Inorganic Chemistry Communications最新文献

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Advances in inorganic NiFe2O4/g-C3N4 composite catalysts: Synthesis, characterization, and application in peroxymonosulfate activation for antibiotic degradation 无机NiFe2O4/g-C3N4复合催化剂的合成、表征及其在过氧单硫酸盐活化降解抗生素中的应用
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-28 DOI: 10.1016/j.inoche.2025.115581
Adeel Ahmed , Mohamed Abdel Rafea , Shamroza Mubarik , Magdi E.A. Zaki , Sami A. Al-Hussain , Abdullah K. Alanazi , Mohamed R. El-Aassar , Muhammad Aadil , Salma Saddeek
{"title":"Advances in inorganic NiFe2O4/g-C3N4 composite catalysts: Synthesis, characterization, and application in peroxymonosulfate activation for antibiotic degradation","authors":"Adeel Ahmed ,&nbsp;Mohamed Abdel Rafea ,&nbsp;Shamroza Mubarik ,&nbsp;Magdi E.A. Zaki ,&nbsp;Sami A. Al-Hussain ,&nbsp;Abdullah K. Alanazi ,&nbsp;Mohamed R. El-Aassar ,&nbsp;Muhammad Aadil ,&nbsp;Salma Saddeek","doi":"10.1016/j.inoche.2025.115581","DOIUrl":"10.1016/j.inoche.2025.115581","url":null,"abstract":"<div><div>The fabrication of exceptionally effective and reusable heterogeneous catalysts for the activation of peroxymonosulfate (PMS) to eliminate the enduring contamination by antibiotic drugs, particularly Tetracycline (TC), in aquatic systems continues to pose a considerable challenge. Herein, we present a unique and efficient magnetic composite catalyst developed by anchoring nickel ferrite over graphitic carbon nitride (NiFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>) through a sol-gel method that can easily activate PMS to effectively degrade TC. Evidently, the NiFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/PMS achieved a maximum TC removal effectiveness of 97.54 % in 42 min, surpassing NiFe<sub>2</sub>O<sub>4</sub>/PMS (72.65 %), respectively, under optimized parameters ([catalyst] = 0.4 g/L, [PMS] = 24 mM, [TC] = 18 mg/L, [pH] = 3.0). The catalytic efficacy of NiFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> composites surpassed that of the alone NiFe<sub>2</sub>O<sub>4</sub> or g-C<sub>3</sub>N<sub>4</sub>, attributable to the cyclic interactions of Ni<sup>2+</sup>/Ni<sup>3+</sup> and Fe<sup>3+</sup>/Fe<sup>2+</sup> at the interfaces of NiFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>. The radical trapping experiments and EPR analyses revealed that SO<sub>4</sub><sup>•−</sup>, <sup>•</sup>OH, and <sup>1</sup>O<sub>2</sub> were the principal reactive species accountable for the mineralization of TC. Additionally, a potential mechanism for the TC degradation process was put forward. The magnetic NiFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> composites have shown remarkable recycling ability and versatility. Ultimately, this work presents an effective, rapid, and eco-friendly PMS activation approach that offers sustainable technological support for the remediation of antibiotic drug contaminants in water.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115581"},"PeriodicalIF":5.4,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on WO3-based photocatalysts: Functionalization, properties and applications for the removal of organic pollutants from wastewater wo3基光催化剂的功能化、性能及其在废水中有机污染物去除中的应用
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-27 DOI: 10.1016/j.inoche.2025.115577
Snahasish Bhowmik , Md. Sahab Uddin , Tirtha Sarker , Purnojyoti Paul , Shaikat Chandra Dey , Argho Sarkar , Farzana Khalil , Mohammad Tariqul Islam , Md. Ashraful Islam Molla , Mithun Sarker
{"title":"A review on WO3-based photocatalysts: Functionalization, properties and applications for the removal of organic pollutants from wastewater","authors":"Snahasish Bhowmik ,&nbsp;Md. Sahab Uddin ,&nbsp;Tirtha Sarker ,&nbsp;Purnojyoti Paul ,&nbsp;Shaikat Chandra Dey ,&nbsp;Argho Sarkar ,&nbsp;Farzana Khalil ,&nbsp;Mohammad Tariqul Islam ,&nbsp;Md. Ashraful Islam Molla ,&nbsp;Mithun Sarker","doi":"10.1016/j.inoche.2025.115577","DOIUrl":"10.1016/j.inoche.2025.115577","url":null,"abstract":"<div><div>Semiconductor metal oxides are promising photocatalysts for the degradation of organic pollutants from wastewater. Among them, tungsten oxide (WO<sub>3</sub>) photocatalyst has garnered significant attention due to its narrow bandgap, stability in acidic and oxidative environments, and low toxicity. In this review, WO<sub>3</sub>-based photocatalysts are thoroughly discussed in terms of their various properties for removing