Critical reviews in analytical chemistry最新文献

{"title":"Spectrum-Effect Relationship in Chinese Herbal Medicine: Current Status and Future Perspectives.","authors":"Si Li, Xi Huang, Yuan Li, Rong Ding, Xuemei Wu, Ling Li, Canlin Li, Rui Gu","doi":"10.1080/10408347.2023.2290056","DOIUrl":"10.1080/10408347.2023.2290056","url":null,"abstract":"<p><p>The quality of Chinese herbal medicine (CHM) directly impacts clinical efficacy and safety. Fingerprint technology is an internationally recognized method for evaluating the quality of CHM. However, the existing quality evaluation models based on fingerprint technology have blocked the ability to assess the internal quality of CHM and cannot comprehensively reflect the correlation between pharmacodynamic information and active constituents. Through mathematical methods, a connection between the \"Spectrum\" (fingerprint) and the \"Effect\" (pharmacodynamic data) was established to conduct a spectrum-effect relationship (SER) of CHM to unravel the active component information associated with the pharmacodynamic activity. Consequently, SER can efficiently address the limitations of the segmentation of chemical components and pharmacodynamic effect in CHM and further improve the quality evaluation of CHM. This review focuses on the recent research progress of SER in the field of CHM, including the establishment of fingerprint, the selection of data analysis methods, and their recent applications in the field of CHM. Various advanced fingerprint techniques are introduced, followed by the data analysis methods used in recent years are summarized. Finally, the applications of SER based on different research subjects are described in detail. In addition, the advantages of combining SER with other data are discussed through practical applications, and the research on SER is summarized and prospected. This review proves the validity and development potential of the SER and provides a reference for the development and application of quality evaluation methods for CHM.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"353-374"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138828606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Performance Liquid Chromatography Methods for Determining the Purity of Drugs with Weak UV Chromophores - A Review.","authors":"Elżbieta Sobolewska, Magdalena Biesaga","doi":"10.1080/10408347.2023.2291815","DOIUrl":"10.1080/10408347.2023.2291815","url":null,"abstract":"<p><p>High-performance liquid chromatography (HPLC) is one of the most useful techniques for the separation and determination of new drugs with a complex nature. The selection of an HPLC detector depends on the chemical nature of molecules, potential impurities, matrix of the sample, sensitivity, availability, and/or cost of the detector. HPLC methods with UV/Vis detectors are the most used and simple analytical procedures in pharmaceutical applications, but it is limited to compounds that possess a chromophore. Hence, this review provides an overview on the development of analytical methods for compounds with weak chromophores. The review described selected papers about HPLC based methods in the PubMed, Scopus, Semantic Scholar and ScienceDirect databases, basically between 2006 and 2023. Of the analytical studies, the HPLC methods with UV-Vis, FLD, CAD, ELSD, RID, ECD, CLND and MS detection were found. This study is a comparison of different types of detection that are described in scientific literature and are routinely used for compounds with weak chromophores. It is expected that this review will be helpful for scientists in the analytical development fields to improve research related to the drug candidates and to ensure its quality according to regulatory levels.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"419-433"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139097522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unlocking the Hidden Depths: Multi-Modal Integration of Imaging Mass Spectrometry-Based and Molecular Imaging Techniques.","authors":"Behnaz Akbari, Bertrand Russell Huber, Janet Hope Sherman","doi":"10.1080/10408347.2023.2266838","DOIUrl":"10.1080/10408347.2023.2266838","url":null,"abstract":"<p><p>Multimodal imaging (MMI) has emerged as a powerful tool in clinical research, combining different imaging modes to acquire comprehensive information and enabling scientists and surgeons to study tissue identification, localization, metabolic activity, and molecular discovery, thus aiding in disease progression analysis. While multimodal instruments are gaining popularity, challenges such as non-standardized characteristics, custom software, inadequate commercial support, and integration issues with other instruments need to be addressed. The field of multimodal imaging or multiplexed imaging allows for simultaneous signal reproduction from multiple imaging strategies. Intraoperatively, MMI can be integrated into frameless stereotactic surgery. Recent developments in medical imaging modalities such as magnetic resonance imaging (MRI), and Positron Emission Topography (PET) have brought new perspectives to multimodal imaging, enabling early cancer detection, molecular tracking, and