Journal of Environmental Chemical Engineering最新文献

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Nanostructured encapsulation for controlled CO2 storage as clathrate hydrate in sub-seabed saline sediments: Containment, stability, and field scale application toward decarbonization. A review 海底盐质沉积物中以笼形水合物形式控制CO2储存的纳米结构封装:安全壳、稳定性和脱碳的现场规模应用。回顾
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-26 DOI: 10.1016/j.jece.2025.117765
Erasto E. Kasala , Jinjie Wang , Wakeel Hussain
{"title":"Nanostructured encapsulation for controlled CO2 storage as clathrate hydrate in sub-seabed saline sediments: Containment, stability, and field scale application toward decarbonization. A review","authors":"Erasto E. Kasala ,&nbsp;Jinjie Wang ,&nbsp;Wakeel Hussain","doi":"10.1016/j.jece.2025.117765","DOIUrl":"10.1016/j.jece.2025.117765","url":null,"abstract":"<div><div>Carbon dioxide (CO₂) sequestration via clathrate hydrate formation in sub-seabed saline sediments offers a promising solution for reducing anthropogenic CO₂ emissions. Nanostructured encapsulation using nanomaterials, such as carbon nanotubes, metal-organic frameworks (MOFs), graphene oxide, and bio-inspired designs has shown potential in stabilizing CO₂ within solid matrices, enabling controlled hydrate formation and storage. However, fluctuating pressure, temperature, and salinity conditions, especially in harsh environments, challenge encapsulation stability, requiring material optimization for sediment compatibility. Nanomaterials additives enhance hydrate stability, CO₂ absorption efficiency, and mass transfer, though the performance depends on type, size, texture, composition, and formation conditions. Synergistic effects between nanomaterials and surfactants/polymers further improve interfacial tension (IFT) reduction, induction time, and storage capacity. This work highlights key mechanisms governing nanomaterials' CO₂ uptake in subseafloor sediments, including adsorption/absorption, diffusion, structural modifications, confinement effects, and hydrophobic interactions. In addition, the study underscores advanced characterization techniques, such as Raman spectroscopy, XRD, and molecular dynamics, providing insights into structural and thermal properties, while field studies in regions like the North Sea and Norway highlight practical challenges. Despite progress, scalability, cost-effectiveness, and environmental safety under variable subsea conditions remain hurdles. Emerging innovations, such as stimuli-responsive nanomaterials and hierarchical encapsulation architectures, could optimize long-term CO₂ storage and controlled release. By integrating the collective findings drawn from both empirical data in published papers and theoretical deductions, this work provides a roadmap to enhance comprehension regarding the screening, design, formation, nucleation, and growth of CO<sub>2</sub> hydrate in nanostructured encapsulation system toward sustainable CO₂ storage and global decarbonization goals.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117765"},"PeriodicalIF":7.4,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144502740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical phosphorus recovery from waste 废弃物中磷的电化学回收
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-25 DOI: 10.1016/j.jece.2025.117695
Zhiqian Xu , Zhijie Chen , Sainan Peng , Song Bai , Xuewei Li , Gaihong Wang , Renji Zheng , Bing-Jie Ni
{"title":"Electrochemical phosphorus recovery from waste","authors":"Zhiqian Xu ,&nbsp;Zhijie Chen ,&nbsp;Sainan Peng ,&nbsp;Song Bai ,&nbsp;Xuewei Li ,&nbsp;Gaihong Wang ,&nbsp;Renji Zheng ,&nbsp;Bing-Jie Ni","doi":"10.1016/j.jece.2025.117695","DOIUrl":"10.1016/j.jece.2025.117695","url":null,"abstract":"<div><div>Phosphorus is a crucial resource for global agricultural production and industrial development. However, its natural reserves are unevenly distributed and increasingly constrained. Meanwhile, phosphorus pollution from agricultural runoff and wastewater discharge seriously threatens ecosystems and exacerbates the greenhouse effect. As a result, the recovery and control of phosphorus has attracted widespread attention. Here, the distribution of different phosphorus forms in wastewater and solid wastes was comprehensively