Swetha P. , Sindhu Swaminathan , Kishore Sridharan , Mohamed Shahin T.H. , Faheema S.
{"title":"Modified negative permittivity and X-band microwave absorption in polyvinyl Alcohol–MWCNT metacomposites","authors":"Swetha P. , Sindhu Swaminathan , Kishore Sridharan , Mohamed Shahin T.H. , Faheema S.","doi":"10.1016/j.coco.2024.102161","DOIUrl":"10.1016/j.coco.2024.102161","url":null,"abstract":"<div><div>Metacomposite films with modifiable negative permittivity are promising for wearable cloaking, sensing, electromagnetic interference shielding, and microwave absorption. The purpose of this study is to fabricate metacomposite films composed of polyvinyl alcohol (PVA) and multi-walled carbon nanotubes (MWCNTs) and demonstrate control of permittivity by varying MWCNT concentration. Drude-Lorentz and Drude models show negative permittivity behaviour as the MWCNT content increases. The Drude-Lorentz and Drude models confirm that at 1 wt% MWCNT loading, percolation occurs, leading to increased conductivity and a transition from positive to negative permittivity (−9 at 10 kHz and −200 at 34 kHz). Drude's model predicts negative permittivity across the entire frequency range of PVA with 3 wt% MWCNT. Metacomposite films exhibit electrical percolation, conductivity switching, permittivity shift, and capacitive-to-inductive transitions. These composites also demonstrate excellent X-band microwave absorption properties (up to −50 dB reflection loss) and a shielding efficiency of 22 dB, suggesting an absorption-dominated shielding mechanism.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102161"},"PeriodicalIF":6.5,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ashwin Khadka , Shrayas Pradhan , Edmund Samuel , Bhavana Joshi , Hao Gao , Ali Aldalbahi , Govindasami Periyasami , Hae-Seok Lee , Sam S. Yoon
{"title":"Rapidly self-healing, highly conductive, stretchable, body-attachable hydrogel sensor for soft electronics","authors":"Ashwin Khadka , Shrayas Pradhan , Edmund Samuel , Bhavana Joshi , Hao Gao , Ali Aldalbahi , Govindasami Periyasami , Hae-Seok Lee , Sam S. Yoon","doi":"10.1016/j.coco.2024.102158","DOIUrl":"10.1016/j.coco.2024.102158","url":null,"abstract":"<div><div>Self-healing hydrogels are widely used in body-attachable sensors because they are stretchable, skin-friendly, highly sensitive, and mechanically strong. We developed a polyvinyl alcohol/poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PVA/PEDOT:PSS) hydrogel that responds rapidly and self-heals following external mechanical damage for use in body-attachable-sensor applications. The addition of ethylenediamine during hydrogel synthesis enhanced the crosslinking reaction and facilitated gelation. The hydrogel demonstrated a self-healing efficiency of 80 % and a gauge factor of 0.67 when strained in the 0–70 % range. The self-healing sensor exhibited response and recovery times of less than 0.25 s, with a self-healing time of less than 5 min. The self-healing sensor was tested for bodily motions, such as finger pressure, bending, voice vibration, severe stretching at 70 % strain, and stretching for 1000 continuous cycles.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102158"},"PeriodicalIF":6.5,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaofei Chen , Xinyuan Lv , Haitao Liu , Ru Jiang , Xun Sun
{"title":"Effect of matrix microstructure on micro- and macro-mechanical properties of 2.5D woven oxide fiber reinforced oxide matrix composites","authors":"Xiaofei Chen , Xinyuan Lv , Haitao Liu , Ru Jiang , Xun Sun","doi":"10.1016/j.coco.2024.102159","DOIUrl":"10.1016/j.coco.2024.102159","url":null,"abstract":"<div><div>A comprehensive learning of the mechanical behavior change mechanism of oxide/oxide composites is of great significance as a guide for their industrial applications. This study focused on examining how matrix microstructure impacted the micro- and macro-mechanical properties of the composites mainly by nanoindentation tests, macro-mechanical tests and x-ray computed tomography. The results showed that the sintering phenomenon of matrix sintered at 1200 °C was more obvious, and there were visible transverse and longitudinal cracks. The in-situ modulus of matrix and interfacial shear modulus of the composite increased by 61.1 % and 36.4 %, respectively, with the increase of matrix sintering densification. Combined with these micro-mechanical parameters of the composites, the He-Hutchinson model predicted the same crack propagation modes as those obtained from fracture toughness tests. Moreover, more matrix cracks directly led to a 45.4 % reduction in the flexural strength of the composites sintered at 1200 °C compared to that sintered at 1100 °C. In addition, a comparison analysis was conducted on the evolution of microstructure, micro- and macro-mechanical properties of 2.5D and 2D composites with the same preparation parameters.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102159"},"PeriodicalIF":6.5,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jinjiu Qi , Yuan Yuan , Qifa He , Pengtao Yang , Hua-Xin Peng , Runhua Fan
