Journal of Saudi Chemical Society最新文献_第2页

Discovery of tetrazole thioethers: An efficient, environmentally friendly and metal-free S-arylation using diaryliodonium salts 发现四氮唑硫醚：使用二月桂碘鎓盐进行高效、环保和无金属的 S-芳基化反应

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-26 DOI: 10.1016/j.jscs.2024.101943

Xiaogang Li , Xuesong Wang , Yan Wang , Yinfeng Tan , Dong Liu , Xueying Zhang , Youbin Li , Junyu Xu

引用次数: 0

Cu(II) complex heterogenized on magnetic mesoporous nanocomposite (SBA-16@Fe3O4) as an efficient catalyst for the reduction of nitro compounds 磁性介孔纳米复合材料（SBA-16@Fe3O4）上异质化的铜（II）络合物作为硝基化合物还原的高效催化剂

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-24 DOI: 10.1016/j.jscs.2024.101944

Yuanlin Shi

{"title":"Cu(II) complex heterogenized on magnetic mesoporous nanocomposite (SBA-16@Fe3O4) as an efficient catalyst for the reduction of nitro compounds","authors":"Yuanlin Shi","doi":"10.1016/j.jscs.2024.101944","DOIUrl":"10.1016/j.jscs.2024.101944","url":null,"abstract":"<div><div>In the present study, a novel magnetic heterogeneous copper catalyst was developed by the immobilization of a Cu(II) complex on the surface of magnetic mesoporous nanocomposite (SBA-16@Fe3O4) through post-synthetic method. The synthesized catalyst was analyzed by various characterization methods including FT-IR, EDS, XRD, Nitrogen physisorption, TEM, TGA, VSM, and ICP-OES. After complete characterization, its catalytic efficiency was evaluated in the hydrogenation of nitroarenes to amines. Taking the nitrobenzene reduction of as an example of a reaction, the reaction conditions were optimized by changing diverse parameters like solvent, temperature, time, amount of catalyst, as well as the type and amount of hydrogen source. The catalyst revealed highly efficient catalytic activity in the hydrogenation of numerous nitroarenes to the corresponding aminoarenes in pure water as the solvent with sodium borohydride as a H2 source at room temperature. Additionally, the catalyst could be simply recovered from the mixture of reaction via magnetic separation and was able to mediate the reaction for multiple times with undiminished catalytic performance.</div></div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101944"},"PeriodicalIF":5.8,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142421992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Sn-ZnO nanostructures on MgO<0001> by hybrid pulsed laser ablation and RF magnetron sputtering tandem system for CO gas-sensing application 利用混合脉冲激光烧蚀和射频磁控溅射串联系统在氧化镁上合成用于 CO 气体传感的 Sn-ZnO 纳米结构

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-16 DOI: 10.1016/j.jscs.2024.101941

Joselito P. Labis , Hamad A. Albrithen , Muhammad Ali Shar , Abdulaziz Alhazaa , Ahmed Algarni , Mohammad A. Alduraibi , Ahamad Imran , Ahmed Mohamed El-Toni

