Sherif A Taalab, Waheed H Mohamed, Said A Shetaia, Meshari Al Meshari, Yasser Alzamil, Ahmad Abanomy, Amjad R Alyahyawi, Atef El-Taher
{"title":"Radiological and environmental hazards of granitic rocks in Wadi Faliq El Sahl and El Waar area, North Eastern Desert, Egypt.","authors":"Sherif A Taalab, Waheed H Mohamed, Said A Shetaia, Meshari Al Meshari, Yasser Alzamil, Ahmad Abanomy, Amjad R Alyahyawi, Atef El-Taher","doi":"10.1080/10934529.2023.2186650","DOIUrl":"https://doi.org/10.1080/10934529.2023.2186650","url":null,"abstract":"<p><p>Chronologically, the main exposures in the study area include; tonalite, granodiorite, adamellite, Hammamat Sediments, monzogranite, syenogranite, rapakivi syenogranite, alkali feldspar granite and dykes. This work aims to determine the suitability of the granitic rocks for using as ornamental stones through detecting their radiological and ecological impacts. The studied samples were measured radiometrically by using Na-I detector for determination of <sup>226</sup>Ra, <sup>232</sup>Th and <sup>40</sup>K concentrations. External hazard indices (H<sub>ex</sub>) in some samples are more than unity, also, the (Raeq) are higher than the exemption limits (370 Bq.kg<sup>-1</sup>) exceeds the upper limit of exposure. The hierarchical cluster analysis (HCA) was applied to investigate the correlation between the radionuclides and the corresponding radiological hazard variables. Based on the statistical analysis, <sup>232</sup>Th and <sup>226</sup>Ra mainly contribute to the radioactive risk of the studied rocks. Regarding ecological indices, 42.1% of younger granite samples have Pollution load index values greater than 1, indicating deterioration, while the majority of older granite samples are lower than 1 suggesting perfection samples. Where, some sample from the older granitoids and younger granites have many radiological and ecological parameters greater than the recommended international limits, so, these samples should not be used in construction for safety reasons.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9195784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Concentrations and distributions of fluorotelomer alcohols and perfluoroalkane sulfonamido substances in the atmosphere in the Pearl River Delta, China.","authors":"Peng Shen, Xiaocong Song, Nankun Li, Ci Zhao","doi":"10.1080/10934529.2023.2174332","DOIUrl":"https://doi.org/10.1080/10934529.2023.2174332","url":null,"abstract":"Abstract Per and polyfluoroalkyl substances (PFASs) have attracted major global concerns because some of them are environmentally persistent, bioaccumulative, and toxic. Perfluoroalkyl acids (PFAAs) have been well-characterized in water, soil, and sediment; however, fluorotelomer alcohols and perfluoroalkane sulfonamido substances have been overlooked. In this study, concentrations of three fluorotelomer alcohols and four perfluoroalkane sulfonamido substances were determined in the air at nine locations representing urban, rural-urban transect, and urban areas in the Pearl River Delta region, China to investigate their seasonal and spatial distributions and potential sources. At least two of the targeted PFASs were detected in all air samples in the Pearl River Delta region, with concentrations ranging from 371 pg/sampler to 18700 pg/sampler. Fluorotelomer alcohols were dominant compounds (contributing 46% to the ∑7PFAS concentration on average) in the atmosphere in the Pearl River Delta region. The total concentrations of the seven targeted PFASs were significantly higher in summer than in other seasons in urban areas. PFAS concentrations were positively related to the population density in the Pearl River Delta region. Local diffusive emission and long range transport could be sources of the seven PFASs in the air in the Pearl River Delta region.","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9172499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ivone Vanessa Jurado-Davila, Ivo André H Schneider, Diego Estumano, Liliana Amaral Féris
