Journal of Environmental Chemical Engineering最新文献

筛选
英文 中文
Dual-emission carbon dots: Synthesis, applications, advances and challenges 双排放碳点:合成、应用、进展与挑战
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-22 DOI: 10.1016/j.jece.2025.117696
Nguyen Minh Hoang , Nguyen Thi Bich Ngoc , Nam-Anh Tran , Nang Xuan Ho , Hai-Linh Thi Dang , Dang Viet Cuong , Vu Thi Trang , Phan Thi Lan Huong , Phan Thi Thanh Huyen , Muhammad Saqlain Jamil , Sining Yun , Le Tuan Tu , Linh Nguyen Duy Pham , Van-Duong Dao
{"title":"Dual-emission carbon dots: Synthesis, applications, advances and challenges","authors":"Nguyen Minh Hoang ,&nbsp;Nguyen Thi Bich Ngoc ,&nbsp;Nam-Anh Tran ,&nbsp;Nang Xuan Ho ,&nbsp;Hai-Linh Thi Dang ,&nbsp;Dang Viet Cuong ,&nbsp;Vu Thi Trang ,&nbsp;Phan Thi Lan Huong ,&nbsp;Phan Thi Thanh Huyen ,&nbsp;Muhammad Saqlain Jamil ,&nbsp;Sining Yun ,&nbsp;Le Tuan Tu ,&nbsp;Linh Nguyen Duy Pham ,&nbsp;Van-Duong Dao","doi":"10.1016/j.jece.2025.117696","DOIUrl":"10.1016/j.jece.2025.117696","url":null,"abstract":"<div><div>Dual emission carbon dots (DE-CDs) have emerged as a transformative class of nanomaterials, offering distinct advantages over single-emission carbon dots (SE-CDs), including superior anti-interference capabilities, built-in self-calibration and broader full-width at half maximum (FWHM) emission spectra. This review comprehensively explores recent advancements in the synthesis of DE-CDs, detailing their physicochemical characteristics and elucidating key hypotheses underlying the formation of dual-emission peaks, such as the roles of core states, surface states, and quantum confinement effects. The diverse applications of DE-CDs are systematically analyzed, emphasizing their use in ratiometric sensing, bioimaging, biosensing, pH monitoring, moisture and water detection, and white light-emitting diodes (WLEDs). A comparative evaluation highlights their advantages and limitations relative to traditional fluorescence materials. Furthermore, recent progress in integrating DE-CDs into dye-sensitized solar cells (DSCs) and solar steam generation (SSG) devices is presented, underscoring their potential in renewable energy technologies. Finally, this review discusses the challenges and prospects for developing DE-CDs, including the need for scalable synthesis techniques, optimization of quantum yields for lighting applications, and enhanced understanding of dual-emission behavior mechanisms. Despite these challenges, DE-CDs hold immense promise for advancing technologies in sensing, bioimaging, lighting, and sustainable energy systems.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117696"},"PeriodicalIF":7.4,"publicationDate":"2025-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances of photocatalysts for nitrogen reduction reaction and mechanism behind them: How and why modifications change properties 氮还原反应光催化剂的研究进展及其机理:修饰如何及为何改变性质
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-21 DOI: 10.1016/j.jece.2025.117679
Jin Feng , Wenxing Xu , Xiaorui Xu , Xinlu Wang , Yan Wang , Fanjun Zhang , Yuanyuan Feng , Yuchen Ma , Dapeng Zhang
{"title":"Recent advances of photocatalysts for nitrogen reduction reaction and mechanism behind them: How and why modifications change properties","authors":"Jin Feng ,&nbsp;Wenxing Xu ,&nbsp;Xiaorui Xu ,&nbsp;Xinlu Wang ,&nbsp;Yan Wang ,&nbsp;Fanjun Zhang ,&nbsp;Yuanyuan Feng ,&nbsp;Yuchen Ma ,&nbsp;Dapeng Zhang","doi":"10.1016/j.jece.2025.117679","DOIUrl":"10.1016/j.jece.2025.117679","url":null,"abstract":"<div><div>With the increasing demand for green production, the employment of pollution-free light in catalyzing ammonia production is receiving increasing attention. In order to achieve higher nitrogen fixation efficiency, many modification strategies including doping, anchoring, functionalization, defect engineering and heterostructure construction have been applied to enlarge the absorption range, facilitate the charge separation. However, in this process, the available type of atoms for doping and coupled substances for heterojunctions are almost obtained through a trial-and-error approach, consuming lots of time and resources. Fortunately, the above-mentioned issue can be significantly alleviated with the assistance of a clear mechanism, which can also provide guidance to select suitable modification measure for various systems, thereby promoting the emergence of more efficient photocatalysts. To this end, we classify and discuss the newly developed nitrogen fixation photocatalysts in recent years, and summarize the mechanism of improving nitrogen fixation efficiency by analyzing the changes in inherent electronic properties at the atomic level. First, we list the basic requirements and the corresponding difficulties of the photocatalytic nitrogen reduction. Second, several strategies, classified based on morphology and working mechanism, are investigated. Finally, the opportunities and future prospects are proposed on the basis of the conclusions we obtained.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117679"},"PeriodicalIF":7.4,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144524323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Induced crystallization techniques for fluoride removal from wastewater: Current developments and applications 诱导结晶技术去除废水中的氟化物:目前的发展和应用
