Journal of Environmental Chemical Engineering最新文献

筛选
英文 中文
Insight into the transformation and influence of soil dissolved organic matter on pollutant degradation by microwave activated peroxymonosulfate 微波活化过氧单硫酸盐对土壤溶解有机质转化及对污染物降解影响的研究
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-10 DOI: 10.1016/j.jece.2026.121165
Xiao Shang , Xiwang Zhao , Xitao Liu , Xiaoyu Ma , Chunye Lin , Mengchang He , Wei Ouyang
{"title":"Insight into the transformation and influence of soil dissolved organic matter on pollutant degradation by microwave activated peroxymonosulfate","authors":"Xiao Shang ,&nbsp;Xiwang Zhao ,&nbsp;Xitao Liu ,&nbsp;Xiaoyu Ma ,&nbsp;Chunye Lin ,&nbsp;Mengchang He ,&nbsp;Wei Ouyang","doi":"10.1016/j.jece.2026.121165","DOIUrl":"10.1016/j.jece.2026.121165","url":null,"abstract":"<div><div>Soil dissolved organic matter (SDOM) plays a critical role in persulfate-based advanced oxidation processes (PS-AOPs) for soil remediation by directly influencing the degradation kinetics of pollutants. In this study, the effect of SDOM on chlorpyrifos (CPF) degradation was investigated in microwave-activated peroxymonosulfate system, the composition and transformation of SDOM by singlet oxygen (<sup>1</sup>O<sub>2</sub>)-dominated PS-AOPs was systematically analyzed through optical characterization and molecular-level analysis. As a result, a significant negative correlation between CPF degradation and SDOM contents demonstrated the inhibitory role of SDOM. The dissolution/extraction, oxidative depolymerization, and oxidative catalysis of SDOM occurred between soil phase and aqueous phase. With increasing PMS dose from 0 to 17.6 g/kg, relatively saturated molecules with lower oxidation degree and aromaticity were converted into unsaturated and oxidized ones with higher aromaticity, concomitant with a reduction in molecular weight. While at 26.4 g/kg of PMS dose, the concentrated aromatic structures and tannins with higher unsaturation were mainly oxidized, accompanying with the production of substances such as lipids, proteins/aminosugars, lignin with lower aromaticity and unsaturation. The <sup>1</sup>O<sub>2</sub>-mediated transformation of SDOM proceeded through multiple reaction pathways including electrophilic addition, single electron transfer, and addition to heteroatom, ultimately resulting in ring opening and cleavage of SDOM molecules. Although an increased PMS dose enhanced CPF degradation, it also led to lower PMS utilization efficiency and higher ecological risks because of the competitive reactions of SDOM. Therefore, elucidating transformation and inhibition mechanisms of SDOM provide a new sight for the application of <sup>1</sup>O<sub>2</sub>-dominated PS-AOPs in soil remediation.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121165"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fouling behavior and cleaning strategy during treatment of practical refractory organic wastewater using anaerobic ceramic membrane bioreactor 厌氧陶瓷膜生物反应器处理难降解有机废水的污染行为及清洗策略
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-08 DOI: 10.1016/j.jece.2026.121077
Ruihui Chen , Lixiu Shi , Xinsen Li , Hongming Yang , Sheng Xiang , Mohd Fadhil MD Din , Eli Hendrik Sanjaya , Lu Peng , Zhengwang Wu , Chengcheng Lin , Hong Chen
{"title":"Fouling behavior and cleaning strategy during treatment of practical refractory organic wastewater using anaerobic ceramic membrane bioreactor","authors":"Ruihui Chen ,&nbsp;Lixiu Shi ,&nbsp;Xinsen Li ,&nbsp;Hongming Yang ,&nbsp;Sheng Xiang ,&nbsp;Mohd Fadhil MD Din ,&nbsp;Eli Hendrik Sanjaya ,&nbsp;Lu Peng ,&nbsp;Zhengwang Wu ,&nbsp;Chengcheng Lin ,&nbsp;Hong Chen","doi":"10.1016/j.jece.2026.121077","DOIUrl":"10.1016/j.jece.2026.121077","url":null,"abstract":"<div><div>Membrane fouling remains a critical bottleneck limiting the application of anaerobic membrane bioreactors (AnMBRs) for high-strength refractory organic wastewater treatment. In this study, a