reviewed, and the mechanisms of existing phosphorus recovery technologies elucidated. Recent advances in electrochemical methods for phosphorus recovery from these waste streams are then highlighted, with a focus on fundamental principles and key influencing parameters. Various processes are systematically evaluated in terms of operational mechanisms, recovery efficiency, energy consumption, and product quality. Integrated electrochemical technologies capable of simultaneously recovering phosphorus, nitrogen, and heavy metals are summarized, and the potential integration of machine learning with electrochemical approaches is explored. Finally, the current challenges and future prospects of electrochemical phosphorus recovery technologies are discussed. This review aims to provide a valuable technical reference for the control of phosphorus pollution and the recovery of resources from waste streams.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117695"},"PeriodicalIF":7.4,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144502800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biogenic Nanoparticles: Synthesis, Characterization, Applications and Scaling Up Limitations in Water Treatment. 生物纳米颗粒:合成、表征、应用和扩大水处理的限制。
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-24 DOI: 10.1016/j.jece.2025.117730
Ortiz-Tirado Alejandra , Luisa F. Medina-Ganem , Erick R. Bandala , Alain S. Conejo-Davila , Vega-Rios Alejandro , Ashantha Goonetilleke , Oscar M. Rodriguez-Narvaez
{"title":"Biogenic Nanoparticles: Synthesis, Characterization, Applications and Scaling Up Limitations in Water Treatment.","authors":"Ortiz-Tirado Alejandra ,&nbsp;Luisa F. Medina-Ganem ,&nbsp;Erick R. Bandala ,&nbsp;Alain S. Conejo-Davila ,&nbsp;Vega-Rios Alejandro ,&nbsp;Ashantha Goonetilleke ,&nbsp;Oscar M. Rodriguez-Narvaez","doi":"10.1016/j.jece.2025.117730","DOIUrl":"10.1016/j.jece.2025.117730","url":null,"abstract":"<div><div>Nanoparticles (NPs) have attracted significant interest due to their unique chemical and physical properties. In this context, biogenic synthesis has emerged as a promising alternative, utilizing natural pathways (e.g., microorganisms and plants) to produce biomolecules such as polyphenols, vitamins, amino acids, and carbohydrates that can reduce and stabilize NP production. However, significant knowledge gaps remain, particularly regarding the interaction between biomolecules and metals, and their influence on the physicochemical properties of NPs. This review critically examines current biogenic synthesis methods and their applications in removing organic contaminants and inactivating microorganisms in water treatment. It also highlights the challenges and opportunities in this field. In terms of scalability, there are significant limitations currently. The variability in the composition of biological extracts makes it difficult to achieve reproducibility and control over NP size and morphology. Additionally, production processes tend to be slow and yields which lower than conventional chemical methods. Optimizing influential parameters such as biomolecule concentration, temperature, and pH remains a challenge. Finally, the lack of studies on toxicity and long-term stability hinders large-scale implementation.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117730"},"PeriodicalIF":7.4,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of the functionalized polymer composite membranes in wastewater treatment 功能化高分子复合膜在污水处理中的应用综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-24 DOI: 10.1016/j.jece.2025.117735
Madhappan Santhamoorthy , Perumal Asaithambi , Ilaiyaraja Perumal , Natarajan Elangovan , Priyadarshini Natarajan , Mei-Ching Lin , Seong-Cheol Kim , Keerthika Kumarasamy , Thi Tuong Vy Phan
