Inorganic Chemistry Communications最新文献

{"title":"Emerging trends in aptasensor technology for pesticide residue analysis","authors":"Zhouxiang Zhang ,&nbsp;Najmeh Zare ,&nbsp;Tao Wu ,&nbsp;Hassan Karimi-Maleh","doi":"10.1016/j.inoche.2025.115193","DOIUrl":"10.1016/j.inoche.2025.115193","url":null,"abstract":"<div><div>Environmental contamination and food safety risks arising from pesticide overuse constitute significant global challenges. Rapid, sensitive pesticide detection is critical for preserving ecosystem integrity and human health. Conventional analytical methods, however, face limitations in meeting these requirements due to labor-intensive procedures, prolonged analysis times, and dependence on specialized instrumentation. Biosensors utilizing aptamer as molecular recognition elements have emerged as a prominent research focus in pesticide detection. Their advantages including facile chemical modification, cost-effective synthesis, structural stability, high specificity, and strong target affinity, positioning them as transformative analytical platforms. The briefly review examines recent advancements in aptasensors for pesticide monitoring. Firstly, we summarize progress in developing high-specificity aptamers for diverse pesticide classes. Secondly, various kinds of aptasensors including fluorescent aptasensor, colorimetric aptasensor, electrochemical aptasensor, chemiluminescent aptasensor and other kinds of aptasensors. Are highlighted. Finally, the present obstacles and prospects associated with pesticide aptasensors are reviewed.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115193"},"PeriodicalIF":5.4,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simple synthesis of fluorine-doped carbon quantum dots for fluorescence-based Amaranth quantification in food matrices","authors":"Xiaofang Tian ,&nbsp;Meijie Xie ,&nbsp;Xinyu Luo,&nbsp;Boyan Zheng,&nbsp;Yongxia Ao,&nbsp;Jiaxin Liu,&nbsp;Mei Wang,&nbsp;Qianchun Zhang,&nbsp;Yun Wu","doi":"10.1016/j.inoche.2025.115195","DOIUrl":"10.1016/j.inoche.2025.115195","url":null,"abstract":"<div><div>The detection of food pigments is essential for ensuring food quality and safety. This study presents the efficient preparation of fluorine-doped carbon quantum dots (F-CQDs) through a simple solvothermal reaction using <em>Zanthoxylum</em> and NH₄F as precursors. The resulting F-CQDs displayed optimal fluorescence characteristics, along with a quantum yield of 4.81 %. Notably, the as-prepared F-CQDs exhibited excellent photostability and were effectively quenched by amaranth, demonstrating their potential as reliable probes for amaranth detection. The probe showed a strong linear response (<em>R</em>² = 0.9992) to amaranth concentrations of 0.15–75 μM, yielding a limit of detection as low as 50 nM. Validation tests across various food matrices, including bayberry, a sugar-sweetened beverage, and candies, yielded good recovery rates of 89.0 %–119 % and a relative standard deviation of less than 4.9 % (<em>n</em> = 5), indicating high reliability. These findings suggest that F-CQDs are viable candidates for detecting amaranth in foods, which can help enhance food safety and quality control.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115195"},"PeriodicalIF":5.4,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomass waste-derived activated carbon for effective Cr(VI) removal from textile wastewater","authors":"Xianmiao Pan ,&nbsp;Changyu Zhou ,&nbsp;Hongjie Wang ,&nbsp;Fangtao Ruan ,&nbsp;He Wang ,&nbsp;Quan Feng","doi":"10.1016/j.inoche.2025.115196","DOIUrl":"10.1016/j.inoche.2025.115196","url":null,"abstract":"<div><div>Cr(VI) contamination in textile wastewater necessitates sustainable removal technologies due to its environmental and health risks, and biomass-derived activated carbon adsorption is a sustainable and effective technique to remove Cr(VI). However, the relatively long growth cycle of conventional biomass carbon sources and their limited specificity to single pollutants (e.g., only heavy metals or dyes) restricts the application in multi-pollutant solutions. This