lab-scale submerged anaerobic ceramic membrane bioreactor (AnCMBR) coupled with a continuous stirred-tank reactor (CSTR) was operated continuously for 254 days to investigate the fouling characteristics, mechanisms, and cleaning strategies of ceramic membrane during treatment of practical swine wastewater. Transmembrane pressure (TMP) reached 25 kPa after 120 days of operation with an average rise rate of 0.24 kPa/d, showing good antifouling performance of the ceramic membrane. Three-Dimensional Excitation-Emission Matrix fluorescence spectroscopy identified tryptophan-like proteins as primary cake layer foulants. A combined physical (high-pressure washing, backwashing) and chemical (2 M NaOH + 0.2 % NaClO) cleaning strategy achieved a maximum of 86.7 % flux recovery ratio (FRR). The post-cleaning membrane showed a shortened fouling cycle, in which TMP reached the critical value in 48 days with a rise rate of 0.45 kPa/d. The proportion of intrinsic membrane resistance (11.3 %) caused by irreversible pore blocking was higher than that in a new membrane (6.5 %), indicating insufficient mitigation of irreversible fouling by the current cleaning strategy. For Proteobacteria, Comamonadaceae and <em>Candidatus Competibacter</em> secrete soluble microbial products (SMP) to enhance microbial adhesion to the membrane surface; this aligns with reports of Comamonadaceae-related genera and <em>Candidatus Competibacter</em> producing extracellular substances that mediate biofilm matrix consolidation. This work provides a basis for analyzing the fouling mechanism of ceramic membranes and optimizing cleaning strategies in the process of treating swine wastewater using AnCMBR.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121077"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional solar evaporator: Directional freezing engineering for concurrent freshwater and electricity production with antibacterial property 多功能太阳能蒸发器:具有抗菌性能的淡水和电力同步生产的定向冷冻工程
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-14 DOI: 10.1016/j.jece.2026.121240
Zhen Li , Zhaoping Song , Jiebin Tang , Xi Gong , Huili Wang , Wenxia Liu
{"title":"Multifunctional solar evaporator: Directional freezing engineering for concurrent freshwater and electricity production with antibacterial property","authors":"Zhen Li ,&nbsp;Zhaoping Song ,&nbsp;Jiebin Tang ,&nbsp;Xi Gong ,&nbsp;Huili Wang ,&nbsp;Wenxia Liu","doi":"10.1016/j.jece.2026.121240","DOIUrl":"10.1016/j.jece.2026.121240","url":null,"abstract":"<div><div>Limited evaporation rates, the threat of bacterial contamination, and the low utilization efficiency of electric potential generated during solar evaporation significantly hinder the development of evaporation processes—particularly in scenarios such as seawater treatment, industrial wastewater processing, and rural applications. In this work, a directionally frozen, architected solar-driven interfacial evaporator was prepared, which can achieve simultaneous high-efficiency evaporation, photocatalytic antibacterial function, and electric potential generation. Specifically, black titanium dioxide (B-TiO<sub>2</sub>) with excellent antibacterial properties was firstly prepared using a high-temperature reduction method. TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl)-oxidized cellulose nanofiber nanoparticles (TOCNFs) incorporated with Polyacrylamide (PAAm) to prepare PAAm/TOCNFs (PT) hydrogel evaporator. Subsequently, B-TiO<sub>2</sub> was coated onto the surface of the PT hydrogel to improve its light-to-heat conversion capability, then finally obtained the B-TiO<sub>2</sub>@PAAm/TOCNFs (PTBT) solar evaporator. The introduction of TOCNFs increased the evaporation rate to 3.94 kg·m<sup>−2</sup>·h<sup>−1</sup>, and decreased the latent heat of water in the PTBT evaporator to 889.75 kJ·kg<sup>−1</sup>. Benefiting from the photocatalytic antibacterial properties of B-TiO<sub>2</sub>, the antibacterial efficiency of PTBT against <em>E. coli</em> and <em>S. aureus</em> reached 99.9 % and 99.8 %, respectively. Additionally, during the evaporation process, the PTBT evaporator exhibited salt tolerance and generated an open-circuit voltage as high as 184 mV. The combination of efficient solar evaporation with superior antibacterial properties is significant for improving solar energy utilization. This technology also holds significant potential for electricity generation via water evaporation.