Composites Part B: Engineering最新文献

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Effect of interlayer stitching in thermoplastic composite-packaged structural battery on electrochemical performance under mechanical loads 热塑性复合材料包装结构电池层间拼接对机械载荷下电化学性能的影响
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112583
Ji-Hun Cha , Jayden Dongwoo Lee , Tae-Hyun Kim , Jong Guk Kim , Yoonkook Son , Chun-Gon Kim
{"title":"Effect of interlayer stitching in thermoplastic composite-packaged structural battery on electrochemical performance under mechanical loads","authors":"Ji-Hun Cha ,&nbsp;Jayden Dongwoo Lee ,&nbsp;Tae-Hyun Kim ,&nbsp;Jong Guk Kim ,&nbsp;Yoonkook Son ,&nbsp;Chun-Gon Kim","doi":"10.1016/j.compositesb.2025.112583","DOIUrl":"10.1016/j.compositesb.2025.112583","url":null,"abstract":"<div><div>Structural batteries are multifunctional systems that integrate mechanical load-bearing capabilities with energy storage functions. However, conventional polymer matrices used in composite materials exhibit poor oxygen and moisture barrier properties, compromising electrolyte stability. To address this issue, a selective encapsulation strategy was implemented using a liquid thermoplastic polymer and masking techniques. A polypropylene barrier, recognized for its superior moisture and oxygen resistance, was selectively integrated around the electrode regions, while a thermoplastic polymer was applied to the external layers. This advanced design significantly enhanced electrolyte protection. One of the primary challenges in structural battery design is the weak interfacial adhesion between current collectors, electrolyte layers, and separators, which can lead to delamination, increased internal resistance, and reduced charge transfer efficiency. To mitigate these issues, a stitching reinforcement strategy was employed, minimizing electrode spacing between the cathode and anode to optimize ion transport pathways. In a static structural battery, the incorporation of a stitching architecture resulted in up to a 13 % increase in energy density compared to the non-stitched configuration. The stitching architecture effectively maintained a narrow electrode spacing between the cathode and anode under mechanical loads, significantly enhancing capacity retention. The proposed structural battery exhibited a tensile strength of 189 MPa and a tensile modulus of 9.1 GPa, achieving an energy density of up to 39.5 Wh/kg based on the total mass of the structural battery. These findings underscore the substantial potential of stitched structural batteries in high-performance applications, providing an innovative approach to improving both mechanical integrity and electrochemical efficiency in multifunctional energy storage systems.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112583"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable electrical energy harvesting via atmospheric water collection using Dual-MOF systems 利用双mof系统通过大气水收集实现可持续电能收集
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112574
Ji Hyun Lee , Dongyeon Kim , Yonggyun Lee , Youngoh Kim , Kihyun Shin , Ho Jun Lee , Heseong An , Jun Young Cheong , Seon-Jin Choi , Hyun You Kim , Joonmyung Choi , Jong Suk Lee , Ki Ro Yoon , Tae Gwang Yun
{"title":"Sustainable electrical energy harvesting via atmospheric water collection using Dual-MOF systems","authors":"Ji Hyun Lee ,&nbsp;Dongyeon Kim ,&nbsp;Yonggyun Lee ,&nbsp;Youngoh Kim ,&nbsp;Kihyun Shin ,&nbsp;Ho Jun Lee ,&nbsp;Heseong An ,&nbsp;Jun Young Cheong ,&nbsp;Seon-Jin Choi ,&nbsp;Hyun You Kim ,&nbsp;Joonmyung Choi ,&nbsp;Jong Suk Lee ,&nbsp;Ki Ro Yoon ,&nbsp;Tae Gwang Yun","doi":"10.1016/j.compositesb.2025.112574","DOIUrl":"10.1016/j.compositesb.2025.112574","url":null,"abstract":"<div><div>Hydro-electric nanotechnology is touted as a promising next-generation renewable energy system because it employs environmentally-friendly and abundant water as an energy resource for producing electricity efficiently. However, the conventional hydro-electric nanogenerators have some limitations, such as difficulty in continuous and artificial induction of water stream and a low level of energy production for practical use. In this study, we devised a sustainable water harvesting and electrical energy generation system to overcome the limitations of conventional renewable energy. The system was successfully achieved with two distinctive metal-organic frameworks (MOFs), that are, an amine functionalized Zr-based MOF (UiO-66-NH<sub>2</sub>) particles for atmospheric water harvesting, and a highly conductive Ni<sub>3</sub>(HITP)<sub>2</sub> (HITP = 2,3,6,7,10,11-hexaiminotriphenylene) MOF-grown cotton-fabric for producing electrical energy. The environmentally responsive UiO-66-NH<sub>2</sub> harvests water from ambient air and the condensed water spontaneously produces electrical potential between wet- and dry-Ni<sub>3</sub>(HITP)<sub>2</sub>, resulting in electrical energy generation with a maximum power and energy densities of 2.6 μW/cm<sup>3</sup> and 1.1 mJ/cm<sup>3</sup>, respectively. Our novel hybrid concept integrating water harvesting and energy generation systems can pave the way for realizing a hydro-electric nanogenerator as a next-generation energy harvesting system in the near future.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112574"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of dyes on the mechanical properties of composites fabricated from waste polyester/cotton fibers and their potential application value in the construction field 染料对废涤/棉复合材料力学性能的影响及其在建筑领域的潜在应用价值
