Chemistry - An Asian Journal最新文献

Charge Carrier Mobility of Phenothiazine Functionalized TCBD Derivatives of Naphthalimide. 吩噻嗪功能化萘酰亚胺TCBD衍生物的载流子迁移率。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500259

Nikhil Ji Tiwari, Tarun, Upendra Kumar Pandey, Rajneesh Misra

{"title":"Charge Carrier Mobility of Phenothiazine Functionalized TCBD Derivatives of Naphthalimide.","authors":"Nikhil Ji Tiwari, Tarun, Upendra Kumar Pandey, Rajneesh Misra","doi":"10.1002/asia.202500259","DOIUrl":"https://doi.org/10.1002/asia.202500259","url":null,"abstract":"A set of naphthalimide functionalized push-pull chromophores NPI 1-3 were designed and synthesized via Pd-catalyzed Sonogashira cross-coupling followed by [2 + 2] cycloaddition-electrocyclic ring-opening reaction. The 1,8-naphthalimide (NPI) and 1,1,4,4-tetracyanobuta-1,3-diene (TCBD) moiety acts as an acceptor unit, whereas phenothiazine (PTZ) unit acts as a donor unit. Their photophysical, electrochemical properties, and charge carrier mobilities were investigated. Density functional theory (DFT) and TD-DFT calculations were performed on NPI 1-3 to analyze the molecular geometry, frontier molecular orbitals, molecular electrostatic potentials (MEPs), and electronic transitions related to their absorption spectra. The incorporation of cyano-based strong electron acceptor TCBD in the phenothiazine functionalized naphthalimide derivatives NPI1 resulted in TCBD incorporated chromophore NPI 2-3 which exhibits red-shifted electronic absorption spectra in the near IR region. The electrochemical properties reveal that the naphthalimide derivatives NPI 1-3 exhibit multiple redox waves, attributed to the presence of NPI and TCBD acceptor units and phenothiazine donor units. The measured hole and electron mobilities for NPI 1-3 are 4.06 × 10-3 and 3.16 × 10-3 cm2 V-1 s-1, 7.5 × 10-3 and 4.48 × 10-3 cm2 V-1 s-1, 6.76 × 10-3 and 3.1 × 10-3 cm2 V-1 s-1, respectively, obtained by space-charge limited current (SCLC) measurements.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00259"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Theoretical Insights into the Ni⁽⁰⁾-Catalyzed Asymmetric Hydroalkylation of Phenylbutadiene and Acetophenone: Mechanism, Selectivity, and Ligand Effect. Ni(0)催化苯丁二烯和苯乙酮不对称氢烷基化反应的理论见解：机理、选择性和配体效应。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500758

Shuwei Tang, Yufei Meng, Ying Liu, Pengfei Zhang, Zhiwei Zhang, Wanrong Guo, Song Pei, Yilong Xiao, Guowei Wang

{"title":"Theoretical Insights into the Ni(0)-Catalyzed Asymmetric Hydroalkylation of Phenylbutadiene and Acetophenone: Mechanism, Selectivity, and Ligand Effect.","authors":"Shuwei Tang, Yufei Meng, Ying Liu, Pengfei Zhang, Zhiwei Zhang, Wanrong Guo, Song Pei, Yilong Xiao, Guowei Wang","doi":"10.1002/asia.202500758","DOIUrl":"https://doi.org/10.1002/asia.202500758","url":null,"abstract":"Transition-metal-catalyzed hydroalkylation of enols/enolates with unsaturated hydrocarbons enables the functionalization via C─C and C-heteroatom bond formation. In this work, the reaction mechanisms of Ni(0)-catalyzed asymmetric hydroalkylation of phenylbutadiene and acetophenone are systematically investigated using density functional theory (DFT) calculations. The Ni(0)/Ni(II) catalytic cycle comprises oxidative addition, proton transfer, and the C(sp3)─C(sp3) bond formation via reductive elimination. The rate-determining oxidative addition step proceeds via a concerted ligand-to-ligand hydrogen transfer (LLHT) mechanism, bypassing an unstable Ni(II)-hydride intermediate. Proton transfer occurs via a ligand exchange with the enolate group within the acetophenone, and the regioselectivity arises from the preferential C(sp3)-C(sp3) bond formation via reductive elimination at the methyl-adjacent carbon in the acetophenone. Furthermore, the electron population analysis on the rate-determining transition state demonstrates that charge transfer from the Ni(0)-ligand moiety to the ─O+H σ* and ─C═C─π* antibonding orbitals facilitates the weakening of the ─O+H bond and η2-coordination of ─C═C─ bond in phenylbutadiene with the nickel center, enabling the LLHT mechanism. Additionally, the influence of ligand on the reactivity of Ni(0)-catalyzed asymmetric hydroalkylation is also explored, and the steric contour maps of percent buried volume (%Vbur) analysis confirm that the bulky ligands increase the %Vbur and enhance catalytic performance.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00758"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocatalytic Anticancer Activity of Cyclometalated Ir(III) Complexes: A Mechanistic Insight. 环金属化Ir（III）配合物的光催化抗癌活性：机理研究。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500681