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121240"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamics of engineered nanomaterials in the rhizosphere: Bidirectional feedback orchestrating multiscale responses 根际中工程纳米材料的动力学:双向反馈协调多尺度响应
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-12 DOI: 10.1016/j.jece.2026.121159
Weicheng Cao , Meng Qin , Yiting Wu , Qingyan Yu , Zhangchunzi Zhao , Xiaodong Nie , Zhongwu Li
{"title":"Dynamics of engineered nanomaterials in the rhizosphere: Bidirectional feedback orchestrating multiscale responses","authors":"Weicheng Cao ,&nbsp;Meng Qin ,&nbsp;Yiting Wu ,&nbsp;Qingyan Yu ,&nbsp;Zhangchunzi Zhao ,&nbsp;Xiaodong Nie ,&nbsp;Zhongwu Li","doi":"10.1016/j.jece.2026.121159","DOIUrl":"10.1016/j.jece.2026.121159","url":null,"abstract":"<div><div>Engineered nanomaterials (ENMs) hold transformative potential for diverse applications such as precision agriculture and soil remediation. However, assessing their subsequent ecological impacts, particularly within the dynamic rhizosphere, is complicated by complex feedback interactions among abiotic soil factors and plant-microbial dynamics. This review establishes a bidirectional feedback framework to elucidate how ENMs reshape rhizosphere microhabitats and, conversely, how soil-plant-microbe crosstalk dictates ENMs fates. Within this framework, soil properties, microbial extracellular matrices and root exudate chemodynamics emerge as master regulators of ENMs transformation cascades, thereby redefining paradigms of nanoecotoxicity and the associated feedback loops. Further, this review proposes the nano-feedback threshold (NFT) hypothesis, suggesting that microbial functional redundancy, plant tolerance and the chemodiversity of soil factors jointly buffer ENMs perturbations until a threshold is crossed, triggering cascading ecosystem reorganization. Critically, interdisciplinary integration approaches integrating multi-scale and multi-dimensional perspectives are necessary for decoding the feedback loops and NFT of ENMs in the rhizosphere. This review provides a conceptual basis for innovative ENMs development and identifies key strategies for leveraging ecologically balanced nanotechnology to support the achievement of Sustainable Development Goals in a changing climate.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121159"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of cyanide-containing wastewater: Sources, hazard and treatment methods 含氰废水的来源、危害及处理方法综述
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-19 DOI: 10.1016/j.jece.2026.121344
Pengyi Wang , Acong Chen , Huihuan Lian , Shah Muhammad Ahmadzai , Fenglin Chang , Yi Pan , Yidi Chen , Bin Zhang , Huabin Zeng , Chaohai Wei
{"title":"A review of cyanide-containing wastewater: Sources, hazard and treatment methods","authors":"Pengyi Wang ,&nbsp;Acong Chen ,&nbsp;Huihuan Lian ,&nbsp;Shah Muhammad Ahmadzai ,&nbsp;Fenglin Chang ,&nbsp;Yi Pan ,&nbsp;Yidi Chen ,&nbsp;Bin Zhang ,&nbsp;Huabin Zeng ,&nbsp;Chaohai Wei","doi":"10.1016/j.jece.2026.121344","DOIUrl":"10.1016/j.jece.2026.121344","url":null,"abstract":"<div><div>Cyanide is regarded as one of the key prebiotic compounds potentially involved in the origin of life on Earth, but it is also a hazardous pollutant with toxic effects on human health and the environment. Before discharge, cyanide-containing wastewater must be treated to mitigate its harmful impact. This article summarizes research achievements