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112576
Feng Liang , Zhen Shi , Rui Dan , Huan Liang , Xu Feng , Xianqin Shang , Yuanyuan Hu
{"title":"The influence of dyes on the mechanical properties of composites fabricated from waste polyester/cotton fibers and their potential application value in the construction field","authors":"Feng Liang ,&nbsp;Zhen Shi ,&nbsp;Rui Dan ,&nbsp;Huan Liang ,&nbsp;Xu Feng ,&nbsp;Xianqin Shang ,&nbsp;Yuanyuan Hu","doi":"10.1016/j.compositesb.2025.112576","DOIUrl":"10.1016/j.compositesb.2025.112576","url":null,"abstract":"<div><div>The waste of a significant quantity of poly-cotton textiles contributes to environmental pollution, making recycling an urgent necessity. This study employed Dimethyl sulfoxide (DMSO), Sodium Hydrosulfite (Na<sub>2</sub>S<sub>2</sub>O<sub>4</sub>), and NaOH for the decolorization of waste polyester/cotton fabric, followed by the preparation of fiber-reinforced composites through a hot pressing process. Notably, no additional resin was incorporated as a matrix material during this process. The study systematically investigated the influence of reactive dyes and vat dyes on the mechanical properties of the composites before and after decolorization. The results revealed that the mechanical properties of reactive dye-dyed fiber composites (RDFC) were significantly inferior to those of undyed fiber composites (UDFC) and decolorized fiber composites, with reductions ranging from approximately 9.76 %–407.72 %. In contrast, the mechanical properties of vat dye-dyed fiber composites (VDFC) exceeded those of UDFC and decolorized fiber composites, showing improvements between 1.1 % and 29.61 %. Under wet conditions, all types of fiber composites exhibited a mechanical property loss of approximately 20 % after decolorization, indicating that the influence of moisture is manageable. Furthermore, the strength of these composites was found to be comparable to traditional materials such as gypsum boards and logistics wood pallets, among other applications. These findings highlight the potential of these materials as sustainable, high-performance alternatives in construction and related fields, offering significant application value and environmental benefits.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112576"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143894416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of B4C addition on irradiation response and tribology behaviors of high entropy alloy films B4C对高熵合金薄膜辐照响应和摩擦学行为的影响
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112579
Qingchun Chen , Linxin He , Juan Du , An Li , Tianyu Zhao , Nan Qiu , Yuan Wang
{"title":"Effect of B4C addition on irradiation response and tribology behaviors of high entropy alloy films","authors":"Qingchun Chen ,&nbsp;Linxin He ,&nbsp;Juan Du ,&nbsp;An Li ,&nbsp;Tianyu Zhao ,&nbsp;Nan Qiu ,&nbsp;Yuan Wang","doi":"10.1016/j.compositesb.2025.112579","DOIUrl":"10.1016/j.compositesb.2025.112579","url":null,"abstract":"<div><div>The inherent strength-ductility trade-off in traditional alloys is exacerbated by irradiation-induced point defect migration and aggregation, posing a critical challenge for extreme irradiation applications. To address this limitation, this study innovatively introduced B<sub>4</sub>C into AlCrFeNi high entropy alloys via magnetron co-sputtering, fabricating high entropy composite films (B10, B60) with short-range order (SRO) structures. Notably, the composite films exhibited exceptional structural stability under 40 keV He ion irradiation compared to their crystalline AlCrFeNi counterpart, which suffered severe lattice damage in the peak irradiation area. The post-irradiation characterization revealed a substantial hardness increase in AlCrFeNi (ΔH = 4.4 GPa), while composite films maintained superior stability with minimal changes (B10: 2.6 GPa; B60: 1.7 GPa). The tribological results showed that for the as-deposited films, the wear rate of the composite films is significantly lower than that of AlCrFeNi films. Molecular dynamics (MD) simulations unveiled that the unique SRO-dominated microstructure could achieve effective shear strain dispersion and enhance the plastic deformation capacity of subsurface. Counterintuitively, the composite films exhibited irradiation-induced wear resistance improvement in wear resistance instead of the degradation of traditional lubricating films. Especially under the high-dose conditions, the wear rate of the B60 films is 5.1 times lower than that of AlCrFeNi films. This work achieved the synergistic enhancement of irradiation resistance and tribological properties by regulating the internal microstructure of high entropy composite materials.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112579"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143894415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Programmable toughening for 3D printed concrete and architected cementitious materials 可编程增韧3D打印混凝土和建筑胶凝材料