real-time progression monitoring. Despite the evidence supporting the role of MMI in surgical decision-making, there is a need for comprehensive studies to validate and perform integration at the intersection of multiple imaging technologies. They were integrating mass spectrometry-based technologies (e.g., imaging mass spectrometry (IMS), imaging mass cytometry (IMC), and Ion mobility mass spectrometry ((IM-IM) with medical imaging modalities, offering promising avenues for molecular discovery and clinical applications. This review emphasizes the potential of multi-omics approaches in tissue mapping using MMI integrated into desorption electrospray ionization (DESI) and matrix-assisted laser desorption ionization (MALDI), allowing for sequential analyses of the same section. By addressing existing knowledge gaps, this review encourages future research endeavors toward multi-omics approaches, providing a roadmap for future research and enhancing the value of MMI in molecular pathology for diagnosis.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"109-138"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41233059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Analytical Methods for the Determination of Quercetin and Quercetin Glycosides in Pharmaceuticals and Biological Samples.","authors":"Fotouh R Mansour, Inas A Abdallah, Alaa Bedair, Mahmoud Hamed","doi":"10.1080/10408347.2023.2269421","DOIUrl":"10.1080/10408347.2023.2269421","url":null,"abstract":"<p><p>Flavonoids are plant-derived compounds that have several health benefits, including antioxidative, anti-inflammatory, anti-mutagenic, and anti-carcinogenic effects. Quercetin is a flavonoid that is widely present in various fruits, vegetables, and drinks. Accurate determination of quercetin in different samples is of great importance for its potential health benefits. This review, is an overview of sample preparation and determination methods for quercetin in diverse matrices. Previous research on sample preparation and determination methods for quercetin are summarized, highlighting the advantages and disadvantages of each method and providing insights into recent developments in quercetin sample treatment. Various analytical techniques are discussed including spectroscopic, chromatographic, electrophoretic, and electrochemical methods for the determination of quercetin and its derivatives in different samples. UV-Vis (Ultraviolet-visible) spectrophotometry is simple and inexpensive but lacks selectivity. Chromatographic techniques (HPLC, GC) offer selectivity and sensitivity, while electrophoretic and electrochemical methods provide high resolution and low detection limits, respectively. The aim of this review is to comprehensively explore the determination methods for quercetin and quercetin glycosides in diverse matrices, with emphasis on pharmaceutical and biological samples. The review also provides a theoretical basis for method development and application for the analysis of quercetin and quercetin glycosides in real samples.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"187-212"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71411025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hair and Nail-On-Chip for Bioinspired Microfluidic Device Fabrication and Biomarker Detection.","authors":"Rohitraj Ray, Amith Rakesh, Sheetal Singh, Harishkumar Madhyastha, Naresh Kumar Mani","doi":"10.1080/10408347.2023.2291825","DOIUrl":"10.1080/10408347.2023.2291825","url":null,"abstract":"<p><p>The advent of biosensors has tremendously increased our potential of identifying and solving important problems in various domains, ranging from food safety and environmental analysis, to healthcare and medicine. However, one of the most prominent drawbacks of these technologies, especially in the biomedical field, is to employ conventional samples, such as blood, urine, tissue extracts and other body fluids for analysis, which suffer from the drawbacks of invasiveness, discomfort, and high costs encountered in transportation and storage, thereby hindering these products to be applied for point-of-care testing that has garnered substantial attention in recent years. Therefore, through this review, we emphasize for the first time, the applications of switching over to noninvasive sampling techniques involving hair and nails that not only circumvent most of the aforementioned limitations, but also serve as interesting alternatives in understanding the human physiology involving minimal costs, equipment and human interference when combined with rapidly advancing technologies, such as microfluidics and organ-on-a-chip to achieve miniaturization on an unprecedented scale. The coalescence between these two fields has not only led to the fabrication of novel microdevices involving hair and nails, but also function as robust biosensors for the detection of biomarkers, chemicals, metabolites and nucleic acids through noninvasive sampling. Finally, we have also elucidated a plethora of futuristic innovations that could be incorporated in such devices, such as expanding their applications in nail and hair-based drug delivery, their potential in serving as next-generation wearable sensors and integrating these devices with machine-learning for enhanced automation and decentralization.