over the past five years alongside established disposal methods. Cyanide-containing wastewater is classified into two categories based on its source: exogenous addition and endogenous generation. Subsequently, the environmental hazards and biological toxicity of cyanide-containing wastewater are evaluated. The stability of cyanide compounds and the reasons behind the difficulties in treating this wastewater are also explored. Treatment methods are categorized according to their underlying principles as physical methods, chemical oxidation methods, chemical precipitation methods, and biological treatment methods. The treatment efficacy and costs associated with these different methods are systematically compared.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121344"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146024405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential and challenges of medium-chain fatty acids production from waste activated sludge using piezoelectric materials 利用压电材料从废活性污泥中生产中链脂肪酸的潜力和挑战
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-29 DOI: 10.1016/j.jece.2026.121480
Jiawei Liu , Xiangkun Li , Pengwei Xu , Ningxin Hu , Hao Ren , Gaige Liu
{"title":"Potential and challenges of medium-chain fatty acids production from waste activated sludge using piezoelectric materials","authors":"Jiawei Liu ,&nbsp;Xiangkun Li ,&nbsp;Pengwei Xu ,&nbsp;Ningxin Hu ,&nbsp;Hao Ren ,&nbsp;Gaige Liu","doi":"10.1016/j.jece.2026.121480","DOIUrl":"10.1016/j.jece.2026.121480","url":null,"abstract":"<div><div>Efficient resource recovery of waste activated sludge (WAS) is essential for advancing circular economy and reducing environmental burdens. Traditional anaerobic fermentation suffers from low-value products and high separation costs, while medium-chain fatty acids (MCFAs) have attracted considerable attention as high-value chemicals. However, the dense extracellular polymeric substances (EPS) in sludge and the electron transfer bottleneck in anaerobic metabolism limit the synthesis efficiency of MCFAs. This study proposes a novel strategy for synergistically enhancing MCFAs production from sludge using piezoelectric materials: initially, at the physicochemical level, piezoelectric materials generate reactive oxygen species (ROS) through mechanical stress to break down the EPS barrier; subsequently, at the biological level, modified piezoelectric materials function as both “electronic bridges” and “field-effect generators” to enhance extracellular electron transfer (EET), promoting carbon flow towards the reverse β-oxidation (RBO) and fatty acid biosynthesis (FAB) pathways. Future research should focus on improving material stability and conducting technical-economic analysis to ensure the feasibility of this technology in practical sludge treatment.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121480"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic effect of Bi₂MoO₆ and expanded MoS₂ heterostructures for highly efficient visible-light-driven environmental remediation Bi₂MoO₆与膨胀MoS₂异质结构的协同效应在高效可见光环境修复中的应用
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-13 DOI: 10.1016/j.jece.2025.120830
Magdeline Tze Leng Lai , Bao Lee Phoon , Kian Mun Lee , Chin Wei Lai , Mohd Rafie Johan , Supakorn Boonyuen , Joon Ching Juan
{"title":"Synergistic effect of Bi₂MoO₆ and expanded MoS₂ heterostructures for highly efficient visible-light-driven environmental remediation","authors":"Magdeline Tze Leng Lai ,&nbsp;Bao Lee Phoon ,&nbsp;Kian Mun Lee ,&nbsp;Chin Wei Lai ,&nbsp;Mohd Rafie Johan ,&nbsp;Supakorn Boonyuen ,&nbsp;Joon Ching Juan","doi":"10.1016/j.jece.2025.120830","DOIUrl":"10.1016/j.jece.2025.120830","url":null,"abstract":"<div><div>A series of Bi₂MoO₆/interlayer-expanded MoS₂ (BM-IEM) heterostructures was synthesized via a two-step hydrothermal method and evaluated for visible-light-driven methylene blue (MB) photodegradation. The 3 wt% BM–IEM composite