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112573
Kailun Xia, Yuning chen, Yu Chen, Lutao Jia, Zijian Jia, Yamei Zhang
{"title":"Programmable toughening for 3D printed concrete and architected cementitious materials","authors":"Kailun Xia,&nbsp;Yuning chen,&nbsp;Yu Chen,&nbsp;Lutao Jia,&nbsp;Zijian Jia,&nbsp;Yamei Zhang","doi":"10.1016/j.compositesb.2025.112573","DOIUrl":"10.1016/j.compositesb.2025.112573","url":null,"abstract":"<div><div>Cementitious materials have been long suffered from toughness issue. Recent advances in 3D printing techniques enable innovative material shaping and customized functionalization. Herein, we propose a novel strategy for achieving multiscale and programmable toughening for cementitious composites by integrating the “wet spinning” industrial manufacturing process of polymer fibers/films into 3D printing procedure. In this strategy, the dehydration-induced polymer precipitation and the hydration of cement are synchronized, while the internal stress generated during the printing process drives the polymers to form desired toughening structure. Within this concept, anisotropic and programmable toughening are achieved by adjusting the printing parameters to control the polymer structure. This strategy is highly compatible with architected material design under high toughening component and extremely small voxel scale. Through this, we achieved an 80 % increase in flexural strength and a 102 % increase in fractured energy for the 3D printed cementitious bouligand structure at centimeter-level for the first time.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112573"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143890838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soft-hard self-alternating flexible organic-inorganic intercalated short-fiber mimetic bone lamellae 软硬自交变柔性有机-无机插层短纤维模拟骨片
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112581
Mingyue Liu , Xiaoyu Han , Guilai Zuo , Pengcheng Xiao , Yue Zhao , Xiumei Mo , Juan Wang , Wenguo Cui
{"title":"Soft-hard self-alternating flexible organic-inorganic intercalated short-fiber mimetic bone lamellae","authors":"Mingyue Liu ,&nbsp;Xiaoyu Han ,&nbsp;Guilai Zuo ,&nbsp;Pengcheng Xiao ,&nbsp;Yue Zhao ,&nbsp;Xiumei Mo ,&nbsp;Juan Wang ,&nbsp;Wenguo Cui","doi":"10.1016/j.compositesb.2025.112581","DOIUrl":"10.1016/j.compositesb.2025.112581","url":null,"abstract":"<div><div>Bone lamellae are the fundamental basis of bone structure and function. Simulating the multilevel ordered soft-hard alternating multilayer microstructures of these materials is extremely challenging. In this study, amorphous and highly structurally connected flexible inorganic silica nanofibers (SiO<sub>2</sub> NF) consisting of a network of silica-oxygen-silica bonds were prepared by sol-gel electrospinning and high-temperature calcination techniques, and highly entangled with organosodium alginate and hydroxyapatite nanoparticles (HAPs) to form soft-hard alternating structures wrapped in fixed-points by hydrogen bonding. Finally, soft-hard self-alternating flexible organic-inorganic intercalated short-fiber mimetic bone lamellae (ASH) were successfully constructed via the selective crystallization technique to adjust the temperature gradient for crystallization, thereby precipitating the intercalated structure. Based on the principles of crystal growth kinetics and solubility product equilibrium, ASH was transformed from a conventional disordered structure to a highly ordered multilayered soft-hard alternating structure with a porosity of up to 95 %. The ASH scaffold demonstrated exceptional shape memory properties, maintaining structural stability under 80 % strain and over 100 compression cycles. <em>In vitro</em> analyses revealed that sustained release of bioactive ions from ASH significantly enhanced osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs), as evidenced by upregulated expression of Fgf and Pdf/Flt4 genes. Furthermore, <em>in vivo</em> studies validated the scaffold's capacity to promote BMSCs recruitment and migration, thereby accelerating bone regeneration. In summary, mimetic bone lamellae were successfully constructed and accurately replicated the microstructure of natural bone lamellae, providing a new perspective and strategy for exploring the structure-function relationships of bone lamellae.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112581"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of impactor geometry and multiple impacts on low-velocity impact response and residual compressive strength of fiber-reinforced composite laminates 冲击器几何形状和多次冲击对纤维增强复合材料层合板低速冲击响应和残余抗压强度的影响
