Journal of Polymer Engineering最新文献

筛选
英文 中文
Electrospinning behavior study of composite fiber membranes loaded with tantalum particles 负载钽颗粒复合纤维膜的静电纺丝行为研究
4区 工程技术
Journal of Polymer Engineering Pub Date : 2026-07-16 DOI: 10.1515/polyeng-2026-0066
Junyao Zhang, Wen Shen, Jiaru Hu, Pi Yan, Rong Wang, Qingxiang Wang
{"title":"Electrospinning behavior study of composite fiber membranes loaded with tantalum particles","authors":"Junyao Zhang, Wen Shen, Jiaru Hu, Pi Yan, Rong Wang, Qingxiang Wang","doi":"10.1515/polyeng-2026-0066","DOIUrl":"https://doi.org/10.1515/polyeng-2026-0066","url":null,"abstract":"Abstract In this study, composite fiber membranes loaded with tantalum particles were prepared by electrostatic spinning technique, and three polymers, poly(lactic acid) (PLA), polycaprolactone (PCL), and poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)), which are widely used in biomedical applications, were selected as the matrix materials and screened for different solvent systems, respectively. The morphology, crystallinity and hydrophilicity of tantalum-induced fibrous membranes were investigated under different material and solvent conditions. The results showed that the conductivity of the spinning solution and its ability to generate induced charges in the electric field were enhanced by dispersion and charge migration, which in turn induced the jets to be stressed in the electric field and form finer fibers. Scanning electron microscope (SEM) and transmission electron microscope (TEM) analyses showed that the charge transfer behavior of tantalum particles promoted fiber stretching, leading to fiber diameter refinement. X-ray diffraction (XRD) and infrared spectroscopy (IR) analyses showed that the incorporation of tantalum particles induced the transformation of P(VDF-TrFE) from α-phase to β-phase, but had less effect on the crystallinity of PCL and PLA. In addition, hydrophilicity tests showed that tantalum particles reduced the hydrophobicity of PCL and PLA fiber membranes through charge-mediated surface modification.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148672207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of the sacrificial material for synergistic molding of microvascular composites 微血管复合材料协同成型牺牲材料的增强
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-11-20 DOI: 10.1515/polyeng-2025-0105
Taizhi Liu, Zeng He, Rulin Shen, Guanyu Liu, Yanling Gong
{"title":"Enhancement of the sacrificial material for synergistic molding of microvascular composites","authors":"Taizhi Liu, Zeng He, Rulin Shen, Guanyu Liu, Yanling Gong","doi":"10.1515/polyeng-2025-0105","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0105","url":null,"abstract":"Abstract Poly(propylene carbonate) (PPC) is a promising material for the synergistic molding of microvascular composites due to its thermal depolymerization characteristics. However, its low mechanical strength makes it susceptible to deformation under the high vacuum pressures required during composite fabrication. To address this limitation, this study investigates the effects of polylactic acid (PLA), poly(vinyl alcohol) (PVA), and nano-sized silicon dioxide (SiO 2 ) as modifying additives, using blending and filling techniques to enhance the mechanical properties of PPC. The results show that all three additives improve the properties of PPC, with the formulation containing 7.5 wt% SiO 2 exhibiting the most significant enhancement. The tensile strength increased from 30.15 MPa to 40.63 MPa (a 34.76 % improvement), and the Young’s modulus increased from 393.05 MPa to 668.23 MPa (a 75.1 % increase). The onset decomposition temperature is 115.5 °C, and the fastest decomposition temperature is 159.3 °C. Microvascular composites were successfully fabricated using the vacuum-assisted resin transfer molding (VARTM) process combined with frontal polymerization. Under a vacuum pressure of −0.95 bar, the aspect ratio (AR) of the microvascular cross section improved from 1.67 ± 0.15 to 1.03 ± 0.01, confirming that the optimized, SiO 2 -reinforced PPC is suitable for use as a sacrificial template in high-pressure composite molding processes.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"46 1","pages":"58-69"},"PeriodicalIF":0.0,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147911529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of polyvinyl alcohol composite films by incorporation of coumarin-3-carboxylic acid modified silica 香豆素-3-羧酸改性二氧化硅复合聚乙烯醇膜的制备及性能研究