{"title":"A comprehensive review of the functionalized polymer composite membranes in wastewater treatment","authors":"Madhappan Santhamoorthy ,&nbsp;Perumal Asaithambi ,&nbsp;Ilaiyaraja Perumal ,&nbsp;Natarajan Elangovan ,&nbsp;Priyadarshini Natarajan ,&nbsp;Mei-Ching Lin ,&nbsp;Seong-Cheol Kim ,&nbsp;Keerthika Kumarasamy ,&nbsp;Thi Tuong Vy Phan","doi":"10.1016/j.jece.2025.117735","DOIUrl":"10.1016/j.jece.2025.117735","url":null,"abstract":"<div><div>The growing demand for efficient wastewater treatment technologies has led to the development of modified polymeric composite membranes, offering improved separation performance, durability, and resistance to fouling. These membranes integrate base polymers with functional additives or coatings to address the limitations of conventional polymeric membranes, such as fouling, low selectivity, and limited mechanical stability. Base polymers, including polyethersulfone (PES), polyvinylidene fluoride (PVDF), and polysulfone (PSF), serve as foundational materials due to their chemical and mechanical properties. Additives such as nanomaterials (e.g., graphene oxide, carbon nanotubes), inorganic fillers (e.g., TiO₂, ZnO), and biopolymers (e.g., chitosan, cellulose) are incorporated to enhance functionality. Various modification techniques, including blending, layer-by-layer assembly, chemical grafting, and surface coating, allow the tailoring of membrane properties such as hydrophilicity, porosity, and antifouling capabilities. Modified membranes are applied across various filtration processes, including microfiltration, ultrafiltration, nanofiltration, and reverse osmosis, to achieve efficient removal of suspended solids, heavy metals, dyes, and organic pollutants. Recent innovations focus on antifouling, adsorptive, and photocatalytic membranes that exhibit superior performance and longevity. Despite significant advancements, challenges such as scalability, long-term stability, and environmental impact persist. Future directions emphasize the development of eco-friendly materials, sustainable fabrication methods, and smart membranes with self-cleaning or responsive properties. The integration of these membranes with other treatment technologies, such as advanced oxidation processes, could further enhance wastewater treatment efficiency. This paper reviews the preparation methods, material innovations, and application advancements in modified polymeric composite membranes for wastewater treatment.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117735"},"PeriodicalIF":7.4,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144502741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrocoagulation or it coupling with ozonation for sustainable wastewater treatment: A comprehensive review of mechanisms, performance, and emerging applications 电絮凝或它与臭氧氧化耦合可持续废水处理:机制,性能和新兴应用的综合综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-23 DOI: 10.1016/j.jece.2025.117685
Yunhan Jia , Osama Shaheen Rizvi , Zhenbei Wang , Chen Li , Yatao Liu , Fei Qi , Javier Navarro-Laboulais , Amir Ikhlaq , Jolanta Kumirska , Ewa Maria Siedlecka , Oksana Ismailova
{"title":"Electrocoagulation or it coupling with ozonation for sustainable wastewater treatment: A comprehensive review of mechanisms, performance, and emerging applications","authors":"Yunhan Jia ,&nbsp;Osama Shaheen Rizvi ,&nbsp;Zhenbei Wang ,&nbsp;Chen Li ,&nbsp;Yatao Liu ,&nbsp;Fei Qi ,&nbsp;Javier Navarro-Laboulais ,&nbsp;Amir Ikhlaq ,&nbsp;Jolanta Kumirska ,&nbsp;Ewa Maria Siedlecka ,&nbsp;Oksana Ismailova","doi":"10.1016/j.jece.2025.117685","DOIUrl":"10.1016/j.jece.2025.117685","url":null,"abstract":"<div><div>To address the increasing global water pollution crisis, efficient water and wastewater treatment technologies are critical for safeguarding sustainable development and ensuring long-term water security. Although ozonation-assisted electrocoagulation (ECO) research has attracted growing attention, there is currently a lack of systematic summary to bridge the gap between lab-scale studies and pilot-scale applications. Therefore, we summarize existing findings on ECO, clarify current challenges and propose future research directions. This review outlines the progress and practical applications of ECO, covering synergistic contaminant removal mechanisms, electrode and reactor design, life cycle assessment and contaminant elimination. The innovative contribution of this review is that it is the first to systematically summarize the research on ECO, providing theoretical guidance for transitioning ECO from the laboratory scale to practical applications. In summary, the maximum synergistic coefficient between electrocoagulation (EC) and ozonation reaches 19.09, depending on the interaction between EC-generated flocs and ozone. Such