Chemistry - An Asian Journal最新文献_第8页

Recent Advances in Polyacrylonitrile-Based Separators for Aqueous Zinc-Ion Batteries. 水锌离子电池用聚丙烯腈基隔膜的研究进展。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-15 DOI: 10.1002/asia.202500810

Md Monjorul Islam, Arshad Hussain, Najia Tahsin Kumkum, Sheikh Jakia Nur Oishee, M Nasiruzzaman Shaikh, Nadeem Baig, Md Abdul Aziz, A J Saleh Ahammad

{"title":"Recent Advances in Polyacrylonitrile-Based Separators for Aqueous Zinc-Ion Batteries.","authors":"Md Monjorul Islam, Arshad Hussain, Najia Tahsin Kumkum, Sheikh Jakia Nur Oishee, M Nasiruzzaman Shaikh, Nadeem Baig, Md Abdul Aziz, A J Saleh Ahammad","doi":"10.1002/asia.202500810","DOIUrl":"https://doi.org/10.1002/asia.202500810","url":null,"abstract":"The electrical energy enhances the proliferation of electronic devices in the modern era. Typically, most electronic devices run on a lithium-ion battery (LIB). However, safety issues prompt researchers to consider alternatives, and the aqueous zinc-ion battery (AZIB) emerged as an alternative with higher merits. One of the fundamental segments of the AZIB is the separator that provides ion transportation on both sides of the battery while deterring direct contact between the cathode and anode. For AZIBs, glass fiber (GF) is the most conventional separator considering their availability and cost-effectiveness, suffering from various hurdles, for instance, dendrite formation, which is the primary concern, causing an explosion during battery operation, and the low mechanical strength. Conversely, the polyacrylonitrile (PAN) prevents dendrite formation through the electrostatic interaction, deposition along the (002) plane, 3D diffusion, and selective zinc ion permeation, and offers high cyclability. We segment this paper into four parts: first, it discusses the basic features of the ideal separator; second, the preparation methods of the separator; third, a critical overview of the PAN-based separator for AZIB, especially the dendrite mitigation strategies; and finally, it provides the future directions and strategies for advance PAN-based separator design.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00810"},"PeriodicalIF":3.3,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145063057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metallic Nanozymes: From Catalytic Mechanisms to Biomedical Therapeutics and Flexible Wearable Integration. 金属纳米酶：从催化机制到生物医学治疗和灵活的可穿戴集成。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-12 DOI: 10.1002/asia.202500814

Zeeshan Ahmad, Isha Ishfaq, Jiajia Li, Ankush Sheoran, Xiaohan Guo, Qingyu He, Zhixuan Chen, Wenjing Liu, Faisal Saleem

{"title":"Metallic Nanozymes: From Catalytic Mechanisms to Biomedical Therapeutics and Flexible Wearable Integration.","authors":"Zeeshan Ahmad, Isha Ishfaq, Jiajia Li, Ankush Sheoran, Xiaohan Guo, Qingyu He, Zhixuan Chen, Wenjing Liu, Faisal Saleem","doi":"10.1002/asia.202500814","DOIUrl":"https://doi.org/10.1002/asia.202500814","url":null,"abstract":"Nanozymes, a groundbreaking class of artificial enzymes, have been recognized as one of the top ten emerging technologies in chemistry by the International Union of Pure and Applied Chemistry in 2022, which has brought biomedical applications and wearable electronic devices to a different stage due to their enzyme-like catalytic activities. These synthetic catalysts effectively overcome the limitations associated with natural enzymes, including their inherent instability and high costs, while simultaneously providing adjustable redox activity and multifunctional capabilities. In this review paper, we summarize the catalytic mechanisms of metallic nanozymes, their biomedical applications, including biosensing, antimicrobial therapies, tumor therapies, and anti-inflammatory strategies, as well as their integration into advanced wearable electronic devices. Finally, we discuss future research directions to guide the progress of next-generation nanozymes for precision medicine and smart diagnostics. This review could provide a pathway for interdisciplinary metallic nanozymes advancements, highlighting their potential to revolutionize personalized medicine and diagnostics, while addressing unsolved challenges in biosafety and scalability.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00814"},"PeriodicalIF":3.3,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145038909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Simple Water-Soluble TREN-1,8-aphthalimide Fluorescent "Turn-On" PET Sensor for Selective and Reversible Detection of Cu(II) Ion and Application in Cellular Imaging. 一种简单的水溶性trenn -1,8-萘酰亚胺荧光“开启”PET传感器，用于选择性和可逆检测Cu（II）离子及其在细胞成像中的应用。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-12 DOI: 10.1002/asia.70309

