Inorganic Chemistry Communications最新文献

{"title":"Advanced synthesis and biomedical applications of colloidal quantum dots: Innovations in Imaging, drug delivery, and theranostics","authors":"Fateme Sadat Razavi ,&nbsp;Zahra Sadat Razavi ,&nbsp;Haniyeh Shahsavari","doi":"10.1016/j.inoche.2025.114533","DOIUrl":"10.1016/j.inoche.2025.114533","url":null,"abstract":"<div><div>Colloidal quantum dots (CQDs) are semiconductor nanoparticles with unusual optical and electrical characteristics due to quantum confinement effects, and hence are versatile in a number of applications. One characteristic that has been of utmost interest is their great tunability in light emission by size and composition, especially in applications for cancer therapy and biomedicine. The recent success of hot-injection, heat-up, and microwave-assisted syntheses of QDs has enabled better control in the size, shape, and surface chemistry of QDs, leading to their performance improvement in bioimaging, drug delivery, and photodynamic therapy. In cancer therapy, QDs are applied to targeted drug delivery and imaging enhancement because of their superior brightness and resistance to photodegradation. However, there are some other significant challenges, such as biocompatibility and toxicity issues linked to heavy metals in some QDs. Research is now evolving both safer, more biocompatible QDs and ways to target them for precision in treatment. The development of synthesis methods will continue with regard to quantum dots and will play an important role in the combination of diagnostic and therapeutic functions on one platform—advancing theranostics within integrated cancer therapy.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114533"},"PeriodicalIF":4.4,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143834182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable Sb-Doped SrSnO3 transparent conductive oxide via sol-gel method","authors":"Ilhem Elgargouri ,&nbsp;Hind Kadiri ,&nbsp;Komla Nomenyo ,&nbsp;Akram Alhussein ,&nbsp;Rached Ben Hassen ,&nbsp;Gilles Lerondel","doi":"10.1016/j.inoche.2025.114487","DOIUrl":"10.1016/j.inoche.2025.114487","url":null,"abstract":"<div><div>Sustainable Perovskite oxide − type transparent and conductive <em>Sb–SrSnO</em><strong>₃</strong> (SSSO) thin films were grown on silicon and quartz using the modified sol–gel method. The efficiency of this method in finding homogeneous, stable and efficient thin films using a simple low-cost method is revealed. The films show high single crystallinity with a cubic perovskite structure with lattice constant of 4.187 Å. These films show good optical transmittance in the visible range, with an indirect bandgap of 4.04 V. The structural, electrical, and optical properties of the SSSO films were probed and a diode based on n-SSSO/ p-Si structure was also demonstrated with a performance higher than previously reported works.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114487"},"PeriodicalIF":4.4,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Substituent position effects on blue light emission of organophosphonium organic compounds for potential OLED applications","authors":"Rui-Xuan Qian ,&nbsp;Meng Cui ,&nbsp;Jian Lu ,&nbsp;Cheng-Rui Liu ,&nbsp;Bo-Wen Fan ,&nbsp;Xiao-Long Wang ,&nbsp;Fa-Kun Zheng ,&nbsp;Guo-Cong Guo","doi":"10.1016/j.inoche.2025.114526","DOIUrl":"10.1016/j.inoche.2025.114526","url":null,"abstract":"<div><div>Blue light-emitting materials are crucial for the commercialization of OLEDs, especially in dark display applications. However, a comprehensive understanding of the relationship between blue light emission and material structure remains lacking. In this study, we synthesized three organic phosphonium salts with blue light emissions using a one-step methylation method. The correlation between molecular structure and light emission was investigated, revealing that the position of the methyl group on the benzene ring introduces varying degrees of steric hindrance, which in turn affects the spatial arrangement and energy level distribution of the compounds. This research paves a significant development in blue light-emitting materials for future OLEDs and facilitates the commercialization of organic phosphonium cationic salts. Moreover, the usage of the position isomerization of methylated organophosphorus salts can achieve stereoscopic controlled blue emissions, providing a low-cost alternative to precious metal-based systems.