Optical Materials最新文献

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Processing and characterisation of polystyrene coatings and free-standing plates 聚苯乙烯涂层和独立板的加工和表征
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-14 DOI: 10.1016/j.optmat.2025.117322
L.J.B. Erasmus , D. Poelman , P.F. Smet , J.J. Terblans , H.C. Swart
{"title":"Processing and characterisation of polystyrene coatings and free-standing plates","authors":"L.J.B. Erasmus ,&nbsp;D. Poelman ,&nbsp;P.F. Smet ,&nbsp;J.J. Terblans ,&nbsp;H.C. Swart","doi":"10.1016/j.optmat.2025.117322","DOIUrl":"10.1016/j.optmat.2025.117322","url":null,"abstract":"<div><div>In this study, polystyrene (PS) coatings were prepared on quartz substrates by using a dip coating method. The refractive index, dispersion, and thickness of the coatings were determined using an extended Swanepoel's method. This method accounted for coatings coated on the front and back sides of the substrate and thickness variation across the coating. By adjusting the solution's molarity, the substrate's rate of withdrawal, and the number of coating process iterations, the impact on the coating's thickness was investigated. These findings were used to create an empirical model that allowed the thickness of the final coatings to be calculated using the experimental parameters. A quartz slide (49 mm × 49 mm x 1 mm) was coated with a 6.1 (±0.2) μm layer of PS. The thickness was verified using an independent method which demonstrated the validity of the empirical relation. Free-standing PS plates were also produced and characterised. These plates were made utilising a purposely made cast using the solution casting method. The PS samples produced have high transmittance in the UV, visible, and near-infrared wavelength ranges with an average absorption coefficient of 1.7 ± 0.9 cm<sup>−1</sup>. Because of this, they are well suited for use in some optical applications.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117322"},"PeriodicalIF":3.8,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visible light photoresistance and response time of samarium doped zinc oxide thin films grown by pulsed laser deposition 脉冲激光沉积法制备掺钐氧化锌薄膜的可见光电阻和响应时间
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-14 DOI: 10.1016/j.optmat.2025.117307
Yu-Tso Liao , Cheng-Hui Li , Jyun-Han Chen , Wei-Lun Wei , Shi-Yu Liu , Hsiang-Lin Liu , Bi-Hsuan Lin , Ming-Yau Chern , Fang-Yuh Lo
{"title":"Visible light photoresistance and response time of samarium doped zinc oxide thin films grown by pulsed laser deposition","authors":"Yu-Tso Liao ,&nbsp;Cheng-Hui Li ,&nbsp;Jyun-Han Chen ,&nbsp;Wei-Lun Wei ,&nbsp;Shi-Yu Liu ,&nbsp;Hsiang-Lin Liu ,&nbsp;Bi-Hsuan Lin ,&nbsp;Ming-Yau Chern ,&nbsp;Fang-Yuh Lo","doi":"10.1016/j.optmat.2025.117307","DOIUrl":"10.1016/j.optmat.2025.117307","url":null,"abstract":"<div><div>Samarium doped zinc oxide (Sm:ZnO) thin films were fabricated on <em>c</em>-oriented sapphire substrates by pulsed-laser deposition with Sm dopant from 0 to 10 at.%. X-ray diffraction patterns, X-ray fluorescence mapping, and X-ray absorption near-edge structure spectra indicated uniform incorporation of Sm into ZnO lattice without secondary phase. With increasing Sm concentration, zinc vacancy or oxygen interstitial is formed to maintain electrical neutrality, which are identified by photoluminescence spectroscopy. The increasing defect concentration and decreasing exciton binding energy enhanced the photoresistance response in visible regime, where the absolute value of normalized resistance response was between 2 % and 8.79 % by 1 mW blue laser (wavelength of 450 nm) illumination for Sm:ZnO thin films. Time-dependent photoresistance measurements revealed two response times. The shorter response time, around 1.2–26.7 s, is contributed by the free electron-hole pair generation/recombination and the response of carriers trapped in deep level defects. The longer response time, around 76–858 s, is contributed by the captured oxygen on the thin film surface. Overall, the 5 at.% Sm:ZnO thin film is the best for photodetection applications due to its high photoresistance response and short response time.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117307"},"PeriodicalIF":3.8,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Luminescence of CaAl2O4:Eu2+ phosphors for high-sensitivity optical thermometry and enhanced cathodoluminescence with carbon dots 高灵敏度光学测温用CaAl2O4:Eu2+荧光粉的发光及碳点增强阴极发光