Mannanthara Kunhumon Noushija, Sweata Hanson, Deivasigamani Umadevi, Nandita Mishra, Sankarasekaran Shanmugaraju

{"title":"A Simple Water-Soluble TREN-1,8-aphthalimide Fluorescent \"Turn-On\" PET Sensor for Selective and Reversible Detection of Cu(II) Ion and Application in Cellular Imaging.","authors":"Mannanthara Kunhumon Noushija, Sweata Hanson, Deivasigamani Umadevi, Nandita Mishra, Sankarasekaran Shanmugaraju","doi":"10.1002/asia.70309","DOIUrl":"https://doi.org/10.1002/asia.70309","url":null,"abstract":"A new water-soluble 1,8-naphthalimide fluorophore, TREN-Nap, is synthesized in quantitative yield through a one-pot imidation reaction between 1,8-naphthalic anhydride and tris(2-aminoethyl)amine (TREN). TREN-Nap is then employed as a fluorescent \"turn-on\" chemosensor for detecting Cu(II) ions in water. The fluorescence titration studies revealed remarkable selectivity and reversible binding affinity of TREN-Nap toward Cu(II) ions, with significant enhancement (turn-on) in fluorescence emission intensity and sensitivity at the micromolar level (0.74 µM, 0.24 ppm). Notably, similar titration studies with other commonly interfering metal cations such as Zn(II), Mg(II), Cd(II), Ni(II), Co(II), Ba(II), Al(III), Pb(II), and Ca(II) caused almost negligible changes in the emission intensity, indicating their weak binding with TREN-Nap. Moreover, TREN-Nap displayed impressive sensing capability for Cu(II) ions even in real water samples. TREN-Nap is further employed as a bioimaging agent in breast cancer (MDA-MB-231) and lung epithelial (L929) cells. These results affirm that TREN-Nap is an excellent fluorescent \"turn-on\" sensor for Cu(II) ion detection in water and biological media.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e70309"},"PeriodicalIF":3.3,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145038916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable Nafion–Cellulose Composite Membrane: Role of Biomass-Derived Cellulose Loading in Suppression of Polysulfide Shuttling for Redox Flow Batteries 可持续钠-纤维素复合膜：生物质纤维素负载在抑制氧化还原液流电池中多硫化物穿梭中的作用。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-11 DOI: 10.1002/asia.202500679

Shakira Allah Baksh, Ata-ur-Rehman, Safyan Akram Khan, Shahid Ali, Majad Khan, Dr. Muhammad Mansha, Faizah Altaf, Dr. Muhammad Nawaz Tahir