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-19 DOI: 10.1016/j.jece.2025.117653
Xilan Gao , Jiuchen Liu , Nan Gai , Jihong Wang , Zhimin Yuan , Beihai Zhou , Rongrong Hou , Rongfang Yuan , Huilun Chen
{"title":"Induced crystallization techniques for fluoride removal from wastewater: Current developments and applications","authors":"Xilan Gao ,&nbsp;Jiuchen Liu ,&nbsp;Nan Gai ,&nbsp;Jihong Wang ,&nbsp;Zhimin Yuan ,&nbsp;Beihai Zhou ,&nbsp;Rongrong Hou ,&nbsp;Rongfang Yuan ,&nbsp;Huilun Chen","doi":"10.1016/j.jece.2025.117653","DOIUrl":"10.1016/j.jece.2025.117653","url":null,"abstract":"<div><div>Excessive fluoride in wastewater poses significant risks to ecosystems and human health. Crystallization methods, including cryolite, calcium fluoride, and fluorapatite, demonstrate high fluoride removal efficiency (&gt;90 %) under optimized conditions and offer the added benefit of resource recovery. Maintaining an optimal pH range (5−7) after chemical dosing enhances removal efficiency, though sulfate interference remains a limiting factor. CaF<sub>2</sub> and FAP typically crystallize at ambient temperature, with molar ratios of Ca/F= 0.6–0.7 and Ca:P:F= 10:4:1, respectively. In contrast, Na<sub>3</sub>AlF<sub>6</sub> crystallization performs best at 20–50°C with an Al/F ratio of 1:6. While the small-scale research on the crystallization methods of the three products is in full swing, only the CaF<sub>2</sub> crystallization has been comprehensively applied in pilot-scale trials and full-scale engineering. Na<sub>3</sub>AlF<sub>6</sub> crystallization is currently at the pilot-scale stage, whereas FAP crystallization has made no progress during the small-scale stage. Each method faces specific challenges. CaF<sub>2</sub> crystallization requires improvements in product purity and effluent quality. FAP crystallization needs effective phosphate control and cost-efficient reactor design. Na<sub>3</sub>AlF<sub>6</sub> must balance product purity with fluoride removal efficiency. Future research should prioritize the optimization of operational parameters, cost reduction, and the development of practical applications for novel approaches to facilitate large-scale implementation.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117653"},"PeriodicalIF":7.4,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Progress in the pretreatment and analysis of organotins: An update since 2012 有机锡的预处理和分析进展:2012年以来的更新
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-18 DOI: 10.1016/j.jece.2025.117625
Yang Song , Yu Bian , Yuan Zhang , Jia-lu Wang , Zhen-wei He , Xue-song Feng
{"title":"Progress in the pretreatment and analysis of organotins: An update since 2012","authors":"Yang Song ,&nbsp;Yu Bian ,&nbsp;Yuan Zhang ,&nbsp;Jia-lu Wang ,&nbsp;Zhen-wei He ,&nbsp;Xue-song Feng","doi":"10.1016/j.jece.2025.117625","DOIUrl":"10.1016/j.jece.2025.117625","url":null,"abstract":"<div><div>As an environmental pollutant, organotins (OTCs) have attracted attention all over the world since their wide distribution in the environment and strong toxicity to organisms. The development of rapid, accurate and sensitive monitoring techniques is of great significance to maintenance of human health and ecological security. This review summarizes the latest progress regarding the occurrence in environment, toxicity, pretreatment and detection methods of OTCs in different environmental matrices. The pretreatment methods that used to extract and purify targets include simple steps, SPE, various microextraction methods, QuEChERS and so on. Detection methods mainly include LC based methods, GC based methods, SFE, CE coupled with different detectors, ICP-MS, sensors and so on. The pros/cons, applications, and trends of the proposed approaches are thoroughly discussed to provide a valuable reference for further studies.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117625"},"PeriodicalIF":7.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144366014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Water security through next-generation surface-engineered membrane technologies for heavy metal removal 通过下一代表面工程膜技术去除重金属的水安全
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-18 DOI: 10.1016/j.jece.2025.117641
Muhammad Syafiq Alias , Wei Lun Ang , Abdul Wahab Mohammad
