Nature EnergyPub Date : 2025-01-15DOI: 10.1038/s41560-024-01699-0
Muireann Á. Lynch, Valentin Bertsch
{"title":"Lessons from wholesale market success for system service procurement design in high renewable electricity markets","authors":"Muireann Á. Lynch, Valentin Bertsch","doi":"10.1038/s41560-024-01699-0","DOIUrl":"10.1038/s41560-024-01699-0","url":null,"abstract":"Climate action and the energy affordability and security crisis caused by the Ukrainian war have accelerated a shift towards variable renewable electricity generation, such as wind and solar power. These energy sources in turn pose new technical challenges for system operators, who must procure new services to support a renewables-based power system. Here we argue that these services have particular economic characteristics that render their optimal procurement a non-trivial exercise. Drawing on the successful collaboration between economic and technical disciplines in wholesale market design, we propose four areas where future collaboration can prove fruitful for designing and procuring the services necessary for secure system operation at high levels of renewable generation. Increased levels of renewable electricity require new flexible operation from generators and consumers. This Perspective considers several challenges in designing markets to procure this flexible operation. Expertise from economists and technicians alike is required to address these challenges.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 2","pages":"166-171"},"PeriodicalIF":49.7,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142981788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-14DOI: 10.1038/s41560-024-01684-7
Adrian Odenweller, Falko Ueckerdt
{"title":"The green hydrogen ambition and implementation gap","authors":"Adrian Odenweller, Falko Ueckerdt","doi":"10.1038/s41560-024-01684-7","DOIUrl":"10.1038/s41560-024-01684-7","url":null,"abstract":"Green hydrogen is critical for decarbonizing hard-to-electrify sectors, but it faces high costs and investment risks. Here we define and quantify the green hydrogen ambition and implementation gap, showing that meeting hydrogen expectations will remain challenging despite surging announcements of projects and subsidies. Tracking 190 projects over 3 years, we identify a wide 2023 implementation gap with only 7% of global capacity announcements finished on schedule. In contrast, the 2030 ambition gap towards 1.5 °C scenarios has been gradually closing as the announced project pipeline has nearly tripled to 422 GW within 3 years. However, we estimate that, without carbon pricing, realizing all these projects would require global subsidies of US$1.3 trillion (US$0.8–2.6 trillion range), far exceeding announced subsidies. Given past and future implementation gaps, policymakers must prepare for prolonged green hydrogen scarcity. Policy support needs to secure hydrogen investments, but should focus on applications where hydrogen is indispensable. Green hydrogen is critical for hard-to-electrify sectors, but faces economic headwinds. Odenweller and Ueckerdt quantify green hydrogen ambition and implementation gaps, showing that meeting expectations will remain challenging and costly.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 1","pages":"110-123"},"PeriodicalIF":49.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41560-024-01684-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142975068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-14DOI: 10.1038/s41560-024-01682-9
Adrian Odenweller, Falko Ueckerdt
{"title":"An adjusted strategy is needed to ground green hydrogen expectations in reality","authors":"Adrian Odenweller, Falko Ueckerdt","doi":"10.1038/s41560-024-01682-9","DOIUrl":"10.1038/s41560-024-01682-9","url":null,"abstract":"Scaling up green hydrogen will be difficult if future projects solely depend on expensive subsidies to overcome competitiveness barriers. Policy makers need to implement supportive policies grounded in realistic expectations, focusing on hydrogen-specific support in sectors where electrification isn’t feasible, while also gradually introducing technology-neutral market mechanisms such as carbon pricing.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 1","pages":"19-20"},"PeriodicalIF":49.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41560-024-01682-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142975064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-14DOI: 10.1038/s41560-024-01697-2
Serhiy Cherevko
{"title":"Electron spin matters","authors":"Serhiy Cherevko","doi":"10.1038/s41560-024-01697-2","DOIUrl":"10.1038/s41560-024-01697-2","url":null,"abstract":"Electrolytic hydrogen production using conventional electrocatalysts suffers from low energy efficiency, due in part to the sluggish nature of the oxygen evolution reaction (OER). Topological chiral semimetals are now explored to facilitate the OER by promoting spin-dependent electron transfer during the reaction.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 1","pages":"13-14"},"PeriodicalIF":49.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142975067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-13DOI: 10.1038/s41560-024-01694-5
