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Modulation of Energy Band Positions in Sb2S3 Thin Films for Enhanced Photovoltaic Performance of FTO/TiO2/Sb2S3/P3HT/Au Solar Cell Sb2S3薄膜能带位置调制对FTO/TiO2/Sb2S3/P3HT/Au太阳能电池光电性能的影响
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-12-08 DOI: 10.1002/ente.202401475
Nithyapremini Gunasekaran, Deepan Chakravarthi Nagarajan, Devaraj Nataraj, Kandasamy Prabakar
{"title":"Modulation of Energy Band Positions in Sb2S3 Thin Films for Enhanced Photovoltaic Performance of FTO/TiO2/Sb2S3/P3HT/Au Solar Cell","authors":"Nithyapremini Gunasekaran,&nbsp;Deepan Chakravarthi Nagarajan,&nbsp;Devaraj Nataraj,&nbsp;Kandasamy Prabakar","doi":"10.1002/ente.202401475","DOIUrl":"https://doi.org/10.1002/ente.202401475","url":null,"abstract":"<p>Antimony sulfide (Sb<sub>2</sub>S<sub>3</sub>) has the potential as an absorber material in photovoltaics due to its suitable bandgap and favorable optoelectronic properties. However, its energy band positions are not extensively explored which are essential for effective charge separation and transfer. This study examines the energy band positions of Sb<sub>2</sub>S<sub>3</sub> thin films as a function of annealing temperature. Sb<sub>2</sub>S<sub>3</sub> thin films are grown by a combination of successive ionic layer adsorption and reaction (SILAR) and chemical bath deposition (CBD) method to enhance the crystallinity, tune the bandgap, and overall quality of Sb<sub>2</sub>S<sub>3</sub> films to enhance the photovoltaic performance. Optical bandgap decreases from 2.41 to 1.67 eV from the as-deposited films to annealed at 300 °C due to changes in interatomic distances. Energy band positions of Sb<sub>2</sub>S<sub>3</sub> films are measured both by cost-effective electrochemical cyclic voltammetry and Mott–Schottky analysis and validated the findings using ultraviolet photoelectron spectroscopy (UPS). The conductivity of Sb<sub>2</sub>S<sub>3</sub> is found to be n-type. Thin-film solar cells are then fabricated by employing Sb<sub>2</sub>S<sub>3</sub> as an absorber layer in an FTO/TiO<sub>2</sub>/Sb<sub>2</sub>S<sub>3</sub>/P3HT/Au structure, achieving an enhanced power conversion efficiency, increasing from 0.4 to 2.8% after annealing. These findings demonstrate the potential of Sb<sub>2</sub>S<sub>3</sub> as a low-cost absorber material for thin-film photovoltaics.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143939056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Review on Minimization of Polysulfide Shuttle Effect of Lithium–Sulfur Batteries by Using Low-Dimensional Carbon Composite as the Sulfur Cathode 低维碳复合材料作为硫阴极减少锂硫电池多硫穿梭效应的研究进展
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-12-06 DOI: 10.1002/ente.202401451
Aishwarya Chalil Suresh, Nagaraju Kottam, Savitha Hosamane
{"title":"A Review on Minimization of Polysulfide Shuttle Effect of Lithium–Sulfur Batteries by Using Low-Dimensional Carbon Composite as the Sulfur Cathode","authors":"Aishwarya Chalil Suresh,&nbsp;Nagaraju Kottam,&nbsp;Savitha Hosamane","doi":"10.1002/ente.202401451","DOIUrl":"https://doi.org/10.1002/ente.202401451","url":null,"abstract":"<p>\u0000Owing to the high specific energy density in theories, abundance of resources, and adherence to environmental standards, rechargeable lithium–sulfur batteries (LSB) have drawn an increasing amount of interest. However, the weak conductivity of the sulfur and discharge products, the drastic breakdown and migration of the intermediates of lithium polysulfide (LiPSs) leading to shuttle effect, and the enormous volumetric change of sulfur particles upon cycle substantially hinder their practical uses. Due to the