Journal of Polymer Engineering最新文献_第2页

Soft materials containing dynamic C–N bonds for fluorescence visualization 含有动态碳氮键的荧光可视化软材料

4区工程技术

Journal of Polymer Engineering Pub Date : 2025-05-26 DOI: 10.1515/polyeng-2025-0021

Yang Gao, Jiaming Hu, Leping Wu, Shuai Zhang, Jing Li, Kai Du

引用次数: 0

Photocatalytic g-C₃N₄/poly(2-acrylamido-2-methylpropane sulfonic acid) composite hydrogel triggering the synergetic effect for long-lasting sustainable purifying organic wastewater 光催化g-C3N4/聚（2-丙烯酰胺-2-甲基丙烷磺酸）复合水凝胶触发协同效应，持久可持续净化有机废水

4区工程技术

Journal of Polymer Engineering Pub Date : 2025-01-22 DOI: 10.1515/polyeng-2024-0216

Shishan Xue, Zhiyong Ye, Herong Zhang, Meiling Guo, Xi Yang, Dengliang He, Shuxin Liu, Ning Chen

引用次数: 0

Preparation and anti-fouling behavior of conductive and hydrophilic polypyrrole modified PVDF composite membrane 导电亲水性聚吡咯改性PVDF复合膜的制备及其防污性能

4区工程技术

Journal of Polymer Engineering Pub Date : 2024-12-26 DOI: 10.1515/polyeng-2024-0153

Ziyu Liu, Yanqing Liu, Chong Zhang, Takashi Sakamaki, Xianning Li

引用次数: 2

Preparation and properties of PLCL/OM-Laponite materials with potential applications in orthopedic bandage 应用于骨科绷带的PLCL/OM-Laponite材料的制备及性能研究

4区工程技术

Journal of Polymer Engineering Pub Date : 2024-12-24 DOI: 10.1515/polyeng-2024-0099

Yan Ren, Yonggang Lin, Yabei Ding, Ruimin Tang, Minglong Yuan, Hongli Li, Yongming Chuan

{"title":"Preparation and properties of PLCL/OM-Laponite materials with potential applications in orthopedic bandage","authors":"Yan Ren, Yonggang Lin, Yabei Ding, Ruimin Tang, Minglong Yuan, Hongli Li, Yongming Chuan","doi":"10.1515/polyeng-2024-0099","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0099","url":null,"abstract":"Abstract Poly( l -lactide- co -caprolactone) (PLCL) is the polymeric material with good biodegradability and biocompatible properties, but it is insufficient in strength properties that the pure PLCL is performed as orthopedic bandage. The PLCL has been blended with the laponite which is modified by cetyltrimethylammonium bromide (CTAB) to prepare composited bandage splines. The organic-modified laponite (OM-laponite) results of Fourier transform infrared (FTIR) and thermogravimetry analysis (TG) indicate that the laponite was successfully grafted with CTAB and the thermal stability was improved with increasing CTAB. The mechanical properties reveal that elongation at break strengthen with the increasing OM-laponite. When the content of OM-laponite is 2.0 %, the elongation at break and tensile strength of composited spline are superior to the medical orthopedic bandage. The results of thermal stability show that it was helpful to improve the crystallization properties of PLCL with the addition of OM-laponite. The water contact angle results demonstrate that the hydrophilicity is enhanced and is beneficial to cell adhesion. The results of cell experiment illustrate that the composite materials have a certain effect on cell proliferation when the content of OM-laponite is less than 2 %. Compared with the medical orthopedic bandage, it is satisfied with the application requirements.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 2","pages":"187-199"},"PeriodicalIF":0.0,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147908798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Acryloyl starch/carboxymethyl cellulose grafting copolymerization composite hydrogel for efficient adsorption of methylene blue 丙烯酰淀粉/羧甲基纤维素接枝共聚复合水凝胶高效吸附亚甲基蓝

4区工程技术

Journal of Polymer Engineering Pub Date : 2024-11-27 DOI: 10.1515/polyeng-2024-0120

