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Performance of a Simplified Computational Fluid Dynamics Model for a Phase Change Material–Water Finned Heat Exchanger Under Different Orientations 相变材料-水翅片热交换器的简化计算流体动力学模型在不同方向上的性能
Energy Storage Pub Date : 2024-08-28 DOI: 10.1002/est2.70021
Francisco Javier González Gallero, Gabriel González Siles, Ismael Rodríguez Maestre, Juan Luis Foncubierta Blázquez, Luis Pérez-Lombard
{"title":"Performance of a Simplified Computational Fluid Dynamics Model for a Phase Change Material–Water Finned Heat Exchanger Under Different Orientations","authors":"Francisco Javier González Gallero,&nbsp;Gabriel González Siles,&nbsp;Ismael Rodríguez Maestre,&nbsp;Juan Luis Foncubierta Blázquez,&nbsp;Luis Pérez-Lombard","doi":"10.1002/est2.70021","DOIUrl":"https://doi.org/10.1002/est2.70021","url":null,"abstract":"<p>The prevalent numerical models for simulating axially finned heat exchangers with phase change materials (PCMs) and water as the heat transfer fluid rely on computational fluid dynamics (CFD) techniques, with a primary focus on phase change modeling. However, the computational demands of these models, incorporating phase change effects and resolving PCM movement in the liquid state, are substantial. From experiments suggesting that conduction in the solidified PCM around the finned tube dominates heat transfer during the heat discharge process, this article introduces a simplified CFD-based model in which convective flow of the PCM is neglected. The model is experimentally validated using a 1-m-long axially finned heat exchanger prototype with four fins, recording temperatures under different water flow rates and orientations (horizontal and vertical). Results show that the proposed model predicts outlet water temperature satisfactorily, with absolute errors below 1.0°C and 2.2°C for the horizontal and vertical orientations, respectively. Additionally, the model can capture the temperature trend inside the PCM for the horizontal orientation.</p>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/est2.70021","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142089835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Increasing the Efficacy of an Air Conditioning Unit by Utilizing Phase Change Material With Cylindrical Configuration 利用圆柱形结构的相变材料提高空调设备的效率
Energy Storage Pub Date : 2024-08-27 DOI: 10.1002/est2.70025
Arun Kumar Sao, Arun Arora, Mukesh Kumar Sahu
{"title":"Increasing the Efficacy of an Air Conditioning Unit by Utilizing Phase Change Material With Cylindrical Configuration","authors":"Arun Kumar Sao,&nbsp;Arun Arora,&nbsp;Mukesh Kumar Sahu","doi":"10.1002/est2.70025","DOIUrl":"https://doi.org/10.1002/est2.70025","url":null,"abstract":"<div>\u0000 \u0000 <p>The goal of the current study is to determine how the SST <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>k</mi>\u0000 <mo>−</mo>\u0000 <mi>ω</mi>\u0000 </mrow>\u0000 <annotation>$$ k-omega $$</annotation>\u0000 </semantics></math> and the standard <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>k</mi>\u0000 <mo>−</mo>\u0000 <mi>ɛ</mi>\u0000 </mrow>\u0000 <annotation>$$ k-varepsilon $$</annotation>\u0000 </semantics></math> turbulence models prediction on PCM with cylindrical configuration affect AC performance and PCM discharging when coupled with an AC unit. For simulation, 308.15 K and 318.15 K, the inflow air temperature has been considered with a fixed 33.6 L/s intake air flow rate. The low outside temperature charges the PCMs during the night. During the daytime, heated ambient air is cooled by the PCM heat exchanger before passing over the unit condenser. The present outcomes show that using the standard <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>k</mi>\u0000 <mo>−</mo>\u0000 <mi>ε</mi>\u0000 </mrow>\u0000 <annotation>$$ k-varepsilon $$</annotation>\u0000 </semantics></math> model, the cylindrical PCM has the lowest time of complete melting. The temperature contours demonstrate that turbulence occurs, particularly at higher temperatures, in the PCM melting zone within the solid region. This implies that there is increased convection in this area. The maximum improved percentage in COP increases as the rising input air temperature for both turbulence models increases. The average power saving of AC at 308.15 K of an input air temperature for 83.33 min is predicted by both the standard <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>k</mi>\u0000 <mo>−</mo>\u0000 <mi>ɛ</mi>\u0000 </mrow>\u0000 <annotation>$$ k-varepsilon $$</annotation>\u0000 </semantics></math> and the SST <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>k</mi>\u0000 <mo>−</mo>\u0000 <mi>ω</mi>\u0000 </mrow>\u0000 <annotation>$$ k-omega $$</annotation>\u0000 </semantics></math> to be 14.0905 W and 14.1089 W, respectively.