Zhuo Li, Hanjiang Zhou, Qingling Meng, Liang Tian, Ying Ma, Peng Liu, Jie Li, Mingfu Yu, Ning Tang, Wenbin Liu, Xianwei Hu
{"title":"Construction of Hollow Cobalt Phosphide Heterostructure for High-Performance Lithium-Ion Batteries","authors":"Zhuo Li, Hanjiang Zhou, Qingling Meng, Liang Tian, Ying Ma, Peng Liu, Jie Li, Mingfu Yu, Ning Tang, Wenbin Liu, Xianwei Hu","doi":"10.1002/ente.70631","DOIUrl":"https://doi.org/10.1002/ente.70631","url":null,"abstract":"<p>Transition metal phosphides (TMPs) have been considered as the prospective anode materials for lithium-ion batteries (LIBs) due to their prominent theoretical capacity. However, their unsatisfactory kinetic performance and ineluctable volume expansion result in rapid capacity decay and the collapse of material structure during cycles, which restrict their commercial application. Herein, a hollow cobalt phosphide with nitrogen-doped carbon nanotube-entangled heterostructure(H-CoP@NCNTs) is constructed using ZIF-67 as a sacrificial host and serves as an anode for LIBs. The elastic hollow carbon framework as a covering layer for CoP-based active material can regulate the volume change during cycles. And the multidimensional conductive network with nitrogen-doped carbon nanotubes wrapped can improve the electron/ion transport. The H-CoP@NCNTs anode presents a considerable reversible capacity of 754.8 mAh g<sup>−1</sup> at 0.1 A g<sup>−1</sup> and a long-cycle stability (418.6 mAh g<sup>−1</sup> after 1000 cycles at 2 A g<sup>−1</sup>). This work provides an efficient approach for designing and exploiting advancing TMP-based anodes.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guanyu Tang, Weiwei Huang, Tingting Wang, Shuangxi Lin, Zhenhua Li
{"title":"Effect of Preparation Method on the Structure of NiCe Catalysts and CO2 Methanation Performance","authors":"Guanyu Tang, Weiwei Huang, Tingting Wang, Shuangxi Lin, Zhenhua Li","doi":"10.1002/ente.70632","DOIUrl":"https://doi.org/10.1002/ente.70632","url":null,"abstract":"<p>CO<sub>2</sub> methanation not only reduces CO<sub>2</sub> emissions but also enables the efficient utilization of carbon resources. The development of highly efficient and stable catalysts is crucial for the application of this reaction. CeO<sub>2</sub> supported Ni catalyst (NiCe) showed high potential for CO<sub>2</sub> methanation. In this paper, we prepared Ni<sub>3</sub>Ce<sub>1</sub> catalysts by three preparation methods: urea hydrothermal method (UHT), coprecipitation method (CP), and sol–gel method (SG), to establish a rational design framework by quantitatively decoupling metal–support interactions (MSI). By comparing the effects of preparation parameters including hydrothermal temperature, precipitation pH, and complexing agent-to-metal ion ratios, on catalyst structure and CO<sub>2</sub> methanation performance, the optimal catalysts for each method were identified. Among them, the catalyst Ni<sub>3</sub>Ce<sub>1</sub>-CP-12 prepared by CP, exhibited the best performance, achieving CO<sub>2</sub> conversion as high as 84.6% at 300 °C with good selectivity. This is attributed to its enhanced reducibility, increased surface oxygen vacancies, suitable distribution of basic sites and high surface Ni<sup>0</sup> sites.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aina Tian, Chengshun Gong, Rongwei Wang, Jiuchun Jiang
{"title":"Joint Estimation of State of Charge and State of Temperature for Solid-State Batteries Based on Dual-Extended Kalman Filter","authors":"Aina Tian, Chengshun Gong, Rongwei Wang, Jiuchun Jiang","doi":"10.1002/ente.70635","DOIUrl":"https://doi.org/10.1002/ente.70635","url":null,"abstract":"<p>Due to significant electrothermal coupling, solid-state lithium-ion batteries pose challenges for accurately estimating battery state in battery management systems. This paper proposes a Dual-Extended Kalman Filter (DEKF) framework for joint estimation of state of charge (SOC) and state of temperature (SOT). A second-order equivalent circuit model and a two-state thermal model are established, with parameters identified via particle swarm optimization and recursive least squares. An electrothermal coupling model is then built, and a DEKF-based estimator is designed to simultaneously estimate SOC, surface temperature, and core temperature. Validation under four typical dynamic driving cycles shows that for SOC estimation, the mean absolute error (MAE), and root mean square error (RMSE) remain below 0.75% and 0.85%, respectively. For temperature estimation, the MAE for surface and core temperatures was kept within 0.5924 and 0.6293 °C, respectively, while the RMSE was kept within 0.7076 and 0.7611 °C, respectively. This study proposes a feasible method for state estimation in solid-state batteries.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anushka Pandey, Rajesh K. Yadav, Rajesh K. Verma, Chinna Bathula, Kanchan Sharma, Anupma Yadav, Geeta Srivastava, Shaifali Mishra, Surendra K. Jaiswal, Jin Ook Baeg