Ashish Kumar Yadav, Virendra Singh, Ishwar Singh, Amit Kunwar, Biplob Koch, Samya Banerjee

{"title":"Photocatalytic Anticancer Activity of Cyclometalated Ir(III) Complexes: A Mechanistic Insight.","authors":"Ashish Kumar Yadav, Virendra Singh, Ishwar Singh, Amit Kunwar, Biplob Koch, Samya Banerjee","doi":"10.1002/asia.202500681","DOIUrl":"https://doi.org/10.1002/asia.202500681","url":null,"abstract":"Three novel cyclometalated Ir(III) complexes, Ir1-Ir3, were synthesized and thoroughly characterized. These complexes exhibited absorption in the 350-480 nm range, making them suitable candidates for visible-light-mediated photocatalytic cancer therapy. Under visible-light exposure in a DMSO:PBS (1:99 v/v) solvent system, all three photocatalysts demonstrated high efficiency in facilitating NADH oxidation, attaining turnover frequencies (TOFs) in the range of 499-698 h⁻1, exceeding the performance of most of the previously reported Ir(III)-based photocatalysts. Mechanistic studies verified the involvement of type I and type II pathways for ROS generation. Cytotoxicity studies highlighted significant photocytotoxic effects of Ir1-Ir3 in human lung adenocarcinoma cells (A549), with Ir3 emerging as the most potent under light exposure. Additionally, the negligible dark and light cytotoxicity of Ir3 against human embryonic kidney cells (HEK-293) demonstrated the safety profile of Ir3. Furthermore, the mechanistic studies in A549 cells revealed that Ir3 promoted mitochondrial membrane depolarization and activated caspase-3/7-dependent apoptotic pathways through light-triggered ROS generation and NADH oxidation. These findings highlight Ir3 as a potent dual-action cancer phototherapeutic, capable of synergistically inducing type-I and type-II anticancer activity, and efficient NADH photo-oxidation. This work presents a promising platform for developing multifunctional photocatalytic agents in cancer therapy.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00681"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocatalytic Disulfide Synthesis Using Trityl Sulfides. 三烷基硫化物光催化合成二硫化物。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500743

Keita Yamazaki, Tetsuhiro Nemoto

引用次数: 0

Benzil-Dihydrazone Based Bis-Schiff Base Dual-Sensor for Expeditious Colorimetric Detection of Ni²⁺ and Fluorometric Detection of Ag⁺: Environmental and Biological Applications. 基于苯二腙的双希夫碱双传感器快速比色检测Ni2+和荧光检测Ag+：环境和生物应用。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500779

Dishen Kumar, Srishti Dutta, Abhilash Pandey, Vanshika Sharma, Devanand Sahu, Sounik Manna, Sujata Maiti Choudhury, Goutam Kumar Patra

{"title":"Benzil-Dihydrazone Based Bis-Schiff Base Dual-Sensor for Expeditious Colorimetric Detection of Ni2+ and Fluorometric Detection of Ag+: Environmental and Biological Applications.","authors":"Dishen Kumar, Srishti Dutta, Abhilash Pandey, Vanshika Sharma, Devanand Sahu, Sounik Manna, Sujata Maiti Choudhury, Goutam Kumar Patra","doi":"10.1002/asia.202500779","DOIUrl":"https://doi.org/10.1002/asia.202500779","url":null,"abstract":"In this research, a novel dual chemosensor L has been reported. It has been characterised by FTIR, 1H-NMR, ESI-MS, elemental analyses, X-ray single crystal analysis and DFT studies. In a 1:1 methanol-water medium (v/v), the receptor L detected Ni2+ with color change from colorless to yellow and Ag+ with turn-on fluorescence enhancement. UV-vis spectroscopy, fluorescence titration, FTIR and ESI-MS have been used to analyse the response mechanisms of fluorescent colorimetric sensing. The colorimetric sensitivity for Ni2+ is 3.0 × 10-7 M and fluorometric sensitivity for Ag+ is 7.2 × 10-7 M; both the values are sufficient below the WHO permissible limits in aqueous solution. From the Job's plot measurements and the ESI-MS spectrum, 2: 1 stoichiometric complexation between L and Ni2+/Ag+ has been established. Receptor L shows remarkable detection ability in a wide pH range of 4-9 and can be successfully applied for the detection and quantification of Ni2+ ions in environmental samples, and Ag+ ions in BSA protein. At the specified doses and incubation times, L can be used as an anticancer drug and a selective sensor for bio-imaging of Ag+ ion without having any cytotoxic effects.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00779"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cobalt-Catalyzed One-Pot Three-Component Cascade Annulation for the Synthesis of Highly Functionalized 3,5-Disubstituted-2,6-Dicyanoanilines at Room Temperature. 钴催化一锅三组分级联环法制备高功能化3,5-二取代-2,6-二氰苯胺。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500634