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142089895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lignocellulosic Biomass-Derived Graphene: Fabrication, Challenges and Its Potential for Hydrogen Storage Application 木质纤维素生物质衍生石墨烯:制造、挑战及其在储氢应用中的潜力
Energy Storage Pub Date : 2024-08-27 DOI: 10.1002/est2.70019
Anjali Singh, Aman John Tudu, Basant Lal, Shafiul Haque, Bhawna Verma
{"title":"Lignocellulosic Biomass-Derived Graphene: Fabrication, Challenges and Its Potential for Hydrogen Storage Application","authors":"Anjali Singh,&nbsp;Aman John Tudu,&nbsp;Basant Lal,&nbsp;Shafiul Haque,&nbsp;Bhawna Verma","doi":"10.1002/est2.70019","DOIUrl":"https://doi.org/10.1002/est2.70019","url":null,"abstract":"<div>\u0000 \u0000 <p>This review explores the utilization of lignocellulosic biomass (LCB) waste in the fabrication of graphene and its applications in hydrogen storage. Several LCB wastes, such as rice straws, coconut shells, wheat straws, and sugarcane bagasse, along with the methodology used and the characteristics of the final graphene, have been discussed in detail. It was found that the coconut shells produced crumpled multilayered graphene, rice husks (RHs) provided a mix of graphene layers and amorphous carbon, wheat straw yielded few-layered graphene, and sugarcane bagasse contributed to different graphene-like materials. This review has also focused on the various synthesis processes, such as carbonization, hydrothermal carbonization (HTC), chemical activation, pyrolysis, chemical vapor deposition (CVD), and Hummers' method for graphene fabrication from LCB waste, along with their advantages and disadvantages, for a better understanding. Various results have been discussed exploring the use of lignocellulosic biomass-derived graphene (LCB-G) and its various modified forms for hydrogen storage applications. Various challenges in graphene fabrication from LCB, such as low yield, product quality, scalability, use of expensive synthesis methods, and toxic chemicals, along with some potential solutions, have been mentioned. Finally, the review concludes with insights into the future of LCB-G and its role in hydrogen storage while identifying some gaps, such as scalability and product quality, for further research and development.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142089874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen Storage Using Platinum-Supported Ceria Dispersed on Activated Carbon 利用分散在活性炭上的铂支撑铈储存氢气
Energy Storage Pub Date : 2024-08-26 DOI: 10.1002/est2.70032
Anass Wahby, Zinab Abdelouahab-Reddam, Rachad El Mail, Joaquín Silvestre-Albero, Antonio Sepúlveda-Escribano
{"title":"Hydrogen Storage Using Platinum-Supported Ceria Dispersed on Activated Carbon","authors":"Anass Wahby,&nbsp;Zinab Abdelouahab-Reddam,&nbsp;Rachad El Mail,&nbsp;Joaquín Silvestre-Albero,&nbsp;Antonio Sepúlveda-Escribano","doi":"10.1002/est2.70032","DOIUrl":"https://doi.org/10.1002/est2.70032","url":null,"abstract":"<div>\u0000 \u0000 <p>In the current work, carbon materials were used in the hydrogen adsorption process, specifically as carbons doped with platinum dispersed on ceria. The textural characterization results of the prepared samples and the starting carbon showed the presence of both micro- and mesopores. On the other hand, it has been observed that the specific areas were inversely proportional to the CeO<sub>2</sub> loading. In addition, the amount of adsorbed hydrogen increased after doping the carbon with platinum and, even more, when the carbon was doped with Pt dispersed on ceria (2.2 mg/g at 25°C and 30 bar). However, there was a ceria optimum from which the adsorption capacity decreased (10% wt). The results of temperature-programmed desorption (TPD) of hydrogen indicated a high affinity between Pt and H<sub>2</sub> that enhanced H<sub>2</sub> adsorption process by establishing chemical bonds between the metal particles and H<sub>2</sub>. Precisely, the presence of metallic Pt particles dispersed on ceria considerably promotes the spillover process of hydrogen on carbon. This can be confirmed by hydrogen adsorption–desorption isotherms, that showed that complete desorption of chemisorbed hydrogen required an increase of temperature.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142084564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing Power Production: A Novel Hydrogen-Based Scheme With Comprehensive Analysis and AI-Optimized Criteria 提高发电量:采用综合分析和人工智能优化标准的新型氢基方案
