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Sol–Gel Synthesis of CuO Nanoparticles and Its Use as Catalyst for Electrochemical CO2 Reduction
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-27 DOI: 10.1002/ente.202401486
Xuan T. Mai, Tuan M. Duong, Duc N. Nguyen, Tung H. To, Hoang H. Luc, Phong D. Tran, Ly T. Le
{"title":"Sol–Gel Synthesis of CuO Nanoparticles and Its Use as Catalyst for Electrochemical CO2 Reduction","authors":"Xuan T. Mai,&nbsp;Tuan M. Duong,&nbsp;Duc N. Nguyen,&nbsp;Tung H. To,&nbsp;Hoang H. Luc,&nbsp;Phong D. Tran,&nbsp;Ly T. Le","doi":"10.1002/ente.202401486","DOIUrl":"https://doi.org/10.1002/ente.202401486","url":null,"abstract":"<p>\u0000Copper and copper-based catalysts have been recognized as attractive heterogeneous catalysts for electrochemical CO<sub>2</sub> reduction. Herein, the synthesis of copper oxide (CuO) nanoparticles via a sol–gel process using agar as the dispersant agent followed by thermal annealing at 400, 600, and 800 °C is reported on. Evolution of chemical composition, morphology, and crystallinity of CuO nanoparticles in function the annealing temperature is examined. These CuO nanoparticles are assayed as catalysts for the CO<sub>2</sub> electrochemical reduction in a 0.1 <span>m</span> NaHCO<sub>3</sub> or 0.1 <span>m</span> KHCO<sub>3</sub> solution saturated with CO<sub>2</sub>, generating hydrogen, carbon monoxide, formate, and acetate as products. Among the CuO catalysts assayed, the CuO-400 sample obtained at the annealing temperature of 400 °C leads to the highest formate production selectivity with a Faradaic efficiency of 26% at −0.9 V versus reversible hydrogen electrode.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143119920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Red-Phosphorus-Based Anode Materials for Sodium-Ion Batteries: Challenges and Progress
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-26 DOI: 10.1002/ente.202401320
Zhen Han, Xiaoxue Yang, Hao Yao, Chaoyang Ran, Chunxi Guan, Ke Lu, Chunliang Yang, Lin Fu
{"title":"Red-Phosphorus-Based Anode Materials for Sodium-Ion Batteries: Challenges and Progress","authors":"Zhen Han,&nbsp;Xiaoxue Yang,&nbsp;Hao Yao,&nbsp;Chaoyang Ran,&nbsp;Chunxi Guan,&nbsp;Ke Lu,&nbsp;Chunliang Yang,&nbsp;Lin Fu","doi":"10.1002/ente.202401320","DOIUrl":"https://doi.org/10.1002/ente.202401320","url":null,"abstract":"<p>The shortage of lithium resources is widely recognized as a key factor that affects the further development of lithium-ion batteries (LIBs). The sodium (Na) has abundant resources in the earth's crust and its physicochemical properties are similar to Li, which ensure that sodium-ion batteries (SIBs) are considered as a substitute for LIBs in certain fields. Unfortunately, the lower energy density of SIBs limits its application range. Therefore, studying high specific capacity anode materials to improve the energy density of batteries is an important direction of SIBs. Red-phosphorus (P)-based anode materials are ideal candidates for high energy density SIBs because of their high theoretical specific capacity and suitable working voltage. However, the red-P-based anode materials for SIBs meet intractable challenges in terms of the poor electrical conductivity and huge volume changes during cycling, resulting in inferior electrochemical performances. In this article, the research progress of red-P-based anode material for SIBs in recent years, including the red-P/carbon composite, element-doped composite, metal phosphide, and stable interface design, is reviewed. Herein, the decisive role is highlighted that composite design with highly conductive carbon materials plays in addressing the challenges associated with red-P-based anodes and a perspective on their development direction is given.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143119410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deionized Water Pretreated Polyimide Nanofiber Membranes as Framework for Polymer Electrolytes Applied to Solid-State Lithium Metal Batteries
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-26 DOI: 10.1002/ente.202401308
Yongqi Liu, Zijian Chen, Haoyu Li, Junyu Hu, Zhengbing Xu, Jinliang Zhu
