Green Synthesis and Catalysis最新文献_第4页

Photoredox/Ti dual-catalyzed dehydroxylative ring-opening Giese reaction of cyclobutanone oximes 环丁酮肟的光氧/钛双催化脱羟基开环基斯反应

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.04.005

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A sustainable synthesis of 3,3-disubstituted oxindoles via CuBr-catalysed capture of carboxylic oxonium ylides with isatylidene malononitrile 通过 CuBr 催化异亚甲基丙二腈捕获羧基氧鎓酰化物可持续合成 3,3-二取代吲哚

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.04.006

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Copper-catalyzed 2,3-dihydro-1,2,4-triazoles synthesis through [3+2]-cycloaddition of nitrile ylides with azodicarboxylates 铜催化偶氮二羧酸腈酰氯与偶氮二羧酸盐的 [3+2]- 环加成反应合成 2,3- 二氢-1,2,4-三唑

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.01.007

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Synthesis of highly functional quinazolins via metal-free, visible-light-enabled radical cascade arylation/cyclization of fluorinated imidoyl isothiocyanates 通过氟化亚胺酰异硫氰酸酯的无金属可见光自由基级联芳基化/环化合成高功能喹唑啉类化合物

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.07.003

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Metal-free and water-compatible nanocatalysts for green photocatalytic dehydrogenation in aqueous medium 用于水介质中绿色光催化脱氢的无金属和水兼容纳米催化剂

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.03.001

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Pd(II)/N,N′-Disulfonyl bisimidazoline-catalyzed asymmetric arylation of isoquinoline-1,3,4-trione-derived ketimines Pd(II)/N,N′-二磺酰基双咪唑啉催化的异喹啉-1,3,4-三酮衍生酮亚胺的不对称芳基化反应

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.07.001

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A H2O2 generation-detection-regulation integrated platform for boosting the efficiency of peroxygenase-catalysed C–H oxidative hydroxylation 提高过氧酶催化C-H氧化羟基化效率的H2O2生成-检测-调控一体化平台

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.11.006

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引用次数: 0

Ate complexes in organic synthesis: From ate reagents to ate catalysts 有机合成中的金属络合物：从金属试剂到金属催化剂

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2024.04.010

{"title":"Ate complexes in organic synthesis: From ate reagents to ate catalysts","authors":"","doi":"10.1016/j.gresc.2024.04.010","DOIUrl":"10.1016/j.gresc.2024.04.010","url":null,"abstract":"<div>The realm of application of organometallic catalysis to organic synthesis has witnessed a transformative shift in recent years, owing much to the evolution of ate complexes from mere reagents to versatile catalysts. Ate complexes, formed through the coordination of a neutral Lewis acid with an organic anionic base, have emerged as pivotal intermediates that not only facilitate organic transformations but also serve as efficient catalysts in a wide range of chemical reactions. This review presents the fascinating journey of ate complexes, highlighting their development from stoichiometric reagents to active catalysts. Historically, ate complexes were primarily regarded as stoichiometric species essential for various metal-catalyzed transformations. However, constant research has unveiled their potential as catalysts in their own right, reshaping the landscape of modern organic synthesis. In this minireview, we discuss the pivotal role of ate complexes in the evolution of organic synthesis, from their early days as reactive intermediates to their current stature as catalytic pioneers offering a glimpse into the exciting future of this dynamic field.</div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 3","pages":"Pages 141-152"},"PeriodicalIF":0.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266655492400053X/pdfft?md5=7a4de4c94a8dbec8c809e1e05e1cb03f&pid=1-s2.0-S266655492400053X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141037151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Light-driven enzymatic conversion of mevastatin into pravastatin by coupling P450sca-2 with cyanobacterial photosynthetic system 通过将 P450sca-2 与蓝藻光合系统耦合，光驱动酶法将美伐他汀转化为普伐他汀

Green Synthesis and Catalysis Pub Date : 2024-07-01 DOI: 10.1016/j.gresc.2024.07.001

Shanmin Zheng, Zhengquan Gao, Yuanyuan Jiang, Jiawei Guo, Fangyuan Cheng, Xuan Wang, Hao-Bing Yu, Bo Hu, Chunxiao Meng, Shengying Li, Xingwang Zhang

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Synthesis of 1,4-oxathiins via [3+3] annulation of pyridinium 1,4‐zwitterionic thiolates with iodonium ylides 通过吡啶鎓-1,4-齐聚物硫醇盐与碘鎓酰化物的[3+3]环化反应合成 1,4-氧硫杂质

Green Synthesis and Catalysis Pub Date : 2024-07-01 DOI: 10.1016/j.gresc.2024.07.002

Zhibin Niu, C. Pi, Yangjie Wu, Xiuling Cui

引用次数: 0