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-11-14 DOI: 10.1515/polyeng-2025-0108
Lu Zhang, Jian Li, Shanshan Luo, Jing Sun, Chengtao Gao
{"title":"Preparation and properties of polyvinyl alcohol composite films by incorporation of coumarin-3-carboxylic acid modified silica","authors":"Lu Zhang, Jian Li, Shanshan Luo, Jing Sun, Chengtao Gao","doi":"10.1515/polyeng-2025-0108","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0108","url":null,"abstract":"Abstract Polyvinyl alcohol (PVA) exhibits excellent film-forming properties, but the limited functionality restricts its broader practical applications. To improve the poor water resistance and lack of antibacterial activity of polyvinyl alcohol (PVA) films, series composites were prepared by using coumarin-3-carboxylic acid (CCA) grafted onto silica nanoparticles (CCAS) and then introduced into PVA matrix along with a plasticizer (PEG). The results showed that the maximum tensile strength of the composite film was increased by 94 %, while its good plasticity was preserved. As the CCAS content in the PVA matrix increased, the composite film presented raised water contact angle but decreased water vapor transmission coefficient, indicating an improvement in water resistance. However, excessive CCAS would affect the films from the aspects of opacity plus mechanical properties. In addition, the UV-shielding ability of the composite films was close to 100 %, which exerted an inhibitory effect on the growth of Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) (≥90 %). In particular, the inhibition rate against S. aureus was as high as 94 %. Compared with PVA film, the composite films exhibited superior mechanical properties, optical properties, antibacterial activity, and water vapor barrier properties, making them more promising for practical applications.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"46 1","pages":"46-57"},"PeriodicalIF":0.0,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147906215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid mesoporous silica composite nano drug carrier modified by CTS-poly(NIPAM-co-AA) CTS-poly(NIPAM-co-AA)修饰的杂化介孔二氧化硅复合纳米药物载体
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-09-22 DOI: 10.1515/polyeng-2025-0052
Keju Zhang, Lei Xie, Qing Xia, Yong Liu
{"title":"Hybrid mesoporous silica composite nano drug carrier modified by CTS-poly(NIPAM-co-AA)","authors":"Keju Zhang, Lei Xie, Qing Xia, Yong Liu","doi":"10.1515/polyeng-2025-0052","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0052","url":null,"abstract":"Abstract At present, the forefront of drug carrier research revolves around crafting nano-sized carriers, particularly using hybrid mesoporous silica nanoparticles (MSNs). This study reported the fabrication of 180 nm MSNs featuring an ethane bridge skeleton structure, starting with the synthesis of MSNs, modifications were made by first applying γ -methacryloxypropyl trimethoxysilane (MPS) onto the MSNs. Following this, N-isopropyl acrylamide (NIPAM), acrylic acid (AA), and carboxymethyl chitosan (CTS) were grafted onto the MSNs, resulting in the successful creation of the composite MSNs-CTS-poly(NIPAM-co-AA) (abbreviated as MSNs-CTS-PNA) nano drug carrier. The experimental findings highlighted a notable drug encapsulation efficiency (75.5 ± 2.7 %) due to the core–shell architecture of MSNs-CTS-PNA. This tiered functionalization synergistically combines structural stability, pH and temperature stimuli-responsiveness, and biocompatibility. The ethane-bridged MSNs synthesis provides a rigid, porous framework for high drug loading, while CTS coating greatly boosts biocompatibility and prolongs circulation time. The optimized shell thickness balances high encapsulation efficiency and controlled drug release. These innovations make MSNs-CTS-PNA an advanced platform for targeted, combination, and environmentally adaptive drug delivery.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 10","pages":"816-827"},"PeriodicalIF":0.0,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147888864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Filtration loss mechanisms of polyacrylamide-based copolymers in high-temperature drilling fluid 高温钻井液中聚丙烯酰胺基共聚物的滤失机理
