xMnO<sub>2</sub> (x = 0, 1, 2, 3 and 4 %) matrix system are prepared by the melt-quenching method. The physical properties have been performed using several techniques such as X-Ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Fourier Transform InfraRed spectroscopy (FTIR), Raman spectroscopy, UV–Visible properties, photoluminescence (PL) and EPR (electron paramagnetic resonance). XRD confirms the amorphous character of the glasses. DSC reveals an improvement of the glass transition temperature T<sub>g</sub> values by increasing the density ρ and the oxygen packing density OPD and decreasing the molar volume V<sub>m</sub> which leads to have a network glass more compact and tightly packed and reticulates the phosphate groups. The Infrared and Raman results show an opposite behaviour with a broken of the phosphate structure and the disruption of the P–O–P linkages. The optical spectra present absorption bands characteristic of Mn<sup>3+</sup> and Mn<sup>2+</sup> ions octahedral transition. Mott and Davis model presents a decrease of the band gap energy winth the MnO<sub>2</sub> addition. The Urbach energy <em>ΔE</em><sub><em>urb</em></sub> shows an increase with increase of manganese amount which is related to the increase of the structural disorder degree as the rate of manganese increases. The EPR spectrum of the 4 % Mn doped glass is characterized by a strong resonance signal centered at <em>g</em> near 2.0 another weak signal at <em>g</em>∼4.3 with no hyperfine structure. PL spectra exhibit emission bands corresponded to the oxygen defects presented in the glass and the appearance of a new band assigned to the Mn<sup>2+</sup> ions as high as Mn increases.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116503"},"PeriodicalIF":3.8,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring optical, electronic and NLO properties: Growth and characterization of rubidium hydrogen (+)- tartrate crystals
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-27 DOI: 10.1016/j.optmat.2024.116487
B. Praveena , T. Sivanesan , S. Elangovan , R. Ranjani , Kalpana Sukumar , E. Mohanapriya , N. Kanagathara , J. Janczak
{"title":"Exploring optical, electronic and NLO properties: Growth and characterization of rubidium hydrogen (+)- tartrate crystals","authors":"B. Praveena ,&nbsp;T. Sivanesan ,&nbsp;S. Elangovan ,&nbsp;R. Ranjani ,&nbsp;Kalpana Sukumar ,&nbsp;E. Mohanapriya ,&nbsp;N. Kanagathara ,&nbsp;J. Janczak","doi":"10.1016/j.optmat.2024.116487","DOIUrl":"10.1016/j.optmat.2024.116487","url":null,"abstract":"<div><div>Rubidium, a highly reactive alkali metal, is used in several research areas, such as electronics for its light-emitting properties, and in making glass, ceramics, and in biomedical studies. Single crystals of Rubidium Hydrogen (+)-Tartrate (RHT) suitable for the X-ray analysis were obtained from water solution. The crystal structure of the RHT crystal was determined using single crystal XRD, revealing an orthorhombic system with a non-centrosymmetric space group, P2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>. The lattice parameters were a = 7.9233 Å, b = 10.9883 Å, and c = 7.6527 Å, with a unit cell volume of 666.272 Å³. The structural vibrations of the RHT compound were analysed using FT-IR and FT-Raman spectroscopy, while NMR provided further insights into its molecular structure. Theoretical investigations at the DFT/RB3LYP/LANL2DZ level were conducted to explore the molecular structure, vibrational spectra, and bonding interactions within the RHT compound's molecular system. Natural Bond Orbital (NBO) analysis of the RHT compound revealed significant charge transfer interactions and stabilization energies, particularly highlighting strong electron donor-acceptor correlations that contribute to the molecule's overall stability. The UV–Vis and HOMO-LUMO calculations were performed in the gas phase. Optical conductivity studies have been performed. The broad spectral curve in the photoluminescence spectrum reflects the optical effects and showed a significant intense peak at 281.22 nm and a moderately intense peak at 395.9 nm. First order hyperpolarizability studies reveals that nonlinear optical efficiency is 1.06 times better than urea and 58.19 times than KDP. Furthermore, Third Harmonic Generation (THG) studies using the Z-scan technique were also conducted to investigate the nonlinear properties.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116487"},"PeriodicalIF":3.8,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of high-k La2O3 interfacial oxide layer on the performance of GaN based Schottky barrier ultraviolet-B and A photodetection sensors