Ao Wang, Jialin Cong, Shujie Zhou, Jialiang Huang, Jingwen Cao, Xin Cui, Xiaojie Yuan, Yin Yao, Zhou Xu, Guojun He, Jefferson Zhe Liu, Julie M. Cairney, Yi-sheng Chen, Martin A. Green, Su-Huai Wei, Kaiwen Sun, Xiaojing Hao
{"title":"Hydrogen-enhanced carrier collection enabling wide-bandgap Cd-free Cu2ZnSnS4 solar cells with 11.4% certified efficiency","authors":"Ao Wang, Jialin Cong, Shujie Zhou, Jialiang Huang, Jingwen Cao, Xin Cui, Xiaojie Yuan, Yin Yao, Zhou Xu, Guojun He, Jefferson Zhe Liu, Julie M. Cairney, Yi-sheng Chen, Martin A. Green, Su-Huai Wei, Kaiwen Sun, Xiaojing Hao","doi":"10.1038/s41560-024-01694-5","DOIUrl":"10.1038/s41560-024-01694-5","url":null,"abstract":"Wide-bandgap kesterite Cu2ZnSnS4 offers an economically viable, sustainably sourced and environmentally friendly material for both single-junction and tandem photovoltaic applications. Nevertheless, since 2018 the record efficiency of such solar cells has stagnated at 11%, largely due to carriers recombining before they are collected. Here we demonstrate enhanced carrier collection in devices annealed in a hydrogen-containing atmosphere. We find that hydrogen is incorporated mainly in n-type layers and on the absorber surface. Furthermore, we show that the hydrogen treatment triggers the out-diffusion of oxygen and sodium from the absorber bulk to the surface, favourably diminishing the acceptor concentration at the surface and increasing the p-type doping in the bulk. Consequently, Fermi-level pinning is relieved and carrier transport in the absorber is facilitated. We achieve a certified efficiency of 11.4% in Cd-free devices. Although hydrogenation already plays a major role in silicon photovoltaics, our findings can further advance its application in emerging photovoltaic technologies. The power conversion efficiency of wide-bandgap pure-sulfide kesterite is low. Wang et al. propose annealing in a hydrogen-containing atmosphere and report the underlying mechanism that enables a certified efficiency of 11.4%.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 2","pages":"255-265"},"PeriodicalIF":49.7,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142968163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-13DOI: 10.1038/s41560-024-01701-9
Adrian Yao, Sally M. Benson, William C. Chueh
{"title":"Critically assessing sodium-ion technology roadmaps and scenarios for techno-economic competitiveness against lithium-ion batteries","authors":"Adrian Yao, Sally M. Benson, William C. Chueh","doi":"10.1038/s41560-024-01701-9","DOIUrl":"10.1038/s41560-024-01701-9","url":null,"abstract":"Sodium-ion batteries have garnered notable attention as a potentially low-cost alternative to lithium-ion batteries, which have experienced supply shortages and price volatility for key minerals. Here we assess their techno-economic competitiveness against incumbent lithium-ion batteries using a modelling framework incorporating componential learning curves constrained by minerals prices and engineering design floors. We compare projected sodium-ion and lithium-ion price trends across over 6,000 scenarios while varying Na-ion technology development roadmaps, supply chain scenarios, market penetration and learning rates. Assuming that substantial progress can be made along technology roadmaps via targeted research and development, we identify several sodium-ion pathways that might reach cost-competitiveness with low-cost lithium-ion variants in the 2030s. In addition, we show that timelines are highly sensitive to movements in critical minerals supply chains—namely that of lithium, graphite and nickel. Our modelled outcomes suggest that being price advantageous against low-cost lithium-ion variants in the near term is challenging and increasing sodium-ion energy densities to decrease materials intensity is among the most impactful ways to improve competitiveness. Sodium-ion batteries are considered a promising substitute for Li-ion, but the timeline and conditions for achieving cost-competitiveness remain uncertain. This study evaluates their techno-economic potential, showing that while challenging, they could compete with low-cost Li-ion batteries by the 2030s under specific conditions.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 3","pages":"404-416"},"PeriodicalIF":49.7,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41560-024-01701-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142968164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-10DOI: 10.1038/s41560-024-01691-8
Nitin P. Padture
{"title":"Trade-offs at the interface","authors":"Nitin P. Padture","doi":"10.1038/s41560-024-01691-8","DOIUrl":"10.1038/s41560-024-01691-8","url":null,"abstract":"The durability of perovskite solar cells is closely linked to the mechanical adhesion toughness of their interfaces, though some toughening strategies could trigger detrimental chemical reactions. Research now shows that this trade-off can be effectively managed through interfacial engineering, informed by innovative mechanical testing.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 2","pages":"153-154"},"PeriodicalIF":49.7,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142961637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-10DOI: 10.1038/s41560-024-01696-3