{"title":"Artificial Photosynthesis Over Ultrasonically Engineered SCN@Fe3O4 Magnetic Nanorods for Selective Carboxylation Reaction","authors":"Anushka Pandey, Rajesh K. Yadav, Rajesh K. Verma, Chinna Bathula, Kanchan Sharma, Anupma Yadav, Geeta Srivastava, Shaifali Mishra, Surendra K. Jaiswal, Jin Ook Baeg","doi":"10.1002/ente.70568","DOIUrl":"https://doi.org/10.1002/ente.70568","url":null,"abstract":"<p>One of the most difficult challenges of this century is the quick conversion of anthropogenic carbon dioxide (CO<sub>2</sub>) into value-added solar chemicals/fuels. The best method for transforming CO<sub>2</sub> into beneficial compounds like glucose and oxygen is natural photosynthesis. In this context, herein, an artificial photosynthesis over ultrasonically engineered SCN@Fe<sub>3</sub>O<sub>4</sub> magnetic nanorods was designed for a selective carboxylation reaction (CO<sub>2</sub>-to-formic acid production). The SCN@Fe<sub>3</sub>O<sub>4</sub> magnetic nanorods were employed as an efficient visible light–responsive photocatalyst for the regeneration of NADH (nicotinamide adenine dinucleotide hydrogenase) from NAD<sup>+</sup> (nicotinamide adenine dinucleotide), where NADH serves as the biologically active hydrogen carrier. Under visible light irradiation, the optimized photocatalytic system achieved an in situ NADH regeneration (74.49%), which subsequently promoted the enzymatic reduction of CO<sub>2</sub>-to-HCOOH using formate dehydrogenase (FDH). The system produced HCOOH (170.70 µM) under optimized conditions in a phosphate buffer medium containing NAD<sup>+</sup>, Rh-based electron mediator, and triethanolamine (TEOA) as a sacrificial agent. The greater yield and high efficiency attained here suggest a sustainable and high-throughput approach to useful enzymatic applications.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xinyue Zhao, Qiuwan Shen, Zhaoyang Zhang, Hongda Li, Shian Li
{"title":"Electrochemical Analysis of Microporous Layer Parameter Optimization in Anion Exchange Membrane Electrolyzer Based on Three-Dimensional Multiphysics Simulation","authors":"Xinyue Zhao, Qiuwan Shen, Zhaoyang Zhang, Hongda Li, Shian Li","doi":"10.1002/ente.70634","DOIUrl":"https://doi.org/10.1002/ente.70634","url":null,"abstract":"<p>This study establishes a three-dimensional, nonisothermal, two-phase flow anion exchange membrane electrolyzer cell (AEMEC) numerical model that includes a microporous layer (MPL). The effects of flow field design, operating parameters, and key component structural parameters on the performance of electrolytic cells were studied. Results indicate that the serpentine flow channel, with its “piston flow” effect, can achieve more uniform species distribution and temperature field compared to parallel flow channels. It exhibits superior electrochemical performance at high operating voltage with a current density increase of approximately 7.8% at 2.3 V. Parameter analysis shows that increasing operating voltage and inlet water temperature can significantly improve gas production rate. For MPLs, there exists an optimal range of MPL parameters (porosity <i>ε </i>= 0.5–0.6, thickness <i>d</i> = 25–35 µm) that can achieve the best balance between mass transfer resistance and conductivity. In addition, reducing the thickness of the AEM can effectively reduce the Ohmic loss. This study provides theoretical basis and data support for the design and optimization of key components of high-performance AEMEC.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148994318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Engineered Antileakage and Low-Corrosion Composite Phase Change Gels for Enhanced Cold Storage: Toward Sustainable Refrigeration","authors":"Chao Lan, Miaomiao Jiang, Musen Li, Xuelai Zhang, Yuanzhe Gu","doi":"10.1002/ente.202502398","DOIUrl":"https://doi.org/10.1002/ente.202502398","url":null,"abstract":"<p>The substantial energy consumption of conventional cold chain systems presents a significant challenge to global sustainability goals. While phase change materials (PCMs) offer promising thermal regulation solutions, they typically suffer from rigidity, leakage risks, and corrosiveness, especially in subzero applications. Composite phase change gels (CPCMGs) emerge as an innovative alternative, overcoming rigidity and leakage issues through their inherent