Chemistry - An Asian Journal最新文献_第9页

Deracemization of Benzoin and its Derivatives via Kinetic, Dynamic Kinetic, Aerobic Oxidative Kinetic and Reagent-mediated resolution.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401693

Venkata Subba Reddy Ummareddy, Raveendra Babu Kothapalli, Anusha Bheemreddy, Naveen Kumar Marri, Sundar Singh P, Ramakrishna S

{"title":"Deracemization of Benzoin and its Derivatives via Kinetic, Dynamic Kinetic, Aerobic Oxidative Kinetic and Reagent-mediated resolution.","authors":"Venkata Subba Reddy Ummareddy, Raveendra Babu Kothapalli, Anusha Bheemreddy, Naveen Kumar Marri, Sundar Singh P, Ramakrishna S","doi":"10.1002/asia.202401693","DOIUrl":"https://doi.org/10.1002/asia.202401693","url":null,"abstract":"The production of enantiomerically pure compounds remains a vital and valuable objective in modern organic chemistry due to their broad applications in fields such as biosensing, optics, electronics, photonics, catalysis, nanotechnology, and drug or DNA delivery. Optically pure α-hydroxy ketones, in particular, are key structural components in many drugs and natural products with significant biological activity. Among these, benzoin type α-hydroxy ketones, which possess two adjacent functional groups, a carbonyl and a hydroxy group, are especially important. These functional groups can be easily transformed into the significant organic compounds such as 1,2 amino alcohols and 1,2 diols etc, which are important intermediates for synthesis of high profile biological active natural products. Deracemization of racemic compounds remains one of the most effective strategies for producing optically pure compounds, despite recent advances in asymmetric synthesis. Many research groups have developed various methods for resolving racemic benzoins, including kinetic resolution, dynamic kinetic resolution, metal-catalyzed aerobic oxidative kinetic resolution, and reagent-mediated resolution. In this context, we aim to provide a comprehensive review of the various resolution methods applied specifically to racemic benzoins. To the best of our knowledge, no comprehensive review on the resolution of racemic benzoins has been published to date.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401693"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ferrocene-Based Metal-Organic Framework for Adsorption and Degradation of Antibiotics.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401246

Shuohan Ma, Xiaojiao Di, Yi Wang, Yuchao Lu, Zhichao Pei, Yuxin Pei

引用次数: 0

Modified Imidazole-Phenol-Based ESIPT Fluorophores as Self-Absorption Free Emitters for Efficient Electroluminescent Devices.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401326

Sujinda Petdee, Kasin Rueantong, Suangsiri Arunlimsawat, Teerapat Itsoponpan, Atthapon Saenubol, Pattarapapa Janthakit, Phattananawee Nalaoh, Taweesak Sudyoadsuk, Vinich Promarak

{"title":"Modified Imidazole-Phenol-Based ESIPT Fluorophores as Self-Absorption Free Emitters for Efficient Electroluminescent Devices.","authors":"Sujinda Petdee, Kasin Rueantong, Suangsiri Arunlimsawat, Teerapat Itsoponpan, Atthapon Saenubol, Pattarapapa Janthakit, Phattananawee Nalaoh, Taweesak Sudyoadsuk, Vinich Promarak","doi":"10.1002/asia.202401326","DOIUrl":"10.1002/asia.202401326","url":null,"abstract":"Excited-state intramolecular proton transfer (ESIPT) molecules are promising fluorophores for various applications including bioimaging, sensing, and optoelectronic devices. Particularly, their self-absorption-free fluorescence properties would make them a perfect choice as emissive materials for organic light-emitting diodes (OLEDs). Nevertheless, to become effective emitters some of their properties need to be altered by structural modifications. Herein, we design and synthesize a series of new ESIPT molecules (2PImBzP, 2ImBzP, and 2FImBzP) by functionalization of imidazole-phenol-based ESIPT cores with electron-deficient benzo[d]thiazole and various ambipolar imidazole moieties (1-phenyl-1H-phenanthro[9,10-d]imidazole (PIm), 1,4,5-triphenyl-1H-imidazole (Im), and (4,5-bis(4-fluorophenyl)-1-phenyl-1H-imidazole (FIm)), respectively. Each molecule displays a complete ESIPT process with intense green emissions from a pure keto form and high solid-state photoluminescence quantum yields (ΦPL) of 65-80 %. These fluorophores with superior thermal stability and balanced charge carrier mobility are effectively employed as non-doped emitters in OLEDs. The non-doped devices emit greenish lights with high brightness, high current efficiency (CE) (10.95-17.66 cd A-1), and low turn-on voltages (2.8-2.9 V). The electroluminescence purely originates from the emission of the keto tautomer of the emissive layers. Specifically, the 2PImBzP-based non-doped OLED stands out by achieving a remarkable brightness of 56,220 cd m-2, a CE of up to 17.66 cd A-1, and an impressive external quantum efficiency (EQE) of 5.65 % with a slight efficiency roll-off.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401326"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dual Activities of Flower-Like Gold-Iron Oxide Nanozyme for Peroxidase-Mimicking and Glucose Detection.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401479