different organic pollutants, including dyes, pesticides, and pharmaceutical compounds from water. Moreover, several strategies, such as doping with metal and non-metal, and coupling graphene and other semiconductor metal oxides with pristine WO<sub>3</sub>, are outlined to improve the photocatalytic performance of WO<sub>3</sub>. Furthermore, the photocatalytic degradation mechanism of dyes, pesticides, and pharmaceutical compounds by WO<sub>3</sub>-based photocatalysts is explored in detail. Finally, some problems associated with WO<sub>3</sub> photocatalysts are summarized and some suggestions are given to overcome the challenges to enhance the photocatalytic degradation capacities. This comprehensive review aims to support the design of scalable pathways for treating organic pollutants in wastewater via visible light-driven photocatalysis using WO<sub>3</sub>.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115577"},"PeriodicalIF":5.4,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145265635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Theoretical study of structure and electronic properties of 2D layered hybrid perovskite (HO(CH2)2NH3)2PbI4 under pressure 压力下二维层状杂化钙钛矿(HO(CH2)2NH3)2PbI4的结构和电子性质的理论研究
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-27 DOI: 10.1016/j.inoche.2025.115575
Dmitry V. Korabel’nikov, Savely V. Polyakov
{"title":"Theoretical study of structure and electronic properties of 2D layered hybrid perovskite (HO(CH2)2NH3)2PbI4 under pressure","authors":"Dmitry V. Korabel’nikov,&nbsp;Savely V. Polyakov","doi":"10.1016/j.inoche.2025.115575","DOIUrl":"10.1016/j.inoche.2025.115575","url":null,"abstract":"<div><div>The structure and electronic properties of two-dimensional hybrid perovskite (EA)<sub>2</sub>PbI<sub>4</sub> (EA, HO(CH<sub>2</sub>)<sub>2</sub>NH<sub>3</sub>) were investigated based on density functional method taking into account dispersion interactions. There are partially covalent Pb<img>I bonds in PbI<sub>6</sub> octahedra and partially covalent relatively strong N-H<sup>…</sup>O hydrogen bonds between ethanolamine organic layers. High-pressure technique was used to understand the structure-property relationships of (EA)<sub>2</sub>PbI<sub>4</sub>. Microscopic mechanisms of compressibility and band gap pressure behavior were established. We revealed quantitative correlations between the band gap and microscopic parameters of the crystal and electronic structure for (EA)<sub>2</sub>PbI<sub>4</sub> under pressure. The pressures corresponding to the optimal band gaps for the power conversion efficiency of (EA)<sub>2</sub>PbI<sub>4</sub> based cells were predicted.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115575"},"PeriodicalIF":5.4,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Developments of ceramic Er2O3/ZrO2 nanoparticles boosted TPU/GO composite for flexible optoelectronic and capacitor applications 陶瓷Er2O3/ZrO2纳米颗粒的发展促进了TPU/GO复合材料在柔性光电和电容器领域的应用
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-26 DOI: 10.1016/j.inoche.2025.115570
Fwzah H. Alshammari
{"title":"Developments of ceramic Er2O3/ZrO2 nanoparticles boosted TPU/GO composite for flexible optoelectronic and capacitor applications","authors":"Fwzah H. Alshammari","doi":"10.1016/j.inoche.2025.115570","DOIUrl":"10.1016/j.inoche.2025.115570","url":null,"abstract":"<div><div>Polymer dielectric materials are attractive for high-power applications but suffer from low energy density and a trade-off between permittivity, breakdown strength, and mechanical integrity, which is exacerbated by poor filler–matrix compatibility and agglomeration. In the present study, thermoplastic polyurethane (TPU) is incorporated through the incorporation of various nanocomposites, including Er<sub>2</sub>O<sub>3</sub>/TPU, ZrO<sub>2</sub>/TPU, Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/TPU, and Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/GO/TPU. The objective is to analyze the impact of each composite on TPU films, aiming to achieve superior performance in dielectric characterization. TPU dielectric composites were prepared using solution-casting technique. XRD is used to investigate the crystal structure of different phases that exist in the film. Er<sub>2</sub>O<sub>3</sub>/TPU, ZrO<sub>2</sub>/TPU, Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/TPU, and Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/GO/TPU showed crystallite sizes of 33, 31.9, 32.8, and 32.9 