flexibility, water retention properties, and salt compatibility. However, material corrosiveness and limited stability continue to hinder practical implementation. This study developed two low-leakage CPCMGs with phase transition temperatures of −21.6 and −21.5 °C. These cryogenic gels demonstrate negligible supercooling, exceptional leakage resistance, and high latent heat values of 246.6 and 243.9 J/g. After 500 thermal cycles, the CPCMGs maintained excellent stability and thermophysical properties. Comprehensive corrosion evaluation through 60-day immersion tests on six common metals, employing mass loss analysis and surface morphology characterization, confirmed the gel’s corrosion resistance. The most susceptible material, carbon steel (Q235), exhibited a minimal corrosion rate of only 0.02698 g/(m<sup>2</sup> day) in CPCMG. This breakthrough resolves the persistent challenge of balancing stability, corrosion resistance, and cost in low-temperature PCMG development, while advancing sustainable cold chain applications for aquatic product preservation and biomedical sample transport.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Polymer–Microbe Interfaces for Enhanced Electron Transfer in Microbial Fuel Cells","authors":"Ishan Sahane, Payal Varma, Neha Neha, Balasubramanian Kandasubramanian","doi":"10.1002/ente.70633","DOIUrl":"https://doi.org/10.1002/ente.70633","url":null,"abstract":"<p>The increasing demand for sustainable energy storage has highlighted the limitations of lithium-ion batteries, including resource depletion, thermal instability, electrode degradation, and limited recyclability. These challenges have stimulated interest in microbial fuel cells (MFCs), which simultaneously generate electricity and treat organic waste through the metabolic activity of electroactive microorganisms. However, their large-scale application is hindered by inefficient extracellular electron transfer (EET), unstable biofilms, and high interfacial resistance. This review summarizes recent advances in electroactive bacteria and polymeric materials for improving MFC performance. Particular emphasis is placed on conductive polymers, biopolymers, polymer composites, and polymer-based membranes that enhance microbial adhesion, biofilm stability, and charge transport. The review highlights how polymeric materials facilitate direct electron transfer (DET) by forming conductive bridges between bacteria and electrodes, while mediated electron transfer (MET) is enhanced through redox-active polymers and electron-shuttling molecules. Recent developments in polymer–carbon and polymer–metal oxide hybrid materials are also discussed for their roles in improving conductivity, durability, and power generation. Overall, this review provides insights into polymer-assisted interface engineering for developing efficient, stable, and scalable MFCs for sustainable bioenergy applications.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 9","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148943695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qingling Wei, Le Meng, Xiaoyang Yu, Zichen Wang, Xiaomin Yang
{"title":"High-Performance Supercapacitors Based on TiO2-Supported Rice Husk-Based Activated Carbon Composite Electrodes","authors":"Qingling Wei, Le Meng, Xiaoyang Yu, Zichen Wang, Xiaomin Yang","doi":"10.1002/ente.70629","DOIUrl":"https://doi.org/10.1002/ente.70629","url":null,"abstract":"<p>The development of high-performance supercapacitors has driven interest in composite electrodes that synergistically combine carbon materials with metal oxides. In this work, TiO<sub>2</sub>/activated carbon (TiO<sub>2</sub>/AC) composites are synthesized via a microwave-assisted method, incorporating different crystalline phases of TiO<sub>2</sub> onto rice husk-derived porous carbon. The anatase phase TiO<sub>2</sub>/AC composite demonstrates outstanding performance, achieving a high specific capacitance of 249.4 F g<sup>−1</sup> and an energy density of 8.6 Wh kg<sup>−1</sup> at a current density of 0.5 A g<sup>−1</sup>. Even at an elevated current density of 20 A g<sup>−1</sup>, the anatase phase TiO<sub>2</sub>/AC electrode maintains 86.6% of its initial specific capacitance and retains an energy density of 6.9 Wh kg<sup>−1</sup>, demonstrating excellent rate capability and energy-power balance. The results of the electrochemical performance tests and the structural analysis of the composite materials indicate that the performance enhancement stems from the synergistic effect between the pseudo-capacitance contributed by anatase phase TiO<sub>2</sub> and the hierarchical porous architecture of the bio-derived activated carbon (AC). These findings underscore the promising potential of TiO<sub>2</sub>/AC composites for advanced energy storage applications.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 8","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148848641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ke Zhao, Jinping Zhang, Jinlei Shi, Ziyuan Fan, Xin Rao, Jiale Yang, Ting Zhang, Wanqiu Yao, Yanan Tang, Chengyan Liu