considerable capacity diminishing caused by the shuttle impact corrosion of the lithium metal, LSBs are thought to have significant commercial application challenges. Engineering nanomaterials’ surface structures can increase the affinity between the cathode with the LiPSs while also enabling the redox kinetics of the LiPSs, which results in a low level of LiPSs in the electrolyte that can restrict the shuttle effect. Sulfur and carbon materials, when combined, effectively increase the efficiency of active materials, increase the conductive properties of cathode components, and serve as a barrier against polysulfides. In this review, a thorough analysis is provided on low-dimensional carbon materials as cathode, by which the electrode modification technique for limiting the shuttle effect of polysulfide in LSBs and forecast future research trends on the same.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessment of the Effects of Intake Temperature and Injector Structure on the Combustion Characteristics of Direct-Injection Spark-Ignition Methanol Engines 评估进气温度和喷油器结构对直喷式火花点火甲醇发动机燃烧特性的影响
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-12-06 DOI: 10.1002/ente.202401540
Tai Yang, Wu Wei, Lun Zhao, Long Zhang, Jin Ba, Ning Xie
{"title":"Assessment of the Effects of Intake Temperature and Injector Structure on the Combustion Characteristics of Direct-Injection Spark-Ignition Methanol Engines","authors":"Tai Yang,&nbsp;Wu Wei,&nbsp;Lun Zhao,&nbsp;Long Zhang,&nbsp;Jin Ba,&nbsp;Ning Xie","doi":"10.1002/ente.202401540","DOIUrl":"https://doi.org/10.1002/ente.202401540","url":null,"abstract":"<p>\u0000In this article, to address the issues of slower droplet evaporation and fuel mixing inhomogeneity caused by the high latent heat of vaporization of methanol, the effects of the number of nozzle holes and spray cone angle (<i>θ</i><sub>sca</sub>) on the combustion characteristics of a direct-injection spark-ignition methanol engine are numerically investigated at different intake temperatures (<i>T</i><sub>int</sub>) under constant injection pressures. In the results, it is indicated that the maximum-indicated thermal efficiency (ITE) is 48.01% at 8 holes and a <i>T</i><sub>int</sub> of 328 K. Although the ITE at 298 K with 8 holes is 1.42% lower than 328 K, NOx emissions and ringing intensity (RI) are reduced by 90.46% and 90.61%, respectively. Simultaneously, emissions of CO, hydrocarbon (HC), Soot, unburned methanol, and formaldehyde remain at a low level. Second, there exists an optimal <i>θ</i><sub>sca</sub> at different holes, thus obtaining the best fuel economy and emissions. The maximum ITE is 48.1% at 8 holes and a <i>θ</i><sub>sca</sub> of 26°. Finally, under the same energy input and parameter, compared with the diesel engine of the optimal start of injection, the ITE of the optimized methanol engine is increased by 1.65%, and the RI, NOx, HC, CO, and Soot emissions are reduced by 98.58%, 77.85%, 99.35%, 85.71%, and 78.38%, respectively.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dielectric Barrier Discharge Reactors for Plasma-Assisted CO2 and CH4 Conversion: A Comprehensive Review of Reactor Design, Performance, and Future Prospects 等离子体辅助CO2和CH4转化的介质阻挡放电反应器:反应器设计、性能和未来展望的综合综述
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-12-06 DOI: 10.1002/ente.202401177
Md Robayet Ahasan, Md Monir Hossain, Ruigang Wang