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114526"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143843591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced antibacterial potential of silver-doped zinc oxide/silver heterostructures","authors":"Fekadu Oli ,&nbsp;Sirnesa Feyen ,&nbsp;Zahrah Alqahtani ,&nbsp;Khairia Mohammed Al-Ahmary ,&nbsp;Saedah R. Al-Mhyawi ,&nbsp;Jamelah S. Al-Otaibi ,&nbsp;Dereje Tsegaye ,&nbsp;Buzuayehu Abebe","doi":"10.1016/j.inoche.2025.114486","DOIUrl":"10.1016/j.inoche.2025.114486","url":null,"abstract":"<div><div>Doping and heterojunction are crucial techniques used to improve the ZnO antimicrobial activity. In this study, silver was incorporated into the ZnO lattice as a dopant using a simple sol–gel followed by a combustion approach. Besides, an intent contact was also formed between silver and ZnO crystals above the solubility level of silver. The doping and heterojunction have been successfully confirmed from the low-angle XRD pattern peak shift and occurrence of independent additional silver peaks, respectively. The HRTEM image d-spacing analysis results of 0.26 and 0.23 nm were also approved for the formation of independent ZnO and Ag crystals, respectively. Thus, Ag-doped ZnO/Ag heterostructure (SDSH) was successfully synthesized. The average crystallite size (XRD) of the SDSH is about 18 nm, and the particle size (TEM) ranges from 20 to 50 nm. Besides, the pure composition and good silver dopant distribution on the surface of ZnO were confirmed from the EDS elemental mapping analysis. The optical property improvement and presence of charge transfer were confirmed from the UV–vis DRS and PL spectrophotometer analysis results. The indirect bandgap values were found to be 3.09 and 2.82 eV for ZnO NPs and SDSH, respectively. The PL spectrum intensity of SDSH is much lower compared to the ZnO NPs, confirming the presence of electron-hole recombination hindrance. The SDSH also showed much better antibacterial potential compared to single ZnO NPs. The major antibacterial deactivation mechanism of SDSH is proposed to be due to the release of silver and zinc ions during NPs and bacterial cell interaction.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114486"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143829458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, characterization of novel CuO doped-TiO2 nanomaterials and their applications in photocatalytic degradation of herbicide 2,4,5-trichlorophenoxyacetic acid in water","authors":"Thi Dung Le ,&nbsp;Thi Hue Nguyen ,&nbsp;Van Long Dang ,&nbsp;Minh Ngoc Nguyen ,&nbsp;Thanh Son Le ,&nbsp;Tien Duc Pham","doi":"10.1016/j.inoche.2025.114531","DOIUrl":"10.1016/j.inoche.2025.114531","url":null,"abstract":"<div><div>The herbicide 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) is a component of Agent Orange that is a serious emerging organic pollutant in the environment. In the present study, the extensive treatment of 2,4,5-T using titania nanoparticles (TiO₂-NPs) doping with copper oxide (CuO) for photocatalytic degradation was studied. The CuO-doped TiO₂ nanoparticles (CDTN) were thoroughly examined by TEM, FT-IR, BET, Raman, UV–Vis-DRS spectroscopic methods, BET and ζ potential measurements. The photocatalytic degradation efficiency of 2,4,5-T enhanced significantly after adding CuO compared to bare TiO₂-NPs. Effective parameters for 2,4,5-T degradation were optimized and found as pH 4, CDTN dosage 33.3 mg/10 mL, and 120 min of photocatalysis duration. The CDTN material indicated as a novel photocatalyst with the degradation performance of 95.32 % under visible light. The degradation of 2,4,5-T using CDTN followed the Langmuir-Hinshelwood model. Our study demonstrates that the CDTN is an excellent material for 2,4,5-T photo-degradation in water environment.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114531"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143829550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unraveling the Synergistic effects of ZnO and Ag@ZnO Nanoparticles: An in Vitro investigation of Anti-Cancer, Anti-Inflammatory, Antioxidant, and Antibacterial Properties","authors":"Sangeetha Alaguvel,&nbsp;Samira Khathoon Kalifathullah,&nbsp;S. Devikala","doi":"10.1016/j.inoche.2025.114522","DOIUrl":"10.1016/j.inoche.2025.114522","url":null,"abstract":"<div><div>The present study utilizes an environmentally benign approach to produce ZnO and Ag@ZnO nanoparticles using <em>Xanthium strumarium</em> leaf extract. ZnO and Ag nanoparticles are recognized for their applications across numerous industries, including biological activities such as antifungal, antioxidant, antibacterial, anti-inflammatory, and anticancer properties. Consequently, in this study, we have doped silver onto zinc oxide to enhance its biological activity. Various analytical methodologies were employed to investigate the structure, morphology, and optical properties of ZnO and Ag@ZnO nanoparticles, including