nm, respectively. However, by using SEM, the average sizes of agglomeration of Er<sub>2</sub>O<sub>3</sub> and ZrO<sub>2</sub> were measured at around 8.08 μm and 5.3 μm, respectively. FTIR and Raman spectroscopy were utilized to investigate the structural and elemental characteristics of nano-fillers. Additionally, the thermal properties of the Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/TPU and Er<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/GO/TPU nanocomposites have been studied using thermogravimetry (TGA) at temperatures from 20 to 600 °C. The mechanical properties of all samples are measured. For specimen loading, GO-filled nanocomposite demonstrates the highest value of tensile strength across 51.86 ± 0.65 MPa, and the elongation at break demonstrated an improvement, rising to 636 % ± 25 with Young's modulus at 3.75 ± 0.53 MPa and hardness value at 84 ± 0.31. Hence, the sample containing TPU/Er<sub>2</sub>O<sub>3</sub>/Zr<sub>2</sub>O and GO exhibited higher ε' when contrasted with other samples at room temperature. However, the pure TPU exhibited the lowest ε', which means the dipole concentration was minimal, and the material exhibited dielectric behavior. The conductivity of the sample, which included GO, has been noted to increase by 1.3 times compared to the other sample, indicating that GO enhances the conductivity of the films. The behavior of dielectric permittivity (ε') of a sample that includes TPU/Er<sub>2</sub>O<sub>3</sub> increased 1.15 times compared to the neat TPU.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115570"},"PeriodicalIF":5.4,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An efficient amorphous ternary Ni-B-Ce catalyst for enhancing electrocatalytic oxidation performance of BH4− 一种提高BH4−电催化氧化性能的高效非晶态三元Ni-B-Ce催化剂
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-26 DOI: 10.1016/j.inoche.2025.115578
Ying Zhang , Xiao Tian , Yanling Li , Jiale Han , Zhihai Wen , Yuxin Li , Fenglong Wu , Wei Li
{"title":"An efficient amorphous ternary Ni-B-Ce catalyst for enhancing electrocatalytic oxidation performance of BH4−","authors":"Ying Zhang ,&nbsp;Xiao Tian ,&nbsp;Yanling Li ,&nbsp;Jiale Han ,&nbsp;Zhihai Wen ,&nbsp;Yuxin Li ,&nbsp;Fenglong Wu ,&nbsp;Wei Li","doi":"10.1016/j.inoche.2025.115578","DOIUrl":"10.1016/j.inoche.2025.115578","url":null,"abstract":"<div><div>The development and utilization of anode catalysts are key to the advancement of direct borohydride fuel cells (DBFC). In this paper, Ni<img>B and Ni-B-Ce compounds were synthesized by the chemical reduction method. The electrocatalytic oxidation properties of Ni-B-Ce compound toward BH<sub>4</sub><sup>−</sup> were systematically investigated. The microstructures of Ni<img>B and Ni-B-Ce were characterized by inductively coupled plasma-optical emission spectrometer (ICP-OES), X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The electrochemical oxidation of BH<sub>4</sub><sup>−</sup> was evaluated on Ni-B/NF and Ni-B-Ce/NF electrodes <em>via</em> cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), chronoamperometry (CA), chronopotentiometry (CP), and electrochemical active surface area (ECSA) measurements. The results showed that the catalytic activity and stability of Ni-B-Ce were better than those of Ni<img>B compound, and the Ce content affected the catalytic performance of Ni-B-Ce compound. The Ce<sub>0.25</sub> catalyst was more conducive to the BOR reaction. To conclude, Ni<img>B and Ni-B-Ce can be used as potential DBFC anode catalyst materials, and introducing rare earth element Ce improves the catalytic performance of Ni<img>B alloy.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115578"},"PeriodicalIF":5.4,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A lysosome-target fluorescence turn-on probe for exogenous and endogenous HClO detection and its biological applications 用于外源性和内源性HClO检测的溶酶体靶荧光开启探针及其生物学应用
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-25 DOI: 10.1016/j.inoche.2025.115549
Wen Qin , Ya-Tong Liu , Guiying Hu , Yan Zhao , Chuanbin Fan , Yue-Li Zou , Zhiyong Xing
