Wenjie Zhang, Yang Shang, Hongyu Jiang, Fanxin Meng, Haixia Zhao, Weijie Shi
{"title":"Simulation and Experimental Research on a New Symmetrical Hydraulic Piezoelectric Energy Harvester","authors":"Wenjie Zhang, Yang Shang, Hongyu Jiang, Fanxin Meng, Haixia Zhao, Weijie Shi","doi":"10.1002/ente.202400867","DOIUrl":"https://doi.org/10.1002/ente.202400867","url":null,"abstract":"This study introduces a new symmetrical hydraulic piezoelectric energy harvester. By integrating theoretical analysis, simulation, and empirical testing, the research delves into the energy‐harvesting potential of monolithic single‐side output, monolithic two‐side parallel‐connected output, stacked one‐side parallel‐connected output, and stacked two‐side parallel‐connected output under varying parameter configurations. Additionally, it elucidates the energy dissipation occurring during the energy‐harvesting process of stacked piezoelectric disks. It has been observed that the primary determinant of voltage is the amplitude of pulsation, not the static pressure. Concurrently, the study also addresses the consistency of power generation between multiple channels. A study is made on whether there is a proportional relationship between single‐channel power generation and multi‐channel power generation. The root mean square (RMS) voltage of each connection sharply rises with resistance from 2 to 100 KΩ. It is found that the performance of parallel connection of monolithic piezoelectric disk is better than that of other connection methods. At 3 MPa and 100 Hz, the optimal resistance is 16 KΩ, yielding a maximum average power of 1155.63 μW and an optimal power density of 1.774 μW (bar mm<jats:sup>3</jats:sup>)<jats:sup>−1</jats:sup>. Consequently, the research offers a novel approach to addressing the issue of sustainable energy supply for low‐power electronic devices and sensors.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Novel Self‐Reconfigurable Battery Pack Design with and without Active Cell Balancing","authors":"Anirudha Bajaj, Wei Li, Maokun Xiong, Jianhui Mou, Akhil Garg, Liang Gao, Bibaswan Bose","doi":"10.1002/ente.202401055","DOIUrl":"https://doi.org/10.1002/ente.202401055","url":null,"abstract":"In electric vehicle industry, rechargeable multicell battery packs commonly with fixed configurations are adopted. Such fixed battery configurations have several drawbacks, including limited fault tolerance during unusual operating situations, poor cell state variation management, etc. Thus, this article proposes a self‐reconfigurable battery pack design considering two scenarios: with and without active cell balancing. Herein, the issue of cell state variation is mostly solved by the proposed configuration mode, and further monitoring, control, and protection can be easily appended to accomplish other functionalities, for example, meeting dynamic voltage requirement. Each proposed design is validated by simulation results for a six‐cell polymer lithium‐ion battery pack. The proposed design can maximally utilize the battery's capacity and help to protect cells from over‐charging and over‐discharging as well. This research could be further extended to other application scenarios involving wide‐range dynamic voltage requirements.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Samrudhi B. M., Abdennacer Idrissi, Said Bouzakraoui, Manoj V. Mane, Deepak Devadiga, Ahipa T. N.