{"title":"Water security through next-generation surface-engineered membrane technologies for heavy metal removal","authors":"Muhammad Syafiq Alias ,&nbsp;Wei Lun Ang ,&nbsp;Abdul Wahab Mohammad","doi":"10.1016/j.jece.2025.117641","DOIUrl":"10.1016/j.jece.2025.117641","url":null,"abstract":"<div><div>Industrialization and wastewater discharge have intensified global clean water scarcity, posing significant threats to human health and ecosystems. Heavy metal contamination, in particular, demands urgent mitigation, making membrane separation technologies critical solutions. However, conventional membranes are often limited by fouling, poor selectivity, and inadequate durability. This review highlights recent advancements in membrane technology for heavy metal sequestration, emphasizing the importance of innovative separation techniques. Key innovations in membrane properties—such as permeability, selectivity, fouling resistance, hydrophilicity, porosity, chemical resistance, and surface charge—are discussed, with a focus on improvements achieved through structural design and surface engineering. A range of membrane types are covered, including polymeric, ceramic, and composite membranes. Modification techniques such as functionalization, coating, doping, and grafting are examined for their roles in enhancing membrane performance for heavy metal removal. Additionally, the review explores strategies for membrane regeneration, fabrication techniques, as well as current challenges and future perspectives. Overall, this comprehensive assessment underscores the transformative potential of advanced membrane technologies in developing next-generation solutions for efficient and sustainable heavy metal removal from water.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117641"},"PeriodicalIF":7.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A critical review on photocatalytic reductive conversion of uranium by CdS-based catalysts 镉基催化剂光催化还原转化铀的研究进展
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-17 DOI: 10.1016/j.jece.2025.117633
Zhiren Guo , Xiyan Xu , Jinlei Song , Dagang Li , Xiao Zhang , Kongqiu Hu , Lei Mei , Hansheng Li , Jinying Li , Dongxiang Zhang , Weiqun Shi
{"title":"A critical review on photocatalytic reductive conversion of uranium by CdS-based catalysts","authors":"Zhiren Guo ,&nbsp;Xiyan Xu ,&nbsp;Jinlei Song ,&nbsp;Dagang Li ,&nbsp;Xiao Zhang ,&nbsp;Kongqiu Hu ,&nbsp;Lei Mei ,&nbsp;Hansheng Li ,&nbsp;Jinying Li ,&nbsp;Dongxiang Zhang ,&nbsp;Weiqun Shi","doi":"10.1016/j.jece.2025.117633","DOIUrl":"10.1016/j.jece.2025.117633","url":null,"abstract":"<div><div>The conversion of soluble hexavalent uranium (U(VI)) to insoluble tetravalent uranium (U(IV)) facilitates uranium recovery. However, current efficient uranium conversion technologies face challenges such as high energy consumption and/or limited selectivity. Photocatalytic technology has emerged as one of the most effective methods for U(VI)/U(IV) conversion, but the necessity of sacrificial agents restrains its real application. CdS has gained significant attention in recent years since CdS-based catalysts avoid sacrificial agent usage to some extent, benefiting from their advantageous conduction band position and narrow bandgap. However, their application remains debated due to potential photocorrosion during treatment processes. The current work conducts a critical review on photocatalytic reductive conversion of U(VI) by CdS-based catalysts. Properties and design strategies of CdS-based materials are discussed based on the structural and physicochemical properties of CdS, including element doping, defect engineering, hetero/homojunction, biohybrid and morphology control. The electron transfer mechanisms and their impact on U(VI) reduction is also elucidated, together with the analysis of intermediates. The effects of various factors, such as oxygen environment, coexisting metal ions, pH, biological contamination, electron sacrificial agents and photocorrosion on the reduction of U(VI) by CdS-based photocatalysts are highlighted. Then, available strategies to overcome complex environmental challenges are summarized. Finally, the challenges and prospects of CdS-based materials for its future applications are discussed.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117633"},"PeriodicalIF":7.4,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144307183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A critical review of oxygen supply and control strategies in single-stage partial nitritation-anammox system for autotrophic nitrogen removal from wastewater 单级部分硝化-厌氧氨氧化系统供氧及控制策略综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-16 DOI: 10.1016/j.jece.2025.117613
Sha Wu , Fei Gao , Chengcheng Lin , Yijie Quan , Yanxiao Wei , Zhihua Liu , Hanbo Yu , Eli Hendrik Sanjaya , Mohd Fadhil Md Din , Hong Chen