work developed a short-growth-cycle biomass waste (golden needle mushroom roots) to prepare an inorganic adsorbent (activated carbon) through one-step H₃PO₄-activated carbonization. The effects of GNMACs dosage, solution pH value, and carbonization temperature on the removal ability of Cr(VI) were studied. The GNMACs possessed a hierarchical pore structure including micropores, mesopores, and macropores with a specific surface area of 782.641 m²/g and an average pore diameter of 5.620 nm. The GNMACs exhibited a Cr(VI) adsorption capacity of 100.95 mg/g. Additionally, the isotherm model and kinetic model results indicated the adsorption of Cr(VI) by GNMACs involved a combination of physical and chemical adsorption. The adsorption mechanism involved electrostatic interaction, redox reaction, and pore filling. Besides, the GNMACs exhibited excellent adsorption performance for Cr(VI) and MO in a binary pollutant solution, and both of them can be totally absorbed within 90 min, indicating the promising application potential for simultaneously removing heavy metals and dyes from textile wastewater. GNMACs maintained a removal rate of 52.60 % after five regeneration cycles. This study prepared an inorganic adsorbent to simultaneously remove heavy metals and dyes from textile wastewater by developing a new carbon source from biomass waste with a short growth cycle, offering an innovative idea for removing pollutants from wastewater treatment.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115196"},"PeriodicalIF":5.4,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Feasible approach to prepare 60 %-purity metallic phase MoS2 with high stability for superior supercapacitor performance","authors":"Liyong Zhang ,&nbsp;Taotao Xia ,&nbsp;Xulong Yuan ,&nbsp;Guanbo Wang ,&nbsp;Yang Liu ,&nbsp;Xing Yang ,&nbsp;Qian Ding ,&nbsp;Juan Tang ,&nbsp;Han Li ,&nbsp;Yongxing Zhang","doi":"10.1016/j.inoche.2025.115171","DOIUrl":"10.1016/j.inoche.2025.115171","url":null,"abstract":"<div><div>Transition metal dichalcogenides (TMDs), particularly molybdenum disulfide (MoS₂), have emerged as promising electrode materials for supercapacitors due to their unique 2D layered structures and high theoretical specific capacitance. Among various phases, metallic 1 T-MoS₂ exhibits superior electrical conductivity and electrochemical activity. However, synthesizing high-purity 1 T-MoS₂ remains challenging. Herein, a facile one-step hydrothermal method to prepare high-purity 1 T-MoS₂ by introducing ethanol is reported, which promotes the formation of hydroxyl groups (-OH) and stabilizes the 1 T phase. The optimized material (M-MoS₂) demonstrates outstanding supercapacitor performance, achieving a specific capacitance of 387 F g⁻¹ at 2 A g⁻¹ and retaining 87.9 % of its capacitance after 5000 cycles. A symmetric supercapacitor device assembled using M-MoS₂ as the negative electrode and the positive electrode delivers an excellent cycling stability. This study provides a scalable approach to synthesize high-purity 1 T-MoS₂, offering new insights into the design of advanced TMD-based energy storage materials.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115171"},"PeriodicalIF":5.4,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green synthesis of gold nanoparticles using mushrooms for medical and industrial applications","authors":"Mohana Priya Shankar ,&nbsp;R. Nisha ,&nbsp;Endla Lavanya ,&nbsp;Ramaji Spandana ,&nbsp;Suresh Kupireddy ,&nbsp;Santhosh Kumar Devarai","doi":"10.1016/j.inoche.2025.115173","DOIUrl":"10.1016/j.inoche.2025.115173","url":null,"abstract":"<div><div>Nanoparticles have attracted considerable attention in the field of nanotechnology due to their unique physicochemical and biomedical properties. However, chemically synthesised nanoparticles often raise environmental concerns due to the use of toxic and harmful chemicals. These limitations have led to the emergence of myconanotechnology, an eco-friendly approach that utilises fungi to produce nanoparticles. Gold nanoparticles are important because of their high stability, biocompatibility, and