{"title":"Theoretical Investigation on Carbazole Derivatives as Charge Carriers for Perovskite Solar Cell","authors":"Samrudhi B. M., Abdennacer Idrissi, Said Bouzakraoui, Manoj V. Mane, Deepak Devadiga, Ahipa T. N.","doi":"10.1002/ente.202400918","DOIUrl":"https://doi.org/10.1002/ente.202400918","url":null,"abstract":"The study explores carbazole‐based organic molecules as transport layers in durable perovskite solar cells, focusing on their optoelectronic and charge transfer properties. Thirteen carbazole derivatives are systematically analyzed via density functional theory (DFT) calculations to understand their structure and optoelectronic characteristics. Substituents like bromo, phenyl, thiophenyl, and pyridyl at positions 3,6‐ and 2,7‐ of carbazole were studied. Phenyl and thiophenyl substitutions lowered highest occupied molecular orbital (HOMO) energy levels, while bromo and pyridyl increased them, tuning HOMO energies from −5.45 to −6.03 eV. These energies align well with perovskite materials valence bands, with absorbance primarily below 400 nm, complementing perovskite absorption. The compounds showed high light‐harvesting efficiencies (LHEs) (0.22 to 0.94) and improved radiative lifetimes. Theoretical investigations identified most compounds as effective p‐type hole‐transport materials (HTM), except 3,6‐ and 2,7‐dithiophenyl carbazoles, which exhibited n‐type behavior due to low hole reorganization energies. Overall, the study highlights computational design's role in developing carbazole derivatives as promising charge carrier precursors for perovskite solar cells.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ultrasmall Fe‐Nanoclusters‐Anchored Carbon Polyhedrons Interconnected with Carbon Nanotubes for High‐Performance Zinc‐Air Batteries","authors":"Haihua Wu, Feng Wu, Juanjuan Zhai, Yudan Li, Xin Xu, Yunfang Gao","doi":"10.1002/ente.202401339","DOIUrl":"https://doi.org/10.1002/ente.202401339","url":null,"abstract":"The catalytic activity of metal catalyst is closely related to its particle size. Yet, the size effect in electrocatalytic oxygen reduction reaction (ORR), an important reaction for metal‐air batteries and fuel cells, has not been clearly studied. Herein, a two‐step anchoring method is utilized to control the Fe catalyst in forms of nanoparticles (NPs), ultrasmall nanoclusters (NCTs), and isolated atoms as well as stabilized and dispersed by carbon polyhedrons interconnected with carbon nanotubes (CNTs). The uniformly distributed Fe NCTs displays superior ORR performance compared with Fe NPs, isolated Fe atoms, and commercial Pt/C. The brilliant ORR activity of Fe NCTs is a result of its unique electron structure and abundant edge and corner active sites. Due to the porous structure of carbon polyhedrons and high electron conductivity of CNTs, Fe NCTs also delivers an excellent discharge performance in zinc‐air battery with a peak power density of 213.3 mW cm<jats:sup>−2</jats:sup> and long‐term stability. In these findings, a new strategy for the design of metal NCTs catalysts applied in various catalytic reactions is opened up.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"State of Health Estimation of Lithium‐Ion Batteries Based on Differential Thermal Voltammetry and Improved Gray Wolf Optimizer Optimizing Gaussian Process Regression","authors":"Peng Xu, Wenwen Ran, Yuan Huang, Yongtai Xiang, Yuhong Liu, Kelin Xiao, Chaolin Xu, Shibin Wan","doi":"10.1002/ente.202400996","DOIUrl":"https://doi.org/10.1002/ente.202400996","url":null,"abstract":"Accurate estimation of the state of health (SOH) of lithium‐ion batteries (LIBs) is essential for their safe operation. Therefore, herein, a novel approach that combines Gaussian process regression (GPR) optimized using an improved gray wolf optimizer (IGWO) with differential thermal voltammetry (DTV) is introduced. In this approach, the peak and valley information of the DTV curves are used to reveal the battery‐aging mechanisms, with the slopes and durations between peaks and valleys used as health characteristics. The correlation between the characteristics and SOH of the battery is analyzed to build a health feature dataset. IGWO optimizes the GPR hyperparameters to address their dependence on the initial values and susceptibility to local optimization and employs a dimension‐learning strategy to enhance the population diversity and prevent premature convergence. DTV curves and an IGWO‐GPR model for SOH estimation using four cells from the NASA LIB public aging dataset are developed and validated. The results show root mean square errors below 0.007 and mean absolute errors under 0.006 for all cells. The coefficient of determination exceeds 0.92 for three cells, with one battery exhibiting a value of 0.866. This method provides accurate and efficient SOH estimation, essential for safe battery operation.