Composites Communications最新文献

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Inverse design of material, structure, and process for dielectric properties of additively manufactured PLA/BaTiO3 polymer composites
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-18 DOI: 10.1016/j.coco.2025.102314
Quanjin Ma , Ke Dong , Feirui Li , Ming Yu , Yi Xiong
{"title":"Inverse design of material, structure, and process for dielectric properties of additively manufactured PLA/BaTiO3 polymer composites","authors":"Quanjin Ma ,&nbsp;Ke Dong ,&nbsp;Feirui Li ,&nbsp;Ming Yu ,&nbsp;Yi Xiong","doi":"10.1016/j.coco.2025.102314","DOIUrl":"10.1016/j.coco.2025.102314","url":null,"abstract":"<div><div>Additive manufacturing holds excellent potential for engineering highly integrated and miniaturized microwave components with targeted dielectric constant and loss tangent for the desired operating frequency bands. However, searching for optimal combinations of material, structure, and process that produce components with desired dielectric properties remains a nontrivial task due to the large design space and complex relationship. This paper proposes an inverse design method for tailoring the dielectric properties of additively manufactured PLA/BaTiO<sub>3</sub> polymer composites by exploring their multidisciplinary design space, including material composition, infill structure, and process parameters. This approach utilizes the theoretical Yamada and first-order models to predict the material-property and structure-property relationships, respectively. For given material composition in PLA/BaTiO<sub>3</sub> polymer composite, the few-shot learning (FSL) model with model-agnostic meta-learning (MAML) algorithm is trained to predict the targeted dielectric properties on the integrated structure-process-property relationship of additively manufactured PLA/BaTiO<sub>3</sub> polymer composites. The inverse design approach of the theoretical Yamada model provided a relative error below 3.25 % on the dielectric constant and 6.15 % on loss tangent in material composition ranging from 5 wt% to 80 wt% of BaTiO<sub>3</sub> filler, achieving 13.913 ± 0.028 and (4.373 ± 0.023) × 10<sup>−2</sup>. The inverse design approach of FSL with the MAML algorithm had a relative error of less than 4.93 % and 4.73 % on the dielectric constant of linear and gradient patterns in the structure-process-property function. This work successfully proposes the FSL model with the MAML algorithm to inversely predict targeted dielectric properties on structure-process-property integration in PLA/BaTiO<sub>3</sub> polymer composites, which can accelerate the inverse design cycle and enlarge the controllable property range of additively manufactured microwave components.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102314"},"PeriodicalIF":6.5,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143454586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The ultra-sensitive flexible pressure sensor based on hierarchical micro-wrinkle/pyramid structure for underwater perturbation monitoring
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102312
Runbin Cao , Fan Chang , Qihe Peng , Chunen Zhao , Yongyao Chen , Xu Zhu , Ning Ma , Xinyue Zhang
{"title":"The ultra-sensitive flexible pressure sensor based on hierarchical micro-wrinkle/pyramid structure for underwater perturbation monitoring","authors":"Runbin Cao ,&nbsp;Fan Chang ,&nbsp;Qihe Peng ,&nbsp;Chunen Zhao ,&nbsp;Yongyao Chen ,&nbsp;Xu Zhu ,&nbsp;Ning Ma ,&nbsp;Xinyue Zhang","doi":"10.1016/j.coco.2025.102312","DOIUrl":"10.1016/j.coco.2025.102312","url":null,"abstract":"<div><div>Underwater flexible pressure sensors have shown indispensable importance in the development of underwater monitoring and marine environment exploration. However, designing a pressure sensor with both a wide detection range and high sensitivity is still a challenge, particularly for the underwater environmental application. Herein, we have prepared a composite micro-wrinkle/pyramid Ag/PDMS sensor just using polymer swelling-electroless deposition method. By packaging the hierarchical structure with the soft electrode face-to-face, the assembled pressure sensor can reach the limit of detection about 2 Pa, high pressure even to 170 kPa, and excellent stability over 5000 cycles. In the water environment, this water proof sensor can also sensitively monitor and precisely distinguish the tiny perturbation of water, like the underwater biological monitoring, the propeller rotating speed, the location of vibration source, and the sound intensity. This flexible and low-cost sensor will become an optimal candidate for the new generation of soft marine detector.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102312"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143465458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phenolic-based porous composite with embedded short carbon fiber/hollow spheres for mechanical properties and thermostability