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-26 DOI: 10.1016/j.optmat.2024.116499
Nallabala Nanda Kumar Reddy , K Vamsidhar Reddy , S. Kaleemulla , Shivani Sharma , V. Manjunath , Suresh Kumar , G. Gopi Krishana , P. Rosaiah , N. Ravi , Venkata Krishnaiah Kummara , Sunil Singh Kushvaha , Vasudeva Reddy Minnam Reddy , Yusuf Siraj Usmani
{"title":"Influence of high-k La2O3 interfacial oxide layer on the performance of GaN based Schottky barrier ultraviolet-B and A photodetection sensors","authors":"Nallabala Nanda Kumar Reddy ,&nbsp;K Vamsidhar Reddy ,&nbsp;S. Kaleemulla ,&nbsp;Shivani Sharma ,&nbsp;V. Manjunath ,&nbsp;Suresh Kumar ,&nbsp;G. Gopi Krishana ,&nbsp;P. Rosaiah ,&nbsp;N. Ravi ,&nbsp;Venkata Krishnaiah Kummara ,&nbsp;Sunil Singh Kushvaha ,&nbsp;Vasudeva Reddy Minnam Reddy ,&nbsp;Yusuf Siraj Usmani","doi":"10.1016/j.optmat.2024.116499","DOIUrl":"10.1016/j.optmat.2024.116499","url":null,"abstract":"<div><div>GaN based metal-semiconductor-metal (MSM) type Schottky heterojunction-based ultraviolet (UV) photodetectors (PDs) have already proven as an efficient candidate for photodetection applications. However, in real time applications, GaN based MSM type UV PD device display higher dark current, weak signal detection and required external bias are seriously limiting their usage. Therefore, self-powered interdigitated electrode type Cr/Cu/La<sub>2</sub>O<sub>3</sub>/GaN: MIS (metal-insulator-semiconductor) heterojunction visible blind UV PD has been fabricated and studied in UV-B and A region. The structure, morphology, chemical and optical parameters of La<sub>2</sub>O<sub>3</sub> films were evaluated using GIXRD, AFM, XPS and UV–Vis techniques, respectively. The reported interdigitated Cr/Cu/La<sub>2</sub>O<sub>3</sub>/GaN: MIS UV PD device yielded a higher Schottky barrier height (SBH) of 0.95 eV (dark) and 0.89 eV (360 nm) indicating the formation of higher potential barrier. At an applied bias of 0 V, the fabricated GaN MIS PD yielded an UV to visible rejection ratio (R<sub>360</sub>/R<sub>400</sub>) of 1.62 × 10<sup>2</sup>. In UV-A region (at 0 V of 360 nm), the fabricated Cr/Cu/La<sub>2</sub>O<sub>3</sub>/GaN: MIS UV PD device exhibited a peak responsivity of 28.9 mAW<sup>−1</sup>, D∗ of 3.57 × 10<sup>12</sup> Jones and EQE of 19.2 %. On the other hand, in UV-B region (at 0 V of 310 nm) the MIS UV PD device exhibited a peak responsivity of 34.4 mAW<sup>−1</sup>, D∗ of 4.2 × 10<sup>12</sup> Jones and EQE of 22.7 %. During 360 nm illumination (at 0 V), the temporal response measurements of GaN UV PD device yielded the best rise/fall times of 70 ms/141 ms. This work validates the fact that the high-<em>k</em> La<sub>2</sub>O<sub>3</sub> thin film as an interfacial oxide layer at the metal/GaN interface provides a novel solution for the photo detection field in the self-powered mode i.e., without any external bias.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116499"},"PeriodicalIF":3.8,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental production and investigations of a new Cu–Al–Fe Schottky diode 新型铜-铝-铁肖特基二极管的实验制作与研究
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-26 DOI: 10.1016/j.optmat.2024.116498
E. Aldirmaz , M. Güler , E. Güler