{"title":"Phosphate removal using dolomite modified with ultrasound: mathematical and experimental analysis.","authors":"Ivone Vanessa Jurado-Davila, Ivo André H Schneider, Diego Estumano, Liliana Amaral Féris","doi":"10.1080/10934529.2023.2196928","DOIUrl":"https://doi.org/10.1080/10934529.2023.2196928","url":null,"abstract":"Abstract We studied the dolomite modified using an ultrasound bath and its application in phosphate removal. The modification was applied to improve the physicochemical properties of the dolomite and then to enhance its suitability as an adsorbent solid. The settings for analyzing the adsorbent modification were bath temperature and sonication time. The modified dolomite was characterized by electron microscopy, N2 adsorption/desorption, pore size, and X-ray diffraction. To grasp the pollutant’s adsorption mechanism more precisely, we used experimental research and mathematical model analysis. Design of Experiments was conducted to determine the ideal circumstances. In addition, the Bayesian method of Markov Chain Monte Carlo was used to estimate the isotherm and kinetic model parameters. A thermodynamic study was done to investigate the adsorption mechanism. Results show that the surface area of the modified dolomite was greater, enhancing its adsorption properties. To remove more than 90% of the phosphate, the optimal operational parameters for the adsorption were pH 9, 1.77 g of adsorbent mass, and 55 minutes of contact time. The pseudo-first-order, Redlich–Peterson and Sips models presented a good fit to the experimental data. Thermodynamics suggested a spontaneous and endothermic process. The mechanism suggested that physisorption and chemisorption could be involved in phosphate removal.","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9713337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Karem Gallardo, Dayana Valdivia, Andrea Jara, Rodrigo Castillo
{"title":"The importance of the pretreatment of samples in Nd quantification from NdFeB magnets through inductively coupled plasma atomic emission spectroscopy (ICP-OES)-a rapid and streamlined methodology.","authors":"Karem Gallardo, Dayana Valdivia, Andrea Jara, Rodrigo Castillo","doi":"10.1080/10934529.2023.2264135","DOIUrl":"10.1080/10934529.2023.2264135","url":null,"abstract":"<p><p>In this study, we emphasize the critical role of sample pretreatment. We report on the behavior of NdFeB magnet samples exposed to four different acid media for digestion. NdFeB magnets are becoming a significant source of neodymium, a rare-earth element critical to many technologies and a potential substitute for traditional mining of the element. To address this, we meticulously tested nitric acid, hydrochloric acid, acetic acid, and citric acid, all at a concentration of 1.6 M, as economical and environmentally friendly alternatives to the concentrated mineral acids commonly used in the leaching of these materials. The pivotal stage involves the initial characterization of samples in the solid state using SEM-EDX and XPS analysis to obtain their initial composition. Subsequently, the samples are dissolved in the four aforementioned acids. Finally, neodymium is quantified using ICP-OES. Throughout our investigation, we evaluated some analytical parameters to determine the best candidate for performing the digestion, including time, limits of detection and quantification, accuracy, recovery of spike samples, and robustness. After careful consideration, we unequivocally conclude that 1.6 M nitric acid stands out as the optimal choice for dissolving NdFeB magnet samples, with the pretreatment of the samples being the critical aspect of this report.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41132302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carolina A Jiménez-Rojas, Carlos Emilio Gutiérrez Ulloa, Sandra M Chingaté-López, Jaime A Lara-Borrero
{"title":"Analysis of drug of abuse compounds using passive sampling and ultrahigh-liquid chromatography coupled to mass spectrometry.","authors":"Carolina A Jiménez-Rojas, Carlos Emilio Gutiérrez Ulloa, Sandra M Chingaté-López, Jaime A Lara-Borrero","doi":"10.1080/10934529.2023.2266327","DOIUrl":"10.1080/10934529.2023.2266327","url":null,"abstract":"<p><p>The present study proposes the monitoring of compounds of drugs of abuse through the use of passive samplers in water systems. Initially, four positive ion compounds of interest were determined according to national surveys, and then composite sampling and passive sampling were implemented using continuous-flow passive samplers containing two types of sorbents, the Empore disk and Gerstel Twister. Two study sites were established at the beginning and at the end of the middle Bogotá River basin. After 4 days, the sorbents were removed so that they could be desorbed and analyzed using UHPLC-MS in the laboratory. For the composite samples, the results were below the first calibration curve point (FCCP) of the chromatographic method, and for passive sampling, peaks of benzoylecgonine (BE) (21427.3 pg mL<sup>-1</sup>), methamphetamine (MET) (67101.5 pg mL<sup>-1</sup>), MDMA (ecstasy) (225844.8 pg mL<sup>-1</sup>) and 2-ethylidene-1,5-dimethyl-3,3-diphenylpyrrolidine (EDDP) (15908.4 pg mL<sup>-1</sup>) were found. Therefore, passive sampling could be suggested as an alternative to composite sampling for the monitoring of compounds.