a high synergistic coefficient demonstrates that the ECO is worthy of in-depth research. ECO can achieve approximately 100 % removal efficiency for SS, over 80 % removal efficiency for COD and ROCs, as well as partial removal of heavy metals. Notably, the energy consumption of the ECO ranges from 3.77 to 47.65 kWh/m³ , which is significantly lower than that of other EC-related processes, proving ECO feasibility for pilot-scale treatment. In the future, ECO research should be focused on the synergistic reaction mechanism, sludge resource utilization, design and optimization of scaling-up reactors, renewable energy integration and multi-technology coupling to advance practical applications.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117685"},"PeriodicalIF":7.4,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144502807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the role of hydrogels in managing water contaminated by per- and polyfluoroalkyl substances: A critical review with emphasis on agricultural applications 揭示水凝胶在管理被全氟烷基和多氟烷基物质污染的水中的作用:重点审查农业应用
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-23 DOI: 10.1016/j.jece.2025.117707
Alessandro F. Martins , Paulo R. Souza , Felipe M. de Souza , Ram K. Gupta , Bruno H. Vilsinski , Rafael Quadrado , André R. Fajardo
{"title":"Unveiling the role of hydrogels in managing water contaminated by per- and polyfluoroalkyl substances: A critical review with emphasis on agricultural applications","authors":"Alessandro F. Martins ,&nbsp;Paulo R. Souza ,&nbsp;Felipe M. de Souza ,&nbsp;Ram K. Gupta ,&nbsp;Bruno H. Vilsinski ,&nbsp;Rafael Quadrado ,&nbsp;André R. Fajardo","doi":"10.1016/j.jece.2025.117707","DOIUrl":"10.1016/j.jece.2025.117707","url":null,"abstract":"<div><div>The contamination of water by per- and polyfluoroalkyl substances (PFAS) poses significant threats to environmental and human health. These chemicals contaminate drinking water and irrigation systems, including surface and groundwater supplies. Despite ongoing efforts to regulate and restrict PFAS, these substances remain widely used, with new variants still being developed. Various treatment processes have been explored to address this issue, with hydrogel-based adsorption emerging as a promising approach. This review evaluates the role of hydrogels and their composites in remediating PFAS-contaminated water. Advanced treatment methods, including oxidation, coagulation, and adsorption with conventional adsorbents, are compared to hydrogel-based adsorbents. Hydrogels offer advantages such as enhanced recovery, reusability, and the ability to concentrate PFAS for subsequent degradation via oxidative methods. Furthermore, their tunable hydrophilic and hydrophobic properties enable efficient removal of both long- and short-chain PFAS. The highest PFAS removal efficiencies, exceeding 90%, and adsorption capacities of up to 1276<!--> <!-->mg/g have been reported for hydrogels containing cationic or quaternary ammonium groups. Theoretical studies suggest that hydrophobic interactions play a dominant role in the removal of long-chain PFAS, such as perfluorooctanoic acid (PFOA). In contrast, effective removal of short-chain PFAS, such as perfluorobutanesulfonic acid (PFBS), relies on both hydrophobic and electrostatic interactions. By highlighting the benefits and limitations of hydrogels, this review underscores their potential as versatile tools for addressing the global challenge of PFAS contamination. Additionally, it rationalizes the challenges and future perspectives in this field, offering valuable insights to guide students and researchers in shaping the direction of future studies.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117707"},"PeriodicalIF":7.4,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-emission carbon dots: Synthesis, applications, advances and challenges 双排放碳点:合成、应用、进展与挑战
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-22 DOI: 10.1016/j.jece.2025.117696
Nguyen Minh Hoang , Nguyen Thi Bich Ngoc , Nam-Anh Tran , Nang Xuan Ho , Hai-Linh Thi Dang , Dang Viet Cuong , Vu Thi Trang , Phan Thi Lan Huong , Phan Thi Thanh Huyen , Muhammad Saqlain Jamil , Sining Yun , Le Tuan Tu , Linh Nguyen Duy Pham , Van-Duong Dao