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102305
Yingjie Qiao , Xiaotian Bian , Hongjun Ke , Zhenquan Zhao , Xiaohong Zhang , Xin Zhang , Yingkai Zhao , Chengying Bai , Lili Zhang , Ting Zheng , Xiaodong Wang
{"title":"Phenolic-based porous composite with embedded short carbon fiber/hollow spheres for mechanical properties and thermostability","authors":"Yingjie Qiao ,&nbsp;Xiaotian Bian ,&nbsp;Hongjun Ke ,&nbsp;Zhenquan Zhao ,&nbsp;Xiaohong Zhang ,&nbsp;Xin Zhang ,&nbsp;Yingkai Zhao ,&nbsp;Chengying Bai ,&nbsp;Lili Zhang ,&nbsp;Ting Zheng ,&nbsp;Xiaodong Wang","doi":"10.1016/j.coco.2025.102305","DOIUrl":"10.1016/j.coco.2025.102305","url":null,"abstract":"<div><div>Lightweight composites, characterized by their high specific strength, hold significant potential for applications and exhibit promising development prospects in industries such as aerospace, marine, and machinery. In this paper, a novel lightweight and high temperature resistant phenolic-based porous composite was designed and prepare using boron-containing phenolic resin (BPF) as the matrix, with short carbon fibers (SCFs) and millimeter-scale SCFs/BPF hollow sphere (MSHS) as fillers, employing a dry powder molding method. The effect of SCFs content in the matrix resin on the density and quasi-static compression properties of the prepared phenolic-based porous composites was systematically investigated. The results showed that the phenolic-based porous composites containing 50 vol% MSHS and 40 wt% SCFs exhibited a favorable compressive strength of 58.1 MPa, with a density of only 0.78 g/cm<sup>3</sup>. Additionally, the prepared phenolic-based porous composites presented excellent high-temperature resistance, maintaining structural integrity and performance stability at temperatures up to 200 °C, where the compressive strength still remained at 14.7 MPa. The results indicated that this method is simple, scalable for mass production, and offers a promising approach to the efficient manufacturing of lightweight, high-performance composite materials.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102305"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143445241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon fiber reinforced isotropic photo-curing 3D printing polymer composites
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102315
Jia-Tao Miao , Binjie Yang , Xinxin Sang , Ren Liu
{"title":"Carbon fiber reinforced isotropic photo-curing 3D printing polymer composites","authors":"Jia-Tao Miao ,&nbsp;Binjie Yang ,&nbsp;Xinxin Sang ,&nbsp;Ren Liu","doi":"10.1016/j.coco.2025.102315","DOIUrl":"10.1016/j.coco.2025.102315","url":null,"abstract":"<div><div>Photo-curing 3D printing has notable advantages such as rapid printing speeds and high-resolution. However, the mechanical properties of traditional photosensitive resins are insufficient and show anisotropy owing to the weak interlayer bond caused by the layer-by-layer printing process. In this study, 4-vinylaniline-modified carbon fibers (CF-Enamine) were synthesized via surface graft modification. The mechanical strength and anisotropy of the printed composites were thoroughly researched. With the additional interfacial bond between the modified fibers and the resin matrix, the tensile strength of the printed samples reached 66.0 MPa, which is 44.7 % higher compared to the pure resin. Furthermore, CF-Enamine plays a role as bridges between the printed layers, significantly reducing the tensile strength anisotropy of the printed samples to 3.3 %. This work prepared the reinforced isotropic 3D printed structures in virtue of the strong bond between CF-Enamine and resin matrix, which is expected to advance the practical application of photo-curing 3D printing in industry.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102315"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of sizing concentration on strength, stiffness, and porosity in textile grade carbon fiber (TCF)-Epoxy composites: Revealing inverse trends
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102310
Vipin Kumar , Komal Chawla , Surbhi Kore , Sanjita Wasti , Subabhrata Saha , Josh Crabtree , Merlin Theodore , Adwoa Owusu , Ahmed Arabi Hassen , Uday Vaidya , Vlastimil Kunc