Xueli Liu, Yali Sun, Zhong-Zhu Hu, Chunfeng Zhu

{"title":"Acryloyl starch/carboxymethyl cellulose grafting copolymerization composite hydrogel for efficient adsorption of methylene blue","authors":"Xueli Liu, Yali Sun, Zhong-Zhu Hu, Chunfeng Zhu","doi":"10.1515/polyeng-2024-0120","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0120","url":null,"abstract":"Abstract An efficient composite adsorbent was prepared based on acryloyl starch/carboxymethyl cellulose grafting copolymerization for the adsorptive removal of methylene blue. The developed composite hydrogels were characterized by means of FTIR, SEM (EDS-SEM), and XRD. Various parameters affecting the removal of methylene blue such as the type of adsorbents, pHs, the amount of adsorbents dosage, initial methylene blue concentration, and contact time were optimized using a series of batch adsorption experiments. The experimental data of the adsorption process were more fitted to Langmuir isotherm ( R 2 = 0.9898) with a maximum adsorption capacity of 483.5 mg/g and batch kinetic experiments revealed that the adsorption process followed quasi-second-order kinetic model. The adsorption process was rapid and equilibrium was reached within 30 min. When the adsorption dosage is 0.2 g L −1 , the adsorption yield for 100 mg L −1 methylene blue solution can reach 96.7 %. Therefore, acryloyl starch/carboxymethyl cellulose grafting copolymerization composite hydrogel present excellent adsorption efficiency, shows the potential application in future treatment of dyes wastewater.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 1","pages":"73-81"},"PeriodicalIF":0.0,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147895900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Synthesis, rheology, cytotoxicity and antibacterial studies of N-acrolylglycine-acrylamide copolymer soft nano hydrogel N- 丙烯酸-丙烯酰胺共聚物软纳米水凝胶的合成、流变学、细胞毒性和抗菌研究

IF 2 4区工程技术

Journal of Polymer Engineering Pub Date : 2024-09-13 DOI: 10.1515/polyeng-2023-0247

Anilkumar Yamala, Jai Shree Kurba, D. Sanjeev Kumar, Ravi Kumar Kanaparthi, Ashok K. Madikonda

{"title":"Synthesis, rheology, cytotoxicity and antibacterial studies of N-acrolylglycine-acrylamide copolymer soft nano hydrogel","authors":"Anilkumar Yamala, Jai Shree Kurba, D. Sanjeev Kumar, Ravi Kumar Kanaparthi, Ashok K. Madikonda","doi":"10.1515/polyeng-2023-0247","DOIUrl":"https://doi.org/10.1515/polyeng-2023-0247","url":null,"abstract":"Hydrogels possess excellent biological properties that make them ideal for biomedical applications. They are compatible with living cells and tissues because they can swell in the presence of water. In this study, we investigated the stability and biocompatibility of hydrogels. We synthesized and characterized N-acryl glycine (NAG) monomer and then synthesized its copolymer using the miniemulsion-polymerization technique, a soft-hydrogel method. To confirm the morphological properties of the dried hydrogel particles, we used the field emission scanning electron microscopy (FESEM) technique. We also investigated the rheological properties of the hydrogels for different concentrations to evaluate their mechanical strength and gel-like properties. Our findings indicated that the 10 % gel had superior strength and yield strain at all examined temperatures (30 °C, 37 °C, and 40 °C) compared to other concentrated gels. We systematically evaluated the biocompatibility of the hydrogel using three different cell lines: HEK 293T, RAW 264.7, and HeLa. Our cell line studies demonstrated that hydrogels are viable when exposed to a concentration of 0.5 mg/mL. Moreover, cell proliferation was observed at concentrations below 0.25 mg/mL. The MTT assay and rheology results suggest that hydrogel characteristics are more suitable for various biomedical applications, such as drug delivery and tissue engineering.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"1 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142264856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Low thickness electromagnetic wave absorbing polyurethane and IIR composites by interfacial polarization of multi-layer structure 通过多层结构的界面极化实现低厚度电磁波吸收聚氨酯和 IIR 复合材料

IF 2 4区工程技术

Journal of Polymer Engineering Pub Date : 2024-09-05 DOI: 10.1515/polyeng-2024-0095

Jinghui Yang

引用次数: 0

An experimental investigation on the influence of pore foaming agent particle size on cell morphology, hydrophobicity, and acoustic performance of open cell poly (vinylidene fluoride) polymeric foams 孔隙发泡剂颗粒大小对开孔聚偏氟乙烯聚合物泡沫的细胞形态、疏水性和声学性能影响的实验研究

IF 2 4区工程技术

Journal of Polymer Engineering Pub Date : 2024-09-05 DOI: 10.1515/polyeng-2024-0124