multifunctionality. These properties make them valuable for advancements in sustainable technology and biomedicine. Certain mushrooms, such as <em>Pleurotus ostreatus</em>, <em>Ganoderma lucidum</em>, and <em>Lentinula edodes</em>, are excellent biological sources for the biosynthesis of gold nanoparticles due to their extracellular enzymes and bioactive compounds. Biosynthesised gold nanoparticles exhibit antimicrobial, antioxidant, anti-cancer, and immunomodulatory properties. Their synthesis is influenced by pH, temperature, and precursor concentration, which determine nanoparticle size and stability. Mushroom-derived gold nanoparticles have applications in biosensors, conductive inks, drug delivery, photothermal cancer therapy, and catalytic pollutant degradation. Additionally, they play a vital role in mycoremediation, helping remove heavy metals and organic pollutants. This review emphasises that the biochemical diversity of mushrooms facilitates a sustainable and efficient method for gold nanoparticle synthesis, while uniquely integrating current breakthroughs that endorse their potential for scalable industrial and biological applications.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115173"},"PeriodicalIF":5.4,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144749298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Novel synthesis of 2-substituted quinoxaline motifs using copper-nikel ferrite magnetic nanoparticles (Cu0.5Ni0.5Fe2O4 MNPs) as robust heterogenous catalyst","authors":"Ashwini A. Pawar ,&nbsp;Swati B. Kale ,&nbsp;Mahesh N. Waman ,&nbsp;Satish U. Deshmukh ,&nbsp;Ravikumar M. Borade","doi":"10.1016/j.inoche.2025.115175","DOIUrl":"10.1016/j.inoche.2025.115175","url":null,"abstract":"<div><div>Copper‑nickel ferrite magnetic nanoparticles (Cu_0.5Ni_0.5Fe₂O₄ MNPs) are a robust, reusable, magnetically separable heterogenous catalyst, employed to an efficient synthesis of 2-substituted quinoxalines (<strong>3a-o</strong>) using 1,2-diaminebenzene (<strong>1</strong>) and substituted phenacyl bromides (<strong>2a-o</strong>). Heterogenous copper‑nickel ferrite magnetic nanoparticles, are synthesis via a sol-gel auto combustion protocol and subsequently studied using UV–Vis spectrophotometer for optical property, FTIR, XRD, FESEM, and HRTEM for structural and morphology analysis, XPS and Zeta Potential for surface charge, M-H hysteresis for magnetic property. The notable highlights of this strategy include green protocol, optimum reaction time, moderate to excellent yield, straightforward experimental methodology, and the use of copper‑nickel ferrite magnetic nanoparticles, potentially recovered adopting a simple magnetic separation process and reused and recycle without losing its catalytic activity. The resulting derivatives were well characterized by IR, ¹H NMR, ¹³C NMR and HRMS.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115175"},"PeriodicalIF":5.4,"publicationDate":"2025-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergy in metal oxide/metal sulfide binary composites for photocatalysis: mechanisms, applications, and emerging trends","authors":"Atiqa Aslam ,&nbsp;Nimra Nadeem ,&nbsp;Balaussa Balgabayeva ,&nbsp;Sami Ullah Khan ,&nbsp;Qamar Abbas ,&nbsp;Saima Noreen ,&nbsp;Muhammad Zahid ,&nbsp;Zhazira Supiyeva","doi":"10.1016/j.inoche.2025.115191","DOIUrl":"10.1016/j.inoche.2025.115191","url":null,"abstract":"<div><div>The uncontrolled release of synthetic toxins and micropollutants from industry and consumer sources into freshwater bodies poses a serious risk to aquatic environments and human health. Advanced oxidation processes, specifically heterogeneous photocatalysis, have drawn attention to solve these issues and a possible route to improve the quality of the aquatic environment. This has been obtained by investigating unique materials that can function synergistically with one another. The scientific society has explored different photocatalyst types. Nevertheless, heterojunction photocatalysts in general and binary heterojunction photocatalysts in particular have demonstrated remarkable