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-09-22 DOI: 10.1515/polyeng-2025-0132
Yuxiu An, Shaocong Pang, Luo Zhao, Tianle Li, Liangliang Yan
{"title":"Filtration loss mechanisms of polyacrylamide-based copolymers in high-temperature drilling fluid","authors":"Yuxiu An, Shaocong Pang, Luo Zhao, Tianle Li, Liangliang Yan","doi":"10.1515/polyeng-2025-0132","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0132","url":null,"abstract":"Abstract Deep and ultra-deep oil and gas exploration imposes stringent requirements on water-based drilling fluids. Conventional fluid loss additives often fail to deliver stable performance in these extreme environments, largely due to inadequate functional group composition and thermal stability. This work introduces an innovative strategy by regulating the structure of quaternary AM/AMPS/NVP/DMDAAC copolymers and clarifying their high-temperature filtration loss mechanisms. Five polymers with different compositions were synthesized, and their structural features, thermal stability, filtration loss performance, and mechanisms were systematically evaluated. The results showed that the monomer composition significantly influenced the polymer’s structural characteristics and thermal stability. Increasing the N-vinylpyrrolidone (NVP) content to 25–40 % enhanced intermolecular interactions and thermal stability at high temperatures, with a filtration volume of 25.7 mL in freshwater-based mud after aging at 240 °C. It was found that Poly D formed a dense filter cake through strong hydrogen bonding with high adsorption. Moreover, high dimethyldiallylammonium chloride (DMDAAC) content triggered charge shielding effect and disrupted bentonite dispersion. And NVP reduces permeability by modulating the equilibrium of filter cake affinity. This study reveals the structure-property relationship of copolymers under high-temperature and high-salt conditions, which provides new perspectives and experimental bases for designing and synthesizing high-temperature water-based fluid loss control agent for drilling fluids.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 10","pages":"871-881"},"PeriodicalIF":0.0,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147911480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Chitosan surface coating modified submicron ordered porous zirconia 壳聚糖表面涂层改性亚微米有序多孔氧化锆
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-09-21 DOI: 10.1515/polyeng-2024-0267
Zhicheng Zhao, Lili Wang, Xu‐ri Hou, Xiao-he He, Hongtao Jiang
{"title":"Chitosan surface coating modified submicron ordered porous zirconia","authors":"Zhicheng Zhao, Lili Wang, Xu‐ri Hou, Xiao-he He, Hongtao Jiang","doi":"10.1515/polyeng-2024-0267","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0267","url":null,"abstract":"Abstract Ordered porous ZrO 2 has good biocompatibility and chemical stability, however, it exhibits low bioactivity and insufficient drug loading. In this study, submicron ordered porous ZrO 2 skeleton was constructed using polystyrene colloidal crystal with an average size of 820 ± 10 nm as the template. It was then modified by chitosan (CS) surface coating to change its surface functional groups, thereby improving its adsorption capacity and obtaining surface bioactivity to expand its potential application in the field of drug slow release. The factors affecting ordered porous morphology of the composite and their influencing rules were studied in detail. The results indicated that morphology of the composite was greatly affected by the concentration of CS, coating time, molecular weight of CS, and degree of deacetylation (DD). When the CS concentration was 1 wt%, the coating time was 1 h, the CS molecular weight was 200 kDa, and the DD was 90 %, the composite had regular ordered porous morphology and uniform thickness, which is expected to become a high performance drug sustained-release carrier material.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 10","pages":"854-860"},"PeriodicalIF":0.0,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147892171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrating low dielectric constant and high thermal conductivity into composite films for 5G circuit package substrate 将低介电常数和高导热系数集成到5G电路封装基板的复合薄膜中
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-08-09 DOI: 10.1515/polyeng-2024-0213