Charles A. S. Hall, Graham Palmer
{"title":"Improving calculations of energy return on investment","authors":"Charles A. S. Hall, Graham Palmer","doi":"10.1038/s41560-024-01696-3","DOIUrl":"10.1038/s41560-024-01696-3","url":null,"abstract":"","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 2","pages":"149-150"},"PeriodicalIF":49.7,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142961636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-09DOI: 10.1038/s41560-024-01692-7
Ran Li, Hao Li, Wentao Huang, Hanqi Tao, Weiwu Xu, Nengling Tai, Canbing Li
{"title":"Accelerating green shipping with spatially optimized offshore charging stations","authors":"Ran Li, Hao Li, Wentao Huang, Hanqi Tao, Weiwu Xu, Nengling Tai, Canbing Li","doi":"10.1038/s41560-024-01692-7","DOIUrl":"10.1038/s41560-024-01692-7","url":null,"abstract":"The decarbonization of marine transport is a global challenge due to the range and capacity limitations of renewable ships. Offshore charging stations have emerged as an innovative solution, despite increased investment and extended voyage durations. Here we develop a route-specific model for the optimal placement and sizing of offshore charging stations to assess their economic, environmental and operational impacts. Analysing 34 global and regional shipping routes, we find that offshore charging stations can reduce the cost for electric ships by US$0.3–1.6 (MW km)−1 and greenhouse gas emissions by 1.04–8.91 kg (MW km)−1 by 2050. The economic cruising range for 6,500 20-foot equivalent unit electric ships can increase from 3,000 km to 9,000 km. Voyage time costs for these enhancements vary between a 0% and 30% grace period of the original delivery time frame. We further investigate power-to-ammonia offshore refuelling stations as a proxy for e-fuels, which could potentially replace heavy fuel oil ships for routes over 9,000 km with only a 5% grace period. Offshore charging stations could be a promising solution to enhance green shipping. This research considers their optimal placement and sizing, extending the economic range of renewable ships to 9,000 km without compromising shipping efficiency.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 2","pages":"243-254"},"PeriodicalIF":49.7,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142937188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature EnergyPub Date : 2025-01-06DOI: 10.1038/s41560-024-01689-2
Bitao Dong, Mingyang Wei, Yuheng Li, Yingguo Yang, Wei Ma, Yueshuai Zhang, Yanbiao Ran, Meijie Cui, Ziru Su, Qunping Fan, Zhaozhao Bi, Tomas Edvinsson, Zhiqin Ding, Huanxin Ju, Shuai You, Shaik Mohammed Zakeeruddin, Xiong Li, Anders Hagfeldt, Michael Grätzel, Yuhang Liu
{"title":"Self-assembled bilayer for perovskite solar cells with improved tolerance against thermal stresses","authors":"Bitao Dong, Mingyang Wei, Yuheng Li, Yingguo Yang, Wei Ma, Yueshuai Zhang, Yanbiao Ran, Meijie Cui, Ziru Su, Qunping Fan, Zhaozhao Bi, Tomas Edvinsson, Zhiqin Ding, Huanxin Ju, Shuai You, Shaik Mohammed Zakeeruddin, Xiong Li, Anders Hagfeldt, Michael Grätzel, Yuhang Liu","doi":"10.1038/s41560-024-01689-2","DOIUrl":"10.1038/s41560-024-01689-2","url":null,"abstract":"The adoption of perovskite solar cells (PSCs) requires improved resistance to high temperatures and temperature variations. Hole-selective self-assembled monolayers (SAMs) have enabled progress in the performance of inverted PSCs, yet they may compromise temperature stability owing to desorption and weak interfacial contact. Here we developed a self-assembled bilayer by covalently interconnecting a phosphonic acid SAM with a triphenylamine upper layer. This polymerized network, formed through Friedel–Crafts alkylation, resisted thermal degradation up to 100 °C for 200 h. Meanwhile, the face-on-oriented upper layer exhibited adhesive contact with perovskites, leading to a 1.7-fold improvement in adhesion energy compared with the SAM–perovskite interface. We reported power conversion efficiencies exceeding 26% for inverted PSCs. The champion devices demonstrated less than 4% and 3% efficiency loss after 2,000 h damp heat exposure (85 °C and 85% relative humidity) and over 1,200 thermal cycles between −40 °C and 85 °C, respectively, meeting the temperature stability criteria outlined in the International Electrotechnical Commission 61215:2021 standards. To improve the tolerance of perovskite solar cells against high temperatures and temperature variations, Dong et al. covalently cross-link two molecules in the charge transport layer to strengthen adhesion with the perovskite layer.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"10 3","pages":"342-353"},"PeriodicalIF":49.7,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41560-024-01689-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142929696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}