{"title":"Experimental production and investigations of a new Cu–Al–Fe Schottky diode","authors":"E. Aldirmaz ,&nbsp;M. Güler ,&nbsp;E. Güler","doi":"10.1016/j.optmat.2024.116498","DOIUrl":"10.1016/j.optmat.2024.116498","url":null,"abstract":"<div><div>The structural, electrical, and photoconductivity features of a metal-semiconductor diode were investigated in this work. A new diode with a Cu–Al–Fe/p-Si/Al structure was produced by coating a Cu–Al–Fe-shaped memory alloy film on p-Si. The microstructural and thermal characteristics of this produced diode were analyzed with scanning electron microscopy (SEM) and differential scanning calorimetry (DSC) where the electrical performance was clarified from Current-Voltage (I–V), Capacity-Voltage (C–V), Conductivity-Voltage (G-V), Capacity-time (C-t), and Current-time (I-t) measurements. In addition, the diode's light sensitivity and photo response properties were analyzed. Due to its structural and electrical properties, the generated diode can be used in optoelectronic applications as a photodiode or optical sensor.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116498"},"PeriodicalIF":3.8,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142724055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Temperature dependence of photoluminescence kinetics, scintillation properties, and coincidence time resolution of Mo co-doped Y1.5Gd1.5Al2Ga3O12:Ce (Mo = 0, 300, 600 ppm) multicomponent garnet crystals
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-26 DOI: 10.1016/j.optmat.2024.116494
Warut Chewpraditkul , Ongsa Sakthong , Weerapong Chewpraditkul , Masao Yoshino , Takahiko Horiai , Shunsuke Kurosawa , Romana Kucerkova , Alena Beitlerova , Tomasz Szczesniak , Martyna Grodzicka-Kobyłka , Martin Nikl , Akira Yoshikawa
{"title":"Temperature dependence of photoluminescence kinetics, scintillation properties, and coincidence time resolution of Mo co-doped Y1.5Gd1.5Al2Ga3O12:Ce (Mo = 0, 300, 600 ppm) multicomponent garnet crystals","authors":"Warut Chewpraditkul ,&nbsp;Ongsa Sakthong ,&nbsp;Weerapong Chewpraditkul ,&nbsp;Masao Yoshino ,&nbsp;Takahiko Horiai ,&nbsp;Shunsuke Kurosawa ,&nbsp;Romana Kucerkova ,&nbsp;Alena Beitlerova ,&nbsp;Tomasz Szczesniak ,&nbsp;Martyna Grodzicka-Kobyłka ,&nbsp;Martin Nikl ,&nbsp;Akira Yoshikawa","doi":"10.1016/j.optmat.2024.116494","DOIUrl":"10.1016/j.optmat.2024.116494","url":null,"abstract":"<div><div>Luminescence and scintillation properties of Mo co-doped Y<sub>1.5</sub>Gd<sub>1.5</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>:Ce,Mo (Mo = 0, 300, 600 ppm) multicomponent garnet crystals grown by the micro-pulling-down method were investigated. To investigate temperature stability, temperature dependence of photoluminescence decay time was measured from 77 to 487 K and thermal activation energy was determined. Y<sub>1.5</sub>Gd<sub>1.5</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>:Ce,Mo (300, 600 ppm) samples showed faster scintillation decay time with a similar LY value compared to Mo-free Y<sub>1.5</sub>Gd<sub>1.5</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>:Ce one. Y<sub>1.5</sub>Gd<sub>1.5</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>:Ce<strong>,</strong>Mo (600 ppm) showed a light yield value of 34,300 photons/MeV along with fast scintillation decay times of 45.2 ns (55 %) +153 ns (45 %) and time resolution of 313 ps. Radioluminescence and afterglow signal were also measured at RT and discussed.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116494"},"PeriodicalIF":3.8,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light control using a double-stacked liquid crystal cell with enhanced viewing angle–blocking performance 利用双层液晶单元进行光控,增强视角遮挡性能
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-25 DOI: 10.1016/j.optmat.2024.116495
Tae-Hoon Choi , Hyun Wook Lee , Jong-Min Baek , Seung-Won Oh
{"title":"Light control using a double-stacked liquid crystal cell with enhanced viewing angle–blocking performance","authors":"Tae-Hoon Choi ,&nbsp;Hyun Wook Lee ,&nbsp;Jong-Min Baek ,&nbsp;Seung-Won Oh","doi":"10.1016/j.optmat.2024.116495","DOIUrl":"10.1016/j.optmat.2024.116495","url":null,"abstract":"<div><div>In the future, there will be technological challenges between providing entertainment to passengers and eliminating driver distractions to ensure safety. Viewing angle control technologies for automotive display panels depending on each mode are required to integrate and provide both entertainment and advanced driver assistance system functions