Nature reviews. Chemistry最新文献_第8页

Author Correction: Closing the loop with reactions at the N-terminus 作者更正：在n端闭合反应环

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-24 DOI: 10.1038/s41570-025-00701-x

Kejia Yan, Ratmir Derda

引用次数: 0

Chiral light–matter interactions in solution-processable semiconductors 溶液可加工半导体中的手性光-物质相互作用

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-17 DOI: 10.1038/s41570-025-00690-x

Zachary A. VanOrman, Winald R. Kitzmann, Antti-Pekka M. Reponen, Tejas Deshpande, Huygen J. Jöbsis, Sascha Feldmann

{"title":"Chiral light–matter interactions in solution-processable semiconductors","authors":"Zachary A. VanOrman, Winald R. Kitzmann, Antti-Pekka M. Reponen, Tejas Deshpande, Huygen J. Jöbsis, Sascha Feldmann","doi":"10.1038/s41570-025-00690-x","DOIUrl":"10.1038/s41570-025-00690-x","url":null,"abstract":"Chirality is a fundamental property widely observed in nature, arising in objects without a proper rotation axis, therefore existing as forms with distinct handedness. This characteristic can profoundly impact the properties of materials and can enable new functionality, especially for spin-optoelectronics. Chirality enables asymmetric light and spin interactions in materials, with widespread potential applications ranging from energy-efficient displays, holography, imaging, and spin-selective and enantio-selective chemistry to quantum information technologies. This Review focuses on the emerging material class of solution-processable chiral semiconductors, a broad material class comprising organic, inorganic and hybrid materials. These exciting materials offer the opportunity to design desirable light–matter interactions based on symmetry rules, potentially enabling the simultaneous control of light, charge and spin. We briefly discuss the various types of solution-processible chiral semiconductors, including small molecules, polymers, supramolecular self-assemblies and halide perovskites. We then examine the interplay between chirality and spin in these materials, the various mechanisms of chiral light–matter interactions, and techniques utilized to characterize them. We conclude with current and future applications of chiral semiconductors that take advantage of their chiral light–matter interactions. Endowing chirality onto solution-processable semiconductors unlocks new bounds for their spin and optoelectronic properties. This Review discusses the synthesis, properties, characterization methods, novel light–matter interactions and applications of this exciting class of materials.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 4","pages":"208-223"},"PeriodicalIF":38.1,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143435408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Later but better peptide modulations 后来但更好的肽调制

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-17 DOI: 10.1038/s41570-025-00696-5

Guoqing Jin

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Closing the loop with reactions at the N-terminus 在n端闭合反应环

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-14 DOI: 10.1038/s41570-025-00697-4

Kejia Yan, Ratmir Derda

引用次数: 0

Octahedral units in halide perovskites 卤化物钙钛矿中的八面体单元

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-10 DOI: 10.1038/s41570-025-00687-6

Yong Wang, Yu Wang, Tiarnan A. S. Doherty, Samuel D. Stranks, Feng Gao, Deren Yang

{"title":"Octahedral units in halide perovskites","authors":"Yong Wang, Yu Wang, Tiarnan A. S. Doherty, Samuel D. Stranks, Feng Gao, Deren Yang","doi":"10.1038/s41570-025-00687-6","DOIUrl":"10.1038/s41570-025-00687-6","url":null,"abstract":"Metal halide perovskites, with an ABX3 crystal structure, possess excellent photophysical properties for (opto)electronic applications including photovoltaics, light-emitting diodes, photodetectors and transistors. To pave the pathway towards commercial applications, enormous efforts have been made to obtain high-performance perovskite-based devices. The octahedral unit is considered to be the fundamental and functional unit of halide perovskite materials, consisting of a central B cation surrounded by six X anions, with typical dimensions of 5−6 Å. One promising pathway towards stable and high-performance perovskite devices is to manipulate this octahedral unit. Although rational engineering of octahedra has been used in oxide perovskites to unlock various functionalities, analogous targeted work has been relatively underexplored in halide perovskites. Here, we present fundamental concepts regarding octahedral configurations in metal halide perovskites and its effects on crystal structures, photophysical properties and device performance. We outline techniques that can be used for characterizing octahedral units and summarize different approaches to rationally manipulate these units. Finally, we discuss the challenges and outlook for future research to align octahedral units with device investigations. The octahedral unit is the fundamental and functional component of halide perovskites. The comprehensive and in-depth understanding of octahedral unit behaviour will facilitate modulation of structure at the atomic level, benefiting perovskite (opto)electronic devices with enhanced efficiency, stability and functionality.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 4","pages":"261-277"},"PeriodicalIF":38.1,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143375733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The man of MOFs and more MOFs和更多的人

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-09 DOI: 10.1038/s41570-025-00691-w

Stephanie Greed, Omar M. Yaghi

引用次数: 0

Free water releases hydrogen 游离水释放氢

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-05 DOI: 10.1038/s41570-025-00693-8

Eleanor Stewart-Jones, James Sappington

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Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets 将动态共价化学带出实验室，进入可再处理的工业热固性

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-31 DOI: 10.1038/s41570-025-00686-7

Stephan Maes, Nezha Badi, Johan M. Winne, Filip E. Du Prez

{"title":"Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets","authors":"Stephan Maes, Nezha Badi, Johan M. Winne, Filip E. Du Prez","doi":"10.1038/s41570-025-00686-7","DOIUrl":"10.1038/s41570-025-00686-7","url":null,"abstract":"Dynamic covalent chemistry (DCC) allows the development of thermally (re)processable and recyclable polymer networks, which is a highly attractive feature for new generations of thermoset materials. However, despite a surge in academic interest wherein soon almost any imaginable DCC platform may have been applied in a thermoset formulation, dynamic or reversible covalent polymer networks have so far found only few industrial applications. This Review provides a perspective on the main strategies for the application of DCC in the design and development of bulk thermoset materials, and it presents some of the key hurdles for their industrial implementation. The polymer design strategies and associated chemistries are viewed from the perspective of how ‘close to market’ their development pathway is, thus providing a roadmap to achieve high-volume breakthrough applications. Ever-increasing society needs have made thermosets crucial, but their recycling poses considerable challenges. Dynamic covalent chemistry (DCC) offers a solution, and industry is ready for its implementation. On the basis of market proximity, three DCC-based strategies are proposed for stimulating industrial uptake of DCC-thermosets.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 3","pages":"144-158"},"PeriodicalIF":38.1,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143072909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Return to Flatland 回到平地。

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-31 DOI: 10.1038/s41570-025-00688-5

Ian Churcher, Stuart Newbold, Christopher W. Murray

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Publisher Correction: Performance metrics and mechanistic considerations for the development of 3D batteries 发行商更正：3D电池开发的性能指标和机制考虑。

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-20 DOI: 10.1038/s41570-025-00689-4

Kelly Nieto, Daniel S. Windsor, Bairav S. Vishnugopi, Partha P. Mukherjee, Amy L. Prieto

引用次数: 0