{"title":"Dielectric Barrier Discharge Reactors for Plasma-Assisted CO2 and CH4 Conversion: A Comprehensive Review of Reactor Design, Performance, and Future Prospects","authors":"Md Robayet Ahasan,&nbsp;Md Monir Hossain,&nbsp;Ruigang Wang","doi":"10.1002/ente.202401177","DOIUrl":"https://doi.org/10.1002/ente.202401177","url":null,"abstract":"<p>Dielectric barrier discharge (DBD) plasma is a promising technology for catalysis due to its low-temperature operation, cost-effectiveness, and silent operation. This review comprehensively analyzes the design and operational parameters of DBD plasma reactors for three key catalytic applications: CH<sub>4</sub> conversion, CO<sub>2</sub> splitting, and dry reforming of methane (DRM). While catalyst selection is crucial for achieving desired product selectivity, reactor design and reaction parameters such as discharge power, electrode gap, reactor length, frequency, dielectric material thickness, and feed gas flow rate, significantly influence discharge characteristics and reaction mechanisms. This review also explores the influence of less prominent factors, such as electrode shape and applied voltage waveforms. Additionally, this review addresses the challenges of DBD plasma catalysis, including heat loss, temperature effects on discharge characteristics, and strategies for enhancing overall efficiency.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Physical Attributes of Sr2GeCrO6, Sr2MgMoO6, Ba2MgMoO6, Ba2ZnMoO6, and Ba2HgWO6 Double Perovskite Oxides Sr2GeCrO6、Sr2MgMoO6、Ba2MgMoO6、Ba2ZnMoO6和Ba2HgWO6双钙钛矿氧化物的物理性质研究
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-12-01 DOI: 10.1002/ente.202401477
Memoona Mehmood, Atia Atiq, Qura Tul Ain, Farah Andleeb, Aqsa Manzoor, Iqra Imran, Muhammad Nasir Rasul
{"title":"Investigation of the Physical Attributes of Sr2GeCrO6, Sr2MgMoO6, Ba2MgMoO6, Ba2ZnMoO6, and Ba2HgWO6 Double Perovskite Oxides","authors":"Memoona Mehmood,&nbsp;Atia Atiq,&nbsp;Qura Tul Ain,&nbsp;Farah Andleeb,&nbsp;Aqsa Manzoor,&nbsp;Iqra Imran,&nbsp;Muhammad Nasir Rasul","doi":"10.1002/ente.202401477","DOIUrl":"https://doi.org/10.1002/ente.202401477","url":null,"abstract":"<p>A density functional theory-based study on the physical properties of significant double perovskite oxides Sr<sub>2</sub>GeCrO<sub>6</sub>, Sr<sub>2</sub>MgMoO<sub>6</sub>, Ba<sub>2</sub>MgMoO<sub>6</sub>, Ba<sub>2</sub>ZnMoO<sub>6</sub>, and Ba<sub>2</sub>HgWO<sub>6</sub> has been conducted using the Vienna Ab initio Simulation Package and WIEN2K code. Structural analysis reveals the simple cubic crystal structure of double perovskite oxides. Phonon properties indicate the dynamical stability of Sr<sub>2</sub>GeCrO<sub>6</sub>, Ba<sub>2</sub>MgMoO<sub>6</sub>, and Ba<sub>2</sub>ZnMoO<sub>6</sub> compounds. The band structure analysis indicates the metallic character of Sr<sub>2</sub>GeCrO<sub>6</sub>. However, generalized gradient approximation of Perdew–Burke–Ernzerhof and modified Becke–Johnson both suggest the indirect semiconducting nature of Ba<sub>2</sub>MgMoO<sub>6</sub> and Ba<sub>2</sub>ZnMoO<sub>6</sub>. The crystal orbital Hamilton population (–COHP) examination evidences the strongest bonding interactions of O–Ba in these perovskite oxides. Both Ba<sub>2</sub>MgMoO<sub>6</sub> and Ba<sub>2</sub>ZnMoO<sub>6</sub> compounds exhibit p-type character, as indicated by the partial charge density distributions in the highest occupied molecular orbital and lowest unoccupied molecular orbital (LUMO) orbitals, which govern the band edges near Fermi level. LUMO orbitals are located on Mo and O atoms and are composed of heteronuclear s- and p-type interactions. The investigation comprehensively analyzes calculated optoelectronic properties, including complex dielectric function, optical conductivity, loss function, refractive index, and so on. These parameters are examined in detail, offering profound insights into the materials’ optical and electronic characteristics.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking the Potential of Emerging SrZrSe3 Solar Cells with Diverse Inorganic Metal Sulfide Hole Transport Layers 利用多种无机金属硫化物空穴传输层释放新兴SrZrSe3太阳能电池的潜力