Caijie Shi, Xuyi Wang, Qiannan Cheng, Qingquan Tang, Luoxin Wang, Hua Wang, Siwei Xiong
{"title":"Integrating low dielectric constant and high thermal conductivity into composite films for 5G circuit package substrate","authors":"Caijie Shi, Xuyi Wang, Qiannan Cheng, Qingquan Tang, Luoxin Wang, Hua Wang, Siwei Xiong","doi":"10.1515/polyeng-2024-0213","DOIUrl":"https://doi.org/10.1515/polyeng-2024-0213","url":null,"abstract":"Abstract The high-frequency, integrated, and miniaturized circuits increase the risks of electromagnetic interference and heat accumulation. However, it is difficult for the traditional circuit package substrate to realize both low dielectric and high thermal conductivity, resulting in high-quality signal transmission and fast heat dissipation cannot be achieved simultaneously. Here, for the first time, composite films (hBN/LCPs) with low dielectric constant in high-frequency and high thermal conductivity are prepared based on liquid crystal aromatic polyesters (LCPs) and hexagonal boron nitride (hBN). The highest thermal conductivity of hBN/LCPs film reaches 0.696 W m −1 K −1 , which is 3.3 times higher than that of the pristine LCPs. In the simulation of wafer heat dissipation, hBN/LCPs film shows a maximum surface temperature decrease of over 20 °C compared to the pristine LCPs, showing the fast heat transfer ability. The dielectric constants and dielectric losses of hBN/LCPs films keep the low values in the range of 0.4–1 GHz, being less than 3.4 and 0.007, respectively, meeting the requirements of 5G communication devices. Meanwhile, the hBN/LCPs films show good mechanical strength and heat resistance. Therefore, a low-cost and facile method is developed to prepare composite films with low dielectric and high thermal conductivity for 5G circuit package substrates.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 9","pages":"769-777"},"PeriodicalIF":0.0,"publicationDate":"2025-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147907533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-mode adaptive isolation bearing with hybrid magnetorheological shear-stiffening materials: development and dynamic performance characterization 混合磁流变剪切加筋材料双模自适应隔震轴承:研制与动态性能表征
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-07-11 DOI: 10.1515/polyeng-2025-0069
Fei Guo, Runpu Li, Xiaoguo Lin, Hanbo Cui, Zhedong Xu, Chengbin Du, Zongyun Mo
{"title":"Dual-mode adaptive isolation bearing with hybrid magnetorheological shear-stiffening materials: development and dynamic performance characterization","authors":"Fei Guo, Runpu Li, Xiaoguo Lin, Hanbo Cui, Zhedong Xu, Chengbin Du, Zongyun Mo","doi":"10.1515/polyeng-2025-0069","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0069","url":null,"abstract":"Abstract This study presents the development and performance evaluation of an innovative intelligent isolation bearing integrating dual magnetorheological shear stiffening units: a magnetorheological shear stiffening gel (MRSSG) and a magnetorheological shear stiffening elastomer (MRSSE). The system’s dynamic shear behavior was systematically investigated under small (5 mm) and large (15–25 mm) displacement regimes. Initially, isotropic MRSSG and anisotropic MRSSE were synthesized and characterized through rheological measurements, demonstrating that their storage modulus and damping factor exhibit autonomous frequency-dependent responses while being magnetically tunable. The bearing architecture employs a hierarchical design: the upper MRSSG unit operates through shear deformation to deliver stiffness and damping enhancement under small displacements, whereas the lower laminated MRSSE unit activates under large displacements to maintain structural stability. Dynamic testing revealed three critical control parameters governing shear performance: excitation frequency, applied current, and axial load. Notably, under a 15 mm displacement and 12.0 MPa axial load, the bearing achieved a maximum shear force output of 247.7 kN. Quantitative performance characterization was conducted through three key metrics: equivalent stiffness ( K h ), post-yield stiffness ( K d ), and equivalent damping ratio ( h eq ). While K h and K d showed positive correlations with frequency, current, and axial load, h eq demonstrated displacement-dependency, with optimal energy dissipation observed at smaller displacements.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"45 8","pages":"688-701"},"PeriodicalIF":0.0,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147892343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Preparation of chitosan/nano-copper sulfide/carrageenan bilayer film and its application in strawberry preservation 壳聚糖/纳米硫化铜/卡拉胶双层膜的制备及其在草莓保鲜中的应用