{"title":"Deionized Water Pretreated Polyimide Nanofiber Membranes as Framework for Polymer Electrolytes Applied to Solid-State Lithium Metal Batteries","authors":"Yongqi Liu,&nbsp;Zijian Chen,&nbsp;Haoyu Li,&nbsp;Junyu Hu,&nbsp;Zhengbing Xu,&nbsp;Jinliang Zhu","doi":"10.1002/ente.202401308","DOIUrl":"https://doi.org/10.1002/ente.202401308","url":null,"abstract":"<p>Incorporating a water-immersed polyimide membrane (WPI) as a framework into a polymer electrolyte PEO/SN/LiTFSI (PSL) can address the challenges faced by solid-state polymer electrolytes in practical applications for all-solid-state lithium-ion batteries (ASSLIBs) used in flexible and wearable electronics. The inferior mechanical performance and inadequate ionic conductivity of polymer electrolytes have hampered their widespread use. By utilizing a matrix of polyethylene oxide (PEO) along with succinonitrile (SN) and lithium bis(trifluoromethane)sulfonimide (LiTFSI) as additives, the WPI enhances the stability of the PSL electrolyte structure through reinforced internal hydrogen bonds of poly(amic acid), its precursor, post-thermal imidization in the presence of deionized water. This structural enhancement leads to improved mechanical properties, evidenced by a tensile strength of 12.2 MPa at a high porosity of 85.6%. The WPI-PSL electrolyte exhibits favorable ionic conductivity, thermal stability, and electrochemical compatibility with lithium metal. As a result, the WPI-PSL configuration demonstrates exceptional performance in a LiFePO<sub>4</sub>/Li ASSLIBs system, showcasing outstanding cycling performance at both 30 and 60 °C, with capacity retention ratios reaching 94.6% and 96% after 100 cycles at 0.3 C, respectively. This research significantly advances the development of polymer solid-state electrolytes, propelling their use in flexible power sources for ASSLIBs.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143119409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust and Highly Stretchable Ionic Conductive Thermoplastic Elastomers Prepared via Easily Scalable Melt Transesterification and Melt Blending for Flexible Triboelectric Nanogenerators 通过易于扩展的熔融酯交换和熔融共混制备用于柔性三电纳米发电机的坚固且高度可拉伸的离子导电热塑性弹性体
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-25 DOI: 10.1002/ente.202400834
Dongguang Yan, Chengyu Gu, Xinrui Pi, Yingqiang Fan, Bingbing Feng, Tianhao Li, Tianran Deng, Guanggui Cheng
{"title":"Robust and Highly Stretchable Ionic Conductive Thermoplastic Elastomers Prepared via Easily Scalable Melt Transesterification and Melt Blending for Flexible Triboelectric Nanogenerators","authors":"Dongguang Yan,&nbsp;Chengyu Gu,&nbsp;Xinrui Pi,&nbsp;Yingqiang Fan,&nbsp;Bingbing Feng,&nbsp;Tianhao Li,&nbsp;Tianran Deng,&nbsp;Guanggui Cheng","doi":"10.1002/ente.202400834","DOIUrl":"https://doi.org/10.1002/ente.202400834","url":null,"abstract":"<p>In recent years, the rapid advancement of self-powered wearable electronic devices has propelled the research focus toward flexible electrodes for single electrode triboelectric nanogenerators (STENG). However, there is currently a lack of reported methods for large-scale preparation and high-efficiency molding of these flexible electrodes. In this study, PBAT<i>-co</i>-PEG/NaSCN blends-based ionic conductive thermoplastic elastomer (ICTE) are successfully prepared by initially conducting melt transesterification, followed by melt blending. The STENG, featuring an ICTE electrode, exhibited a remarkable open-circuit voltage of 50 V, short-circuit current of 460 nA and charge transfer of 16 nC. With the aid of Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC), the conduction mechanism of ICTE is elucidated. Due to good fluidity and processing performance, bars of ICTE suitable for mechanical properties test could be conveniently prepared via injection molding, which demonstrates the tensile strength and elongation, 13 MPa and 2500%, respectively. A 4 × 4 cm<sup>2</sup> STENG fabricated with ICTE electrode could not only have good energy-harvesting performance but also could be used in a sensor to sense the motion detection. The ICTE, with its simple and environmentally friendly preparation process and high-efficiency molding, exhibits a promising prospect in the large-scale preparation and application of flexible STENG.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"12 12","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental Investigation of the Process and Product Parameter Pressure, Temperature, and Aspect Ratio on the Wetting Behavior of Lithium-Ion Battery Cells