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-11-28 DOI: 10.1002/ente.202401459
Eupsy Navis Vincent Mercy, Aruna-Devi Rasu Chettiar, Dhineshkumar Srinivasan, Latha Marasamy
{"title":"Unlocking the Potential of Emerging SrZrSe3 Solar Cells with Diverse Inorganic Metal Sulfide Hole Transport Layers","authors":"Eupsy Navis Vincent Mercy,&nbsp;Aruna-Devi Rasu Chettiar,&nbsp;Dhineshkumar Srinivasan,&nbsp;Latha Marasamy","doi":"10.1002/ente.202401459","DOIUrl":"https://doi.org/10.1002/ente.202401459","url":null,"abstract":"<p>SrZrSe<sub>3</sub> chalcogenide perovskites are being considered as an alternative to lead halide perovskite due to their promising optoelectronic properties. Nevertheless, choosing an hole transport layer (HTL) with optimal band alignment, superior carrier mobility, and low cost remains crucial for stable and efficient solar cells. In this regard, a series of inorganic metal sulfide HTLs such as FeS<sub>2</sub>, WS<sub>2</sub>, TiS<sub>2</sub>, HfS<sub>2</sub>, TaS<sub>2</sub>, and NiS<sub>2</sub> is proposed to unveil its potential for novel SrZrSe<sub>3</sub> absorber via SCAPS-1D by varying the key parameters of electron transport layer, absorber, and HTLs respectively. Interestingly, optimizing their properties boosts the built-in potential up to 1.06 V, resulting in effective separation and transportation of charge carriers toward their respective contacts. Furthermore, it increases absorption up to ≈6.5% by extending the absorption range toward the NIR region (700–850 nm) in all the solar cells. Finally, maximum power conversion efficiency of 21.77, 26.78, 27.60, 27.65, 27.63% with <i>J</i><sub>SC</sub> of ≈29.3 mA cm<sup>−2</sup> and less energy loss of ≈0.3 V for FeS<sub>2</sub>, WS<sub>2</sub>, TiS<sub>2</sub>, HfS<sub>2</sub>, TaS<sub>2</sub>, and NiS<sub>2</sub> solar cells is accomplished. Thus, this work highlights the potential of SrZrSe<sub>3</sub> solar cells with inorganic metal sulfide HTLs and sets the stage for its efficient fabrication.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comprehensive Review on Energy Management Strategies for Fuel-Cell-Based Electric Vehicles 基于燃料电池的电动汽车能源管理策略综述
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-11-25 DOI: 10.1002/ente.202401341
Sandeep Kumar, Ankur Bhattacharjee
{"title":"A Comprehensive Review on Energy Management Strategies for Fuel-Cell-Based Electric Vehicles","authors":"Sandeep Kumar,&nbsp;Ankur Bhattacharjee","doi":"10.1002/ente.202401341","DOIUrl":"https://doi.org/10.1002/ente.202401341","url":null,"abstract":"<p>The rapid growth of the transportation sector in the past few decades has contributed significantly to global warming issues, leading to extensive research on vehicles having nearly zero or total zero tailpipe carbon emissions. The automobiles within this classification belong to hybrid electrical vehicles (HEVs), plug-in HEVs, battery–electric vehicles (BEVs), fuel-cell (FC) EVs (FCEVs), and FC HEVs. FCHEVs are powered by a combination of FC systems, rechargeable batteries, ultracapacitors, and/or mechanical flywheels. FC technology appears to hold potential in terms of extended driving distances and quicker refueling times for vehicles that emit no exhaust fumes. A significant number of research studies have examined various types of energy-storage devices as vehicle power supply, their interfacing with the drive mechanism using power converters and their energy management strategies (EMS). In this article, various EMS  for FC-based EVs are discussed. Classifications of FCEVs, BEVs, and EMSs for FCHEVs are developed by various researchers. In this review report, it is indicated that the existing EMS are capable of performing well, yet further research is required for better reliability and intelligence toward achieving greater fuel efficiency and lifetime of upcoming FCHEVs.