Kanika Bharti, Sancharika Dalal, Avni Tyagi, Kalyan K Sadhu

{"title":"Dual Activities of Flower-Like Gold-Iron Oxide Nanozyme for Peroxidase-Mimicking and Glucose Detection.","authors":"Kanika Bharti, Sancharika Dalal, Avni Tyagi, Kalyan K Sadhu","doi":"10.1002/asia.202401479","DOIUrl":"10.1002/asia.202401479","url":null,"abstract":"Nanozymes, constituting of inorganic nanomaterials, are the sustainable and cost-effective alternatives of the naturally abundant enzymes. For more than a decade, nanozymes have shown astonishingly enhanced enzymatic activity as compared to its naturally occurring counterpart and emerged as a potential platform in biomedical science. The current study reports a novel flower shaped gold-iron oxide nanocomposite prepared via a facile and green solution phase redox mediated synthesis. The precursor gold salt conversion to nanometallic Au(0) is mediated by iron metal powder, which acts both as reductant and metal source in the resultant gold nanoparticle decorated iron oxide nanocomposite. Calcination of the synthesized nanocomposites leads to morphological evolution into unique flower shape with improved homogeneity between gold and iron components along with metal surface exposure. The gold-iron oxide nanocomposites have been utilized first time for peroxidase mimicking study and exhibit enhanced catalytic activity at 25 °C with low Michaelis-Menten constant (Km) and higher maximum reaction velocity (Vmax) as compared to the natural enzyme Horseradish peroxidase (HRP). In addition, combined assembly of this nanozyme with natural enzyme glucose oxidase also serves a potential platform for the visible colorimetric detection and quantification of glucose with limit of detection (LOD) of 15 μM.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401479"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Harnessing RNA-Protein Interactions for Therapeutic Interventions.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401117

Khushboo Goel, Ishu Saraogi

{"title":"Harnessing RNA-Protein Interactions for Therapeutic Interventions.","authors":"Khushboo Goel, Ishu Saraogi","doi":"10.1002/asia.202401117","DOIUrl":"10.1002/asia.202401117","url":null,"abstract":"Interactions between RNAs and proteins play a crucial role in various diseases, including viral infections and cancer. Hence, understanding and inhibiting these interactions are important for the development of novel therapeutics. However, the identification of drugs targeting RNA-protein interactions with high specificity and affinity is challenged by our limited molecular understanding of these interactions. Recent focus on structural and biochemical characterization, coupled with high-throughput screening technologies and computational modeling, have accelerated the identification of new RBPs and optimization of potential inhibitors. This review discusses key examples of inhibitors developed over the past decade that effectively disrupt pathogenic RNA-protein interactions. We focus on small molecule and peptide-based inhibitors that have shown promise in disrupting crucial RNA-protein interactions in eukaryotes, prokaryotes, and viruses. We also present the challenges and future directions in this field, emphasizing the need to achieve improved specificity and reduce the off-target effects of the inhibitors. This review aims to contribute to ongoing efforts towards the development of novel therapeutic agents targeting RNA-protein interactions by providing an in-depth analysis of significant developments and emerging trends in this rapidly growing field.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401117"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photothermal Miniemulsion Polymerization by Amphiphilic Gold Nanoclusters.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401194

Ning Yang, Yuetong Kang, Jiaren Liu, Jiaxi Wang, Yonghui Zan, Xuan Zhao, Xiaoyu Wang, Lidong Li