{"title":"Modeling-Based Optimization of Defects, Grain Boundaries, and Interfaces in Kesterite Solar Cells: A Review","authors":"Ke Zhao, Jinping Zhang, Jinlei Shi, Ziyuan Fan, Xin Rao, Jiale Yang, Ting Zhang, Wanqiu Yao, Yanan Tang, Chengyan Liu","doi":"10.1002/ente.70628","DOIUrl":"https://doi.org/10.1002/ente.70628","url":null,"abstract":"<p>Solar cells play a pivotal role in driving the global energy transition toward a sustainable, distributed, and eco-friendly energy landscape by providing clean, renewable, and cost-effective power, thereby reducing reliance on traditional fossil fuels. Among various thin-film solar cell technologies, Cu<sub>2</sub>ZnSn(S, Se)<sub>4</sub> (CZTSSe) has emerged as one of the most promising inorganic photovoltaic materials due to its structure stability, environmental benignity, earth-abundant constituents, favorable electronic properties, and high theoretical efficiency. However, as multielemental and layered-stacking devices, CZTSSe solar cells suffer from severe deep-level states and unfavorable band alignments, arising from complicated defects, grain boundaries, and interfacial states at both front and back contacts. These intrinsic issues result in pronounced carrier nonradiative recombination and inefficient charge extraction, restricting their efficiency to a record 16.6%, well below the theoretical Shockley–Queisser limit of 32.0%. To address these efficiency bottlenecks, we review recent advances in first-principles calculations and solar cell capacitance simulator in one dimension (SCAPS-1D) simulations of bulk defects, grain boundaries, and interfaces, systematically analyzing critical challenges and discussing potential defect engineering strategies to optimize the performance of kesterite-based photovoltaics.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 8","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148785008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tamer M. Ismail, Abubakr A. Yehia, Hussein Emad, Abd El-Wahab Hamed, AbdElfattah Tamer, M. Abd El-Salam
{"title":"Region-Resolved Machine-Learning Forecasting of Photovoltaic-Driven Hydrogen Production Potential in Uganda: A Long Short-Term Memory–Prophet Comparison","authors":"Tamer M. Ismail, Abubakr A. Yehia, Hussein Emad, Abd El-Wahab Hamed, AbdElfattah Tamer, M. Abd El-Salam","doi":"10.1002/ente.70627","DOIUrl":"https://doi.org/10.1002/ente.70627","url":null,"abstract":"<p>This study develops a region-resolved machine-learning framework for forecasting photovoltaic-derived hydrogen-production potential in Entebbe, Kampala, Mbarara, and Gulu, Uganda. Hourly meteorological data from 21 December 2023 to 20 December 2024 were used for model development, while the subsequent 45 days were reserved for independent chronological testing. Global horizontal irradiance, air temperature, wind speed, and relative humidity were selected through correlation analysis, principal-component assessment, and chronological validation. Photovoltaic electrical-energy availability was estimated first and then converted into hydrogen-production potential using a screening-level constant-efficiency electrolyzer model. Long short-term memory and Prophet forecasts were compared using <i>R</i><sup>2</sup>, MAE, RMSE, and nRMSE. Long short-term memory (LSTM) consistently outperformed Prophet, achieving <i>R</i><sup>2</sup> values of 0.931–0.958 compared with 0.829–0.949 for Prophet. Relative to Prophet, LSTM reduced RMSE by 15.6%–37.2% and MAE by 43.2%–50.0%. Kampala and Gulu exhibited the highest monthly hydrogen-production potential, approximately 41 000 kg H<sub>2</sub> km<sup>−2</sup> of active PV area month<sup>−1</sup>, corresponding to about 2.16 GWh km<sup>−2</sup> month<sup>−1</sup> of PV electricity. The results demonstrate that regional meteorological variability affects both production potential and forecastability, while LSTM provides the more reliable basis for comparative site screening, reserve assessment, and preliminary scheduling of PV–hydrogen systems.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"14 8","pages":""},"PeriodicalIF":3.6,"publicationDate":"2026-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148784800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}