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-24 DOI: 10.1002/ente.202401338
Nicolaj Kaden, Weihan Guo, Mats Göhrmann, Tobias Koch, Jincai Cheng, Do Minh Nguyen, Ricarda Schlimbach, Klaus Dröder
{"title":"Experimental Investigation of the Process and Product Parameter Pressure, Temperature, and Aspect Ratio on the Wetting Behavior of Lithium-Ion Battery Cells","authors":"Nicolaj Kaden,&nbsp;Weihan Guo,&nbsp;Mats Göhrmann,&nbsp;Tobias Koch,&nbsp;Jincai Cheng,&nbsp;Do Minh Nguyen,&nbsp;Ricarda Schlimbach,&nbsp;Klaus Dröder","doi":"10.1002/ente.202401338","DOIUrl":"https://doi.org/10.1002/ente.202401338","url":null,"abstract":"<p>The production of lithium-ion batteries (LIBs) is crucial for advancing energy-storage technologies, yet uncertainties remain regarding key influencing factors along the process chain. Specifically, the electrolyte filling process is critical for optimal cell performance. In this study, the unknown effects of differential pressure, different temperature for the materials, and the geometrical cell design are investigated through the aspect ratio (lengths to height ratio) on the wetting behavior of LIB cells. Using a custom-designed test stand, impedance change |ż| at 1 Hz is measured during electrolyte dispensing and wetting while varying temperature, pressure, and the cells’ aspect ratio. In the results, it is indicated that lower evacuation pressures significantly increase the wetting rate, reducing wetting durations. Higher differential pressures enhance wetting efficiency by compressing the electrode-separator composite (ESC) materials. Elevated electrolyte temperatures decrease viscosity, resulting in faster wetting times. Temperature variations between the ESC material and electrolyte lead to heat equalization, with no discernible impact on partial gas pressure. Additionally, increased aspect ratios in cell design reduce wetting times due to shorter distances for the wetting front to travel. In these findings, valuable insights are provided for optimizing battery cell manufacturing, contributing to improved efficiency and performance in next-generation battery technologies.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ente.202401338","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143119087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of Ionomer for High-Performance Self-Humidifying Air-Breathing Proton-Exchange Membrane Fuel Cells in Portable Device Power Systems
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-24 DOI: 10.1002/ente.202400445
Junho Kim, Hee Ji Choi, Hyukjae Choi, Sun Young Kang, Hosung Choi, Chi-Yeong Ahn, Yunho Kim, Ilchai La, Ok-Hee Kim, Yong-Hun Cho, Yung-Eun Sung
{"title":"Optimization of Ionomer for High-Performance Self-Humidifying Air-Breathing Proton-Exchange Membrane Fuel Cells in Portable Device Power Systems","authors":"Junho Kim,&nbsp;Hee Ji Choi,&nbsp;Hyukjae Choi,&nbsp;Sun Young Kang,&nbsp;Hosung Choi,&nbsp;Chi-Yeong Ahn,&nbsp;Yunho Kim,&nbsp;Ilchai La,&nbsp;Ok-Hee Kim,&nbsp;Yong-Hun Cho,&nbsp;Yung-Eun Sung","doi":"10.1002/ente.202400445","DOIUrl":"https://doi.org/10.1002/ente.202400445","url":null,"abstract":"<p>This study investigates the impact of ionomer types and content in the catalyst layer on the performance of proton exchange membrane fuel cells (PEMFCs) under room temperature and atmospheric pressure. Four commercially available ionomers with varying equivalent weights (EWs) and side-chain lengths are evaluated as catalyst layer binders in membrane-electrode assemblies (MEAs). The assessments are conducted at room temperature and ambient pressure without additional humidification, focusing on understanding the distinctive characteristics of each ionomer. In addition, this study investigates the prospective application of an air-breathing passive-type cell, dependent exclusively on natural convection for air supply. The notable performance of the passive-type cell shown in this study indicates its suitability as a compact mobile power source, especially for drone applications. Furthermore, the stability of various ionomer binders is also compared to establish a correlation between EW and side-chain length of ionomer binder stability. Overall, the findings will serve as a valuable reference for optimizing ionomer selection and composition in specialized applications for powering portable devices.