Energy Storage Pub Date : 2024-08-22 DOI: 10.1002/est2.70013
Vahid Mohammadzadeh, Zoheir Saboohi, Fathollah Ommi, Ehsan Gholamian
{"title":"Enhancing Power Production: A Novel Hydrogen-Based Scheme With Comprehensive Analysis and AI-Optimized Criteria","authors":"Vahid Mohammadzadeh,&nbsp;Zoheir Saboohi,&nbsp;Fathollah Ommi,&nbsp;Ehsan Gholamian","doi":"10.1002/est2.70013","DOIUrl":"https://doi.org/10.1002/est2.70013","url":null,"abstract":"<div>\u0000 \u0000 <p>Despite being a cutting-edge technology, the proton exchange membrane fuel cell (PEMFC) generates a lot of heat as it works, which makes it wasteful with energy. In order to enhance energy efficiency via waste heat recovery, we provide and analyze a novel integrated energy system that utilizes PEMFC and ORC technology. There are a lot of ways to put the waste heat from fuel cells (FCs) to good use, but the most efficient one is the organic Rankine cycle (ORC) with the right working fluid. This research aims to find the optimal way to use the waste heat of the FC by testing several working fluids. The optimal solution is derived using a genetic algorithm by monitoring the objective functions that characterize the system's overall performance as they vary across different system parameters. The results show that the proposed efficient integration achieves high energy and exergy efficiency levels and achieves rates of total cost and environmental impact that are within acceptable limits. Since the fuel usage element's content significantly affects the system indicators in several ways, the results also demonstrate that it is quite relevant. Since the exergo-environmental metric and the exergy efficiency meter are always moving in different directions, choosing a design condition that meets several requirements is crucial. According to the results, fuel cells had the highest irreversibility rate at 12.2, making them the most energy-conserving piece of machinery.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142045312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Performance Single-Phase Bi-Directional Novel On-Board Charger for Electric Vehicles 用于电动汽车的高性能单相双向新型车载充电器
Energy Storage Pub Date : 2024-08-21 DOI: 10.1002/est2.70014
Md Inayat Ali, Rajib Mandal, Amitesh Kumar
{"title":"High-Performance Single-Phase Bi-Directional Novel On-Board Charger for Electric Vehicles","authors":"Md Inayat Ali,&nbsp;Rajib Mandal,&nbsp;Amitesh Kumar","doi":"10.1002/est2.70014","DOIUrl":"https://doi.org/10.1002/est2.70014","url":null,"abstract":"<div>\u0000 \u0000 <p>The design and development of a 550 W non-isolated single-phase two-stage level-1 bidirectional on-board battery charger (OBC) for electric vehicles (EVs) have been discussed in this article, which is also capable of supplying the utility grid's reactive power needs. There are two stages in this topology. The first stage consists of a full bridge bidirectional AC to DC converter, and the second stage consists of a half-bridge bidirectional DC to DC converter with enhanced vehicle-to-vehicle (V2V) capabilities for emergency roadside charging assistance scenarios. In an emergency, if there is not a charging station nearby and the battery is dead, EVs can use this feature to charge from other EVs. It can also work like a regular vehicle-to-grid (V2G) or grid-to-vehicle (G2V) system. The suggested charging topology has a maximum efficiency of 99.09%, a power factor of 0.99, and a total harmonic distortion (THD) of 6.31%. MATLAB/Simulink is used to develop and simulate the suggested EV charger, and simulation results are compared with the other on-board chargers in the literature.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electric Vehicle Smart-Charging Control for Parking Lots Based on Individual State of Charge Priority 基于个人充电状态优先级的停车场电动汽车智能充电控制