{"title":"Photothermal Miniemulsion Polymerization by Amphiphilic Gold Nanoclusters.","authors":"Ning Yang, Yuetong Kang, Jiaren Liu, Jiaxi Wang, Yonghui Zan, Xuan Zhao, Xiaoyu Wang, Lidong Li","doi":"10.1002/asia.202401194","DOIUrl":"https://doi.org/10.1002/asia.202401194","url":null,"abstract":"Gold nanoclusters (AuNCs), which are approximately 2 nm in size, exhibit distinctive photophysical and catalytic properties, but their performance is often compromised by environmental factors. To mitigate these challenges, attempts have been made to incorporate AuNCs into polymer matrices to enhance their stability. Miniemulsion polymerization has proven to be an effective method for fabricating organic-inorganic composites. Here, we present a facile photothermal-assisted method for miniemulsion polymerization utilizing AuNCs, which serve as co-stabilizers of the emulsion and photothermal conversion agents. By grafting tryptamine onto hydrophilic AuNCs, the amphiphilic AuNCs were spontaneously adsorbed at the styrene/water interfaces, resulting in stable nanoemulsions. Taking advantage of the photothermal properties of surface-bounded AuNCs, rapid polymerization of styrene within the nanoemulsion was successfully initiated by external laser irradiation. The prepared nanocomposites inherited the photothermal activity of AuNCs and exhibited good photothermal stability and repeatability. This approach not only facilitates remote control of chemical reactions, but also optimizes the distribution of AuNCs within the final polymer matrix, thereby enabling the efficient synthesis of nanocomposites while exploiting the unique photofunctionality of AuNCs.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401194"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Single-Atom based Metal-Organic Frameworks for Efficient C-S Cross-Coupling.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401578

Jayaramulu Kolleboyina, Gobbilla Sai Kumar, Deepak Kumar, Aditya Thakur, Mukul Gupta, Praveen Kumar Velpula, Rabindranath Lo

{"title":"Single-Atom based Metal-Organic Frameworks for Efficient C-S Cross-Coupling.","authors":"Jayaramulu Kolleboyina, Gobbilla Sai Kumar, Deepak Kumar, Aditya Thakur, Mukul Gupta, Praveen Kumar Velpula, Rabindranath Lo","doi":"10.1002/asia.202401578","DOIUrl":"https://doi.org/10.1002/asia.202401578","url":null,"abstract":"Single-atom-based Metal-Organic Frameworks (MOFs) hold great promising candidates for heterogeneous catalysis, demonstrating outstanding catalytic activity and exceptional product selectivity. This is attributed to their optimal atom utilization, high surface energy, and the presence of unsaturated coordination environments. Here in, we have developed a nickel single-atom catalyst (UiO-66/Ni) featuring Ni single atoms covalently attached to defect-engineered Zr-oxide clusters within the stable UiO-66 framework, synthesized via a straightforward solution impregnation method. The resulting UiO-66/Ni catalyst, with a uniform distribution of nickel single atoms, exhibits remarkable stability and demonstrates exceptional performance in C-S coupling reactions of various aryl thiols and aryl halides, yielding desired products with outstanding catalytic activity and selectivity, regardless of electron-donating or withdrawing substituents at room temperature and maintains robust stability even after six cycles. Advanced density functional theory calculations have been exploited to clarify the mechanism of C-S cross-coupling for examining the influence of substituents on the aromatic ring of aryl thiols through free energy profiles. The collaborative action of nickel single atoms and the defects of UiO-66 during the oxidative addition and reductive elimination steps facilitated the formation of energetically favorable C-S cross-coupling products.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401578"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bimetallic Cooperativity of a Ferrocene-based Iridium NHC Complex in Water Oxidation Catalysis: A New Frontier for Efficient Oxygen Evolution.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401357

Debashree Bora, Himangshu Pratim Bhattacharyya, Firdaus Rahaman Gayen, Sudip Baguli, Pitambar Patel, Manabendra Sarma, Biswajit Saha

{"title":"Bimetallic Cooperativity of a Ferrocene-based Iridium NHC Complex in Water Oxidation Catalysis: A New Frontier for Efficient Oxygen Evolution.","authors":"Debashree Bora, Himangshu Pratim Bhattacharyya, Firdaus Rahaman Gayen, Sudip Baguli, Pitambar Patel, Manabendra Sarma, Biswajit Saha","doi":"10.1002/asia.202401357","DOIUrl":"https://doi.org/10.1002/asia.202401357","url":null,"abstract":"Bimetallic catalysts have gained attention as promising contenders, owing to the synergistic interaction between two distinct metal centers. In this study, we present two N-heterocyclic carbene iridium(III) pentamethylcyclopentadienyl complexes [Cp*Ir(fcpyNHC)Cl]PF6 (1) and [Cp*Ir(pyNHC)Cl]PF6 (2) where 1 includes a ferrocene moiety acting as a bimetallic complex. Using ceric ammonium nitrate as a sacrificial oxidant, both complexes were tested for water oxidation. Complex 2 achieved a maximum turnover number (TONmax) of 3240 and a turnover frequency (TOFmax) of 231 min-1. In comparison, complex 1 demonstrated nearly double the activity with a TONmax of 6047 and TOFmax of 431 min-1 compared to 2, which was attributed to the cooperative effect of the catalyst in water oxidation reaction. This bimetallic Fe^Ir catalyst (1) exhibited outstanding catalytic efficiency for oxygen evolution from water at ambient conditions. We identified a proposed FeIII^IrIV intermediate experimentally via UV-Vis spectroscopy and XPS study. Theoretically, this intermediate was more stable by 7.84 kcal/mol than the traditional FeII^IrV electromer intermediate. This delineates the pronounced bimetallic cooperative participation of both Fe and Ir metal centres for better activity.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401357"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of protonation induced distortions on the spectral properties and electronic structure of Octaphenylporphyrins: UV-vis, electrochemical, VT-NMR and ab initio studies.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202400719