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112575
Peyman Shabani , Lucy Li , Jeremy Laliberte
{"title":"Effects of impactor geometry and multiple impacts on low-velocity impact response and residual compressive strength of fiber-reinforced composite laminates","authors":"Peyman Shabani ,&nbsp;Lucy Li ,&nbsp;Jeremy Laliberte","doi":"10.1016/j.compositesb.2025.112575","DOIUrl":"10.1016/j.compositesb.2025.112575","url":null,"abstract":"<div><div>Fiber-reinforced composite panels used in aerospace applications often experience low-velocity impacts (LVI) during service and maintenance by objects of various shapes, sizes, and masses, which can significantly reduce the panel's residual compressive strength. This study provides a detailed numerical and experimental analysis of LVI and compression after impact (CAI) failure mechanisms of laminates impacted by different impactor sizes and masses, along with damage accumulation during multiple impacts, and presents an effective approach for modeling progressive damage in composite laminates. The experiments were conducted using three hemispherical impactors with diameters of 6.35 mm (sharp), 25.4 mm (standard), and 96 mm (blunt), at impact energy levels of 30 J and 75 J, corresponding to barely and clearly visible impact damage (BVID and CVID). Quasi-isotropic IM7/977-3 composite specimens, sized 254 mm × 304.8 mm, were used to better represent large composite panels and study a wider range of impact scenarios. A finite element modeling methodology was developed based on the integrated enhanced LaRC05 failure criteria and the cohesive zone modeling technique to predict various composite failure modes, such as fiber breakage, pull-out, kinking, crushing, and splitting, as well as matrix cracking and delamination. The LaRC05 fiber tensile failure criterion was revised based on experimental data, improving the accuracy of the model at higher impact energies. At the same energy level, the sharp impactor caused more concentrated and severe damage, leading to lower CAI strength. The blunt impactor caused less surface damage but similar internal delamination and CAI strength compared to the standard impactor.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112575"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143913190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Topology design of additively manufactured CFRP for impact resistance via B-spline-based equivalent static load method 基于b样条等效静载荷法的增材CFRP抗冲击拓扑设计
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-28 DOI: 10.1016/j.compositesb.2025.112577
Xiaobao Zhi , Shangqin Yuan , Shijie Xu , Zhonghao Zhao , Chenyang Li , Yamin Li , Jihong Zhu , Weihong Zhang
{"title":"Topology design of additively manufactured CFRP for impact resistance via B-spline-based equivalent static load method","authors":"Xiaobao Zhi ,&nbsp;Shangqin Yuan ,&nbsp;Shijie Xu ,&nbsp;Zhonghao Zhao ,&nbsp;Chenyang Li ,&nbsp;Yamin Li ,&nbsp;Jihong Zhu ,&nbsp;Weihong Zhang","doi":"10.1016/j.compositesb.2025.112577","DOIUrl":"10.1016/j.compositesb.2025.112577","url":null,"abstract":"<div><div>Additive manufacturing (AM) extends the design freedom of continuous fiber-reinforced polymer (CFRP) composites, enabling the fabrication of complex structures with tailored properties. However, it is still challenging of structural topology optimization for impact resistance, due to its inherent nonlinearity. In this work, a B-spline-based Equivalent Static Load (BSESL) method is proposed for impact-resistant designs with low-velocity loading and manufacturability constraints. Pseudo-density and fiber orientation are concurrently optimized and parameterized through B-splines, ensuring smooth fiber orientations without additional filtering due to the high-order continuity of splines. By adjusting the control parameter sizes (CPS) of the B-spline fields, a trade-off between mechanical performance and manufacturability is evaluated. The effectiveness of the proposed method is validated through theoretical design and drop-weight experiments, exhibiting significant improvements in impact resistance and manufacturability.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112577"},"PeriodicalIF":12.7,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143894413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Developing a bio-based, continuous fibre reinforcement to push the impact energy limits of engineered wood in structural applications 开发一种基于生物的连续纤维增强材料,以推动工程木材在结构应用中的冲击能量极限
