{"title":"竹制多孔活性炭在对称超级电容器电极上的电荷存储性能","authors":"Rohit Yadav, Savita Sharma, Hitesh Borkar, Kusum Kumari","doi":"10.1002/est2.70178","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Activated carbon (AC) obtained from bamboo stems is used in this study as an electrode material for the symmetric supercapacitor as it is cost-effective and bio-renewable. The activated carbon was synthesized in two steps at the optimal temperature of 700°C, involving thermal carbonization and chemical activation with ZnCl<sub>2</sub>. The distorted honeycomb and void-containing surface morphology of the synthesized activated carbon (AC<sub>b</sub>) was confirmed by scanning electron microscope (SEM) analysis. X-ray diffraction (XRD) was performed for the crystallography, and X-ray photoelectron spectroscopy (XPS) was performed for the elements' chemical states. Brunauer–Emmett–Teller (BET) analysis confirmed the mesoporosity (avg. pore radius 42.1 Å) and high specific surface area (92.1 m<sup>2</sup> g<sup>−1</sup>) of the AC<sub>b</sub>. Electrochemical studies revealed that the three-electrode system demonstrated a specific capacitance of 75.8 F g<sup>−1</sup> at 5 mV s<sup>−1</sup> in 1 M NaOH electrolyte. A capacitance retention of 75% was obtained even after 10,000 cyclic voltammetry (CV) cycles. An LED light was illuminated using a fabricated two-electrode symmetric device. However, for practical applications, more durability study is needed. This study offers insightful new information about how to best utilize chemically processed AC derived from bamboo stems in modern energy conservation systems.</p>\n </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Charge Storage Performance of Porous Activated Carbon Derived From Bamboo Stems for Symmetric Supercapacitor Electrodes\",\"authors\":\"Rohit Yadav, Savita Sharma, Hitesh Borkar, Kusum Kumari\",\"doi\":\"10.1002/est2.70178\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>Activated carbon (AC) obtained from bamboo stems is used in this study as an electrode material for the symmetric supercapacitor as it is cost-effective and bio-renewable. The activated carbon was synthesized in two steps at the optimal temperature of 700°C, involving thermal carbonization and chemical activation with ZnCl<sub>2</sub>. The distorted honeycomb and void-containing surface morphology of the synthesized activated carbon (AC<sub>b</sub>) was confirmed by scanning electron microscope (SEM) analysis. X-ray diffraction (XRD) was performed for the crystallography, and X-ray photoelectron spectroscopy (XPS) was performed for the elements' chemical states. Brunauer–Emmett–Teller (BET) analysis confirmed the mesoporosity (avg. pore radius 42.1 Å) and high specific surface area (92.1 m<sup>2</sup> g<sup>−1</sup>) of the AC<sub>b</sub>. Electrochemical studies revealed that the three-electrode system demonstrated a specific capacitance of 75.8 F g<sup>−1</sup> at 5 mV s<sup>−1</sup> in 1 M NaOH electrolyte. A capacitance retention of 75% was obtained even after 10,000 cyclic voltammetry (CV) cycles. An LED light was illuminated using a fabricated two-electrode symmetric device. However, for practical applications, more durability study is needed. This study offers insightful new information about how to best utilize chemically processed AC derived from bamboo stems in modern energy conservation systems.</p>\\n </div>\",\"PeriodicalId\":11765,\"journal\":{\"name\":\"Energy Storage\",\"volume\":\"7 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-05-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy Storage\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/est2.70178\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Storage","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/est2.70178","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
从竹茎中提取的活性炭(AC)具有成本效益和生物可再生性,因此在本研究中用作对称超级电容器的电极材料。在700℃的最佳温度下,分热炭化和ZnCl2化学活化两步合成活性炭。通过扫描电镜(SEM)分析,证实了所合成活性炭(ACb)的表面形貌为扭曲的蜂窝状和含孔洞状。用x射线衍射(XRD)分析了晶体学,用x射线光电子能谱(XPS)分析了元素的化学态。brunauer - emmet - teller (BET)分析证实了ACb的介孔性(平均孔半径42.1 Å)和高比表面积(92.1 m2 g−1)。电化学研究表明,在1 M NaOH电解液中,三电极体系在5 mV s−1下的比电容为75.8 F g−1。在10000次循环伏安(CV)循环后,电容保持率仍为75%。采用自制的双电极对称器件照明LED灯。然而,为了实际应用,还需要进行更多的耐久性研究。该研究为如何在现代节能系统中最好地利用来自竹茎的化学处理交流电提供了有见地的新信息。
Charge Storage Performance of Porous Activated Carbon Derived From Bamboo Stems for Symmetric Supercapacitor Electrodes
Activated carbon (AC) obtained from bamboo stems is used in this study as an electrode material for the symmetric supercapacitor as it is cost-effective and bio-renewable. The activated carbon was synthesized in two steps at the optimal temperature of 700°C, involving thermal carbonization and chemical activation with ZnCl2. The distorted honeycomb and void-containing surface morphology of the synthesized activated carbon (ACb) was confirmed by scanning electron microscope (SEM) analysis. X-ray diffraction (XRD) was performed for the crystallography, and X-ray photoelectron spectroscopy (XPS) was performed for the elements' chemical states. Brunauer–Emmett–Teller (BET) analysis confirmed the mesoporosity (avg. pore radius 42.1 Å) and high specific surface area (92.1 m2 g−1) of the ACb. Electrochemical studies revealed that the three-electrode system demonstrated a specific capacitance of 75.8 F g−1 at 5 mV s−1 in 1 M NaOH electrolyte. A capacitance retention of 75% was obtained even after 10,000 cyclic voltammetry (CV) cycles. An LED light was illuminated using a fabricated two-electrode symmetric device. However, for practical applications, more durability study is needed. This study offers insightful new information about how to best utilize chemically processed AC derived from bamboo stems in modern energy conservation systems.