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"434-460"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138884672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Recent Advancement in Food Quality Assessment: Using MOF-Based Sensors: Challenges and Future Aspects.","authors":"Muhammad Saqaf Jagirani, Weiqiang Zhou, Ahsan Nazir, Muhammad Yasir Akram, Pengwei Huo, Yongsheng Yan","doi":"10.1080/10408347.2023.2300660","DOIUrl":"10.1080/10408347.2023.2300660","url":null,"abstract":"<p><p>Monitoring food safety is crucial and significantly impacts the ecosystem and human health. To adequately address food safety problems, a collaborative effort needed from government, industry, and consumers. Modern sensing technologies with outstanding performance are needed to meet the growing demands for quick and accurate food safety monitoring. Recently, emerging sensors for regulating food safety have been extensively explored. Along with the development in sensing technology, the metal-organic frameworks (MOF)-based sensors gained more attention due to their excellent sensing, catalytic, and adsorption properties. This review summarizes the current advancements and applications of MOFs-based sensors, including colorimetric, electrochemical, luminescent, surface-enhanced Raman scattering, and electrochemiluminescent sensors. and also focused on the applications of MOF-based sensors for the monitoring of toxins such as heavy metals, pesticide residues, mycotoxins, pathogens, and illegal food additives from food samples. Future trends, as well as current developments in MOF-based materials.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"581-602"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139512035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Malondialdehyde Analysis in Biological Samples by Capillary Electrophoresis: The State of Art.","authors":"Maria Patrícia do Nascimento, Bruna Marchiori Berlande, Marina Guedes Fraga Lopes, Mário Flávio Cardoso de Lima, Claudio Teodoro de Souza, Marcone Augusto Leal de Oliveira","doi":"10.1080/10408347.2023.2296948","DOIUrl":"10.1080/10408347.2023.2296948","url":null,"abstract":"<p><p>Lipid peroxidation occurs when substances, such as reactive oxygen species, attack lipids. Polyunsaturated fatty acids are the main targets. Several products are formed, including primary products such as lipid hydroperoxides and secondary products such as malondialdehyde (MDA), the most used lipid peroxidation biomarker. As MDA levels are elevated in several diseases, MDA is an essential indicator for assessing pathological states. The thiobarbituric acid reactive substances assay is the most widely used method for MDA determination. However, it lacks specificity. Capillary Electrophoresis (CE) is a separation technique that has been used to quantify MDA in biological samples. This technique has advantages such as the low amount of biological sample required, absence or low volume of organic solvent, short analysis time, separation of interferents, sample preparation step with only protein precipitation, and the possibility of direct detection of the MDA, without derivatization. To our knowledge, this review article is the first to show the CE background for analyzing MDA in biological samples. Therefore, given the potential of MDA in evaluating pathological states, this article demonstrates the potential of CE to become a reference method for MDA determination in clinical analysis laboratories, which will play a significant role in diagnosing and monitoring diseases.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"489-501"},"PeriodicalIF":4.2,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139037508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Glycolipid and Lipopeptide Biosurfactants: Structural Classes and Characterization-Rhamnolipids as a Model.","authors":"Nadin Darwiche, Christelle Dufresne, Agnès Chartier, Bérengère Claude, Cyril Colas, Laëtitia Fougère, Muriel Sebban, Marie-Elisabeth Lucchesi, Stéphane Le Floch, Reine Nehmé","doi":"10.1080/10408347.2024.2441428","DOIUrl":"https://doi.org/10.1080/10408347.2024.2441428","url":null,"abstract":"<p><p>In recent years, biosurfactants (BS) produced by various bacteria, fungi and yeast strains have attracted much interest because of their unique properties and potential applications in many industries ranging from bioremediation to agriculture and biomedical to cosmetics. Glycolipids are a popular group of BS that include rhamnolipids, sophorolipids, mannosylerythritol, trehalose lipids, xylolipids and cellobiose lipids. Lipopeptides e.g., surfactins, iturins and fengycins are of major biotechnological interest because of their antitumor, immunomodulatory, and antimicrobial activities effects. This review addresses the structural properties of glycolipids and lipopeptides, their main domains of application as well as the screening tests of BS production. Glycolipids are mostly composed of a carbohydrate moiety linked to a ß-hydroxy fatty acid chain with a glycosidic bond. The properties of glycolipids are related to the nature of the carbohydrate moiety and the length of the fatty acid chain. The lipopeptide structure is mainly composed of a linear or cyclic peptide linked to fatty acids of different chain lengths. The structural complexity of these compounds requires various analytical techniques for characterization and quantification. As an example, the analytical techniques used for the characterization of rhamnolipids are presented in this review. RLs are very promising BS with a wide range of applications in various fields, such as cosmetics, food science, pharmaceuticals, and environmental remediation.