qualities and unique advantages. The combined impacts of metal oxides (MOx) and metal sulfides (MS) have a dominant synergistic effect. Therefore, metal oxide/metal sulfide heterojunctions are emerging as revolutionary photocatalysts in environmental solutions. Binary composites such as ZnO/ZnS, CuO/CuS, ZnO/CuS, and many others are discussed for their synergetic photocatalytic efficiencies in the degradation of a variety of pollutants, including insecticides, dyes, pesticides, antibiotics, and heavy metals. This review explores multifaceted roles of MOx/MS highlighting the potential of these heterojunctions as a promising pathway towards a more sustainable future. Further, a detailed understanding is provided on how heterojunctions have been employed to catalyze environmental remediation by investigating their different electrical interactions and catalytic capabilities. Finally, the manuscript will recommend guidelines for further advancement in this rapidly evolving, multidisciplinary field of current interest.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115191"},"PeriodicalIF":5.4,"publicationDate":"2025-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"DFT study of hydrogen-substituted KMgF3 fluoroperovskite: Structural, electronic, and storage implications","authors":"Mubashar Ali ,&nbsp;Zunaira Bibi ,&nbsp;Abdul Farhan Khan ,&nbsp;Imran Taj ,&nbsp;Muhammad Jawad","doi":"10.1016/j.inoche.2025.115186","DOIUrl":"10.1016/j.inoche.2025.115186","url":null,"abstract":"<div><div>The commitment to an environmentally green energy system has drawn attention to hydrogen storage technologies, but efficient storage remains challenging. Fluoroperovskites have exciting potential owing to their tailored properties and structural stability. This study investigates the impact of hydrogen substitution on the physical properties of KMgF₃ fluoroperovskites at varying hydrogen concentrations. By substituting the fluorine atoms with hydrogen, we investigate the impact of these alterations on the stability of the electronic structure and the thermodynamic behavior of the material. The computation of formation enthalpies and phonon dispersion curves indicates the structural stability and potential to synthesize KMgF_3˗xH_x (x = 0, 1, 2, 3) through the modulation of hydrogen concentration. The evaluation of the mechanical properties indicates that all KMgF_3˗xH_x compounds demonstrate mechanical stability, possess intrinsic brittleness, and show a decrease in elastic moduli with increasing H concentration. The analysis concentrated on band gap renormalization and the Burstein-Moss shift to elucidate the mechanism by which the absorption edge approaches the valence band, leading to a reduction in the electronic bandgap. The optical characteristics of KMgF_3˗xH_x compounds were examined and evaluated. It is worth mentioning that the storage capabilities for hydrogen have been improved to 4.55 wt% (gravimetric) and 74.41 <span><math><mi>g</mi><msub><mi>H</mi><mn>2</mn></msub><msup><mi>l</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup></math></span>(volumetric). This enhancement results from the incorporation of hydrogen at the anion positions inside the KMgF₃ host compound. In short, this research can substantially contribute to current and future studies on the discovery of hydrogen storage materials.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115186"},"PeriodicalIF":5.4,"publicationDate":"2025-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144749303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Novel SO42‐/ Tin (IV) Phosphate Nanomaterial for Selective Pb2+ Removal and Efficient Synthesis of Dihydropyrimidinone and Xanthene Derivatives","authors":"Wafaa S. Abo El-Yazeed ,&nbsp;Omnia E. Elmenshawy ,&nbsp;Awad I. Ahmed ,&nbsp;S.A. El-Hakam","doi":"10.1016/j.inoche.2025.115176","DOIUrl":"10.1016/j.inoche.2025.115176","url":null,"abstract":"<div><div>From a sustainable chemistry perspective, the development of materials with multiple functionalities for solving both environmental and pharmaceutical challenges is critical. This