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-13 DOI: 10.1016/j.optmat.2025.117316
Su-Hua Yang, Chih-Chieh Ho, Yi-Yan Tsai, Shun-Ming Liao
{"title":"Luminescence of CaAl2O4:Eu2+ phosphors for high-sensitivity optical thermometry and enhanced cathodoluminescence with carbon dots","authors":"Su-Hua Yang,&nbsp;Chih-Chieh Ho,&nbsp;Yi-Yan Tsai,&nbsp;Shun-Ming Liao","doi":"10.1016/j.optmat.2025.117316","DOIUrl":"10.1016/j.optmat.2025.117316","url":null,"abstract":"<div><div>This study investigated the crystalline phases and functional properties of CaAl<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup> phosphors synthesized via the sol-gel method, with a focus on applications in optical thermometry and cathodoluminescence (CL) devices. During phosphor synthesis, heat treatment facilitated the formation of the primary CaAl<sub>2</sub>O<sub>4</sub> phase; however, intermediate phases, such as CaAl<sub>4</sub>O<sub>7</sub> and Ca<sub>12</sub>Al<sub>14</sub>O<sub>33</sub> were also produced. These miscellaneous phases gradually diminished with increasing synthesis temperature. A nearly single-phase monoclinic CaAl<sub>2</sub>O<sub>4</sub> phosphor was obtained at 1400 °C. The critical energy transfer distance between Eu<sup>2+</sup> ions was calculated to be 17.83 Å, with shorter Eu<sup>2+</sup>-Eu<sup>2+</sup> separations leading to dipole-dipole interactions that decreased photoluminescence (PL) intensity. The CaAl<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup> exhibited excellent thermometric sensitivity, achieving an absolute sensitivity of 7.91 × 10<sup>−3</sup> K<sup>−1</sup> and a relative sensitivity of 2.02 × 10<sup>−2</sup> K<sup>−1</sup> at 383 K. Furthermore, carbon coating suppressed the PL intensity but enhanced the CL intensity by 1.74-fold compared to the uncoated phosphor.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117316"},"PeriodicalIF":3.8,"publicationDate":"2025-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Infrared dielectric function of photochromic thiazolothiazole-embedded polymer 光致变色噻唑噻唑包埋聚合物的红外介电功能
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-13 DOI: 10.1016/j.optmat.2025.117290
Nuren Z. Shuchi , Tyler J. Adams , Naz F. Tumpa , Dustin Louisos , Glenn D. Boreman , Michael G. Walter , Tino Hofmann
{"title":"Infrared dielectric function of photochromic thiazolothiazole-embedded polymer","authors":"Nuren Z. Shuchi ,&nbsp;Tyler J. Adams ,&nbsp;Naz F. Tumpa ,&nbsp;Dustin Louisos ,&nbsp;Glenn D. Boreman ,&nbsp;Michael G. Walter ,&nbsp;Tino Hofmann","doi":"10.1016/j.optmat.2025.117290","DOIUrl":"10.1016/j.optmat.2025.117290","url":null,"abstract":"<div><div>Optical technologies that offer dynamic spectral control have been becoming more prevalent in recent years. Driven by this increased demand for tunable optical devices, substantial research efforts have been dedicated to the development of novel photo-responsive materials. In recent years, photochromic thiazolo[5,4-d]thiazole (TTz)-embedded polymers has emerged as promising candidate for technologies ranging from optical recording systems, tunable metasurfaces, to tinted lenses and smart windows. To effectively design, fabricate, and optimize tunable optical devices incorporating photochromic thiazolothiazole-embedded polymers, an accurate understanding of their complex dielectric function is fundamental to contemporary research. In this work, the infrared dielectric function of photochromic dipyridinium thiazolo[5,4-d]thiazole embedded in polymer is reported. Bulk TTz-embedded polymer samples were prepared by drop casting and dehydration in room temperature. The samples were investigated using spectroscopic ellipsometry in the infrared spectral range from 500 cm<sup>−1</sup> to 1800 cm<sup>−1</sup> before and after photochromism induced by a 405 nm diode laser. The model dielectric functions of the thiazolothiazole-embedded polymer film for its TTz<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span> (unirradiated) and TTz<sup>0</sup> (irradiated) states are composed of a series of Lorentz oscillators in the measured spectral range. A comparison of the obtained complex dielectric functions for the TTz<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span> and TTz<sup>0</sup> states shows that the oscillators located in the spectral ranges 500 cm<sup>−1</sup>–700 cm<sup>−1</sup>, 1300 cm<sup>−1</sup>–1400 cm<sup>−1</sup>, and 1500 cm<sup>−1</sup>–1700 cm<sup>−1</sup> change in both amplitude and resonant frequency upon transition between the states. Additionally, a resonance at approximately 1050 cm<sup>−1</sup> exhibited a change in oscillator amplitude but not resonant frequency due to the photochromic transition.