{"title":"A critical review of oxygen supply and control strategies in single-stage partial nitritation-anammox system for autotrophic nitrogen removal from wastewater","authors":"Sha Wu ,&nbsp;Fei Gao ,&nbsp;Chengcheng Lin ,&nbsp;Yijie Quan ,&nbsp;Yanxiao Wei ,&nbsp;Zhihua Liu ,&nbsp;Hanbo Yu ,&nbsp;Eli Hendrik Sanjaya ,&nbsp;Mohd Fadhil Md Din ,&nbsp;Hong Chen","doi":"10.1016/j.jece.2025.117613","DOIUrl":"10.1016/j.jece.2025.117613","url":null,"abstract":"<div><div>The single-stage partial nitritation and anerobic ammonium oxidation (PN/A) process stands out as a sustainable and energy-efficient approach for nitrogen removal from wastewater. While oxygen is essential for the metabolic activities of ammonium oxidizing bacteria, yet its concentration must be delicately balanced. This critical review provides an in-depth analysis of oxygen supply and control approaches in single-stage PN/A systems, focus on methods such as intermittent aeration and continuous low-rate aeration. It examines the interactions between oxygen availability and the microbial communities, and evaluates the operational effectiveness and impact on system performance. The review also introduces several strategies that have been employed to optimize oxygen supply, identifies gaps in current knowledge regarding oxygen's role in the PN/A process and proposes future research directions to address these issues. These include a deeper understanding of microbial ecology under varying oxygen regimes, the development of advanced monitoring and control technologies for real-time optimization of oxygen levels, and the exploration of novel reactor designs to enhance oxygen utilization efficiency and microbial synergy. This review underscores the importance of developing oxygen supply strategies in PN/A systems and calls for further research to refine these strategies, thereby enhancing the process's energy efficiency and nitrogen removal performance. By addressing these challenges, the innovative strategies discussed in this review pave the way for the practical implementation of Anammox technology, offering a sustainable solution for wastewater nitrogen removal.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117613"},"PeriodicalIF":7.4,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
State-of-the-art approaches in sago wastewater treatment and resource recovery: Towards a circular and sustainable industry 西米废水处理和资源回收的最新方法:迈向循环和可持续的工业
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-16 DOI: 10.1016/j.jece.2025.117617
Jaga Sahsiny Jaganathan , Siti Rozaimah Sheikh Abdullah , Jarinah Mohd Ali , Setyo Budi Kurniawan , Suriya Vathi Subramaniam
{"title":"State-of-the-art approaches in sago wastewater treatment and resource recovery: Towards a circular and sustainable industry","authors":"Jaga Sahsiny Jaganathan ,&nbsp;Siti Rozaimah Sheikh Abdullah ,&nbsp;Jarinah Mohd Ali ,&nbsp;Setyo Budi Kurniawan ,&nbsp;Suriya Vathi Subramaniam","doi":"10.1016/j.jece.2025.117617","DOIUrl":"10.1016/j.jece.2025.117617","url":null,"abstract":"<div><div>The sago industry plays a crucial role in global food security, but its production generates wastewater rich in nutrients and organic matter, which pose serious environmental challenges. This study critically reviews recent advances in sago wastewater treatment technology and proposes a scalable, nature-based, integrated treatment framework that is in line with Malaysia’s Sustainable Development Goals (SDG6, SDG12, SDG14 and SDG15) and the principles of the circular economy. The proposed system combines anaerobic digestion, coagulation–flocculation, bioadsorption and phytoremediation. Scientific reports show that anaerobic digestion can reduce chemical oxygen demand (COD) by 70 %–95 %, but residual total suspended solids (TSS ≥200 mg/L) and nutrients (nitrogen ≥100 mg/L, phosphorus ≥30 mg/L) still require further treatment. The coagulation–flocculation method using natural biocoagulants successfully removes up to 81.5 % of TSS, and bioadsorption using activated carbon achieves impressive removal efficiencies of 81.16 % for total dissolved solids, 87.58 % for TSS, 91.32 % for COD and 48.66 % for biochemical oxygen demand (BOD) in sago industry wastewater. Phytoremediation using <em>Scirpus grossus</em> and <em>Chlorella pyrenoidosa</em> improves effluent quality by reducing TSS by up to 98 %, COD by up to 90.2 % and BOD by up to 93 %. These findings confirm the feasibility of a cost-effective, phased, sustainable, nature-based effluent treatment model. Analysis of strengths, weaknesses, opportunities and threats is also conducted to assess the potential implementation and feasibility of this system in the context of a circular economy. This study provides a strategic plan for policymakers, industry players and researchers to accelerate the transition towards sustainable sago industry development.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117617"},"PeriodicalIF":7.4,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photocatalyst deactivation in gaseous VOCs photooxidation: Mechanisms, stability enhancement, and regeneration strategies 气态VOCs光氧化中的光催化剂失活:机制、稳定性增强和再生策略