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"1-21"},"PeriodicalIF":4.2,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142902627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrogen Peroxide Quantification Using Zero Dimensional Carbon Nanostructured Materials: A Review.","authors":"Priti Sharma, Sopan N Nangare, Shashikant B Bagade, Sandeep S Sonawane, Dipak D Patil","doi":"10.1080/10408347.2024.2427130","DOIUrl":"https://doi.org/10.1080/10408347.2024.2427130","url":null,"abstract":"<p><p>Hydrogen peroxide (H₂O₂) is suspected to promote cancer. Higher concentrations of H₂O₂ have always harmed mammalian cells, other living things, as well as the environment. As well, elevated concentrations of H₂O₂ might cause major health problems such as cancer, cardiovascular disease, asthma, Alzheimer's disease, etc. As all, bioanalysis, environmental protection, and food security are needed for the rapid and accurate sensing of H₂O₂. For the sensing of H₂O₂, nanoparticle construction of carbon-based sensors has been used. Zero-dimensional (0D) nanostructures or nanosized designs of carbon-based fluorescent probes such as graphene quantum dots (GQDs) and carbon quantum dots (CQDs/CDs) are gaining popularity in sensing. Therefore, this review focused on current developments in sensing systems made possible by innovative applications of GQDs with CQDs, with a focus on how these materials significantly enhance overall H₂O₂ detection. In brief, the review article focuses on the basic insights of H₂O₂ and carbon-based nanomaterials. After this, the use of GQDs and CQDs-based sensors for H₂O₂ detection is discussed in a brief period from 2015 to 2024. At last, the current challenges, future prospects, and concluding remarks have been added. As an outcome, GQDs and CQDs showed the potential for sensing H₂O₂ because of their distinctive electrical, fluorescent, photoluminescent, chemiluminescent, and electrochemiluminescent features. Carbon-based sensors for the recognition of H₂O₂ utilized a variety of methods, counting PET, IFF, static quenching, dynamic quenching, FRET, etc. As an outcome, it appears that carbon-based nanoscale sensors offered potential options for highly effective yet precise sensors for the detection of H₂O₂. In winding up, the GQDs and CQDs-based sensing nanosystems provide a new platform for the recognition of H₂O₂ that can open an innovative era for the diagnosis of health issues as well as monitor several environmental processes and issues at the point of care.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"1-21"},"PeriodicalIF":4.2,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142766991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Paraquat-Induced Toxicities: Epidemiological Insights and Advances in Colorimetric and Fluorimetric Detection Methods.","authors":"Faris J Tayeb, Mohammed Fareed Felemban, Amal Adnan Ashour, Alaa Shafie","doi":"10.1080/10408347.2024.2433005","DOIUrl":"https://doi.org/10.1080/10408347.2024.2433005","url":null,"abstract":"<p><p>Paraquat (PQ) is a potent and widely utilized herbicide known for its effectiveness in controlling a broad spectrum of weeds. Its chemical properties make it an invaluable tool in agriculture, where it helps maintain crop yields and manage invasive plant species. However, despite its benefits in weed management, PQ poses significant risks due to its severe toxicity, which affects multiple organ systems in both humans and animals. The dual nature of PQ, as both a valuable agricultural chemical and a hazardous toxicant, necessitates a comprehensive understanding of its toxicological impacts and the development of effective detection and development strategies. This review aims to provide a comprehensive overview of PQ-induced toxicities, including neurotoxicity, lung toxicity, liver toxicity, kidney toxicity, and immunotoxicity. By synthesizing current knowledge on PQ health impacts, highlighting epidemiological trends, and exploring recent advancements in colorimetric and fluorimetric detection methods, this review seeks to contribute to the development of strategies for improving public health outcomes and enhancing our ability to manage the risks associated with PQ exposure. Addressing PQ toxicity through a multidisciplinary approach, incorporating toxicological, epidemiological, and technological perspectives, is essential for safeguarding health and promoting effective interventions.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":" ","pages":"1-31"},"PeriodicalIF":4.2,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142726724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}