achieved the highest photocatalytic efficiency, removing 98.2 % of MB in 60 min and sustaining its photocatalytic performance through five continuous cycles. This superior enhanced activity results from the strong interfacial coupling of Bi₂MoO₆ with the expanded MoS₂ structure, thereby enlarging the interlayer spacing, increasing the surface area, and creating strong electronic coupling at the Bi–O–S–Mo interface. These features enhance light absorption, facilitate charge separation, and promote the generation of reactive oxygen species (ROS). Oxygen-vacancy (O<sub>V</sub>) formation within the composite introduces mid-gap states that extend light responsiveness and support efficient electron transfer to adsorbed O₂, forming superoxide (•O₂⁻) and hydroxyl (•OH) radicals. The photocatalytic mechanism was analyzed through radical trapping and LC-MS experiments, revealing degradation pathways involving ring-opening oxidation, hydroxylation, and N-demethylation. The results demonstrate that tailoring interlayer spacing and defect states in MoS₂-based heterojunctions provides an effective design strategy for high-performance, visible-light-responsive photocatalysts for wastewater purification.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 120830"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sludge-derived hydrochar enhances anaerobic digestion of sludge with tetracycline: Focusing on synergistic mechanism and microbial response 污泥衍生碳氢化合物增强污泥与四环素厌氧消化:聚焦协同机制和微生物响应
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-15 DOI: 10.1016/j.jece.2026.121256
Jiaojiao Shi , Guoqing Li , Saiyu Yuan , Zhouyang Lian , Shengwei Wang , Huiwen Zhang
{"title":"Sludge-derived hydrochar enhances anaerobic digestion of sludge with tetracycline: Focusing on synergistic mechanism and microbial response","authors":"Jiaojiao Shi ,&nbsp;Guoqing Li ,&nbsp;Saiyu Yuan ,&nbsp;Zhouyang Lian ,&nbsp;Shengwei Wang ,&nbsp;Huiwen Zhang","doi":"10.1016/j.jece.2026.121256","DOIUrl":"10.1016/j.jece.2026.121256","url":null,"abstract":"<div><div>Anaerobic digestion is an effective strategy for the degradation of organic matter and recovery of high value-added products. While the inhibitory effect of antibiotics such as tetracycline (TC) on anaerobic digestion is known, and though biochar-based carriers have been explored to mitigate such inhibition, the potential of hydrocha to simultaneously remove antibiotics and enhance microbial activity remains unclear. In this study, sludge-derived hydrothermal carbon prepared with rice husk (SHC-IV) was applied as a bio-carrier to enhance the anaerobic digestion performance of tetracycline(TC)-contaminated sludge. Results showed that moderate TC addition (TC100) improved methane production, with a maximum cumulative yield of 44.97 mL/g·VS, 15.89 % higher than the Raw. The incorporation of SHC-IV further enhanced hydrolysis, acidogenesis, and methanogenesis, with the TC50 +SHC-IV achieving the highest improvement (7.61 %) compared to TC50 alone. Microbial diversity analysis revealed that TC and SHC-IV increased Chao1 and Shannon indices, indicating enhanced microbial richness and diversity. TC addition shifted the dominant methanogen from <em>Methanosaeta</em> to <em>Methanobacterium</em>, while SHC-IV enriched <em>Syntrophomonas</em> and <em>Methanosarcina</em>, promoting syntrophic interactions and optimizing the methanogenic pathway. Furthermore, SHC-IV addition enhanced the removal of TC, with the TC50 +SHC-IV group reaching the highest removal increase of 4.93 % compared to TC50 alone. These findings demonstrate that SHC-IV not only mitigates the environmental risks of TC in sludge but also enhances anaerobic digestion performance, offering a sustainable approach for in-plant sludge hydrothermal product utilization.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121256"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Addition of CuEDTA to a full-scale air scrubber eliminates emissions of H2S and methanethiol from livestock facilities 在全尺寸空气洗涤器中添加CuEDTA可以消除牲畜设施中H2S和甲硫醇的排放