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring Ni/Fe Doping for Superior Thermoelectric Performance of Zr2Ni2−xFexSnSb (x = 0.30, 0.35, 0.40) High-Entropy Alloys 定制Ni/Fe掺杂Zr2Ni2−xFexSnSb (x = 0.30, 0.35, 0.40)高熵合金优越热电性能
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-11-25 DOI: 10.1002/ente.202401718
Chalchisa Getachew Adamo, Ashutosh Srivastava, Dipanjan Kumar, Surafel Shiferaw Legese, Punathil Raman Sreeram, Neethu Mohan Mangalassery, Yoshihito Kawamura, Femi Emmanuel Olu, Chandra Sekhar Tiwary, Abhishek Kumar Singh, Kamanio Chattopadhyay
{"title":"Tailoring Ni/Fe Doping for Superior Thermoelectric Performance of Zr2Ni2−xFexSnSb (x = 0.30, 0.35, 0.40) High-Entropy Alloys","authors":"Chalchisa Getachew Adamo,&nbsp;Ashutosh Srivastava,&nbsp;Dipanjan Kumar,&nbsp;Surafel Shiferaw Legese,&nbsp;Punathil Raman Sreeram,&nbsp;Neethu Mohan Mangalassery,&nbsp;Yoshihito Kawamura,&nbsp;Femi Emmanuel Olu,&nbsp;Chandra Sekhar Tiwary,&nbsp;Abhishek Kumar Singh,&nbsp;Kamanio Chattopadhyay","doi":"10.1002/ente.202401718","DOIUrl":"https://doi.org/10.1002/ente.202401718","url":null,"abstract":"<p>Half-Heusler (hH) compounds are emerging as promising materials for thermoelectric applications, owing to their exceptional mechanical and thermal stability, combined with the absence of toxic elements. These characteristics make hH compounds an attractive subject for detailed study and potential use in advanced thermoelectric systems. However, its thermoelectric applicability is limited because of high lattice thermal conductivity (<i>κ</i><sub>l</sub>). Various strategies, such as phase separation, grain-boundary scatterings, and electron–phonon interactions, have been used to reduce <i>κ</i><sub>l</sub>, which enhances phonon scatterings. Recently, high-entropy hH alloys have gained significant attention due to their distorted structure that inherently incorporates high phonon scattering features, addressing the key issue of hH. Herein, hH high-entropy alloys (Zr<sub>2</sub>Ni<sub>2−<i>x</i></sub>Fe<sub><i>x</i></sub>SnSb; <i>x</i> = 0.30, 0.35, 0.40) have been synthesized by arc melting and heat treatment. A significantly reduced lattice thermal conductivities (&lt;2.25 W mK<sup>−1</sup> at 985 K) are obtained due to the presence of multicomponents, which scatter phonon significantly. Experimental observation is very well complimented with density functional theory findings by analyzing phonon dispersions, chemical bonding, group velocities, and anharmonicity. Thereby, it is demonstrated that a high thermoelectric figure of merit is achieved in the proposed hH high-entropy alloys by strengthening the phonon scatterings.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large-Area Perovskite Solar Cells with PTAA/Ag Combination: Performance Evaluation of the Solar Cell via SCAPS 1D Simulation PTAA/Ag复合的大面积钙钛矿太阳能电池:基于SCAPS一维模拟的太阳能电池性能评估
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-11-22 DOI: 10.1002/ente.202400933
Naba Kumar Rana, Tapas Das, Parul Garg, Ashok Bera, Asim Guchhait