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"54229273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Health risk assessment of heavy metals in PM<sub>2.5</sub> and PM<sub>10</sub> in Sarajevo air, Bosnia and Herzegovina.","authors":"Nejira Trako, Ferida Mašić, Faruk Ajanović, Samra Merdan, Jasna Huremović, Sabina Žero, Adnan Mašić, Sabina Gojak-Salimović","doi":"10.1080/10934529.2024.2307834","DOIUrl":"10.1080/10934529.2024.2307834","url":null,"abstract":"<p><p>The concentrations of eight heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) associated with PM<sub>2.5</sub> and PM<sub>10</sub> in Sarajevo air, Bosnia and Herzegovina (BiH) have been studied. A total of 136 PM<sub>2.5</sub> and PM<sub>10</sub> samples were simultaneously collected from 21 February to 11 November 2020. Metal contents were determined by atomic absorption spectrometry, flame (FAAS) and electrothermal (ETAAS) techniques. The mean concentrations of metals in PM<sub>10</sub> are 2.93 ng/m<sup>3</sup> (Cd), 7.21 ng/m<sup>3</sup> (Cr), 12.02 ng/m<sup>3</sup> (Cu), 126 ng/m<sup>3</sup> (Fe), 20.74 ng/m<sup>3</sup> (Mn), 6.98 ng/m<sup>3</sup> (Ni), 8.74 ng/m<sup>3</sup> (Pb) and 128 ng/m<sup>3</sup> (Zn). In PM<sub>2.5</sub> samples the mean concentrations of Cd, Cr, Cu, Fe, Mn, Ni and Zn are 0.39, 4.06, 2.26, 110, 0.63, 1.93 and 5.28 ng/m<sup>3</sup>, respectively. Pb was not detected in PM<sub>2.5</sub> samples. Strong correlation was obtained for metal pairs Mn-Cu in PM<sub>10</sub> and moderate for Ni-Fe in PM<sub>2.5</sub>. The health risk assessment shows that the adult population of Sarajevo is at increased lifetime risk of experiencing cancer because of exposure to Cd concentrations in PM<sub>10</sub>.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139545885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pranvera Lazo, Zdravko Špirić, Trajče Stafilov, Flora Qarri, Lirim Bekteshi, Lambe Barandovski, Robert Šajn, Katerina Bačeva Andonovska, Ivana Vučković
{"title":"Regional air quality study by assessing trace metal atmospheric deposition.","authors":"Pranvera Lazo, Zdravko Špirić, Trajče Stafilov, Flora Qarri, Lirim Bekteshi, Lambe Barandovski, Robert Šajn, Katerina Bačeva Andonovska, Ivana Vučković","doi":"10.1080/10934529.2024.2315921","DOIUrl":"10.1080/10934529.2024.2315921","url":null,"abstract":"<p><p>This study addresses the atmospheric deposition of trace elements investigated in Albania, Croatia and Macedonia in 2010 as part of the European Moss Study. This study provides data on the concentration of ten metals (Cd, Cr, Cu, Ni, Pb, V, Zn, Fe, Al, and Li) in naturally growing mosses. In general, all concentration data follow a lognormal distribution. Cd, Cr, Ni, and Zn show strong fluctuations in the moss samples from Albania and Macedonia, and Pb, Fe, and Al in the mosses from Croatia. The concentrations of Cd, Cu, and Zn were higher in the samples from Croatia than in those from Albania and Macedonia; the concentrations of Cr, Ni, V, Fe, Al, and Li were higher in the samples from Albania than in those from Croatia and Macedonia; and a higher concentration of Pb was found in the samples from Macedonia. The observed relationship between the concentration of lithogenic elements (Al, Fe, and V) and the air quality index (AQI) confirms that moss species have a high capacity to retain atmospheric deposition particles. The anthropogenic emission sources of these elements from local and long-range transport were considered to be the most important factors affecting air quality in the studied areas.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139940039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuyang Cai, Zhen Wang, Dunyu Liu, Jun Chen, Jing Jin, Qi Qin, Ke Liu, Haixiang Hu, Sijie Li, Huancong Shi
{"title":"Transient simulation of SO<sub>2</sub> absorption into water in a bubbling reactor.","authors":"Yuyang Cai, Zhen Wang, Dunyu Liu, Jun Chen, Jing Jin, Qi Qin, Ke Liu, Haixiang Hu, Sijie Li, Huancong Shi","doi":"10.1080/10934529.2023.2238586","DOIUrl":"10.1080/10934529.2023.2238586","url":null,"abstract":"<p><p>A bubbling reactor is an important type of gas scrubber to reduce SO<sub>2</sub> emissions in maritime shipping. Both experiments and simulations were conducted to study the relationship between the periodic gas bubbling process and SO<sub>2</sub> concentration at the outlet of the reactor, and the entrainment of liquid droplets on SO<sub>2</sub> absorption. The accuracy of the model was verified by comparing the