{"title":"Sustainable Nafion–Cellulose Composite Membrane: Role of Biomass-Derived Cellulose Loading in Suppression of Polysulfide Shuttling for Redox Flow Batteries","authors":"Shakira Allah Baksh,  Ata-ur-Rehman, Safyan Akram Khan, Shahid Ali, Majad Khan, Dr. Muhammad Mansha, Faizah Altaf, Dr. Muhammad Nawaz Tahir","doi":"10.1002/asia.202500679","DOIUrl":"10.1002/asia.202500679","url":null,"abstract":"The cross-shuttling of polysulfide ions in bromine/polysulfide-based redox flow batteries (RFBs) is one of the major challenges that hinder their overall performance. Herein, we utilized cellulose extracted from waste date palm trees (DPT) and Nafion to fabricate an in-house membrane that contributes to mitigating this problem. A series of Nafion membranes with cellulose ratios of 5, 10, 20, and 30 wt% were fabricated and labeled CNF5, CNF10, CNF20, and CNF30, respectively. The CNF20 displayed promising thickness (∼77 µm) and mechanical stability, and as a result, it was investigated further and compared with the commercial Nafion 117 membrane. CNF20 exhibited an ion exchange capacity of 1.35 meq/g, water uptake of 39% and ionic conductivity of 0.090 S/cm. Both membranes exhibited a charge capacity of approximately 555.5 mAh/L. However, CNF20 retained 99.9% of its capacity, as compared to 93.7% for Nafion 117, after 100 cycles. The charge capacity decay and discharge capacity decay for CNF20 were 18 times and 120.6 times lower, respectively, than for the Nafion 117 membrane. The CNF20 showed energy efficiency of 31.3% whereas Nafion 117 exhibited 23.2% over 100 cycles. The cost analysis for CNF20 resulted in a 57.7% reduction as compared to the commercial price of Nafion 117. These results position CNF20 as a cost-effective, sustainable, and eco-friendly alternative compared to a membrane composed solely of Nafion 117.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":"20 19","pages":""},"PeriodicalIF":3.3,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Donor-extended meso-Disubstituted Dipyrromethane-Based Dipodal Ligands and Their Metal Complexes: An Overview. 供体扩展介位二取代二吡咯烷基双足配体及其金属配合物综述。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-11 DOI: 10.1002/asia.70256

Monalisa Giri, Satabdi Roy, Tapas Guchhait

{"title":"Donor-extended meso-Disubstituted Dipyrromethane-Based Dipodal Ligands and Their Metal Complexes: An Overview.","authors":"Monalisa Giri, Satabdi Roy, Tapas Guchhait","doi":"10.1002/asia.70256","DOIUrl":"https://doi.org/10.1002/asia.70256","url":null,"abstract":"The meso-disubstituted dipyrromethanes are an important class of ligand system which coordinate metal-ions across the periodic table as they feature two σ-donor anionic pyrrolic-N-atoms and offer pyrrole-π-electrons to the metal centres. They have the active 1,9-positions for preparing their variants that may contain additional donor atoms in the side arms. The introduction of the arms to the dipyrromethane moieties not only make them polyfunctional but also enhances flexibility of the system. In this review article, we highlight the syntheses and metal-ion coordination of various donor-extended meso-disubstituted dipyrromethane-based ligands that include the scaffolds decorated with diamine, diimine, bis-azo, diphosphine, or bis-pyrazole functions on both sides. The resulting NNNN and PNNP types of tetradentate dipodal ligands yield a large number of transition or alkali metal complexes with attractive structural and coordination properties, expressing the main focus of this article. We also emphasize the structural variations of the complexes dictated by the steric-bulk of the substituents at the meso-position or at the termini of the dipods. In addition, certain metal complexes bearing the extended ligand(s) participate in distinct catalytic transformations and also show interesting magnetic behaviors that are minutely discussed. Finally, a few hints of research endeavours are outlined for future purview.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e70256"},"PeriodicalIF":3.3,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sensing Picric Acid with Dinuclear Triazole Chelated Iridium(III) Nanoaggregates: Insights into the AIEE Quenching Process. 用双核三唑螯合铱（III）纳米聚集体感应苦味酸：对AIEE猝灭过程的洞察。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-11 DOI: 10.1002/asia.70275