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117290"},"PeriodicalIF":3.8,"publicationDate":"2025-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasmon-enhanced optical performance in S-bend pedestal-type TeO2–ZnO waveguides doped with Nd3+ 掺Nd3+的s弯基座型TeO2-ZnO波导的等离子体增强光学性能
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-12 DOI: 10.1016/j.optmat.2025.117317
Daniel K. Kumada , Igor Y. Abe , Thiago V. Fernandes , Marcos V.M. Nishimura , Marco I. Alayo , Luciana R.P. Kassab
{"title":"Plasmon-enhanced optical performance in S-bend pedestal-type TeO2–ZnO waveguides doped with Nd3+","authors":"Daniel K. Kumada ,&nbsp;Igor Y. Abe ,&nbsp;Thiago V. Fernandes ,&nbsp;Marcos V.M. Nishimura ,&nbsp;Marco I. Alayo ,&nbsp;Luciana R.P. Kassab","doi":"10.1016/j.optmat.2025.117317","DOIUrl":"10.1016/j.optmat.2025.117317","url":null,"abstract":"<div><div>We report the fabrication and optical characterization of curved pedestal waveguides based on Nd<sup>3+</sup> doped TeO<sub>2</sub>–ZnO (TZ) thin films, with and without gold nanoparticles (Au NPs), for near-infrared photonic applications at 1064 nm. The waveguides were fabricated using RF sputtering, direct-write photolithography, and reactive ion etching (RIE), and exhibit well-defined S-bend geometries. Scanning electron microscopy (SEM) was employed to verify structural fidelity and confirm the defined waveguide geometry, while atomic force microscopy (AFM) confirmed low surface roughness (Sa = 0.5 ± 0.3 nm), supporting efficient light coupling. Propagation losses of about 1.0 dB/cm were determined for 10 μm S-bend waveguides, whereas smaller widths showed higher losses that reached 6.0 dB/cm. Samples containing Au NPs exhibited an approximate 33 % increase in photoluminescence intensity, attributed to local electric field enhancement effects. The best performance was observed for 2 and 4 μm width S-bend waveguides whose relative gains reached ∼4.0 dB/cm, at 1064 nm, indicating an increase of about 100 % due to Au NPs. However, considering the propagation losses, the internal gain analysis revealed positive values for the 10, 8, and 4 μm wide S-bend waveguides with and without Au NPs. These findings confirm the potential of Nd<sup>3+</sup> TZ S-bend waveguides with plasmonic enhancement for integrated near-infrared (NIR) amplifiers and light sources.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117317"},"PeriodicalIF":3.8,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144623830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phase dependent luminescence properties of Pr3+ doped BaLu2F8–BaLuF5 materials Pr3+掺杂BaLu2F8-BaLuF5材料的相依赖性发光特性
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-12 DOI: 10.1016/j.optmat.2025.117315
Sanu Bifal Maji , Alexander Vanetsev , Hugo Mändar , Vitali Nagirnyi , Kirill Chernenko , Jekaterina Kozlova , Aleksei Kotlov , Yevheniia Smortsova , Marco Kirm
{"title":"Phase dependent luminescence properties of Pr3+ doped BaLu2F8–BaLuF5 materials","authors":"Sanu Bifal Maji ,&nbsp;Alexander Vanetsev ,&nbsp;Hugo Mändar ,&nbsp;Vitali Nagirnyi ,&nbsp;Kirill Chernenko ,&nbsp;Jekaterina Kozlova ,&nbsp;Aleksei Kotlov ,&nbsp;Yevheniia Smortsova ,&nbsp;Marco Kirm","doi":"10.1016/j.optmat.2025.117315","DOIUrl":"10.1016/j.optmat.2025.117315","url":null,"abstract":"<div><div>This work presents a comparative luminescence study of Pr<sup>3+</sup> doped phase-pure BaLuF<sub>5</sub> and mixed-phase BaLu<sub>2</sub>F<sub>8</sub> – BaLuF<sub>5</sub> materials synthesized via a hydrothermal route. The spectroscopic studies were mainly performed for phase-pure BaLuF<sub>5</sub> and two mixed-phase materials, which, according to structural and phase compositional analysis, contained 90 or 70 wt% of orthorhombic BaLu<sub>2</sub>F<sub>8</sub> and 10 or 30 wt% of cubic