{"title":"Influence of sizing concentration on strength, stiffness, and porosity in textile grade carbon fiber (TCF)-Epoxy composites: Revealing inverse trends","authors":"Vipin Kumar ,&nbsp;Komal Chawla ,&nbsp;Surbhi Kore ,&nbsp;Sanjita Wasti ,&nbsp;Subabhrata Saha ,&nbsp;Josh Crabtree ,&nbsp;Merlin Theodore ,&nbsp;Adwoa Owusu ,&nbsp;Ahmed Arabi Hassen ,&nbsp;Uday Vaidya ,&nbsp;Vlastimil Kunc","doi":"10.1016/j.coco.2025.102310","DOIUrl":"10.1016/j.coco.2025.102310","url":null,"abstract":"<div><div>The effect of fiber sizing (i.e., surface treatment) concentration (0 %, 1.36 %, 1.52 %, 1.94 %, and 2.13 %) on the mechanical properties (tensile, flexural, interlaminar shear strength (ILSS), and low velocity impact) of textile grade carbon fiber (TCF)-epoxy composite is examined. An inverse relationship between the strength and stiffness of the composite is observed with increased sizing concentration. The root mean square (RMS) roughness of the fiber surface increased from 17.8 nm (unsized) to 22.7 nm with 2.13 % sizing concentration. It was found that the tensile strength increased by 131 % from 221.4 ± 18.5 MPa (unsized) to 510.8 ± 28.05 MPa (for 1.36 % sizing) and further by 155 %–563.7 ± 14.95 MPa at 2.13 % sizing. On the contrary, the stiffness is initially increased by 126 % from 33.52 ± 7.80 GPa (unsized) to 75.9 ± 3.21 GPa (for 1.36 % sizing) but reduced with further increase in the sizing concentration. A single fiber pull-out test is simulated using the finite element method to validate the reverse trend in strength and stiffness. The varying sizing concentration is simulated by introducing an interface of varying thickness between fibers and matrix. Simulation results confirm that a thicker interface, corresponding to a higher sizing concentration, decreases interfacial shear stress, enhancing material strength while decreasing stiffness. The reverse trend in strength and stiffness with the sizing concentration aligns with experimental observations. The present study emphasizes the importance of sizing concentration for mechanical properties and provide a design criterion for customized high-strength and high-stiffness applications.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102310"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143445240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strong, ductile and transparent biaxially oriented poly(lactic acid) with low content of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) by temperature-gradient stretching: The role of mesophase
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102311
Dongfu Wang, Bo Liu, Deyu Niu, Weijun Yang, Xu Zhang, Pengwu Xu, Piming Ma
{"title":"Strong, ductile and transparent biaxially oriented poly(lactic acid) with low content of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) by temperature-gradient stretching: The role of mesophase","authors":"Dongfu Wang,&nbsp;Bo Liu,&nbsp;Deyu Niu,&nbsp;Weijun Yang,&nbsp;Xu Zhang,&nbsp;Pengwu Xu,&nbsp;Piming Ma","doi":"10.1016/j.coco.2025.102311","DOIUrl":"10.1016/j.coco.2025.102311","url":null,"abstract":"<div><div>Polylactic acid (PLA) is an ideal material for fabricating low-carbon, environmentally friendly biaxially-oriented stretch films due to its significant application potential in sustainable packaging. However, biaxially-oriented PLA films exhibit inherent brittleness, and the role of the PLA mesophase in governing their physico-mechanical properties remains unclear. In this study, microbial poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) was employed as a novel toughening agent, which was melt-blended with PLA to simultaneously enhance toughness and stretchability. Subsequently, biaxially-oriented PLA/PHBH films (BO-PLA/PHBH) with controlled mesophase contents but comparable crystallinity and orientation were fabricated through one-step and temperature-gradient stretching methodologies. The temperature-gradient stretched BO-PLA/PHBH containing 8 % mesophase achieved a tensile strength of 153 MPa, while notably maintaining an elongation at break of 80 % and optical transparency of 92 %. The mesophase serves as a structural bridge between crystalline and amorphous domains, facilitating stress transfer and thereby enhancing mechanical strength. This study proposes a scalable, industrially viable strategy for manufacturing fully biodegradable PLA/PHBH films with superior rigidity-ductility balance.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102311"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143465460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D printing and properties of carbon nanotube modified basalt fiber/nylon 6 composites
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-17 DOI: 10.1016/j.coco.2025.102313