{"title":"Synthesis of Sn-ZnO nanostructures on MgO<0001> by hybrid pulsed laser ablation and RF magnetron sputtering tandem system for CO gas-sensing application","authors":"Joselito P. Labis , Hamad A. Albrithen , Muhammad Ali Shar , Abdulaziz Alhazaa , Ahmed Algarni , Mohammad A. Alduraibi , Ahamad Imran , Ahmed Mohamed El-Toni","doi":"10.1016/j.jscs.2024.101941","DOIUrl":"10.1016/j.jscs.2024.101941","url":null,"abstract":"<div>An exceptional method of incorporating Sn ions into Zinc Oxide (ZnO) using a tandem system of Pulsed Laser Deposition (PLD) and Radio-Frequency Magnetron Sputtering (RFMS) to synthesize and functionalize ZnO nanostructures is demonstrated in this study for gas-sensing application. The RFMS power was varied up to 50 W to sputter a pure Sn metal target, while simultaneously or successively growing ZnO nanostructures on a templated MgO < 0001 > substrate and on an Au-plated Al2O3 gas sensor, via PLD process at the substrate temperature of 700 °C in 100–500 millitorr oxygen/argon gas background. The morphologies of the grown Sn-ZnO nanostructures were characterized by Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and X-ray Diffraction (XRD), and while their chemical/oxidation states and optical properties were analyzed by X-ray photospectroscopy (XPS) and photoluminescence (PL), respectively. For simultaneous deposition, the resulting (0002)-dominated 2D grain-like ZnO nanostructures were influenced by the interaction of the dynamic PLD plasma with static RFMS plasma at different powers. For successive growth, at 50 W-RF power, a remarkable increase in the sensor response to 50-ppm carbon monoxide (CO) gas was observed at 250 °C, which could be attributed to the creation of more adsorption sites in the Sn-ZnO depletion region caused by the replacement of some Zn sites with Sn ions in the ZnO matrix. This study, therefore, exhibits the viability of this hybrid system to design, synthesize, and functionalize Sn-ZnO nanomaterials, either by simultaneous/successive deposition, for gas-sensing applications.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101941"},"PeriodicalIF":5.8,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001364/pdfft?md5=fc3853e1510a40089b4ca396d1eceb54&pid=1-s2.0-S1319610324001364-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142270773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pine sawdust immobilized zeolitic imidazolate framework-67 derived magnetic composites: An efficient and recycable adsorbent for norfloxacin removal 松树锯屑固定唑基咪唑啉框架-67衍生磁性复合材料：去除诺氟沙星的高效可回收吸附剂

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-13 DOI: 10.1016/j.jscs.2024.101939

Yu Zheng , Qing Shen , Jie Gao , Tian Liang , Xiao-Bing Han , Yuan Zhao , Tao Chen

{"title":"Pine sawdust immobilized zeolitic imidazolate framework-67 derived magnetic composites: An efficient and recycable adsorbent for norfloxacin removal","authors":"Yu Zheng , Qing Shen , Jie Gao , Tian Liang , Xiao-Bing Han , Yuan Zhao , Tao Chen","doi":"10.1016/j.jscs.2024.101939","DOIUrl":"10.1016/j.jscs.2024.101939","url":null,"abstract":"<div>Antibiotic contamination is a global environmental problem. The emerging contaminant norfloxacin (NOR) may increase the risk of drug resistance and thereby harm human health. The practical application of metal–organic framework crystals is usually limited by their powder form and difficulty in recovery. In this study, a magnetic Co-MPS-800 composite was prepared from carbonization with ZIF-67@pine sawdust, and significantly raised the NOR removing ability from wastewater. The changes in functional group composition, elemental contents, morphology, thermal stability and adsorption mechanism of the magnetic Co-MPS-800 composite were interpreted using FT-IR, XRD, SEM, BET, TGA and XPS. The Co-MPS-800 has an isoelectric point of 9.15 and a large specific surface area (174.58 m2·g−1). The impacts of pH, contact time, temperature and dosage on the performance of Co-MPS-800 were also studied. The adsorption capacity over NOR reached 221.98 mg·g−1 at 303 K, pH=6.0. The NOR adsorption is best suited a pseudo-2nd-order kinetic model and the Freundlich isotherm. Co-MPS-800 also had excellent reusability, and the removal rate reached 82.94 % after four repeated uses. Therefore, the magnetic Co-MPS-800 composite is effective in removing NOR from aqueous solutions. Altogether, this functional MOF-derived porous carbon may serve as a promising pollutant biosorbent, and its preparation strategy may provide insights for future studies.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101939"},"PeriodicalIF":5.8,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001340/pdfft?md5=1707ff61c413333dede1f1e4a46b7817&pid=1-s2.0-S1319610324001340-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabricating 3D hierarchical hollow CoAl-LDHs@CoSx-rGO ball-flower for degrading sulfamethoxazole via visible-light coupling PMS activation: Performance and mechanism insight 通过可见光耦合 PMS 激活制造三维分层空心 CoAl-LDHs@CoSx-rGO 球花降解磺胺甲噁唑：性能和机理见解