BaLuF<sub>5</sub>, respectively. Low-temperature time-integrated photoluminescence measurements under both host excitation at 45 eV and intracenter excitation of Pr<sup>3+</sup> ions at 6.75 eV revealed pronounced differences in luminescence between the two systems. The phase-pure BaLuF<sub>5</sub> material exhibited only narrow 4f<sup>2</sup>→4f<sup>2</sup> transitions of Pr<sup>3+</sup>, because the 4f<sup>1</sup>5d<sup>1</sup>states are energetically situated above the highest lying 4f<sup>2</sup> <sup>1</sup>S<sub>0</sub> level. In contrast, the BaLu<sub>2</sub>F<sub>8</sub> rich mixed-phase material showed multiple intense broad bands in the UV-C spectral region due to the 4f<sup>1</sup>5d<sup>1</sup>→4f<sup>2</sup> transitions, in addition to intense 4f<sup>2</sup>→4f<sup>2</sup> emissions in the visible spectral range, indicating enhanced energy transfer processes influenced by the orthorhombic host matrix. A cascade emission mechanism in Pr<sup>3+</sup> starting from the <sup>1</sup>S<sub>0</sub> level was revealed in both materials by the presence of characteristic emissions at 3.04 eV (<sup>1</sup>S<sub>0</sub>→<sup>1</sup>I<sub>6</sub>) and 2.57 eV (<sup>3</sup>P<sub>0</sub>→<sup>3</sup>H<sub>4</sub>) appearing in two sequent radiative relaxation stages. Time-integrated excitation spectra highlighted distinct excitation bands associated with different Pr<sup>3+</sup> energy levels populated below the fundamental absorption edge. Time-resolved spectroscopy of the 4f<sup>1</sup>5d<sup>1</sup>→4f<sup>2</sup> emissions revealed bi-exponential decay kinetics, distinguishing surface-perturbed and bulk Pr<sup>3+</sup> centers, with significantly different lifetimes in each phase. The varying intensity ratio of the 4f<sup>1</sup>5d<sup>1</sup>→4f<sup>2</sup> and 4f<sup>2</sup>→4f<sup>2</sup> emissions demonstrates that, depending on the phase composition, it is possible to control the nature of Pr<sup>3+</sup> emissions, enabling the design of multifunctional luminescent nanomaterials for diverse applications of deep UV emissions in phototherapy and optoelectronics.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117315"},"PeriodicalIF":3.8,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible SERS sensing substrate for highly sensitive detection and in-situ detection of Hazardous substances 柔性SERS传感基板,用于高灵敏度检测和有害物质的原位检测
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-11 DOI: 10.1016/j.optmat.2025.117313
Jiangfeng Liu, Zhao Xu, Sumei Wang, Xin Li, Xiaolin Qi, Lan Jiang
{"title":"Flexible SERS sensing substrate for highly sensitive detection and in-situ detection of Hazardous substances","authors":"Jiangfeng Liu,&nbsp;Zhao Xu,&nbsp;Sumei Wang,&nbsp;Xin Li,&nbsp;Xiaolin Qi,&nbsp;Lan Jiang","doi":"10.1016/j.optmat.2025.117313","DOIUrl":"10.1016/j.optmat.2025.117313","url":null,"abstract":"<div><div>Surface-enhanced Raman scattering (SERS) has emerged as a powerful technique for the detection of ultralow concentration molecules. Flexible SERS substrates, in contrast to their rigid counterparts, offer unique merits, leading to their broad applications in point of care diagnosis, food safety assessment, and environmental monitoring. In this work, we exploited the outstanding micro-nano structure processing capabilities of femtosecond lasers to precisely engineer the surface structure of materials. By integrating periodic superhydrophobic structure with hydrophobicity of polydimethylsiloxane (PDMS), we achieved the stable fixation of droplets at designated positions. This configuration effectively concentrated target detection molecules within a 400 μm diameter hydrophobic region. Notably, employing microliter scale samples, we successfully achieved sensitive detection at femtomolar level (10<sup>−16</sup> M) with relatively stable performance. Leveraging the remarkable flexibility of PDMS, the flexible substrate can be used to sample from complex curved surfaces, enabling in-situ detection of sweat components and pesticide residues on vegetable surfaces. The limit of detection for thiram on eggplant surfaces is 10 ppb. This research presents a novel method for fabricating flexible SERS substrates with high detection sensitivity, which hold great potential for various practical applications.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117313"},"PeriodicalIF":3.8,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Continuous 5.22–5.31 μm wavelength lasing in optical fiber based on Tb3+-doped gallium-free selenide glass 基于Tb3+掺杂无镓硒化玻璃的光纤连续5.22 ~ 5.31 μm波长激光