because watching videos while driving is regulated in most countries. In automotive display panels, unique electro-optical characteristics are required to control blocking or transmission only from the driver's direction while always being well observed from the passenger's direction. In this study, we developed a viewing angle control technology using double-stacked twisted nematic liquid crystal (TN-LC) films with excellent light-blocking performance only in the driver's direction over wide polar angle ranges in the privacy mode. By configuring the two TN-LC films in ordinary-ray mode and the other in the extraordinary-ray mode, the light could be completely blocked in the privacy mode, whereas it remained well transmitted in the normal mode in a specific left direction. Moreover, using double-stacked TN-LC films, light leakage at high polar angles in the privacy mode can be completely eliminated even without an optical compensation film, which is typically used to eliminate light leakage at high polar angles. Electro-optical films based on polarization optics are potential candidates for accelerating the growth of infotainment in self-driving cars.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116495"},"PeriodicalIF":3.8,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142724052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of a vitamin B6-tetrazole hydrazone as a fluorescence probe for selective detection of Cd2+ and Ga3+ ions 维生素 B6-四唑腙的合成与表征--用作选择性检测 Cd2+ 和 Ga3+ 离子的荧光探针
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-25 DOI: 10.1016/j.optmat.2024.116493
Zavalishin M.N, Maltseva M.A, Osokin V.S, Aleksandriiskii V.V, Petrova U.A, Knyazeva A.A, Eroshin A.V, Zhabanov Yu.A, Gamov G.A
{"title":"Synthesis and characterization of a vitamin B6-tetrazole hydrazone as a fluorescence probe for selective detection of Cd2+ and Ga3+ ions","authors":"Zavalishin M.N,&nbsp;Maltseva M.A,&nbsp;Osokin V.S,&nbsp;Aleksandriiskii V.V,&nbsp;Petrova U.A,&nbsp;Knyazeva A.A,&nbsp;Eroshin A.V,&nbsp;Zhabanov Yu.A,&nbsp;Gamov G.A","doi":"10.1016/j.optmat.2024.116493","DOIUrl":"10.1016/j.optmat.2024.116493","url":null,"abstract":"<div><div>A simple selective fluorescence probe for cadmium(II) and gallium(III) ions was designed and prepared by a reaction of hydrazone formation between pyridoxal-5′-phosphate and 5-hydrazinyl-<em>1H</em>-tetrazole. The probe shows an enhanced blue fluorescence in the presence of Cd<sup>2+</sup> ions and a yellow-green fluorescence in the presence of Ga<sup>3+</sup> ions in aqueous DMSO. The conditional stability constants and stoichiometry of the Cd<sup>2+</sup> and Ga<sup>3+</sup> complexes were determined using the maximum likelihood method. Gallium(III) ions form two complexes of different structures with probe in solution. The DFT quantum chemical calculations were performed for obtaining molecular structures of probe <strong>1</strong> and its complexes with Ga<sup>3+</sup> and Cd<sup>2+</sup>. Simulation of electronic absorption spectra and NMR spectra by TDDFT and GIAO methods allowed to determine the structures, which was obtained. The probe demonstrated a low detection limit of 0.19 μM for Cd<sup>2+</sup> and 0.97 μM for Ga<sup>3+</sup>, making it suitable for water analysis. This research offers important insights into the design and enhancement of fluorescence probes for the selective detection of metal ions.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116493"},"PeriodicalIF":3.8,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142724056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modulation of optical, mechanical and radiation shielding characteristics in TeO₂-B2O3–BaO–CeO₂ glasses with varying CeO₂ level
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-24 DOI: 10.1016/j.optmat.2024.116492
M.I. Sayyed