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research Progress on Characteristics of On‐Line Hydrogen Production by Methanol Steam Reforming","authors":"Bin Chen, Zonghua Wang","doi":"10.1002/ente.202400987","DOIUrl":"https://doi.org/10.1002/ente.202400987","url":null,"abstract":"On‐line hydrogen production via methanol steam reforming (MSR) has gained considerable interest due to its high efficiency, affordability, and eco‐friendliness. Currently, this technology has been widely applied in the industry and has become an important method for hydrogen energy production. However, there are still some issues with this technology, such as short catalyst lifespan and CO pollution, which require further research and improvement. This article provides a comprehensive review of the research progress made in this field, with a particular focus on the catalyst development, reaction mechanism, theoretical calculation, and reactor design. Additionally, the challenges and prospects of on‐line hydrogen production by MSR are also discussed. In conclusion, MSR technology for hydrogen production has vast application prospects and development potential. It will be further explored in‐depth and extensively in future research.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nitrogen and Oxygen Dual‐Doped Carbon as High‐Rate Long‐Cycle‐Life Anode Materials for Lithium‐Ion Batteries","authors":"Yuxiu Li, Yanjun Cai, Qianying Jiang, Yanshan Wu, Qiwei Wu, Yue Zhang, Zhi Su","doi":"10.1002/ente.202401211","DOIUrl":"https://doi.org/10.1002/ente.202401211","url":null,"abstract":"Defect‐type carbon, doped with nitrogen and oxygen, is synthesized using the high‐temperature solid‐phase method. X‐ray photoelectron spectroscopy analysis reveals the presence of nitrogen, including pyridine nitrogen, pyrrole nitrogen, and graphitized nitrogen, incorporated into the carbon structure. Additionally, oxygen is introduced into carbon, with both CO and CO functionalities are observed. Transmission electron microscopy and scanning electron microscopy indicate that all samples exhibit a morphology of carbon microblocks with localized turbocharged lattice regions. Electrochemical tests demonstrate that the nitrogen‐ and oxygen‐doped carbon microblocks exhibit excellent cycling performance and high rate capacity. Specifically, at current densities of 1 and 2 A g<jats:sup>−1</jats:sup>, the rate capacity remains at 385.6 and 214.4 mA h g<jats:sup>−1</jats:sup>, respectively. Furthermore, the discharge capacity at 5 A g<jats:sup>−1</jats:sup> remains at 58.3 mA h g<jats:sup>−1</jats:sup> on the 3500th cycle. The defects introduced by nitrogen and oxygen doping not only enhance reactivity and electronic conductivity but also improve lithium‐ion diffusion dynamics.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ekaterina V. Astrova, Irina Yu Sapurina, Alesya V. Parfeneva, Galina V. Li, Alexey V. Nashchekin, Darina A. Lozhkina, Aleksander M. Rumyantsev
{"title":"Nanocomposites for Lithium‐Ion Battery Anodes Made of Silicon and Polyaniline Doped with Phytic Acid","authors":"Ekaterina V. Astrova, Irina Yu Sapurina, Alesya V. Parfeneva, Galina V. Li, Alexey V. Nashchekin, Darina A. Lozhkina, Aleksander M. Rumyantsev","doi":"10.1002/ente.202401156","DOIUrl":"https://doi.org/10.1002/ente.202401156","url":null,"abstract":"The properties of lithium‐ion battery (LIB) anodes fabricated from nanoscale silicon Si and polyaniline (PANI) as a binder are reported. PANI is prepared by in situ polymerization of aniline in the presence of phytic acid, which serves both as dopant and as a gel‐forming agent. PANI pellets obtained by dry compression are used to investigate the morphology and to measure the resistivity of PANI and Si/PANI composites. The anodes are fabricated using the slurry technique. Their properties as a function of precursor ratio are studied in the half‐cell cells by charge–discharge characteristics, cyclic voltammetry, electrochemical impedance spectroscopy and cyclic lifetime. It is shown that stable cycling (>350 cycles at a current of 300 mA g<jats:sup>−1</jats:sup>) is inherent only to thin Si/PANI layers with composite loading <0.7 mg cm<jats:sup>−2</jats:sup>. The discharge capacity in this case is as high as 500–800 mAh g<jats:sup>−1</jats:sup>.