{"title":"Dual-emission carbon dots: Synthesis, applications, advances and challenges","authors":"Nguyen Minh Hoang ,&nbsp;Nguyen Thi Bich Ngoc ,&nbsp;Nam-Anh Tran ,&nbsp;Nang Xuan Ho ,&nbsp;Hai-Linh Thi Dang ,&nbsp;Dang Viet Cuong ,&nbsp;Vu Thi Trang ,&nbsp;Phan Thi Lan Huong ,&nbsp;Phan Thi Thanh Huyen ,&nbsp;Muhammad Saqlain Jamil ,&nbsp;Sining Yun ,&nbsp;Le Tuan Tu ,&nbsp;Linh Nguyen Duy Pham ,&nbsp;Van-Duong Dao","doi":"10.1016/j.jece.2025.117696","DOIUrl":"10.1016/j.jece.2025.117696","url":null,"abstract":"<div><div>Dual emission carbon dots (DE-CDs) have emerged as a transformative class of nanomaterials, offering distinct advantages over single-emission carbon dots (SE-CDs), including superior anti-interference capabilities, built-in self-calibration and broader full-width at half maximum (FWHM) emission spectra. This review comprehensively explores recent advancements in the synthesis of DE-CDs, detailing their physicochemical characteristics and elucidating key hypotheses underlying the formation of dual-emission peaks, such as the roles of core states, surface states, and quantum confinement effects. The diverse applications of DE-CDs are systematically analyzed, emphasizing their use in ratiometric sensing, bioimaging, biosensing, pH monitoring, moisture and water detection, and white light-emitting diodes (WLEDs). A comparative evaluation highlights their advantages and limitations relative to traditional fluorescence materials. Furthermore, recent progress in integrating DE-CDs into dye-sensitized solar cells (DSCs) and solar steam generation (SSG) devices is presented, underscoring their potential in renewable energy technologies. Finally, this review discusses the challenges and prospects for developing DE-CDs, including the need for scalable synthesis techniques, optimization of quantum yields for lighting applications, and enhanced understanding of dual-emission behavior mechanisms. Despite these challenges, DE-CDs hold immense promise for advancing technologies in sensing, bioimaging, lighting, and sustainable energy systems.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117696"},"PeriodicalIF":7.4,"publicationDate":"2025-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Induced crystallization techniques for fluoride removal from wastewater: Current developments and applications 诱导结晶技术去除废水中的氟化物:目前的发展和应用
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-19 DOI: 10.1016/j.jece.2025.117653
Xilan Gao , Jiuchen Liu , Nan Gai , Jihong Wang , Zhimin Yuan , Beihai Zhou , Rongrong Hou , Rongfang Yuan , Huilun Chen
{"title":"Induced crystallization techniques for fluoride removal from wastewater: Current developments and applications","authors":"Xilan Gao ,&nbsp;Jiuchen Liu ,&nbsp;Nan Gai ,&nbsp;Jihong Wang ,&nbsp;Zhimin Yuan ,&nbsp;Beihai Zhou ,&nbsp;Rongrong Hou ,&nbsp;Rongfang Yuan ,&nbsp;Huilun Chen","doi":"10.1016/j.jece.2025.117653","DOIUrl":"10.1016/j.jece.2025.117653","url":null,"abstract":"<div><div>Excessive fluoride in wastewater poses significant risks to ecosystems and human health. Crystallization methods, including cryolite, calcium fluoride, and fluorapatite, demonstrate high fluoride removal efficiency (&gt;90 %) under optimized conditions and offer the added benefit of resource recovery. Maintaining an optimal pH range (5−7) after chemical dosing enhances removal efficiency, though sulfate interference remains a limiting factor. CaF<sub>2</sub> and FAP typically crystallize at ambient temperature, with molar ratios of Ca/F= 0.6–0.7 and Ca:P:F= 10:4:1, respectively. In contrast, Na<sub>3</sub>AlF<sub>6</sub> crystallization performs best at 20–50°C with an Al/F ratio of 1:6. While the small-scale research on the crystallization methods of the three products is in full swing, only the CaF<sub>2</sub> crystallization has been comprehensively applied in pilot-scale trials and full-scale engineering. Na<sub>3</sub>AlF<sub>6</sub> crystallization is currently at the pilot-scale stage, whereas FAP crystallization has made no progress during the small-scale stage. Each method faces specific challenges. CaF<sub>2</sub> crystallization requires improvements in product purity and effluent quality. FAP crystallization needs effective phosphate control and cost-efficient reactor design. Na<sub>3</sub>AlF<sub>6</sub> must balance product purity with fluoride removal efficiency. Future research should prioritize the optimization of operational parameters, cost reduction, and the development of practical applications for novel approaches to facilitate large-scale implementation.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117653"},"PeriodicalIF":7.4,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Progress in the pretreatment and analysis of organotins: An update since 2012 有机锡的预处理和分析进展:2012年以来的更新