Nivedhitha Durgam Muralidharan, Jeyanthi Subramanian

{"title":"An experimental investigation on the influence of pore foaming agent particle size on cell morphology, hydrophobicity, and acoustic performance of open cell poly (vinylidene fluoride) polymeric foams","authors":"Nivedhitha Durgam Muralidharan, Jeyanthi Subramanian","doi":"10.1515/polyeng-2024-0124","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0124","url":null,"abstract":"Globally, the development of porous structured materials has been receiving incredible responses for various high-performance engineering applications. Piezoelectric cellular foams have recently attracted the attention of researchers to emerging applications of acoustic sensors, low-frequency hydrophones, and energy-harvesting devices. As pore morphology is closely related to the shape and the size of the pore-foaming agent, it is necessary to address the influence of particle size of the foaming agent on cell morphology to expand their application area. Hence, this research article establishes the impact of particle size of pore foaming agents on pore morphology, hydrophobicity, and acoustic characteristics of open-cell polyvinylidene fluoride (PVDF) based piezoelectric cellular composites. Open-cell PVDF cellular composites have been fabricated using the template removal method with sodium chloride (NaCl) as a sacrificial templating agent in three different particle sizes: larger, medium, and finer. Based on the experimental results, it can be stated that the particle size of the templating agents dramatically influences the pore morphology, hydrophobicity, and acoustics performance of the PVDF foam samples. The PVDF foams possessing medium pore size have exhibited a maximum sound absorption coefficient of 0.89 at a frequency range of 1,000–1,500 Hz, indicating that PVDF foams have great potential for noise-controlling applications.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"2 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and properties of reed-based polyurethane (PU) coating 芦苇基聚氨酯（PU）涂层的合成与性能

IF 2 4区工程技术

Journal of Polymer Engineering Pub Date : 2024-08-29 DOI: 10.1515/polyeng-2024-0109

Ruiying Wu, Meng Chen, Wenjing Zhang, Wenqing Yang, Libin Bai, Li Huo

{"title":"Synthesis and properties of reed-based polyurethane (PU) coating","authors":"Ruiying Wu, Meng Chen, Wenjing Zhang, Wenqing Yang, Libin Bai, Li Huo","doi":"10.1515/polyeng-2024-0109","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0109","url":null,"abstract":"The reuse of agricultural waste and the development of bio-based materials are the main strategies for solving the global energy crisis and environmental problems. Agricultural waste reeds containing natural nano-silica (SiO2) were liquefied with PEG-400, Castor oil, and acid to produce reed-based polyols (R–P). The result shows that the liquefied product is a polyol with a hydroxyl value of 171 mgKOH/g, a viscosity of 1.221 Pa S, the number average molecular weight (Mn) of 1.202 kg/mol. Then reed-based two-component polyurethane emulsion (R-T-PU) and reed-based one-component waterborne polyurethane emulsion (R-O-WPU) with good glossiness and excellent mechanical properties were prepared. Because of the natural nano-SiO2 in reed and castor oil, the coatings exhibit excellent mechanical properties and hydrophobicity. The results show that the series of reed-based polyurethane has excellent mechanical properties, a maximum hardness of 6H, good hydrophobic effect, a maximum contact angle of 109°, high thermal stability, and a maximum initial decomposition temperature can reach 299.1 °C. Therefore, the environmental protection bio-based polyurethane coating with excellent properties can be prepared with the reed, which is expected to replace fossil resources. It provides an experimental basis for the high-added-value utilization of reed.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"71 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of epoxidized soybean oil on melting behavior of poly(l-lactic acid) and poly(d-lactic acid) blends after isothermal crystallization 环氧化大豆油对聚（l-乳酸）和聚（d-乳酸）混合物等温结晶后熔融行为的影响

IF 2 4区工程技术

Journal of Polymer Engineering Pub Date : 2024-08-27 DOI: 10.1515/polyeng-2024-0081

Wenwei Li, Jun Shen, Dutchanee Pholharn, Keartisak Sriprateep, Patnarin Worajittiphon, Yottha Srithep

{"title":"Effect of epoxidized soybean oil on melting behavior of poly(l-lactic acid) and poly(d-lactic acid) blends after isothermal crystallization","authors":"Wenwei Li, Jun Shen, Dutchanee Pholharn, Keartisak Sriprateep, Patnarin Worajittiphon, Yottha Srithep","doi":"10.1515/polyeng-2024-0081","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0081","url":null,"abstract":"The effect of epoxidized soybean oil (ESO) on homocrystallization (HC) and stereocomplex (SC) formation behavior of poly(l-lactide) (PLLA) and poly(d-lactide) (PDLA) bends was investigated utilizing differential scanning calorimetry (DSC). Isothermal crystallization was performed on ESO/PLLA/PDLA blends with varying ESO contents (0, 5, 8, and 10 wt%) and temperatures (90 °C, 120 °C, and 150 °C) for a different duration (12.5, 25, and 125 min). It was found that the ESO could effectively inhibit HC crystallization and promote SC crystallization. For the sample without ESO (ESO-0), the isothermal crystallization temperature and duration had little effect on the melting behavior, whereas sample with 5 wt% ESO (ESO-5), HC crystallization decreased while SC crystallization continued to increase with increasing duration. Additionally, at higher crystallization temperatures with constant ESO content, the melting temperature of SC crystals did not significantly change, suggesting that ESO did not degrade PLLA/PDLA blends. These findings imply that ESO modifies crystallization kinetics, suppressing HC formation and enhancing SC formation, which could benefit for specific material properties and applications.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"49 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142184719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0