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ente.202400445","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143119085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Research Advancement of High-Temperature Dense Membrane Materials for Hydrogen Separation
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-23 DOI: 10.1002/ente.202400233
Jianqiu Zhu, Xurui Huang, Jinyong Lei, Peng Du, Yuxuan Zhang, Zhiwei Hu, Xiangyong Zhao, Jian-Qiang Wang, Linjuan Zhang
{"title":"The Research Advancement of High-Temperature Dense Membrane Materials for Hydrogen Separation","authors":"Jianqiu Zhu,&nbsp;Xurui Huang,&nbsp;Jinyong Lei,&nbsp;Peng Du,&nbsp;Yuxuan Zhang,&nbsp;Zhiwei Hu,&nbsp;Xiangyong Zhao,&nbsp;Jian-Qiang Wang,&nbsp;Linjuan Zhang","doi":"10.1002/ente.202400233","DOIUrl":"https://doi.org/10.1002/ente.202400233","url":null,"abstract":"<p>Hydrogen separation and purification technologies are crucial for hydrogen energy development. Dense membranes with efficient proton–electron conduction are notable for their effective hydrogen separation and purification from gas mixtures produced by large-scale steam reforming. However, the limited understanding of the functions of various materials in hydrogen separation membranes has hindered their development. In this article, the physical and chemical properties of various materials are introduced, the impact of each on single–phase hydrogen separation membranes is analyzed, and the synergistic effects of multiple materials in two-phase membranes are discussed. Herein, the mechanisms of hydrogen separation are elucidated and the proton and electron transfer within these membranes is described. Additionally, hydrogen transport in ceramic membranes is analyzed and the methods to prevent hydrogen leakage during separation are discussed. Finally, suggestions for the development of hydrogen separation membranes are proposed. In this review, it is aimed to summarize existing knowledge and promote innovation in this field.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143118468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tracing Root Causes of Electric Vehicle Fires 追踪电动汽车火灾的根本原因
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-23 DOI: 10.1002/ente.202400931
Zhenqian Zhang, Honglei Dong, Li Wang, Yan Wang, Xiangming He
{"title":"Tracing Root Causes of Electric Vehicle Fires","authors":"Zhenqian Zhang,&nbsp;Honglei Dong,&nbsp;Li Wang,&nbsp;Yan Wang,&nbsp;Xiangming He","doi":"10.1002/ente.202400931","DOIUrl":"https://doi.org/10.1002/ente.202400931","url":null,"abstract":"<p>As electric vehicles (EVs) emerge as the backbone of modern transportation, the concurrent uptick in battery fire incidents presents a disconcerting challenge. To tackle this issue effectively, it is imperative to pierce beyond the superficial causes of lithium-ion battery (LIB) failures—such as equipment malfunctions or physical damage—and to excavate the underlying triggers. This nuanced approach is pivotal to refining EV quality, diminishing fire incidents, and bolstering consumer trust. While issues that are readily apparent to consumers, like spontaneous battery degradation, vehicular collisions, or submersion, may seem like the primary culprits, they merely scratch the surface of a more complex problem. The true mechanisms behind these fires involve internal and external short circuits, yet these explanations fall short in providing actionable guidance for manufacturers or end-users to enhance LIB safety. The heart of the issue is identifying the root causes that bridge failure triggers and resulting fires. A total of 20 root causes are identified, linking them to real-world scenarios like overcharging causing internal shorts or wire harness issues leading to external shorts. With this insight, stakeholders can more effectively investigate and understand EV LIB fire incidents, bolstering EV safety and reliability, and promoting consumer confidence.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"12 12","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D Biomass-Based Interfacial Solar Steam Generation: Component, Optimization, and Application 3D生物质界面太阳能蒸汽发电:组件、优化和应用