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Organic and Inorganic Photoactive Absorbers for Wavelength‐Selective Transparent Photovoltaic Devices: Focus Review","authors":"Terence K. S. Wong","doi":"10.1002/ente.202400961","DOIUrl":"https://doi.org/10.1002/ente.202400961","url":null,"abstract":"The present status of wavelength‐selective transparent photovoltaic (TPV) devices for green buildings and self‐powered wireless sensors is comprehensively reviewed. Photoactive absorbers for both UV and near‐infrared (NIR)‐selective TPV are discussed. UV‐selective devices based on engineered small organic molecules have demonstrated high transparency (>80%). However, their power conversion efficiency (PCE) is ≈1%. Higher PCE of 3.15% and transparency of 51.4% are obtained from the bulk heterojunction (BHJ) of a wide energy gap conjugated polymer and nonfullerene acceptor (NFA). The highest transparency of 84.6% together with device stability and scalability is realized for CsPbCl<jats:sub>2.5</jats:sub>Br<jats:sub>0.5</jats:sub> perovskite absorbers. The few reported NIR‐selective TPV devices are all organic solar cells. Using BHJs comprising ultranarrow energy gap conjugated polymer and NFA, a PCE of 5.74% and transparency of ≈60% can be obtained. However, current IR‐selective devices are generally limited by an absorption tail that encroaches into the visible region and result in suboptimal color rendering. To address this, a new spectral range ratio (SRR) parameter is proposed to classify absorbers for IR‐selective TPV devices. A molecular design strategy to increase the SRR based on frontier molecular orbital theory is outlined.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ang Li, Chengliang Fan, Hongjie Tang, Zutao Zhang, Genshuo Liu, Linyang He, Jie Zhao, Jianhong Zhou, Yongli Hu
{"title":"Smart Railway Transportation: Self‐Powered and Self‐Sensing Vibration Energy Harvester","authors":"Ang Li, Chengliang Fan, Hongjie Tang, Zutao Zhang, Genshuo Liu, Linyang He, Jie Zhao, Jianhong Zhou, Yongli Hu","doi":"10.1002/ente.202401253","DOIUrl":"https://doi.org/10.1002/ente.202401253","url":null,"abstract":"Safety monitoring sensors in smart railways need a sustainable onboard power supply. This article proposes a counter‐rotating gear energy harvester (CG‐EH) to convert the longitudinal vibration energy of trains into electricity for onboard sensors.CG‐EH consists of a vibration input module, a motion conversion module, and an energy conversion module. The vibration input module converts the longitudinal displacement of the coupler into the rotational motion of the gears. The motion conversion module realizes the conversion of the reciprocating input displacement into the unidirectional rotation based on a counter‐rotating gear set, multi‐stage spur gear sets can effectively mitigate the effects of excitation on CG‐EH. The energy conversion module transforms the kinetic energy of the unidirectional rotation into electrical energy through a generator. Experimental results show that the energy outputs of CG‐EH are improved with longitudinal vibration compared with the usual onboard energy harvester. From the result, the peak output power of CG‐EH is 14.59 W, the peak efficiency reaches 39.2%, enough to power relevant onboard sensors. Moreover, CG‐EH can monitor the running status of trains based on deep learning. From the experiment results and application prospects, CG‐EH is a favorable solution for the power supply problems of onboard sensors in smart railways.","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":null,"pages":null},"PeriodicalIF":3.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}