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-18 DOI: 10.1016/j.jece.2025.117625
Yang Song , Yu Bian , Yuan Zhang , Jia-lu Wang , Zhen-wei He , Xue-song Feng
{"title":"Progress in the pretreatment and analysis of organotins: An update since 2012","authors":"Yang Song ,&nbsp;Yu Bian ,&nbsp;Yuan Zhang ,&nbsp;Jia-lu Wang ,&nbsp;Zhen-wei He ,&nbsp;Xue-song Feng","doi":"10.1016/j.jece.2025.117625","DOIUrl":"10.1016/j.jece.2025.117625","url":null,"abstract":"<div><div>As an environmental pollutant, organotins (OTCs) have attracted attention all over the world since their wide distribution in the environment and strong toxicity to organisms. The development of rapid, accurate and sensitive monitoring techniques is of great significance to maintenance of human health and ecological security. This review summarizes the latest progress regarding the occurrence in environment, toxicity, pretreatment and detection methods of OTCs in different environmental matrices. The pretreatment methods that used to extract and purify targets include simple steps, SPE, various microextraction methods, QuEChERS and so on. Detection methods mainly include LC based methods, GC based methods, SFE, CE coupled with different detectors, ICP-MS, sensors and so on. The pros/cons, applications, and trends of the proposed approaches are thoroughly discussed to provide a valuable reference for further studies.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117625"},"PeriodicalIF":7.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144366014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Water security through next-generation surface-engineered membrane technologies for heavy metal removal 通过下一代表面工程膜技术去除重金属的水安全
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-06-18 DOI: 10.1016/j.jece.2025.117641
Muhammad Syafiq Alias , Wei Lun Ang , Abdul Wahab Mohammad
{"title":"Water security through next-generation surface-engineered membrane technologies for heavy metal removal","authors":"Muhammad Syafiq Alias ,&nbsp;Wei Lun Ang ,&nbsp;Abdul Wahab Mohammad","doi":"10.1016/j.jece.2025.117641","DOIUrl":"10.1016/j.jece.2025.117641","url":null,"abstract":"<div><div>Industrialization and wastewater discharge have intensified global clean water scarcity, posing significant threats to human health and ecosystems. Heavy metal contamination, in particular, demands urgent mitigation, making membrane separation technologies critical solutions. However, conventional membranes are often limited by fouling, poor selectivity, and inadequate durability. This review highlights recent advancements in membrane technology for heavy metal sequestration, emphasizing the importance of innovative separation techniques. Key innovations in membrane properties—such as permeability, selectivity, fouling resistance, hydrophilicity, porosity, chemical resistance, and surface charge—are discussed, with a focus on improvements achieved through structural design and surface engineering. A range of membrane types are covered, including polymeric, ceramic, and composite membranes. Modification techniques such as functionalization, coating, doping, and grafting are examined for their roles in enhancing membrane performance for heavy metal removal. Additionally, the review explores strategies for membrane regeneration, fabrication techniques, as well as current challenges and future perspectives. Overall, this comprehensive assessment underscores the transformative potential of advanced membrane technologies in developing next-generation solutions for efficient and sustainable heavy metal removal from water.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117641"},"PeriodicalIF":7.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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