Nivedita Rana, Soni Kumari, Muniappan Sankar

{"title":"Effect of protonation induced distortions on the spectral properties and electronic structure of Octaphenylporphyrins: UV-vis, electrochemical, VT-NMR and ab initio studies.","authors":"Nivedita Rana, Soni Kumari, Muniappan Sankar","doi":"10.1002/asia.202400719","DOIUrl":"https://doi.org/10.1002/asia.202400719","url":null,"abstract":"The extent of conformational alteration of the porphyrin macrocycle during the course of protonation was observed, both experimentally and theoretically. For synthesized β-substituted octaphenylporphyrin (OPP) ring systems this macrocyclic distortions have been investigated by spectroscopic and computational analysis. Protonation induced nonplanarity in macrocyclic system is experimentally observed in a single step during spectrophotometric titration. The progress of the protonation by TFA was monitored i.e. the addition of proton to the core of the ring was monitored by UV/Vis spectroscopy, which was also determined logβ value. The spectral changes demonstrate the conformational flexibility of these macrocyclic systems correlating with the photophysical properties. The degree of nonplanarity exhibited incremental progress in response to protonation, with a specific order observed: H2TPP < H2OPP < H2OPPBr4 < H2OPPBr3NO2. Furthermore, our study delved into the structural aspects, frontier molecular orbitals and ground state energies of H4P(CF3COO)2 absorption bands computed at the TD-B3LYP/6-31G level of theory, anticipated a red shift in both the Soret and Q0,0 bands. This theoretical prediction aligns seamlessly with the experimental findings from spectrophotometric titrations, providing validation to our computation insights. In summary, this comprehensive study elucidates the extent of conformational changes occurring in β-substituted OPP ring systems upon protonation and deprotonation.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202400719"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Triazine-functionalized Nitrogen-rich Covalent Organic Framework as an electrode material for Aqueous Symmetric Supercapacitor.

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2024-12-23 DOI: 10.1002/asia.202401149

Ikrar Ahmad, Omkar Singh, Jahangeer Ahmed, Saad M Alshehri, Priyanka Priyanka, Chitranjan Bharti, Vidivay Vidivay

{"title":"Triazine-functionalized Nitrogen-rich Covalent Organic Framework as an electrode material for Aqueous Symmetric Supercapacitor.","authors":"Ikrar Ahmad, Omkar Singh, Jahangeer Ahmed, Saad M Alshehri, Priyanka Priyanka, Chitranjan Bharti, Vidivay Vidivay","doi":"10.1002/asia.202401149","DOIUrl":"https://doi.org/10.1002/asia.202401149","url":null,"abstract":"Covalent triazine frameworks, with their ordered pores and crystalline structure that exhibit heteroatom impacts, demonstrate outstanding chemical stability, making them designable for charge storage applications. In this study, the TPT@BDA-COF was synthesized using 4',4''',4'''''-(1,3,5-Triazine-2,4,6-triyl)tris(([1,1'-biphenyl]-4-amine)) (TPT) and 4,4'-Oxydibenzaldehyde (BDA) following polycondensation process. Interestingly, these resulted in the fabrication of a well-connected, orderly porous crystalline structure, redox-active moiety, and high doping N (~13.6%). The three-electrode electrochemical study, showed a stable electrochemical potential window of 1.8 V (-0.45 to +1.35) in 1 M NaClO4 electrolyte, it exhibited a high specific capacitance of 92.6 mF/cm2 with a high energy density 41.7 Wh/kg respectively. The symmetric supercapacitor designed using TPT@BDA-COF as both anode and cathode exhibited high specific capacitance (F/g) and gravimetric energy density (Wh/kg):17.8, 36.9, 43.7, 47.7 and 3.5, 16.6, 13.7, 21.6 in 1 M CH3COONa, 1 M Na2SO4, 1 M NaNO3, 1 M NaClO4 electrolyte respectively. It showed excellent cyclic stability (105.2%), and Coulombic efficiency (97.5%) even after 10k GCD cycles in 1 M NaClO4 at 2 A/g. Interestingly, ClO4- anions exhibited a better chaotropic nature (water structure breaker) as compared to CH3COO-, SO4-2, and NO3-.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401149"},"PeriodicalIF":3.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0