Ultraviolet–Visible (UV–vis) Spectroscopy, Field Emission Scanning Electron Microscopy (FESEM), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared (FT-IR) Spectroscopy. The antibacterial investigation of Ag@ZnO and ZnO nanoparticles demonstrated their exceptional efficacy against both <em>S. aureus</em> and <em>E. coli</em>. The zone of inhibition for both gram-positive (18 ± 0.18 mm) and gram-negative (23 ± 0.63 mm) bacteria was better achieved by Ag@ZnO NPs at 1000 µg/mL. The outcomes of the anti-inflammatory assay demonstrated that produced Ag@ZnO and ZnO nanoparticles had significant inhibition properties against protein denaturation. It was found at 1000 μg/mL, the percentage inhibition of the protein denaturation (BSA) assay has shown 94.34 ± 0.08 % for Ag@ZnO, 94.35 ± 0.11 % for ZnO NPs and the proteinase inhibitory activity has shown 94.34 ± 0.08 for Ag@ZnO Nps, 90.78 ± 0.07 for ZnO NPs respectively. The antioxidant properties of Ag@ZnO and ZnO nanoparticles were assessed, revealing their enhanced antioxidant effectiveness. It was found to be 82.04 ± 0.07 % for Ag@ZnO, 74.29 ± 0.04 % for ZnO NPs at 1000 µg/mL, respectively. The cytotoxic activity revealed that, at a concentration of 512 mg mL⁻¹, Ag@ZnO (20.743 ± 0.086 %) and ZnO (25.134 ± 0.065 %) nanoparticles exhibited significant cytotoxicity against the MCF7 cell line in a concentration-dependent manner, revealing their potential as therapeutic agents for breast cancer.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114522"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assembly of lanthanide-included arsenomolybdate containing a new [AsMo10O35]7− ligand and its sensitive electrochemical detection of nitrite","authors":"Qiao Gao ,&nbsp;Xue-Rui Dong ,&nbsp;Ling-Kun Meng ,&nbsp;Jing Yang ,&nbsp;Zhi-Dong Qiu ,&nbsp;Lin Xu","doi":"10.1016/j.inoche.2025.114525","DOIUrl":"10.1016/j.inoche.2025.114525","url":null,"abstract":"<div><div>The rational design of electrocatalytic materials based on polyoxometalates is a promising approach for the sensitive electrochemical determination of NO₂⁻. In this study, a novel lanthanide-included arsenomolybdate, formulated as the H₄(NH₄)₂(Him)₁₆[Na(im)]₂[Pr_0.5Na_0.5(H₂O)₃]₂[AsMo₁₀O₃₅]₄·32H₂O (<strong>1</strong>) (im = imidazole), is obtained through one-pot self-assembly synthesis method. Compound <strong>1</strong> features a ring-shaped framework composed of {AsMo₁₀O₃₅} clusters connected by {Pr_0.5Na_0.5(H₂O)₃} and {Na(im)₂} units. Furthermore, compound <strong>1</strong> is combined with carboxylated multi-walled carbon nanotubes (CMCNT) to form a <strong>1</strong>@CMCNT composite, which is modified onto the glassy carbon electrode (GCE) to construct the <strong>1</strong>@CMCNT/GCE. Due to the synergistic effect between the excellent redox capacity of compound <strong>1</strong> and the rapid electron transfer rate of CMCNT, the <strong>1</strong>@CMCNT/GCE exhibits outstanding performance for NO₂⁻ detection with a sensitivity of 0.5535 μA·μM⁻¹, a detection limit of 0.54 μM (S/N = 3), as well as good selectivity and stability. Moreover, the <strong>1</strong>@CMCNT/GCE is employed to detect NO₂⁻ in tap water samples with a desired recovery of 98.30 %-100.24 %. This work provides a new method for the design of a POM-based electrochemical sensing platform for NO₂⁻ detection.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114525"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lanthanide(III)-based complexes for potential dual 1H/19F MRI contrast agents: Synthesis, structure, relaxivity and 19F NMR spectroscopy studies","authors":"Ziyi Jin ,&nbsp;Ping Yue ,&nbsp;Feng Chen ,&nbsp;Qiuyun Chen ,&nbsp;Goran Angelovski ,&nbsp;Gaoji Wang","doi":"10.1016/j.inoche.2025.114518","DOIUrl":"10.1016/j.inoche.2025.114518","url":null,"abstract":"<div><div>Magnetic resonance imaging (MRI) is an effective technique for diagnosing diseases. Its most used modality is based on the <em>T</em>₁-weighted contrast but is limited by the background signal of water in the tissue. A combination of different MR imaging modalities together can reduce this consideration and exclude background interference. Paramagnetic lanthanide cations have versatile magnetic and optical characteristics along with similar reactivities; hence, their complexes are good candidates as multimodal agents. Also, fluorinated probes are gaining increasing attention for the use due to the advantageous features of ¹⁹F MRI. Herein, the prototypes of LnDO3A-based fluorine-containing complexes were developed, providing potential detection by <em>T</em>₁-weighted (Gd³⁺ complex) and ¹⁹F-based (Y³⁺, Eu³⁺ and Yb³⁺ complexes) MRI, or by means of optical imaging using lanthanide-based luminescence in the visible range (Tb³⁺ complex). The use of different Ln³⁺ ions causes only minor changes in the structure of complexes, while these probes are predicted to possess comparable structural stability while performing experiments with different imaging modalities.