study presents a series of ammonium sulfate-supported tin (IV) phosphate (AS/SnP) composites with different loadings of AS, intended for two purposes: wastewater treatment and environmentally friendly catalysis. Various techniques, TGA, FTIR, XRD, TEM, XPS, and EDX, were utilized to investigate thermal stability, structural integrity, morphology, and functional groups. TGA analysis confirmed the high thermal stability of AS/SnP, while XRD revealed that the composites retained their amorphous nature, preserving the original SnP structure. TEM images reflected the morphological changes by the incorporation of AS, leading to more spherical and smaller nanoparticles. 25AS/SnP-II composite displayed the highest acid strength as the optimal composition, enabling efficient catalytic synthesis of 3,4-dihydropyrimidinones and 14-aryl-14H-dibenzoxanthenes. Furthermore, the adsorption behavior of AS/SnP-II for Pb²⁺ removal from aqueous solutions was systematically evaluated under varying conditions, involving contact time, initial ion concentration, adsorbent amount, and pH. 10AS/SnP-II exhibited the highest Pb²⁺ removal efficiency (98.4 %) with the process following a pseudo-second-order model (R² = 0.9923). The chemical stability of SnP-II was demonstrated by its activity within five successive cycles. These results indicate the dual functionality of AS/SnP composites as effective materials for wastewater purification and catalytic applications, providing an eco-friendly solution for environmental restoration.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115176"},"PeriodicalIF":5.4,"publicationDate":"2025-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144722285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Functional activities of UO22+ ion toward 1,2,3-triaminoguanidinium based organic donors: Influential role of anions and hydration water accompanied with uranyl salts and donor bases amid complexation reaction","authors":"Preeti Mishra,&nbsp;Jai Deo Singh","doi":"10.1016/j.inoche.2025.115172","DOIUrl":"10.1016/j.inoche.2025.115172","url":null,"abstract":"<div><div>The present work aims to understand the functional activities of UO₂²⁺ ion toward biologically relevant C₃-symmetric triaminoguanidine-based donor [{C(-HN–N=CH-RC₆H₄-OH)₃}⁺Cl⁻] (R = -H, (H₄<strong>L</strong>_{<strong>1</strong>})Cl, = -OCH₃, (H₄<strong>L</strong>_{<strong>2</strong>})Cl or = -OC₂H₅, (H₄<strong>L</strong>_{<strong>3</strong>})Cl species in solution and solid states. The donor species are accomplished by three easily accessible (NNO) coordination pockets to seize one, two, or three UO₂²⁺ ions, respectively, in a tri-directional manner. The solution behavior of UO₂²⁺ ion with donor species is studied by UV–visible spectrophotometry and corroborated with their ESI-MS.</div><div>The interactive behavior of UO₂²⁺ and donors principally rely on <em>protonolysis reactivity</em> of UO₂(OCOCH₃)₂·2H₂O or UO₂(NO₃)₂·6H₂O in solution. In particular, the behavior of UO₂²⁺ with (H₄<strong>L</strong>_{<strong>1</strong>})Cl, in solution and as solid in crystalline form are incomparable and signify the circumstantial role of released hydration water, anions (acetate/nitrate) (associated with uranyl salts) and chloride (Cl⁻) ion (associated with donors) in coordination processes. In complexes, inter- or intramolecular interactions between UO₂²⁺ ion, solvent molecules, or H-bonding (donor-acceptor) fragments of donor species, are found as causative factors affecting the strength of linear U<img>O bonds. This study may be fundamental in understanding the behavior of UO₂²⁺ ions in extraction, fuel reprocessing, and geo- and biogeochemistry of their migratory routes. The results of the present findings are also practical in realizing the effect of weaker interactions between uranyl and donor species, where a minor variation in reaction conditions can alter the formation of new and different species</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"181 ","pages":"Article 115172"},"PeriodicalIF":5.4,"publicationDate":"2025-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}