Deep Lahan, Parna Gupta

{"title":"Sensing Picric Acid with Dinuclear Triazole Chelated Iridium(III) Nanoaggregates: Insights into the AIEE Quenching Process.","authors":"Deep Lahan, Parna Gupta","doi":"10.1002/asia.70275","DOIUrl":"https://doi.org/10.1002/asia.70275","url":null,"abstract":"We synthesized a mononuclear and two dinuclear Ir(III) complexes with a substituted triazole and two triazolyl bidentate chelators bridged through propyl and m-phenylene linkers, respectively. The complexes exhibit a considerable enhancement in emission intensity upon aggregation. The formation of nanoaggregates was confirmed through dynamic light scattering (DLS) and transmission electron microscopy (TEM) studies. The dinuclear complexes quench aggregation-induced enhanced emission in the presence of trinitrophenol (TNP/Picric Acid: PA) selectively from a batch of nitroaromatics in water, whereas the mononuclear complex is not selective. Therefore, dinuclear complexes were employed to selectively detect the explosive nitroaromatic picric acid (PA) in aqueous solution. For Ir1 and Ir2, the Stern-Volmer quenching constants (KSV) for the detection of PA were determined to be 0.17 × 106 and 0.34 × 106 M-1, with a low limit of detection (LOD) of 107 and 68 nM, respectively. The practical applicability was further evaluated through a selectivity study involving various metal ions and quenchers under identical conditions. Finally, the quenching process has been studied in detail to understand the participation of possible electron-transfer and energy-transfer processes. The analysis of the combined spectroscopic and theoretical results confirms that both electron-transfer and energy-transfer processes are operative here.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e70275"},"PeriodicalIF":3.3,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Evaluation of Tacrinocerins, Tacrine Hybrids with α-Onocerin from Phlegmariurus nummulariifolius (Blume) Ching, as a Novel Class of Acetylcholinesterase Inhibitor. 一类新型乙酰胆碱酯酶抑制剂——麻麻菌α-胆碱杂交体的合成与评价

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-11 DOI: 10.1002/asia.202500705

Chuleeporn Ngernnak, Sutthida Wongsuwan, Somsak Ruchirawat, Nopporn Thasana

{"title":"Synthesis and Evaluation of Tacrinocerins, Tacrine Hybrids with α-Onocerin from Phlegmariurus nummulariifolius (Blume) Ching, as a Novel Class of Acetylcholinesterase Inhibitor.","authors":"Chuleeporn Ngernnak, Sutthida Wongsuwan, Somsak Ruchirawat, Nopporn Thasana","doi":"10.1002/asia.202500705","DOIUrl":"https://doi.org/10.1002/asia.202500705","url":null,"abstract":"This study reports the synthesis and biological evaluation of tacrinocerins, a series of hybrid compounds derived from tacrine (1) and the natural product α-onocerin (2), which was isolated from the Thai club moss Phlegmariurus nummulariifolius (Blume) Ching. The primary aim was to develop potent and safe therapeutics for Alzheimer's disease (AD). The compounds were assessed for their inhibitory activity against acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE), as well as their cytotoxicity and potential for cancer chemoprevention. The results showed that compound 8b was the most potent AChE inhibitor but exhibited high cytotoxicity to neuronal and hepatic cells, making it a better candidate for anticancer applications. Additionally, tacrinocerin 4u, which exhibited moderate AChE inhibition, low toxicity, and anticancer potential, makes it an attractive candidate for the development of safer therapeutic agents. Meanwhile, tacrinocerin 4c emerged as the most promising candidate for AD therapy, combining potent AChE inhibition with a favorable safety profile. It showed moderate to low toxicity to neuronal and hepatic cells, while also demonstrating significant anticancer activity against MOLT-3 cells and excellent multitarget chemopreventive potential. This research successfully identified 4c as a leading dual-action agent, providing a strong foundation for designing next-generation tacrinocerins with optimized therapeutic indices.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00705"},"PeriodicalIF":3.3,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Re-Based Rectangles as Potential Low-Temperature Nanoprobes: Synthesis, Structure, and Study of Permittivity 作为潜在低温纳米探针的重基矩形：合成、结构和介电常数研究。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-11 DOI: 10.1002/asia.202500463

Dr. Chung-Chou Lee, Dr. Muhammad Usman, Prof. Dr. Ming-Yu Kuo, Prof. Dr. Pounraj Thanasekaran, Chia-Chun Liu, Prof. Dr. Jing-Yun Wu, Guan Ru Chiou, Prof. Dr. Jenq-Wei Chen, Dr. Cheng-Hua Lee, Dr. Li-Wei Lee, Yi-Hsuan Pan, Prof. Dr. Long-Li Lai, Prof. Dr. Chen-Hsiung Hung, Prof. Dr. Kuang-Lieh Lu