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114518"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green synthesis-driven gold nanoparticles using Lilium wallichianum leaf extract for biomedical applications","authors":"Nattan Stalin ,&nbsp;Dharmaraj Ramar ,&nbsp;Masanam Esakkirajan ,&nbsp;Vimalanathan ArunPrasanna ,&nbsp;Ayyakannu Arumugam ,&nbsp;Kasi Gopinath","doi":"10.1016/j.inoche.2025.114507","DOIUrl":"10.1016/j.inoche.2025.114507","url":null,"abstract":"<div><div>Recently, chemical methods for synthesizing nanoparticles have raised concerns due to their harmful effects on human health and the environment. To overcome this hurdle, researchers are looking for alternative approaches, with eco-friendly synthesis methods gaining attention. However, their toxicity still requires further validation. This study highlights the green synthesis of gold nanoparticles (Au NPs) using <em>Lilium wallichianum</em> leaf extract through a single-step method, aiming to develop eco-friendly NPs for biomedical applications. The synthesized Au NPs were characterized by optical, functional, structural, and morphological analysis. The Au NPs showed a spherical shape with an average size of 11.98 nm. The biological effects of Au NPs were assessed using three model systems: RAW 264.7 macrophage cells, <em>Artemia salina</em> nauplii, and <em>Allium cepa</em> root tip cells. The Au NPs showed biocompatible in RAW 264.7 cells at a concentration of 50 μg/ml, with a maximum mitotic index of 73.93 % in <em>Allium cepa</em> root tip cells, suggesting enhanced cell proliferation. Furthermore, the Au NPs accumulated in the gut region of <em>Artemia salina</em> without inducing mortality. These findings indicate that green-synthesized Au NPs are biocompatible and demonstrate a potential for many biomedical applications like drug delivery, tissue and even plant regeneration.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114507"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly water soluble metallophthalocyanines and investigation of their AChE/BuChE enzyme inhibition and cytotoxic activity against human neuroblastoma (SH-SY5Y) cell","authors":"Turgut Keleş ,&nbsp;Zekeriya Biyiklioglu ,&nbsp;Gökçe Seyhan ,&nbsp;Elif Öz ,&nbsp;Rengin Reis ,&nbsp;Burak Barut","doi":"10.1016/j.inoche.2025.114508","DOIUrl":"10.1016/j.inoche.2025.114508","url":null,"abstract":"<div><div>The new morpholine substituted Mn(III), Co(II), Cu(II) and Zn(II) phthalocyanines compounds were synthesized for the first time by cyclotetramerization reaction. In addition, their water-soluble derivatives were obtained using a simple method, stirring CH₃I in chloroform at room temperature in the dark. The water-soluble compounds are highly soluble in water at room temperature. The inhibitory activities of these compounds against the cholinergic enzyme AChE/BuChE were investigated using a spectrophotometric method. When compared to the positive control galantamine, all of the water-soluble phthalocyanine compounds demonstrated strong inhibition of AChE/BuChE with values of 4.51 µM and 7.37 µM, respectively. <strong>MT-C3-ZnQ</strong> had the highest inhibition activity of the compounds tested. Kinetic studies were performed in a systematic manner to determine the type of inhibition and the inhibitor’s binding constant to the enzyme. As a result, it was discovered that compound <strong>MT-C3-ZnQ</strong> inhibited AChE/BuChEs of mixed type. Furthermore, the cell viability of the <strong>MT-C3-ZnQ</strong> compound on the human neuroblastoma (SH-SY5Y) cell line was assessed at 24 and 48 h using the MTT assay. The MTT assay revealed that SH-SY5Y cells exposed to <strong>MT-C3-ZnQ</strong> for 24 h exhibited no cytotoxicity, with no apparent dose–response relationship. Similarly, no cytotoxicity was observed after 48 h of exposure and cell viability above 70 % was observed, compared to the control group. All of these findings suggest that the <strong>MT-C3-ZnQ</strong> compound, with its low cytotoxicity and high enzyme inhibition activity against AChE/BuChE enzymes, could be a viable alternative to drugs used in the treatment of Alzheimer’s. Furthermore, this study is expected to serve as a model for future research in this area.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"178 ","pages":"Article 114508"},"PeriodicalIF":4.4,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143855126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}