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-09 DOI: 10.1016/j.jece.2026.121123
Pernille Lund Kasper , Anders Feilberg
{"title":"Addition of CuEDTA to a full-scale air scrubber eliminates emissions of H2S and methanethiol from livestock facilities","authors":"Pernille Lund Kasper ,&nbsp;Anders Feilberg","doi":"10.1016/j.jece.2026.121123","DOIUrl":"10.1016/j.jece.2026.121123","url":null,"abstract":"<div><div>The relatively low aqueous solubility of reduced sulfur compounds limits odor removal in chemical and biological filters for emissions from livestock facilities due to low filter bed residence times. This can be overcome by the addition of an oxidizing agent to enhance mass transfer to the liquid phase. In the present study, the addition of cupric ions to a full-scale alkaline scrubber for eliminating odorant emissions from a finisher pig facility was tested. To minimize precipitation, cupric ions were added in a complex with EDTA with the purpose of enabling catalytic oxidation of sulfur compounds. The experiments were carried out over a 10-week period and odorant concentrations were measured continuously with PTR-TOF-MS (Proton-Transfer-Reaction Time-Of-Flight Mass Spectrometry). During the period, pH was gradually increased from approximately 7.5–9.6. Removal efficiencies of H<sub>2</sub>S and methanethiol were found to increase significantly at pH &gt; 8.5, mostly pronounced for methanethiol. The modified scrubber was able to reduce H<sub>2</sub>S and methanethiol emissions by &gt; 99 % and &gt; 80 %, respectively, at pH &gt; 8.5. This was achieved at an empty-bed residence time of only 1.6 s. The total odor emission determined as SOAV (sum of odor activity values) under these conditions was shown to be reduced by <span><math><mn>96</mn></math></span>%.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121123"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient biodegradation and decolorization of azo dyes using peroxidase/chitosan-based enzyme-assisted coagulation 过氧化物酶/壳聚糖酶辅助混凝对偶氮染料的高效生物降解和脱色
IF 7.2 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2026-04-01 Epub Date: 2026-01-14 DOI: 10.1016/j.jece.2026.121235
Na-won Baek , Shin-hee Lee
{"title":"Efficient biodegradation and decolorization of azo dyes using peroxidase/chitosan-based enzyme-assisted coagulation","authors":"Na-won Baek ,&nbsp;Shin-hee Lee","doi":"10.1016/j.jece.2026.121235","DOIUrl":"10.1016/j.jece.2026.121235","url":null,"abstract":"<div><div>This study presents a novel enzyme-assisted coagulation (EAC) system as a low-carbon, energy-free strategy for the efficient treatment of azo dyes in textile wastewater. The EAC system integrates enzymatic oxidation with natural polymer-based coagulation and operates effectively under mild conditions without external energy input. Using horseradish peroxidase (HRP) and chitosan as model components, the system was applied to three representative azo dyes—Allura Red, Eriochrome Black, and Sunset Yellow—achieving decolorization efficiencies exceeding 98 %. Analytical techniques, including UV–Vis spectroscopy, FTIR, HPLC, and GC–MS, confirmed effective dye degradation and the stable aggregation of byproducts. The EAC mechanism involves the dual functionality of chitosan, which initially acts as an adsorbent and flocculant to enhance enzyme accessibility and subsequently serves as a stabilizing matrix that immobilizes and facilitates the removal of degradation products. This synergistic interaction between HRP and chitosan offers an efficient, biodegradable, and environmentally friendly approach for sustainable dye wastewater treatment.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"14 2","pages":"Article 121235"},"PeriodicalIF":7.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145981685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书