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-11 DOI: 10.1016/j.optmat.2025.117314
M.V. Sukhanov, E.N. Lashmanov, T.V. Kotereva, A.P. Velmuzhov, V.S. Shiryaev
{"title":"Continuous 5.22–5.31 μm wavelength lasing in optical fiber based on Tb3+-doped gallium-free selenide glass","authors":"M.V. Sukhanov,&nbsp;E.N. Lashmanov,&nbsp;T.V. Kotereva,&nbsp;A.P. Velmuzhov,&nbsp;V.S. Shiryaev","doi":"10.1016/j.optmat.2025.117314","DOIUrl":"10.1016/j.optmat.2025.117314","url":null,"abstract":"<div><div>A gallium-free terbium-doped Ge–Sb–Se chalcogenide glass, suitable for preparation and purification by effective and relatively low-labor methods of reactive and simple distillation of germanium and antimony selenides, is proposed as a middle IR laser material. The effect of impurities in terbium on the glass purity is reduced by decreasing rare earth metal concentration. A 15/230 μm diameter core-clad Tb<sup>3+</sup>-doped Ge–Sb–Se/As–Ge–S glass fiber is fabricated by a double crucible technique. It is shown that a 7 m long piece of produced active fiber provides continuous wave lasing in the spectral range of 5.22–5.31 μm with an output power of up to 60 mW and a slope efficiency of 3.7 %. Transition metal impurities with a total content of 0.7 ppm(wt), impurities of H<sub>2</sub>O, SeH-, GeH-, Ge–O groups and bonds with absorption coefficients of 0.002–0.007 cm<sup>−1</sup>, and total optical losses of 2.5 dB/m at 1.46 μm do not limit the possibility of achieving mid-IR laser emission in this active fiber.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117314"},"PeriodicalIF":3.8,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144611624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
FA+ and Cs+ substituted thermally stable MA-based triple cation perovskite absorber layer on spray deposited TiO2 ETL layer 在喷雾沉积TiO2 ETL层上用FA+和Cs+取代热稳定的ma基三阳离子钙钛矿吸收层
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-11 DOI: 10.1016/j.optmat.2025.117310
Asim Aftab, Md Imteyaz Ahmad
{"title":"FA+ and Cs+ substituted thermally stable MA-based triple cation perovskite absorber layer on spray deposited TiO2 ETL layer","authors":"Asim Aftab,&nbsp;Md Imteyaz Ahmad","doi":"10.1016/j.optmat.2025.117310","DOIUrl":"10.1016/j.optmat.2025.117310","url":null,"abstract":"<div><div>Pure methylammonium lead iodide (MAPbI<sub>3</sub>) perovskites are sensitive to moisture and processing conditions. MAPbI<sub>3</sub> is comparatively more sensitive to moisture than FAPbI<sub>3</sub>; however, unlike FAPbI<sub>3</sub>, it does not show any non-perovskite phase at room temperature (RT). Although stabilization of FAPbI<sub>3</sub>-based perovskite through partial substitution of the A-site has been explored extensively, a similar strategy for MAPbI<sub>3</sub> stabilization has not been explored much. We have partially substituted FA<sup>+</sup> and Cs<sup>+</sup> for MAPbI<sub>3</sub> (forming Cs<sub>0.1</sub>FA<sub>0.15</sub>MA<sub>0.75</sub>PbI<sub>3</sub> perovskite) to improve the structural and thermal stability. Adding Cs<sup>+</sup> along with FA<sup>+</sup> restricts the formation of any undesired phase, while the structure remained stable up to 1000 h when stored at 70 °C, thus improving structural and thermal stability. The device fabricated on spray-deposited TiO<sub>2</sub> ETL realized PCE close to 16 %. The cells retained about 65 % of their original efficiency after ageing for 1000 h at 70 °C.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"167 ","pages":"Article 117310"},"PeriodicalIF":3.8,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144604533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boosting energy transfer from self-trapped exciton to Er3+ in rare-earth based Cs2NaGdCl6 double perovskites via antimony sensitization for dual-functional applications 稀土基Cs2NaGdCl6双钙钛矿中通过锑敏化促进自捕获激子向Er3+的能量转移
IF 3.8 3区 材料科学
Optical Materials Pub Date : 2025-07-10 DOI: 10.1016/j.optmat.2025.117308
Yanzhu Wang, Yanting Liu, Siqi Sheng, Qiumei Li, Lili Meng, Hua Yao, Qian Chen, Jieni Meng
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