Adrija Majumdar, Subham Sau, Arunabha Thakur

{"title":"Cobalt-Catalyzed One-Pot Three-Component Cascade Annulation for the Synthesis of Highly Functionalized 3,5-Disubstituted-2,6-Dicyanoanilines at Room Temperature.","authors":"Adrija Majumdar, Subham Sau, Arunabha Thakur","doi":"10.1002/asia.202500634","DOIUrl":"https://doi.org/10.1002/asia.202500634","url":null,"abstract":"A facile one-step, three-component domino reaction has been established for the efficient synthesis of 3,5-disubstituted-2,6-dicyanoaniline derivatives, utilizing aldehydes in conjunction with aromatic, cyclic, and acyclic ketones, as well as malononitrile. This methodology employs CoCl2·6H2O as a catalyst specifically for aromatic and acyclic ketones, whereas a metal-free, base-catalyzed approach is applied for cyclic ketones. The reaction proceeds via a sequential mechanism that encompasses Knoevenagel condensation, Michael addition, and nucleophilic cyclization. Conducted at room temperature, this reaction accommodates both aromatic and aliphatic aldehydes, leveraging inexpensive and readily available substrates, thereby obviating the necessity for costly cocatalysts or ligands. It offers simple conditions, shorter reaction times, high yields, and an atom-economical, eco-friendly one-pot approach. It also provides a broad substrate scope of total 21 compounds, including 14 new compounds. The photo-physical properties, assessed via UV-vis and fluorescence spectroscopy, revealed that some compounds showed red-shifted emissions, indicating their potential as fluorescent probes for bioimaging and as dye candidates for optoelectronic applications such as OLEDs. Gram-scale synthesis confirms its industrial relevance, whereas mechanistic studies, including control experiments and Hammett analysis provide insights into the reaction pathway.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00634"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

trans-Configured Ligands Boost Spin Crossover to Room Temperature in Mononuclear Fe(II) Complexes. 反式配体促进单核铁（II）配合物室温自旋交叉。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500638

Guang-Wen Fu, Yan Kong, Xin Chen, Ying-Ying Wu, Zi-Han Yan, Zhao-Yang Li, Yan-Hui Shi, Jing-Wei Dai, Xi-Guang Han, Feng-Lei Yang

{"title":"trans-Configured Ligands Boost Spin Crossover to Room Temperature in Mononuclear Fe(II) Complexes.","authors":"Guang-Wen Fu, Yan Kong, Xin Chen, Ying-Ying Wu, Zi-Han Yan, Zhao-Yang Li, Yan-Hui Shi, Jing-Wei Dai, Xi-Guang Han, Feng-Lei Yang","doi":"10.1002/asia.202500638","DOIUrl":"https://doi.org/10.1002/asia.202500638","url":null,"abstract":"Seven new mononuclear complexes [Fe(aqin)2(NCS)2] (1), [Fe(aqin)2(NCSe)2] (2), [Fe(aqin)2(NCBH3)2] (3), [Fe(2-pic)2(NCS)2] (4), [Fe(2-pic)2(NCSe)2] (5), [Fe(2-pic)(NCBH3)2] (6), [Fe(tpa)(NCBH3)2] (7), [aqin = 8-aminoquinoline, 2-pic = 2-picolylamine, tpa = tris(2-pyridylmethyl)amine)] are investigated. Structurally, except for 3, which affords a trans-configuration, all the complexes adopt a cis-configuration. Their propensity to crystallize without any solvent molecules facilitates the study of the influence of the \"pure\" ligand on spin-crossover (SCO) characteristics. Magnetically, 1, 2, and 4 remain in the high-spin state, and 3, 5, 6, and 7 display SCO with transition temperatures T1/2 of approximately 310, 162, 262, and 400 K, respectively. The T1/2 values of all the complexes except 3 follow the sequence of ligand-field strength, whereas the T1/2 value of 3 is increased to room temperature, beyond that of the whole cis-[Fe(2-pic)2(NCE)2] family. Theoretical modeling based on the harmonic approximation via Gaussian and periodic DFT+U+D3 calculations via the QE reveals that the lower distortion effect of the trans-configuration resulted in the LS stabilization increasing T1/2.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00638"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Impact of Advances in Anion Exchange Membranes and Ionomers on Alkaline Fuel Cells. 阴离子交换膜和离聚物研究进展对碱性燃料电池的影响。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500100