Dong Xiang , He Tian , Jingxiong Ma , Eileen Harkin-Jones , Yuanqing Li , Menghan Wang , Libing Liu , Yuanpeng Wu , Jinbo Cheng , Dong Li
{"title":"3D printing and properties of carbon nanotube modified basalt fiber/nylon 6 composites","authors":"Dong Xiang ,&nbsp;He Tian ,&nbsp;Jingxiong Ma ,&nbsp;Eileen Harkin-Jones ,&nbsp;Yuanqing Li ,&nbsp;Menghan Wang ,&nbsp;Libing Liu ,&nbsp;Yuanpeng Wu ,&nbsp;Jinbo Cheng ,&nbsp;Dong Li","doi":"10.1016/j.coco.2025.102313","DOIUrl":"10.1016/j.coco.2025.102313","url":null,"abstract":"<div><div>This study modified basalt fibers (BFs) by cyclic soaking and drying in an aqueous carbon nanotube (CNT) dispersion. Melt mixing was employed to prepare the unmodified and modified 10 wt% BFs reinforced nylon 6 (PA6) composites, which were subsequently granulated for fused granular fabrication (FGF) 3D printing. The results showed that the CNT content on the fiber surface increased with increased modification time. The warping degree of 3D-printed samples was reduced significantly by adding BFs. The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) showed that adding BFs improved the thermal stability and crystallization temperature of PA6. The samples' tensile and flexural properties were remarkably enhanced by the CNT modification of BFs. The mechanical properties of 3D-printed and hot-pressed samples were in close approximation, indicating a robust interfacial interaction between modified BFs and the PA6 matrix. At the modification time of 45 min, the BF/PA6 composite with 0.04 wt% CNTs demonstrated excellent mechanical properties and wear resistance. Compared with PA6 and unmodified composites, the modified composite's tensile strength was increased by 122.5 % and 44.6 %, and the friction coefficient was reduced by 36.1 % and 33.4 %, respectively.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102313"},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143437017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomimetic, mechanically strong and sensitive cyclic fire warning sensor based on high-concentration exfoliated MoS2 and poly-p-phenylene benzobisoxazole film
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-15 DOI: 10.1016/j.coco.2025.102309
Haorui Duan , Chuanshen Wang , Lu Liu , Na Sun , Xiaowei Mu , Hongliang Ding , Hongfei He , Wei Wang , Wei Wu , Bin Yu
{"title":"Biomimetic, mechanically strong and sensitive cyclic fire warning sensor based on high-concentration exfoliated MoS2 and poly-p-phenylene benzobisoxazole film","authors":"Haorui Duan ,&nbsp;Chuanshen Wang ,&nbsp;Lu Liu ,&nbsp;Na Sun ,&nbsp;Xiaowei Mu ,&nbsp;Hongliang Ding ,&nbsp;Hongfei He ,&nbsp;Wei Wang ,&nbsp;Wei Wu ,&nbsp;Bin Yu","doi":"10.1016/j.coco.2025.102309","DOIUrl":"10.1016/j.coco.2025.102309","url":null,"abstract":"<div><div>The design and development of fire alarm sensors (FAS) with early fire warning and flame-retardant functions are significant in monitoring critical fire risks of combustible material. However, FAS with high flexibility, strength, environmental resistance, high temperature resistance, and sensitive fire detection still face challenges. In this work, we report a green and simple tannic acid-assisted mechanical exfoliation method to prepare few-layer modified molybdenum disulfide (TA-MoS<sub>2</sub>) nanosheets, which exhibit good dispersibility in water and polar organic solvents. Subsequently, the sol-gel and low-temperature self-assembly methods were used to prepare biomimetic TA-MoS<sub>2</sub>/p-phenylene benzobisoxazole (PBO) films with a biomimetic nacre structure. The films exhibit excellent flexibility and strength, with a tensile strength of 177.9 MPa. Besides, the films can maintain good integrity after folding and ultrasonic treatment. In addition, the film has excellent flame retardancy and can maintain good structural and dimensional stability under long-term (&gt;500 s) flame attack. More importantly, TA-MoS<sub>2</sub>/PBO films show sensitive reversible fire alarm response when attacked by fire and can repeat the warning with a super-fast recovery time (&lt;0.5 s). After multiple flame attacks, it can achieve long-lasting alarm (&gt;1200 s). Even after simulated complex environmental treatment, it can maintain good mechanical performance and warning effect and adapt to complex outdoor conditions. Therefore, this work provides a new approach for preparing high-strength flexible cyclic sensitive warning sensors.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102309"},"PeriodicalIF":6.5,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143422335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wet twisting treatment, process parameter optimisation and mechanical failure mechanisms of 3D printed carbon fibre reinforced composites