{"title":"A lysosome-target fluorescence turn-on probe for exogenous and endogenous HClO detection and its biological applications","authors":"Wen Qin ,&nbsp;Ya-Tong Liu ,&nbsp;Guiying Hu ,&nbsp;Yan Zhao ,&nbsp;Chuanbin Fan ,&nbsp;Yue-Li Zou ,&nbsp;Zhiyong Xing","doi":"10.1016/j.inoche.2025.115549","DOIUrl":"10.1016/j.inoche.2025.115549","url":null,"abstract":"<div><div>A new fluorescence probe <strong>QW-Lyso</strong> conjugated by isophorone and 2-hydroxy-1-naphthaldehyde was synthesized and characterized by <sup>1</sup>H NMR, <sup>13</sup>C NMR, HRMS and X-ray Crystallography. The probe demonstrated outstanding selectivity and high sensitivity to HClO with an obvious color change and fluorescence turn on response, and the limit of detection was calculated as 85 nM. Furthermore, the possibility mechanism was verified by <sup>1</sup>H NMR titration, HRMS, and DFT calcualtion. Moreover, <strong>QW-Lyso</strong> was successfully used to image both endogenous and exogenous HClO in living cells, zebrafish, and mice. Colocalization investigation demonstrated that probe <strong>QW-Lyso</strong> had good lysosomal-targeting and high-contrast imaging abilities, which provided a beneficial tool for the development of HClO fluorescent probe with more efficient application in biological imaging.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115549"},"PeriodicalIF":5.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ growth of hollow Cu2O nanosoheres on BiOBr nanosheets and its synergistic photocatalysis-persulfate activation activity 空心Cu2O纳米微球在BiOBr纳米片上的原位生长及其协同光催化-过硫酸盐活化活性
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-25 DOI: 10.1016/j.inoche.2025.115567
Zhenqi Liu , Gangya Cheng , Chengyue Han , Yiran Teng , Yanbo Chen , Juan Xu , Tongguang Xu , Fei Teng
{"title":"In situ growth of hollow Cu2O nanosoheres on BiOBr nanosheets and its synergistic photocatalysis-persulfate activation activity","authors":"Zhenqi Liu ,&nbsp;Gangya Cheng ,&nbsp;Chengyue Han ,&nbsp;Yiran Teng ,&nbsp;Yanbo Chen ,&nbsp;Juan Xu ,&nbsp;Tongguang Xu ,&nbsp;Fei Teng","doi":"10.1016/j.inoche.2025.115567","DOIUrl":"10.1016/j.inoche.2025.115567","url":null,"abstract":"<div><div>In this work, uniform hollow Cu₂O nanospheres are <em>in situ</em> grown on BiOBr nanosheets (Cu<sub>2</sub>O@BiOBr, C<img>B). The synergistic photocatalysis‑sodium persulfate (PS) activation was utilized to degrade tetracycline (TC) and rhodamine B (RhB). The RhB degradation efficiency of Vis/Cu<sub>2</sub>O@BiOBr/PS system was 3.16 and 7.97 times higher than that of Vis/BiOBr/PS system and Vis/BiOBr system, respectively. Theoretical calculations showed that the Cu<sub>2</sub>O@BiOBr heterojunction could effectively promote the charge separation of photogenerated electron-hole pairs. For TC, the degradation efficiency reached 90 % at 180 min by Vis/Cu<sub>2</sub>O@BiOBr/PS. Furthermore, the toxicity of the degradation products for TC were evaluated by quantitative structure-effect relationship (QSAR), showing that compared to TC, some products have a higher acute toxicity and a higher bioaccumulation factor. As a result, the degraded solution had a higher toxicity to bacteria. This work warns us that the analysis of degradation products is crucial, otherwise, secondary pollution will pose a greater danger to the ecosystem. It is an urgent and crucial need to develop truly safe technology and it is highly desirable to get a complete mineralization technology for environmental sustainability.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115567"},"PeriodicalIF":5.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring structure and bioactivity of sol-gel derived borate glasses and glass-ceramics through calcination for tissue engineering 组织工程用溶胶-凝胶衍生硼酸盐玻璃和玻璃陶瓷的煅烧裁剪结构和生物活性
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-25 DOI: 10.1016/j.inoche.2025.115554
D. Rajeshwari , D. Swathi Rohitha , A. Prasad , Raghavendra Gujjala , P. Venkateswara Rao , Narayanan Madaboosi , Mutlu Özcan , P. Syam Prasad
{"title":"Tailoring structure and bioactivity of sol-gel derived borate glasses and glass-ceramics through calcination for tissue engineering","authors":"D. Rajeshwari ,&nbsp;D. Swathi Rohitha ,&nbsp;A. Prasad ,&nbsp;Raghavendra Gujjala ,&nbsp;P. Venkateswara Rao ,&nbsp;Narayanan Madaboosi ,&nbsp;Mutlu Özcan ,&nbsp;P. Syam Prasad","doi":"10.1016/j.inoche.2025.115554","DOIUrl":"10.1016/j.inoche.2025.115554","url":null,"abstract":"<div><div>Borate bioactive glasses (BBGs) and glass ceramics are emerging biomaterials with enormous applications in repairing damaged tissues, owing to their controlled degradation, antimicrobial properties, and ability to promote tissue regeneration. In this work, BBG with composition B<sub>2</sub>O<sub>3</sub>-CaO-Li<sub>2</sub>O-P<sub>2</sub>O<sub>5</sub> was produced