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-06-20 DOI: 10.1515/polyeng-2025-0076
Yue Zeng, Zhixin Xue, Cunzhen Geng, Cuixia Qiao
{"title":"Preparation of chitosan/nano-copper sulfide/carrageenan bilayer film and its application in strawberry preservation","authors":"Yue Zeng, Zhixin Xue, Cunzhen Geng, Cuixia Qiao","doi":"10.1515/polyeng-2025-0076","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0076","url":null,"abstract":"Abstract This study developed a bilayer film (CS-xCuS/CA) for food packaging, using chitosan (CS), nano-copper sulfide (CuS NP) and carrageenan (CA) through a casting method and a layer-by-layer approach. The structure of CS-xCuS/CA was analyzed by Fourier transform infrared spectroscopy and X-ray diffraction. The mechanical properties, swelling degree, water vapor permeability, water contact angle, and optical properties of the film were evaluated. At 0 % humidity, tensile strength of the film increased with concentration of CuS NP. Conversely, at 25 % and 50 % humidity, tensile strength initially increased and then decreased with rising CuS NP concentration, a behavior attributed to hydrogen bonding. Furthermore, the incorporation of CuS NP enhanced the hydrophobicity of the film, achieving a contact angle of 118.88° at a CuS NP mass fraction of 0.75 wt%. Additionally, CuS NP significantly improved the UV resistance of the composite film. In tests for strawberry preservation, the efficacy of CS-xCuS/CA increased with the concentration of CuS NP. This film holds promise for applications in fruit packaging and food preservation industry.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147893248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of ER/NR foamed composites with adjustable shape memory and oil adsorption properties 具有可调形状记忆和吸油性能的ER/NR泡沫复合材料的制备
4区 工程技术
Journal of Polymer Engineering Pub Date : 2025-06-05 DOI: 10.1515/polyeng-2025-0051
Mingyue Pang, Haibiao Wang, Zheng Yuan, Yaotu Han, Hui Zhang, Jieting Geng
{"title":"Preparation of ER/NR foamed composites with adjustable shape memory and oil adsorption properties","authors":"Mingyue Pang, Haibiao Wang, Zheng Yuan, Yaotu Han, Hui Zhang, Jieting Geng","doi":"10.1515/polyeng-2025-0051","DOIUrl":"https://doi.org/10.1515/polyeng-2025-0051","url":null,"abstract":"Abstract A novel class of eco-friendly natural Eucommia rubber (ER)/natural rubber (NR) foam composites with tunable shape memory and oil adsorption capabilities has been successfully developed through optimized vulcanization-foaming integration technology. This study utilized comprehensive characterization techniques such as universal testing machine measurements, scanning electron microscopy, and complementary analytical methods to systematically evaluate the foamed composites’ mechanical properties, shape memory behavior, and oil absorption characteristics. Through these advanced characterization approaches, we elucidated the precise influence of foaming agent H concentration on both the macroscopic performance and microstructural evolution of the foam composites. When increasing the foaming agent H content, the cellular morphology exhibited substantial expansion. This structural transformation was accompanied by a marked density reduction from 0.52 g/cm 3 to 0.18 g/cm 3 , concurrently driving a corresponding decline in tensile strength from 11.1 MPa to 4.3 MPa. Beyond these fundamental property variations, the composites manifested distinctive functional characteristics including notable shape memory effects and temperature-responsive oil absorption capabilities. Particularly noteworthy was the precisely tunable oil adsorption performance, which could be strategically modulated through controlled physical state transitions of the composites under thermal stimuli. This thermal responsiveness establishes promising potential for intelligent material applications requiring adaptive oil–water separation functionality.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147922306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书