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-23 DOI: 10.1002/ente.202401261
Xiahui Liu, Ting Shu, Tao Liu, Yuliang Zhang
{"title":"3D Biomass-Based Interfacial Solar Steam Generation: Component, Optimization, and Application","authors":"Xiahui Liu,&nbsp;Ting Shu,&nbsp;Tao Liu,&nbsp;Yuliang Zhang","doi":"10.1002/ente.202401261","DOIUrl":"https://doi.org/10.1002/ente.202401261","url":null,"abstract":"<p>The seawater desalination and wastewater treatment by the interfacial solar steam generation (ISSG) technique is considered as a green, economical, sustainable, low-energy-consumption, and potential fresh water production strategy to solve the water shortage and energy crisis. Recently, efficient biomass-based ISSGs (BISSGs) have been widely reported due to its efficient photothermal conversion efficiency and good hydrophilic performance. The BISSGs with efficient solar absorption and water transmission performance by design and optimization their various forms and structures and related photothermal properties is also significantly great for its scale application. This review highlights recent advancements in 3D BISSG systems, with a focus on the design and optimization of photothermal conversion materials and substrate materials. Then, the review also discusses the potential of biomass materials in BISSG applications, aiming to provide a theoretical basis for developing cost-effective, efficient, and sustainable water purification technologies. Finally, the challenges and development prospects of the BISSG system in basic research and practical application will provide theoretical guidance for the further development of this technology.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"12 12","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research Progress in Dielectric Properties of Inorganic Two-Dimensional Nano-Fillers Polyvinylidene Fluoride Nano-Dielectric Materials 无机二维纳米填料聚偏氟乙烯纳米介电材料的介电性能研究进展
IF 3.6 4区 工程技术
Energy technology Pub Date : 2024-09-19 DOI: 10.1002/ente.202400967
Jinqi Qin, Hongwei Lu, Shijia Yang, Weitao Su, Yu Xing
{"title":"Research Progress in Dielectric Properties of Inorganic Two-Dimensional Nano-Fillers Polyvinylidene Fluoride Nano-Dielectric Materials","authors":"Jinqi Qin,&nbsp;Hongwei Lu,&nbsp;Shijia Yang,&nbsp;Weitao Su,&nbsp;Yu Xing","doi":"10.1002/ente.202400967","DOIUrl":"https://doi.org/10.1002/ente.202400967","url":null,"abstract":"<p>Two-dimensional (2D) nanofillers can effectively improve the performance of nano-dielectrics by having larger aspect ratios and larger electron-scattering interfaces than one-dimensional (1D) nanofillers and zero-dimensional (0D) nanofillers; the formation of a large interfacial area in the polymer matrix effectively traps or scatters the mobile charges and increases the curvature of the propagation paths of the electric tree, thus effectively increasing the breakdown strength and the energy-storage density of nanodielectrics. In this article, the intrinsic mechanism of 2D nanodielectrics is elaborated using percolation theory, microcapacitance theory, interfacial model, and ping-pong racket model. Surface modification, oriented alignment, and multilayer structural design are reviewed to enhance the dielectric properties of nanodielectrics. Additionally, an outlook on the multiple challenges and potential opportunities in the process of preparing energy-storage capacitors with excellent performance is provided.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"12 12","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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