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-16 DOI: 10.1016/j.jece.2025.117569
Asad Mahmood
{"title":"Photocatalyst deactivation in gaseous VOCs photooxidation: Mechanisms, stability enhancement, and regeneration strategies","authors":"Asad Mahmood","doi":"10.1016/j.jece.2025.117569","DOIUrl":"10.1016/j.jece.2025.117569","url":null,"abstract":"<div><div>Air pollution from volatile organic compounds (VOCs) has raised interest in photocatalytic oxidation for air cleaning. However, photocatalysts often lose activity under real conditions. Unlike laboratory settings, real air contains many organic compounds. These can cause competitive adsorption, form reactive byproducts, and poison the surface. As a result, photocatalytic performance drops over time. This review explains the main reasons for deactivation in gas-phase systems. These include the buildup of carbon residues, formation of byproducts with nitrogen or sulfur, coke deposits, and damage to the material’s structure. We also discuss how surface defects, crystal structure, and particle shape affect both activity and durability. Different methods to restore activity are reviewed. These include heating, chemical cleaning, and light-based recovery. We also highlight recent advances in material design. Examples include single-site catalysts and porous structures such as metal organic frameworks. These materials can improve selectivity and resist deactivation. Machine learning is also gaining attention. It can help predict stability and guide the design of better photocatalysts. Although deactivation is widely studied, few reports focus on gas-phase systems with a clear mechanistic view. This review fills that gap. It combines experiments with analysis to support the design of stable and reusable photocatalysts for clean air.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117569"},"PeriodicalIF":7.4,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144297327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of polymers and their derivatives for enhanced oil recovery 聚合物及其衍生物提高采收率的综合综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-16 DOI: 10.1016/j.jece.2025.117601
Abhishek Tyagi , Sugandha Mahajan , Ganshyam Prajapat , Bharat Shivnani , Devesh M Sawant , Akhil Agrawal
{"title":"A comprehensive review of polymers and their derivatives for enhanced oil recovery","authors":"Abhishek Tyagi ,&nbsp;Sugandha Mahajan ,&nbsp;Ganshyam Prajapat ,&nbsp;Bharat Shivnani ,&nbsp;Devesh M Sawant ,&nbsp;Akhil Agrawal","doi":"10.1016/j.jece.2025.117601","DOIUrl":"10.1016/j.jece.2025.117601","url":null,"abstract":"<div><div>The production of crude oil must be increased to fulfil the world energy demand. As the global need for energy is growing rapidly, oil will serve as the main energy source for next ∼30 years. This energy requirement can be attained through the application of enhanced oil recovery (EOR) technology into marginal wells or by exploring new oil fields. However, the world has reached to a point where the oil recovery from existing reservoirs is more economical than drilling new wells. As the traditional recovery methods are inefficient and less economically sustainable, EOR emerged as viable method to extract the residual oil (∼50 %) from existing mature reservoirs. Within EOR, biopolymers are gaining popularity in the oil industry because of their accessibility, cost-effectiveness, environmental sustainability, viscoelastic behaviour, and biodegradability. Biopolymers like Guar gum, Xanthan gum, Cellulose, Welan gum, Scleroglucan, Schizophyllan, and Gum tragacanth are expected to replace synthetic polymers. However, the main challenge for biopolymers are microbial deterioration and shear-stress stability. Factors like temperature, salinity, polymer concentration, and chemical functional groups significantly impact biopolymer efficiency. To improve these parameters several studies have been conducted for the development of modified polymers using methods like grafting copolymerization, esterification with acylants, nanocomposite functionalization, crosslinking, and hydrogel formation. Recently, chemo-selectively modified and thermo-viscosifying biopolymers have been developed to increase sweep efficiency under reservoir conditions. Modified polymers may enhance EOR performance by viscosity increment, wettability alteration and emulsification. This review discusses polymers used in laboratory and field studies, highlighting their application in EOR.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117601"},"PeriodicalIF":7.4,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144330204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信