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-12 DOI: 10.1016/j.jscs.2024.101940

Tao Wu , Wanyue Wang , Jiacheng Huang , Xin Ren , Xuesong Zhao , Tianyu Zhou

{"title":"Fabricating 3D hierarchical hollow CoAl-LDHs@CoSx-rGO ball-flower for degrading sulfamethoxazole via visible-light coupling PMS activation: Performance and mechanism insight","authors":"Tao Wu , Wanyue Wang , Jiacheng Huang , Xin Ren , Xuesong Zhao , Tianyu Zhou","doi":"10.1016/j.jscs.2024.101940","DOIUrl":"10.1016/j.jscs.2024.101940","url":null,"abstract":"<div>Sulfamethoxazole (SMX) is an extensively applied antibacterial drug, and it is also a pollutant that poses a serious threat to human and ecosystem health. In this research, a 3D hierarchical hollow ball-flower structure catalyst (CoAl-LDHs@CoSx-rGO) was tailored for the first time to efficiently degrade SMX via visible light coupling PMS activation. A series of characterizations confirm that the target catalyst is successfully prepared and the optimized 0.1CoAl-LDHs@CoSx-rGO sample possesses superior specific surface area of 306.0 m2/g, and significantly higher photocurrent response and lower electrochemical impedance. More importantly, 0.5 g/L of the sample can degrade 98.59 % of SMX within 50 min via visible light coupling PMS activation, and after 7 degradation cycles, the degradation rate only decreased by 8.49 %. A series of parameters that affect degradation rate have been optimized in detail. Capture experiments and ESR indicate that e−, •OH and SO4•− make major contributions to degradation, and visible light coupling PMS activation generates stronger signals than alone visible-light or PMS system. LC-MS, TEST toxicity assessment and theoretical calculation were conducted to elucidate degradation route and intermediate toxicity. The research provides a new approach to design catalysts with highly exposed activity sites for efficiently removing SMX from environmental water.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101940"},"PeriodicalIF":5.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001352/pdfft?md5=469ab44a6f756711939d39388f5c6f01&pid=1-s2.0-S1319610324001352-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The promotion effects of alkaline earth metals on the properties of Cr/η-Al2O3 catalysts for propane dehydrogenation 碱土金属对用于丙烷脱氢的 Cr/η-Al2O3 催化剂性能的促进作用

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-06 DOI: 10.1016/j.jscs.2024.101929

Hamid Karami , Saeed Soltanali , Mozhdeh Amanati , Weiyu Song , Jian Liu , Khashayar Sharifi

{"title":"The promotion effects of alkaline earth metals on the properties of Cr/η-Al2O3 catalysts for propane dehydrogenation","authors":"Hamid Karami , Saeed Soltanali , Mozhdeh Amanati , Weiyu Song , Jian Liu , Khashayar Sharifi","doi":"10.1016/j.jscs.2024.101929","DOIUrl":"10.1016/j.jscs.2024.101929","url":null,"abstract":"<div>The Cr/Al2O3 catalyst, a prevalent system in commercial applications, plays a significant role in propane dehydrogenation (PDH). Notable improvements in this catalyst’s efficiency are essential for its continued use. In order to examine the effect of alkaline earth metals on the catalyst performances in the propane dehydrogenation reaction, a series of Cr/η-Al2O3 were synthesized by the impregnation method. The synthesized catalysts were designated as Cr-T/η-Al2O3, where T represents Ca, Mg, Sr, and Ba. The supports and the catalysts were studied using the following techniques: XRD, N2 adsorption–desorption, temperature-programmed desorption and reduction, UV–Vis and Raman spectroscopy, and XPS analyses. The findings reveal that the Cr-Ba/η-Al2O3 catalyst exhibits better catalytic performance, with significantly higher propane conversion and propylene selectivity (with initial values of 66 % and 86.2 %, respectively) compared to other catalysts. The enhanced performance is attributed to the increased dispersion of Cr species, stabilization of Cr6+ species, and reducing the total amount of acid sites and strong acid sites, which are crucial for maintaining active sites and minimizing coke deposition. The Ba-modified catalyst also demonstrated excellent stability, with a lower deactivation rate (Ba(0.201 h−1) < Sr(0.213 h−1) < Ca(0.270 h−1) < Mg(0.310 h−1) < parent(0.338 h−1)) and robust regenerative capacity over multiple cycles.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101929"},"PeriodicalIF":5.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001248/pdfft?md5=b9e04321a7b244f955cc3a5fe82425e8&pid=1-s2.0-S1319610324001248-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High durable SPEEK/TiO2 nanopaper composite membrane for vanadium redox flow battery 用于钒氧化还原液流电池的高耐久性 SPEEK/TiO2 纳米纸复合膜