{"title":"Large-Area Perovskite Solar Cells with PTAA/Ag Combination: Performance Evaluation of the Solar Cell via SCAPS 1D Simulation","authors":"Naba Kumar Rana,&nbsp;Tapas Das,&nbsp;Parul Garg,&nbsp;Ashok Bera,&nbsp;Asim Guchhait","doi":"10.1002/ente.202400933","DOIUrl":"https://doi.org/10.1002/ente.202400933","url":null,"abstract":"<p>Efficient and stable large-area perovskite solar cells (PSCs) are essential for the translation of the technology. However, the fabrication of large-area PSCs remains very challenging. Uniformity and homogeneity of different layers of a device over a large area are concerning issues. Poly[bis(4-phenyl) (2,4,6-trimethylphenyl) amine] (PTAA) has shown excellency as a hole transport layer (HTL) due to its stability and homogeneity over large areas. This work focuses on large-area (2.0 cm<sup>2</sup>) PSCs using PTAA as HTL with a device structure of FTO/m-TiO<sub>2</sub>/RbCs(MAFA)PbI<sub>3</sub>/PTAA/Ag. This PSC yields a power conversion efficiency (PCE) of 9.35% and retains 72% of the initial PCE even after 2000 h of storage in ambient conditions, which is optimistic for the translation of the technology. The uniformity of the PTAA layer over the large area and proper band alignment at interfaces result in good performance of PSCs. A numerical model is studied for further optimization of this PSC. A large-area monolithic tandem PSC is demonstrated using RbCs (MAFA)PbI<sub>3</sub>/PTAA combination along with a low bandgap perovskite, yielding a PCE of 21.85% with a <i>V</i><sub>OC</sub> of 1.83 V, which is quite significant for an active area of 2 cm<sup>2</sup>. Therefore, this research will aid success in developing effective and stable large-area PSCs.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 3","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143565420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in CdTe Thin-Film Solar Cells: Is Doping an Effective Strategy for Performance Enhancement? CdTe薄膜太阳能电池的进展:掺杂是提高性能的有效策略吗?
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-11-20 DOI: 10.1002/ente.202401542
Ipsita Jena, Udai Pratap Singh
{"title":"Advancements in CdTe Thin-Film Solar Cells: Is Doping an Effective Strategy for Performance Enhancement?","authors":"Ipsita Jena,&nbsp;Udai Pratap Singh","doi":"10.1002/ente.202401542","DOIUrl":"https://doi.org/10.1002/ente.202401542","url":null,"abstract":"<p>Cadmium telluride (CdTe) thin-film solar cells that are introduced in 1970s have emerged as one of the forefront materials of the second generation-based solar cells. They are preferred as an ideal candidate for the fabrication of reliable and economical photovoltaic systems owing to high optical absorption coefficient, nearly optimum bandgap for ensuring maximum conversion efficiency and chemical stability. The major challenges associated with these solar cells are low concentration of carriers, which limits the photovoltaic parameters notably the open-circuit voltage and fill factor as well as short life time of absorber minority carriers. This article explores the pivotal role of doping in enhancing the electrical properties and life time of minority carriers of CdTe solar cells through extensive literature study of the complexity of mechanisms and output parameters achieved in various reported works. Doping has been systematically reviewed with emphasis on types of doping, classification of dopants into group I and group V dopants along with a concise summary of different dopants. This comprehensive review not only evaluates the recent advancements of CdTe solar cells but also addresses these issues and provides future perspectives and paves way for development of improved stable and highly efficient cells.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 3","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143565254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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