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-14 DOI: 10.1016/j.coco.2025.102308
Yaru Zhang , Wenkai Zheng , Xueming Feng , Yuzhong Wang , Qianyu Ji , Kaiyue Ma , Feifan Wu , Yuhang Xue , Wenhua Guo , Bingheng Lu
{"title":"Wet twisting treatment, process parameter optimisation and mechanical failure mechanisms of 3D printed carbon fibre reinforced composites","authors":"Yaru Zhang ,&nbsp;Wenkai Zheng ,&nbsp;Xueming Feng ,&nbsp;Yuzhong Wang ,&nbsp;Qianyu Ji ,&nbsp;Kaiyue Ma ,&nbsp;Feifan Wu ,&nbsp;Yuhang Xue ,&nbsp;Wenhua Guo ,&nbsp;Bingheng Lu","doi":"10.1016/j.coco.2025.102308","DOIUrl":"10.1016/j.coco.2025.102308","url":null,"abstract":"<div><div>Advancing continuous carbon fibre-reinforced polymers (CFRP) is vital for efficient stress transfer, lightweight design and fabrication of complex structures. 3D printing technology promises to be able to form arbitrarily specified structures of continuous carbon fibre (CCF). However, the chemical inertness and high viscosity of carbon fibres and resins render them susceptible to severe interfacial bonding problems and printing defects. The optimisation of materials and processes represents an efficacious methodology for the pursuit of improvement. Therefore, this study aimed to improve the mechanical properties of CCF-reinforced thermoplastic polyurethane (CCF/TPU) material system by optimising printing process parameters, path planning and proposing a novel wet-twist treatment strategy. The failure behaviour was further investigated and the mechanisms to improve CCF impregnation, reduce defects and enhance interfacial bonding were analysed. The findings revealed that the failure behaviour at optimum printing parameters was fibre breakage. The wet twisting process effectively improves the impregnation of CCF by TPU and imparts a macroscopic helical morphology to CCF, eliminating weak fibre knots. The tensile strength and modulus of elasticity of the optimised printed parts were significantly increased by 62.18 % and 87.16 %. This provides a feasible way to improve the mechanical properties of CFRP and broaden the application scenarios.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102308"},"PeriodicalIF":6.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143428660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of the shielding/passivation dual functions of PANI-SSA/epoxy composite coatings by rGO for long-term anti-corrosion of Al alloy
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-02-14 DOI: 10.1016/j.coco.2025.102302
Guohui Wang , Fandi Meng , Shenglong Zhu , Fuhui Wang , Li Liu
{"title":"Enhancement of the shielding/passivation dual functions of PANI-SSA/epoxy composite coatings by rGO for long-term anti-corrosion of Al alloy","authors":"Guohui Wang ,&nbsp;Fandi Meng ,&nbsp;Shenglong Zhu ,&nbsp;Fuhui Wang ,&nbsp;Li Liu","doi":"10.1016/j.coco.2025.102302","DOIUrl":"10.1016/j.coco.2025.102302","url":null,"abstract":"<div><div>Conductive polymers have attracted significant attention in the field of anti-corrosion coatings due to their unique passivation effects on certain metal substrates. In this work, a sulfosalicylic acid doped polyaniline (PANI-SSA)/reduced graphene oxide (rGO)/epoxy (P-r/EP) composite coating was proposed for the long-term anti-corrosion of Al alloys. The strategic introduction of rGO not only enhances the passivation ability of PANI-SSA but also improves the barrier effect of the composite coatings to the corrosive media. The results indicate that the addition of rGO reduces the defects of the composite coatings and improves the compactness of the composite coatings. Additionally, rGO exhibits outstanding electrical conductivity, facilitating the connection of PANI-SSA to form passivation networks in the local area of the composite coatings, thereby fully passivating the Al substrate to form a homogeneous and continuous oxide film. The P-r<sub>0.5</sub>/EP composite coating exhibits the most durable anti-corrosion performance with the |Z|<sub>0.01 Hz</sub> value of 5.55 × 10<sup>9</sup> Ω⋅cm<sup>2</sup> after 360 days of immersion, achieving an optimal balance between oxide film formation and the shielding performance of the composite coatings. Consequently, the P-r/EP composite coatings achieve a sustained passivation effect on the Al substrate and show broad potential for long-term anti-corrosion.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"55 ","pages":"Article 102302"},"PeriodicalIF":6.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143465457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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