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-06 DOI: 10.1016/j.jscs.2024.101931

Song Il Han, Song Hyok Jon, Un Hyang Kim, Gang Hyok Kim, Sang Mo Jon

引用次数: 0

Effect of small-molecule organic matter on methane adsorption in anthracite 小分子有机物对无烟煤中甲烷吸附的影响

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-05 DOI: 10.1016/j.jscs.2024.101930

Dameng Gao , Jiawei Liang , Lin Hong , Dan Zheng , Zhi Yang , Jiren Wang

{"title":"Effect of small-molecule organic matter on methane adsorption in anthracite","authors":"Dameng Gao , Jiawei Liang , Lin Hong , Dan Zheng , Zhi Yang , Jiren Wang","doi":"10.1016/j.jscs.2024.101930","DOIUrl":"10.1016/j.jscs.2024.101930","url":null,"abstract":"<div>This study employs the grand canonical ensemble Monte Carlo (GCMC) method to investigate the effect of small-molecule organic matter on methane adsorption in anthracite. Specifically, the adsorption characteristics of methane in anthracite are analyzed considering the type and concentration of single-component and multi-component small-molecular organic matter, alongside parameters such as adsorption heat, adsorption potential energy, interaction energy, and charge transfer amount. Results indicate that methane adsorption exhibits physical adsorption behavior, with adsorption heat decreasing with increasing temperature and adsorption potential energy inversely correlated with adsorption capacity. The influence of different types and concentrations of small-molecular organic matter on methane adsorption varies. The presence of small-molecular organic matter alters the charge transfer amount of methane, with a greater absolute value corresponding to enhanced anthracite adsorption capacity. The interaction hierarchy among single-component small-molecule organic compounds and methane is as follows: methyl benzene > tetrahydrofuran > n-hexane. Additionally, in the presence of multi-component small-molecule organic matter, the simultaneous occurrence of methyl benzene and n-hexane or tetrahydrofuran inhibits adsorption due to chemical reactions.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101930"},"PeriodicalIF":5.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S131961032400125X/pdfft?md5=aef1a11b311fd242a76e92f2d4fa25fa&pid=1-s2.0-S131961032400125X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design, synthesis, and antifungal activity of novel cyanoacrylate derivatives containing a naphthalene moiety as potential myosin-5 inhibitor 含有萘分子的新型氰基丙烯酸酯衍生物的设计、合成和抗真菌活性及其作为肌球蛋白-5 抑制剂的潜力

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-03 DOI: 10.1016/j.jscs.2024.101928

Fei Jin , Feng Peng , Wen-Rui Li , Jian-Qi Chai , Min Chen , Ai-Min Lu , Chun-Long Yang , Ming-Guo Zhou