Zhongyang Wang, Shrihari Sankarasubramanian, Jianping Chen, Vijay K Ramani

引用次数: 0

Polyhydroxyurethane/Cobalt Nanocomposites as Green Non-PGM Electrocatalysts for OER. 聚羟基聚氨酯/钴纳米复合材料作为绿色非pgm OER电催化剂。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500609

Bantumelli Prasannatha, Sateesh Mulkapuri, Tushar Jana

{"title":"Polyhydroxyurethane/Cobalt Nanocomposites as Green Non-PGM Electrocatalysts for OER.","authors":"Bantumelli Prasannatha, Sateesh Mulkapuri, Tushar Jana","doi":"10.1002/asia.202500609","DOIUrl":"https://doi.org/10.1002/asia.202500609","url":null,"abstract":"Developing low-cost, efficient non-platinum group metal (non-PGM) electrocatalysts for the oxygen evolution reaction (OER) is critical for advancing green hydrogen production. In search of such a non-PGM catalyst, in this study, biodegradable polyhydroxyurethane (PHU) and cobalt salt nanocomposites were developed as green OER electrocatalysts for alkaline conditions (pH ∼13). Various amino acid-based PHUs were blended with cobalt salt and sodium alginate (NaAL), yielding non-PGM electrocatalysts (PHU1-PHU6). NaAL enhanced catalytic performance by improving ion and mass transport at the PHU-alginate interface. The hybrid catalysts exhibited superior OER activity, with PHU6 achieving a current density of 32 mA/cm2 at 1.58 V, outperforming the benchmark RuO₂ (17 mA/cm2 at 1.45 V) and CoOx (12 mA/cm2 at 1.53 V). PHU6 also demonstrated a lower Tafel slope (102 mV/dec), higher electrochemical surface area (53 cm2), double-layer capacitance (1.32 mF), and similar overpotential (239 mV @ 10 mA/cm2) compared to RuO₂ and CoOx. Its Faradic efficiency (∼80%) surpassed RuO₂ (76%) and CoOx (73%). The structure of PHUs significantly influenced these electrochemical parameters, showcasing PHU6's promise as a cost-effective, sustainable OER catalyst with excellent performance and stability.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00609"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymeric Membranes for Advanced Separation and Sensing: Materials and Mechanisms for Emerging Applications-A Review. 用于高级分离和传感的聚合物膜：新兴应用的材料和机制综述。

IF 3.5 3区化学

Chemistry - An Asian Journal Pub Date : 2025-07-21 DOI: 10.1002/asia.202500714

Salma Sultana, Debdyuti Chakraborty, Mohammad Anwar Parvez, Mohammed Rehaan Chandan, Mostafizur Rahaman

{"title":"Polymeric Membranes for Advanced Separation and Sensing: Materials and Mechanisms for Emerging Applications-A Review.","authors":"Salma Sultana, Debdyuti Chakraborty, Mohammad Anwar Parvez, Mohammed Rehaan Chandan, Mostafizur Rahaman","doi":"10.1002/asia.202500714","DOIUrl":"https://doi.org/10.1002/asia.202500714","url":null,"abstract":"Polymeric membranes have emerged as pivotal tools in advanced separation technologies due to their tunable properties, processability, and cost-effectiveness. This review critically evaluates recent advancements in membrane technologies, with a focus on their applications in water treatment, energy systems, and biomedical fields. Notable developments include nanocomposite membranes with enhanced performance, such as PSF/MXene membranes achieving > 95% rejection of bovine serum albumin (BSA) and water permeabilities exceeding 400 L·m⁻2·h⁻¹·bar⁻¹. Electrospun nanofibrous membranes demonstrated flux values ranging from 6898 to 18,614 L·m⁻2·h⁻¹ for oily wastewater filtration. Functionalized UF membranes incorporating TiO₂-HNTs and Ag-PDA-HNTs achieved > 98% BSA rejection and superior antifouling capabilities. Smart membranes, such as PNIPAM-modified systems, showed reversible wettability changes and temperature-responsive permeability. Additionally, 3D-printed and TIPS-fabricated membranes showcased improved selectivity and mechanical robustness. Environmentally friendly fabrication using green solvents, such as Rhodiasolv PolarClean®, enabled the production of high-performance membranes with rejection rates of over 85% for NaCl and over 93% for MgCl₂. Despite these advancements, challenges like fouling, high fabrication costs, and the permeability-selectivity trade-off persist. Strategies such as nanomaterial integration, stimuli-responsive design, and circular economy-aligned biodegradable polymers are analyzed as pathways for next-generation sustainable membranes.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e00714"},"PeriodicalIF":3.5,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0