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-26 DOI: 10.1016/j.compositesb.2025.112536
Bernhard Ungerer , Philipp Matz , Florian Kupelwieser , Hajir Al-Musawi , Gabriel Praxmarer , Stefan Hartmann , Ulrich Müller
{"title":"Developing a bio-based, continuous fibre reinforcement to push the impact energy limits of engineered wood in structural applications","authors":"Bernhard Ungerer ,&nbsp;Philipp Matz ,&nbsp;Florian Kupelwieser ,&nbsp;Hajir Al-Musawi ,&nbsp;Gabriel Praxmarer ,&nbsp;Stefan Hartmann ,&nbsp;Ulrich Müller","doi":"10.1016/j.compositesb.2025.112536","DOIUrl":"10.1016/j.compositesb.2025.112536","url":null,"abstract":"<div><div>Laminated birch veneers were reinforced with a layer of unidirectional, continuous filaments for an investigation on the potential increase in fracture toughness. By proposing a new type of reinforcement based on regenerated cellulose filaments, an alternative for conventional glass fibres was introduced featuring a reduction in carbon footprint and enabling a circularity perspective in combination with engineered wood. Impact bending tests based on ISO179-1/2 were performed to assess the mechanical potential of such a novel reinforcement. Two sources of fibre reinforcement were considered for a comparison; glass fibres (E-glass) and high-tenacity viscose filaments. Based on biomimetic considerations, structural features such as yarn twist and a partial impregnation of the yarn were implemented to foster a tough composite failure. A Finite Element (FE) model was proposed to describe the effect of cellulosic reinforcements under dynamic loading, considering the impregnation with different adhesive systems. The results indicated a strong influence of the fibre impregnation. With a mean impact strength of 38.6 kJ/m<sup>2</sup> cellulose filaments impregnated with epoxy showed only a moderate improvement compared to 34.7 kJ/m<sup>2</sup> for non-reinforced wood. When impregnated with an emulsion polymer isocyanate, impact strength more than doubled to 88.9 kJ/m<sup>2</sup>. This was traced back to the partial impregnation of the yarn cross-section. A comparison of the FE simulation with the experimental data showed consistency in the failure behaviour and the quantitative effect of reinforcement. This novel reinforcing approach and its underlying model demonstrated a considerable progress in increasing the crash-safety of wood by means of a bio-based and easily applicable solution.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112536"},"PeriodicalIF":12.7,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143913198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microcrystalline reconfiguration assisted pore structure regulation towards high performance coal-derived hard carbon anodes for sodium-ion batteries 微晶重构对钠离子电池高性能煤基硬碳阳极孔结构调控的影响
IF 12.7 1区 材料科学
Composites Part B: Engineering Pub Date : 2025-04-26 DOI: 10.1016/j.compositesb.2025.112562
Zeren Zhou , Zhijiang Wang , Yixiang Zhang , Qiaoyan Lin , Qinghe Jing , Shouqing Yan , Jie Guo , Yong Shuai , Lishuang Fan
{"title":"Microcrystalline reconfiguration assisted pore structure regulation towards high performance coal-derived hard carbon anodes for sodium-ion batteries","authors":"Zeren Zhou ,&nbsp;Zhijiang Wang ,&nbsp;Yixiang Zhang ,&nbsp;Qiaoyan Lin ,&nbsp;Qinghe Jing ,&nbsp;Shouqing Yan ,&nbsp;Jie Guo ,&nbsp;Yong Shuai ,&nbsp;Lishuang Fan","doi":"10.1016/j.compositesb.2025.112562","DOIUrl":"10.1016/j.compositesb.2025.112562","url":null,"abstract":"<div><div>Hard carbon (HC) is regarded as a highly promising anode material for sodium-ion batteries (SIBs) due to its low cost and excellent performance. However, low initial coulombic efficiency (ICE) and sodium storage capacity hinder its development. Closed pore structures are considered an effective strategy to improve ICE and the capacity of hard carbon. Nonetheless, template agents are unavoidable in the closed pores creation process, and more steps lead to low productivity. Herein, turbostratic microcrystalline structures and abundant closed pores are induced without additional template agents via a self-reconfiguration strategy inspired by the plant stomata bionic structure. Benefiting from closed pores formation, ICE and Na<sup>+</sup> storage specific capacity are improved to 85 % and 341 mAh∙g<sup>−1</sup> (HC-PC) significantly, compared with HC-C (79 %, 250 mAh∙g<sup>−1</sup>). HC-PC also exhibits an outstanding capacity retention ratio of 96.9 % (0.3 A g<sup>−1</sup>) and 91.3 % (1 A g<sup>−1</sup>) after 1000 cycles.</div></div>","PeriodicalId":10660,"journal":{"name":"Composites Part B: Engineering","volume":"303 ","pages":"Article 112562"},"PeriodicalIF":12.7,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143894414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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