{"title":"Design, synthesis, and antifungal activity of novel cyanoacrylate derivatives containing a naphthalene moiety as potential myosin-5 inhibitor","authors":"Fei Jin , Feng Peng , Wen-Rui Li , Jian-Qi Chai , Min Chen , Ai-Min Lu , Chun-Long Yang , Ming-Guo Zhou","doi":"10.1016/j.jscs.2024.101928","DOIUrl":"10.1016/j.jscs.2024.101928","url":null,"abstract":"<div>In search of innovative antifungal solutions for the control of plant diseases, a series of cyanoacrylate derivatives containing naphthalene groups were designed and synthesized, and their inhibition activity against four plant pathogenic fungi was evaluated. The results of in vitro bioassay revealed that some target compounds possessed obvious antifungal effect against Fusarium graminearum. As the most prominent one, compound A2 showed a inhibition rate of 98.46 % at 10 µg/mL and an EC50 value of 0.26 µg/mL, which was close to that of the positive control phenamacril (with a inhibition rate of 100 % at 10 µg/mL and EC50 value of 0.14 µg/mL). The compound A2 also markedly inhibited the growth of F. graminearum inoculated on rice leaves at 200 μg/mL with the protective and curative efficiencies of 89.03 % and 90.91 %, respectively, which were close to that of the positive control phenamacril (with the protective and curative efficiencies of 94.54 % and 96.36 %, respectively). The observation under scanning electron microscopy and measurement of relative conductivity revealed that compound A2 caused the hyphal surface become shrunken and rough, and made the cell membrane permeability increased. Molecular docking and molecular dynamics simulation analyses showed that compound A2 interacted with the key residues in the active site of myosin-5 in a similar mode as phenamacril. These results suggested that target compounds were potential myosin-5 inhibitors, they could serve as the lead compounds for further structural optimization to develop new fungicides against F. graminearum.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 6","pages":"Article 101928"},"PeriodicalIF":5.8,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001236/pdfft?md5=ac0a26afb1117918b62f51bd2061c09c&pid=1-s2.0-S1319610324001236-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nitric acid dissolution of germanium overlay in hard zinc slag to enhance germanium leaching and optimization of response surface methodology 硝酸溶解硬锌渣中的锗覆盖层以提高锗浸出率以及响应面方法的优化

IF 5.8 2区化学

Journal of Saudi Chemical Society Pub Date : 2024-09-01 DOI: 10.1016/j.jscs.2024.101925

Jie Lan, Ming Liang, Kun Yang, Kun Zhu

{"title":"Nitric acid dissolution of germanium overlay in hard zinc slag to enhance germanium leaching and optimization of response surface methodology","authors":"Jie Lan, Ming Liang, Kun Yang, Kun Zhu","doi":"10.1016/j.jscs.2024.101925","DOIUrl":"10.1016/j.jscs.2024.101925","url":null,"abstract":"<div>With the rapid development of global digital economy and aerospace, the gap between the supply and demand of germanium is expanding, and the establishment of a new process for the deep leaching of germanium from hard zinc slag is imminent. In this paper, on the basis of analyzing the reasons for the low germanium leaching rate from hard zinc slag, a new process of germanium leaching enhanced by HNO3 dissolution of externally wrapped ZnFe2O4 is established, and response surface optimization is carried out. The PbggGe4O7 phase in hard zinc slag is externally wrapped with ZnFe2O4 phase, and the non-reaction between ZnFe2O4 and hydrochloric acid is the main reason for the low leaching rate of germanium from hard zinc slag, so it is necessary to add HNO3 to dissolve the external ZnFe2O4 in leaching, and then use hydrochloric acid to leach the PbGe4O7 containing germanium in the interior. The potential pH diagram of the Pb-Ge-Cl-H2O system was also plotted, indicating that increasing the concentration of chloride ions during hydrochloric acid leaching contributes to the generation of GeCl4 at low acidity. When the hydrochloric acid concentration was 134.65 g/L, the liquid–solid ratio was 6, the theoretical dosage of HNO3 was 0.3, and the leaching time was 236 min, the optimum leaching rate of germanium was 93.72%, which was 23.72% higher than that of germanium leaching from hard zinc slag.</div>","PeriodicalId":16974,"journal":{"name":"Journal of Saudi Chemical Society","volume":"28 5","pages":"Article 101925"},"PeriodicalIF":5.8,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1319610324001200/pdfft?md5=eac238989625f6ba81d986f05853a846&pid=1-s2.0-S1319610324001200-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142130028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0