{"title":"Modulation of optical, mechanical and radiation shielding characteristics in TeO₂-B2O3–BaO–CeO₂ glasses with varying CeO₂ level","authors":"M.I. Sayyed","doi":"10.1016/j.optmat.2024.116492","DOIUrl":"10.1016/j.optmat.2024.116492","url":null,"abstract":"<div><div>The TeO₂-BaO-CeO₂-B₂O₃ glass samples are synthesized using the melt quenching technique in order to examine the impact of varying concentrations of CeO₂ on their physical, mechanical, optical, and gamma ray shielding capabilities. With an increase in the CeO₂ concentration, the density (ρ) of the glasses increased, so the glass structure became more compact, as shown by the drop in molar volume (V<sub>m</sub>) from 27.895 to 27.554 cm³/mol and the reduction in the average distance between boron atoms (&lt;d<sub>B-B</sub>&gt;) from 4.045 × 10⁻⁸ to 3.919 × 10⁻⁸ cm. The Young's modulus (E) increases from 93.209 to 93.527 GPa, the bulk modulus (B) increased from 73.763 to 74.236 GPa, the shear modulus (G) increased from 38.497 to 38.609 GPa, and the longitudinal modulus (L) increased from 125.093 to 125.714 GPa. The absorption edge shifts towards the longer wavelength side as the amount of CeO₂ increased, changing from 336 nm to 527 nm. This shift was followed by a drop in the energy difference between the valence band and the conduction band, known as the band gap energy (E<sub>g</sub>), which decreased from 3.082 to 1.574 eV.The radiation shielding properties for the prepared glasses were investigated using Phy-X software in the energy range of 0.015–15 MeV. The increase of CeO₂ content showed a direct relationship with the radiation shielding characteristics.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116492"},"PeriodicalIF":3.8,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sol-gel prepared TiO2 – PMMA composite thin film for high laser induced damage threshold optical coating 用于高激光诱导损伤阈值光学镀膜的溶胶-凝胶制备型二氧化钛-PMMA 复合薄膜
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2024-11-23 DOI: 10.1016/j.optmat.2024.116486
Suparna Pal , Rajiv Kamparath , V.V.V. Subrahmanyam , Neha Sharma , Y.P. Kumar , S.K. Tiwari , Sharad Karwal , P. Ram Sankar , N.S. Benerji
{"title":"Sol-gel prepared TiO2 – PMMA composite thin film for high laser induced damage threshold optical coating","authors":"Suparna Pal ,&nbsp;Rajiv Kamparath ,&nbsp;V.V.V. Subrahmanyam ,&nbsp;Neha Sharma ,&nbsp;Y.P. Kumar ,&nbsp;S.K. Tiwari ,&nbsp;Sharad Karwal ,&nbsp;P. Ram Sankar ,&nbsp;N.S. Benerji","doi":"10.1016/j.optmat.2024.116486","DOIUrl":"10.1016/j.optmat.2024.116486","url":null,"abstract":"<div><div>We report high-quality TiO<sub>2</sub> and TiO<sub>2</sub>-PMMA composite thin films prepared by sol-gel process for application in optical coatings. The addition of PMMA to the TiO<sub>2</sub> sol exhibits significant improvements in the optical quality and morphology of the TiO<sub>2</sub> films. A comparison between TiO<sub>2</sub> and TiO<sub>2</sub>-PMMA composite thin films is described with respect to various optical properties and their application in optical coatings for high-energy laser applications. The refractive index and bandgap of TiO<sub>2</sub> are tailored by controlling the TiO<sub>2</sub> sol: PMMA volume ratio. The refractive index varies in the range of 2.4 to 2.0 at 550 nm by controlling the TiO<sub>2</sub>: PMMA composition. Incorporation of PMMA leads to reduction in absorption from 1000 ppm to 20 ppm in the composite films, which is attributed to passivation of defect states. In addition, incorporation of PMMA into the TiO<sub>2</sub> sol results in the filling of voids and a significant improvement in surface figure (from λ/6 to λ/10) of the composite films. These properties collectively enhance the laser induced damage threshold (LIDT) of 2.1 J/cm<sup>2</sup> for TiO<sub>2</sub> film to 17 J/cm<sup>2</sup> of the TiO<sub>2</sub>-PMMA composite film. LIDT mechanisms in the films are discussed. Demonstration of antireflection coatings (AR) as well as high reflection coatings (HR) exhibiting wavelength tuning of the reflection peak using TiO<sub>2</sub>-PMMA composite thin films, is presented. An AR coating @1200 nm with 11.5 J/cm<sup>2</sup> LIDT is reported.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"158 ","pages":"Article 116486"},"PeriodicalIF":3.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142724060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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