{"title":"Re-Based Rectangles as Potential Low-Temperature Nanoprobes: Synthesis, Structure, and Study of Permittivity","authors":"Dr. Chung-Chou Lee, Dr. Muhammad Usman, Prof. Dr. Ming-Yu Kuo, Prof. Dr. Pounraj Thanasekaran, Chia-Chun Liu, Prof. Dr. Jing-Yun Wu, Guan Ru Chiou, Prof. Dr. Jenq-Wei Chen, Dr. Cheng-Hua Lee, Dr. Li-Wei Lee, Yi-Hsuan Pan, Prof. Dr. Long-Li Lai, Prof. Dr. Chen-Hsiung Hung, Prof. Dr. Kuang-Lieh Lu","doi":"10.1002/asia.202500463","DOIUrl":"10.1002/asia.202500463","url":null,"abstract":"Molecular metallacycles capable of undergoing specific movements upon thermal stimulation hold significant potential in various nanotechnology applications. In this study, Re-based rectangles were self-assembled via a one-pot synthesis, exhibiting thermal chair‒boat transformations. These transformations were confirmed using single-crystal X-ray diffraction analysis and 1H NMR spectroscopy. Additionally, dielectric spectroscopy provided further physical evidence of these conformational transformations, revealing a linear relationship between the dielectric constant and the thermal vibrations of the molecular rectangles at low temperatures. This chair‒boat transformation in Re-based molecular rectangles represents a significant and encouraging advancement, paving the way for novel applications of such molecules as low-temperature-dependent dielectrics. This work also adds a compelling dimension to the intriguing field of molecular metallacycles.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":"20 19","pages":""},"PeriodicalIF":3.3,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Strategies for the Development of Donors and Precursors of Hydrogen Selenide (H₂Se). 硒化氢（H2Se）供体和前体的开发策略。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-10 DOI: 10.1002/asia.202500842

Jinxin Hu, Wenfang Liang, Long Yi

引用次数: 0

Synergistic Engineering of NiCoFe Layered Hydroxides for Enhanced Energy Storage and Electrocatalytic Water Splitting. NiCoFe层状氢氧化物增强储能和电催化水分解的协同工程。

IF 3.3 3区化学

Chemistry - An Asian Journal Pub Date : 2025-09-09 DOI: 10.1002/asia.70294

Boyao Zhang, Ruiyu Li, Xinxin Zhao, Huiya Zhou, Xin Li, Yibo Wang, Rongda Zhao, Lihua Miao

{"title":"Synergistic Engineering of NiCoFe Layered Hydroxides for Enhanced Energy Storage and Electrocatalytic Water Splitting.","authors":"Boyao Zhang, Ruiyu Li, Xinxin Zhao, Huiya Zhou, Xin Li, Yibo Wang, Rongda Zhao, Lihua Miao","doi":"10.1002/asia.70294","DOIUrl":"https://doi.org/10.1002/asia.70294","url":null,"abstract":"The rational design of electrode materials with outstanding energy and power density for supercapacitors (SCc) and high-performance electrocatalysts in alkaline media plays an indispensable role in the application of energy storage and overall water splitting. In this paper, we prepared NiCoFe layered ternary hydroxides (LTH) using a hydrothermal synthesis method. The sample with a Ni/Co/Fe ratio of 1:2:0.5 (Co) exhibited the best performance, achieving a specific capacitance of 860 C g-1 at a current density of 1 A·g-1. When assembled into a supercapacitor, it achieved an energy density of 72.3 Wh·kg-1 at a power density of 4050 W·kg-1, and after 7200 charge-discharge cycles, the capacity retention rate was 69.2%. For the hydrogen evolution reaction (HER), the overpotential was 100.4 mV at 10 mA·cm-2; in oxygen evolution, the sample with a Ni/Co/Fe ratio of 2:1:1.5 (Ni,Co) showed better performance, presenting an overpotential of 235.3 mV at 50 mA·cm-2. Moreover, when constructing a symmetrical two-electrode system using both ratios of NiCoFe layered hydroxides, the water splitting voltage was only 1.861 V at 100 mA·cm-2. It is hoped that NiCoFe-LDH prepared under appropriate conditions can optimise its applicability as fundamental components for SCc and water-splitting systems.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e70294"},"PeriodicalIF":3.3,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145022453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0