Energy Storage Pub Date : 2024-08-21 DOI: 10.1002/est2.70017
Frederico Haasis, Oscar Solano, Daniel Dias, Bruno Borba
{"title":"Electric Vehicle Smart-Charging Control for Parking Lots Based on Individual State of Charge Priority","authors":"Frederico Haasis,&nbsp;Oscar Solano,&nbsp;Daniel Dias,&nbsp;Bruno Borba","doi":"10.1002/est2.70017","DOIUrl":"https://doi.org/10.1002/est2.70017","url":null,"abstract":"<div>\u0000 \u0000 <p>The integration of electric vehicles (EVs) into the power grid could pose challenges to power quality (PQ) depending on quantity of EVs and when they are connected. To mitigate these impacts without using drastic measures, such as disconnecting EVs, this study investigates centralized control strategies within parking facilities that prioritize EV charging based on individual State of Charge (SoC) levels. The study utilizes the IEEE 34 Bus system and conducts 3888 simulations for different scenarios to assess the impact of the quantity and placement of EVs in parking lots. The study applies the Monte Carlo method to compare the performance of different proposed controls: (i) limiting the charging current to a fixed level and (ii) varying the current based on the voltage droop step. Furthermore, Power Hardware-in-the-Loop (PHIL) simulations were carried out to validate the hierarchical control using the droop step control, demonstrating the best average performance in the previous scenarios. The findings indicated that the control responded within the expected timeframe and successfully addressed voltage sag issues, maintaining PQ in the distribution system in most cases, with its performance being influenced by the placement of parking lots in the network. Additionally, it was confirmed through quartiles that the classification based on SoC leads to a more balanced charging time for different SoC levels.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the Dual Synergistic Amalgamation of CeO2@WO3/GO Electrodes for Supercapacitor Application 研究超级电容器应用中 CeO2@WO3/GO 电极的双重协同混合物
Energy Storage Pub Date : 2024-08-20 DOI: 10.1002/est2.70020
Raphael M. Obodo, Hope E. Nsude, Chimezie U. Eze, Miletus O. Duru, Imosobomeh L. Ikhioya, Joseph N. Anosike, Joseph N. Aniezi, Ekwevugbe Omugbe, Chinonso Mbamara, Ugochukwu C. Elejere, Muhammad Usman, Ishaq Ahmad, M. Maaza
{"title":"Investigating the Dual Synergistic Amalgamation of CeO2@WO3/GO Electrodes for Supercapacitor Application","authors":"Raphael M. Obodo,&nbsp;Hope E. Nsude,&nbsp;Chimezie U. Eze,&nbsp;Miletus O. Duru,&nbsp;Imosobomeh L. Ikhioya,&nbsp;Joseph N. Anosike,&nbsp;Joseph N. Aniezi,&nbsp;Ekwevugbe Omugbe,&nbsp;Chinonso Mbamara,&nbsp;Ugochukwu C. Elejere,&nbsp;Muhammad Usman,&nbsp;Ishaq Ahmad,&nbsp;M. Maaza","doi":"10.1002/est2.70020","DOIUrl":"https://doi.org/10.1002/est2.70020","url":null,"abstract":"<div>\u0000 \u0000 <p>Scientists and researchers are investigating new energy conversion and storage devices continuously because of the current global hike in energy crisis. In this study, we utilized graphene oxide (GO) and composites of transition metallic oxides (CeO<sub>2</sub>@WO<sub>3</sub>) to fabricate electrodes intended for use in supercapacitor electrodes. These electrodes' morphology demonstrates a uniform distribution of sphere and platelet nanoparticles. The XRD measurements for these manufactured electrodes showed a noticeable crystalline character. These electrodes have outstanding electrochemical performance due to their relatively low bandgap energies. The electrochemical tests demonstrated the exceptional charge storage capabilities of the different electrodes, suggesting that CeO<sub>2</sub>/GO, WO<sub>3</sub>/GO, and CeO<sub>2</sub>@WO<sub>3</sub>/GO electrodes could be useful electrodes for supercapacitor applications. Numerous electrochemical findings made it abundantly evident that the creation of bimetallic CeO<sub>2</sub>@WO<sub>3</sub>/GO composites enhanced the supercapacitive performance and cycle stability of the electrodes.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142021721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of an eco-friendly polyacrylic acid binder system on LiFePO4 cathode electrode processing to enhance the performance of coin-cell and pouch-cell graphite||LiFePO4 batteries 研究环保型聚丙烯酸粘合剂系统对磷酸铁锂电池正极电极的处理,以提高纽扣电池和袋式电池石墨||磷酸铁锂电池的性能
Energy Storage Pub Date : 2024-08-06 DOI: 10.1002/est2.70006