bubble size, the depth of bubbles injected into the water, and the SO<sub>2</sub> concentration obtained in both experiments and simulations. The gas bubbling process is accompanied by bubble formation, rise, and collapse. The gas bubbling period is affected by the disturbance of the liquid level. The period of the SO<sub>2</sub> concentration at the outlet of the gas bubbling reactor is smaller than that at the gas jar outlet which acts as the gas buffering region. The amounts of water carried out of the bubbling reactor by the gas bubbling process increase with the gas flow rates. The droplets and liquid film in the gas jar and the connecting tube play an important role in the absorption of SO<sub>2</sub>. This study encourages more research to reduce the fluctuation of SO<sub>2</sub> concentration and consider droplet entrainment in the design of bubbling reactors.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9947138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis and risk assessment of vinyl chloride emitted from aerosol products.","authors":"Naeko Sugaya, Kaoru Inoue, Maiko Tahara, Tsuyoshi Kawakami","doi":"10.1080/10934529.2023.2173925","DOIUrl":"https://doi.org/10.1080/10934529.2023.2173925","url":null,"abstract":"<p><p>The objectives of this study were to develop a novel analytical method for quantifying vinyl chloride (VC) emitted from aerosol products, to provide analytical data on VC in aerosol products, and to evaluate consumer VC exposure by aerosol products. Our quantitative method involves absorbing VC into dimethyl sulfoxide and analyzing it using headspace gas chromatography/mass spectrometry. The correlation coefficients of the VC calibration curves were ≥ 0.9994 in the range of 0.16-80 µg/mL VC standard gases, which were prepared under either nitrogen or emission gases containing dimethyl ether or liquid petroleum gas. VC concentrations in these emission gases were calculated using a VC calibration curve from standard gases prepared under nitrogen; they were within ± 10% of the actual concentrations. We analyzed 39 household aerosol products; VC concentrations of 0.095, 0.098, and 0.28 μg/L were detected in three polyvinyl chloride spray paints. Consumer VC inhalation exposure level was estimated through an exposure scenario, and the hazard quotient was confirmed to be very low when comparing the exposure level with a cancer risk level of 10<sup>-5</sup> for inhaled VC. These results suggest that the human health risk from VC in spray paint was low.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9571076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fang Zhao, Yao Peng, Lin Huang, Ziwei Li, Weinan Tu, Biao Wu
{"title":"Fugitive emissions of volatile organic compounds from the pharmaceutical industry in China based on leak detection and repair monitoring, atmospheric prediction, and health risk assessment.","authors":"Fang Zhao, Yao Peng, Lin Huang, Ziwei Li, Weinan Tu, Biao Wu","doi":"10.1080/10934529.2023.2204806","DOIUrl":"https://doi.org/10.1080/10934529.2023.2204806","url":null,"abstract":"<p><p>In this study, a leak detection and repair program was conducted on five pharmaceutical factories in China to analyze the volatile organic compounds (VOCs) emission characteristics of leaking equipment. The results indicated that the monitored components were mainly flanges, accounting for 70.23% of the total, and open-ended lines were the components most prone to leaks. The overall percentage of VOCs emissions reduction after the repair was 20.50%, and flanges were the most repairable components, with an average emission reduction of 47.5 kg/a for each flange. In addition, atmospheric predictions were conducted for the VOCs emissions before and after the repair of the components at the research factories. The atmospheric predictions showed that emissions from equipment and facilities have a noticeable impact on VOCs concentration at boundary and the emissions are positively correlated with the pollution source strength. The hazard quotient of the investigated factories was lower than the acceptable risk level set by the US Environmental Protection Agency (EPA). The quantitative assessment of the lifetime cancer risk showed that the risk levels of factories A, C, and D exceeded the EPA's acceptable risk level, and the on-site workers were exposed to inhalation cancer risk.</p>","PeriodicalId":15671,"journal":{"name":"Journal of Environmental Science and Health Part A-toxic\\/hazardous Substances & Environmental Engineering","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9660584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}