using the sol-gel technique and subsequently calcinated at temperatures of 600, 650, 700, 750, and 800 °C. A range of characterization techniques was employed to assess the impact of calcination temperature on the structural and biological responses of the glasses. BET analysis confirmed their mesoporous texture and observed the change in pore diameter with calcination temperatures, which is perfect for prolonged ion release and cell contact. Further, the structural modification with temperature and in vitro bioactivity, evidenced by hydroxyapatite (HAp) deposition on the material's surface, was verified by XRD, FTIR, and FESEM analysis. A dense and enhanced HAp layer was deposited with an immersion period in SBF, and it predominantly covers the crystalline phases CaB<sub>2</sub>O<sub>4,</sub> Li₂B₄O₇, and Ca₃(PO₄)₂ at 750 and 800 °C. This ability validated the glasses bioactivity and demonstrated their capacity to promote tissue regeneration. Moreover, the hemocompatibility experiments revealed that all BBGs were biocompatible, with no hemolytic effects and a lysis rate of below 5 %. The cell viability assays by culturing the cells with MG-63 osteoblast cells demonstrated superior cytocompatibility, non-toxic behavior, and increased cell proliferation. Over all these results demonstrate the promise of BBGs as useful materials for applications involving soft and hard tissue engineering.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115554"},"PeriodicalIF":5.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of novel silver vanadate nanofibers and consideration of the effects on MCF-7 and HDF cell line 新型钒酸银纳米纤维的合成、表征及对MCF-7和HDF细胞系的影响
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-25 DOI: 10.1016/j.inoche.2025.115576
Sareh Sarhangi , Mehrdad Hashemi , Hakimeh Ziyadi
{"title":"Synthesis and characterization of novel silver vanadate nanofibers and consideration of the effects on MCF-7 and HDF cell line","authors":"Sareh Sarhangi ,&nbsp;Mehrdad Hashemi ,&nbsp;Hakimeh Ziyadi","doi":"10.1016/j.inoche.2025.115576","DOIUrl":"10.1016/j.inoche.2025.115576","url":null,"abstract":"<div><div>With the aim of introducing novel anticancer ceramic nanofibers, silver vanadate (AgVO<sub>3</sub>) nanofibers were successfully created by electrospinning and calcination in the search for novel anticancer ceramic nanofibers. Originally, a homogenous solution including silver nitrate, ammonium metavanadate, and poly vinyl alcohol was electrosppined to create composite polymer nanofibers. Silver vanadate ceramic nanofibers were created by calcining these composite nanofibers thereafter. Field emission-scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDAX), elemental mapping analysis (EMPA), Fourier transform infrared spectroscopy (FT-IR), and X-ray powder diffraction (XRD) were used to characterize the produced nanofibers.</div><div>The analysis verified that composite nanofibers with a smooth surface and homogeneous shape had been successfully electrosppined. The precursor was annealed at 300 °C for three hours, resulting in well-crystallized fiber-like morphology in the ceramic nanostructures, which had diameters ranging from 40 to 120 nm. By using elemental mapping analysis and EDAX, the presence of <em>V</em>, O, and Ag elements was confirmed. Diffraction peaks consistent with silver vanadate's monoclinic crystal structure were found by XRD investigation.</div><div>The MTT assay results showed that silver vanadate nanofibers exhibited a time-dependent cytotoxic effect on MCF-7 cells with IC50 values of 28.2 μM (24 h), 10.82 μM (48 h), and 4.906 μM (72 h). In contrast, higher IC50 values were observed in HDF cells, including 569.5 μM (24 h), 181.5 μM (48 h), and 153.2 μM (72 h), indicating a favorable selectivity toward cancer cells. These findings offer new insights into the potential application of ceramic nanofibers for targeted cancer therapy.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115576"},"PeriodicalIF":5.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Progress and challenges on reduced graphene (rGO)-based Co-catalysts for efficient photocatalytic hydrogen production via water splitting 基于还原石墨烯(rGO)的高效光催化水裂解制氢共催化剂的研究进展与挑战
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2025-09-25 DOI: 10.1016/j.inoche.2025.115557
A.A. Musa , Hafeez Yusuf Hafeez , J. Mohammed , Chifu Ebenezer Ndikilar , Abdussalam Balarabe Suleiman
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