Tram Tran Bich Vo, Minh Thu Nguyen, Thanh Liem Pham, Trung Thien Nguyen, Van Gia Tran, Van Man Tran, Phung My Loan Le
{"title":"Investigation of an eco-friendly polyacrylic acid binder system on LiFePO4 cathode electrode processing to enhance the performance of coin-cell and pouch-cell graphite||LiFePO4 batteries","authors":"Tram Tran Bich Vo,&nbsp;Minh Thu Nguyen,&nbsp;Thanh Liem Pham,&nbsp;Trung Thien Nguyen,&nbsp;Van Gia Tran,&nbsp;Van Man Tran,&nbsp;Phung My Loan Le","doi":"10.1002/est2.70006","DOIUrl":"https://doi.org/10.1002/est2.70006","url":null,"abstract":"<p>This study investigates the influence of two types of binders (aqueous and nonaqueous) on the LiFePO<sub>4</sub> (LFP) electrode processing and its electrochemical properties. Specifically, polyvinylidene fluoride (PVDF) and polyacrylic acid (PAA) were dissolved in NMP (<i>N</i>-methyl-2-pyrrolidone) or the aqueous solvent (H<sub>2</sub>O) at varying mass ratios of 5%, 10%, and 15%. Binder durability and inertness were assessed by immersing prepared LFP electrodes in an electrolyte comprising 1.0 M LiPF<sub>6</sub> in EC:DEC:DMC (1:1:1 in vol%). Notably, PVDF/NMP 10% and PAA/H<sub>2</sub>O 10%-based electrodes displayed good durability without peeling. Electrochemical characteristics were evaluated through cycling voltammetry and galvanostatic cycling with potential limitation. The PAA/H<sub>2</sub>O 10%-based-LFP electrode exhibited a specific capacity of ~148.9 mAh g<sup>−1</sup> with a Coulombic efficiency (CE) of around 97.27%, surpassing PVDF/NMP 10%. The graphite||PAA/H<sub>2</sub>O 10%-based-LFP electrode in a full cell demonstrated higher capacity and superior retention after 30 cycles. In a pouch cell (6 cm × 4 cm), utilizing graphite||LFP with PAA/H<sub>2</sub>O 10%, a capacity of 25.5 mAh was achieved, maintaining 93% capacity with a CE of about 99% after 30 cycles at a rate of 0.1C.</p>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of Flexible High-Efficient Aluminum ion Supercapacitors With 2D Niobium MXene Electrode 利用二维铌 MXene 电极开发柔性高效铝离子超级电容器
Energy Storage Pub Date : 2024-08-06 DOI: 10.1002/est2.70012
Latha Malyala, Sampath Karingula, Thirupathi Bhookya, Gobi K Vengatajalabathy
{"title":"Development of Flexible High-Efficient Aluminum ion Supercapacitors With 2D Niobium MXene Electrode","authors":"Latha Malyala,&nbsp;Sampath Karingula,&nbsp;Thirupathi Bhookya,&nbsp;Gobi K Vengatajalabathy","doi":"10.1002/est2.70012","DOIUrl":"https://doi.org/10.1002/est2.70012","url":null,"abstract":"<div>\u0000 \u0000 <p>A high-performance aluminum-ion supercapacitor is fabricated using 2D few-layered Nb<sub>2</sub>CT<sub>x</sub> MXene, as an active electrode material and Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub> electrolyte for efficient energy storage. Nb<sub>2</sub>CT<sub>x</sub> MXene has been synthesized from Nb<sub>2</sub>AlC MAX phase using HF. Nb<sub>2</sub>CT<sub>x</sub> MXene coated on carbon cloth (Nb@CC) displays a capacitance of 307 F g<sup>−1</sup> with 90% coulombic efficiency. The specific capacitance of Nb@CC in Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub> electrolyte is exceptionally high compared to those (≤32.2 F g<sup>−1</sup>) in H<sub>2</sub>SO<sub>4</sub>, Na<sub>2</sub>SO<sub>4</sub>, and MgSO<sub>4</sub> electrolytes. Both symmetric and asymmetric aluminum ion supercapacitors are fabricated with Nb@CC electrode. The Nb@CC//Nb@CC symmetric device exhibits a capacitance of 122 F g<sup>−1</sup> with a high energy density (E<sub><i>d</i></sub>) of 33.2 Wh kg<sup>−1</sup> at 1.41 kW kg<sup>−1</sup> power density (P<sub><i>d</i></sub>). An asymmetric supercapacitor device (ASC), Nb@CC//CNT@CC, with carbon nanotube (CNT@CC) cathode delivers a maximum E<sub><i>d</i></sub> of 24.7 Wh kg<sup>−1</sup> at 3.41 kW kg<sup>−1</sup> P<sub><i>d</i></sub> and excellent stability with 90% capacitance retention after 4000 cycles. A remarkably high P<sub><i>d</i></sub> of 34 kW kg<sup>−1</sup> is maintained with 13.2 Wh kg<sup>−1</sup> E<sub><i>d</i></sub>, and the rate capability is 53% for a 10-fold increase in current density. These results offer the feasibility of efficient aqueous supercapacitors with Al-ion as guest species, presenting new possibilities for supercapacitors.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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