{"title":"Realizing radio-frequency epsilon-near-zero response via embedding cobalt nanoparticles into polyimide","authors":"Jinjiu Qi , Yuan Yuan , Qifa He , Pengtao Yang , Hua-Xin Peng , Runhua Fan","doi":"10.1016/j.coco.2024.102160","DOIUrl":"10.1016/j.coco.2024.102160","url":null,"abstract":"<div><div>Epsilon-near-zero (ENZ) materials have drawn considerable attention due to their enticing properties, such as large wavelength, quasi-static and tunneling. Most research on ENZ behaviors is conducted in the visible, microwave, and infrared bands, but there is seldom research in radio frequency (MHz ∼ GHz). In this work, polyimide (PI) embedded cobalt nanoparticles (NPs) were fabricated to realize ENZ behavior in MHz-bands. The percolation networks were constructed and the dielectric resonance frequency was observed for PI-35 wt% Co composite at 580 MHz. As Co content increased, the ENZ response was obtained due to dielectric resonance and plasma oscillation. Also, conduction mechanism of PI/Co composites undergo a change from hopping state to metal-like state. The reactance value changed from negative to positive with increasing frequency, corresponding to the transition of permittivity from positive to negative value.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102160"},"PeriodicalIF":6.5,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chuang Wang , XinFa Yang , HaoLin Zhang , Chi Chen , ZaiQin Zhang , He Li
{"title":"Comprehensive properties analysis of epoxy composites synergistically toughened with liquid nitrile rubber and polyethersulfone","authors":"Chuang Wang , XinFa Yang , HaoLin Zhang , Chi Chen , ZaiQin Zhang , He Li","doi":"10.1016/j.coco.2024.102154","DOIUrl":"10.1016/j.coco.2024.102154","url":null,"abstract":"<div><div>In this paper, epoxy resin (EP) composites with different phase structures were prepared by introducing hydroxyl-terminated liquid nitrile rubber (HTBN) and hydroxyl-terminated polyethersulfone (PES) individually or simultaneously into the resin matrix. The results revealed that the rational distribution of phase structure of rigid PES and flexible HTBN can effectively contributed to the enhancement in their mechanical and electrical insulation strengths. The synergistic effect of the two reinforcing fillers granted the optimized ternary composite a tougher structural network, leading to significant improvements of 73.13 % and 18.98 % in mechanical impact strength and electrical breakdown strength, respectively, compared to the pristine EP. Furthermore, compared to HTBN, PES exhibited inhibited HTBN dielectric interfacial polarization and EP molecular chain segment relaxation, resulting in decreased dielectric constant and loss in the composites. This study provide insights into the dielectric properties and design strategies for the development of resin-based dielectric materials, ensuring their broader applicability.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102154"},"PeriodicalIF":6.5,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Design optimization of continuous fiber composites with thermo-mechanical coupling and load uncertainties","authors":"Zhelong He , Jing Zheng , Qiang Chen , Jie Liu","doi":"10.1016/j.coco.2024.102143","DOIUrl":"10.1016/j.coco.2024.102143","url":null,"abstract":"<div><div>This paper introduces a theoretical framework for the design optimization of continuous fiber composites reinforced with continuous fiber trajectories subject to thermo-mechanical coupling and load uncertainties. Different uniform temperature variations are applied in the structure to investigate the influence of ambient temperature change on the structural performance. To consider the external load uncertainties, a robust design optimization model is proposed where the loads are modeled as hybrid variables, namely magnitudes as random variables and directions as interval variables, with the robust objective determined through a hybrid orthogonal polynomial expansion method. Furthermore, we use a level-set function to represent the structural boundary, with its evolution driven by shape derivatives calculated based on uncertainty analysis. The continuous fiber paths are subsequently determined by the level-set isoline extracted from the structural boundary, which in turn influences the structural mechanical performance due to the material anisotropy of composites. The continuity of continuous fiber and the equal space between adjacent trajectories largely ensure the additive manufacturability of the composites. Three numerical examples are presented to demonstrate the effectiveness of the developed framework. The results show that the ambient temperature variations and load uncertainties largely impact the optimized topology and fiber infill patterns of composites, thus are important to be considered in the design stage. Moreover, the optimized structure can have a 5-fold stiffness per unit mass compared with the initial design thus largely increasing the material efficiency in carrying external uncertain loads.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102143"},"PeriodicalIF":6.5,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study on the photocatalytic properties of the ternary ZnO/MgAl-LDH/FeOOH composite photocatalyst with a Type-II and S-scheme linked carrier migration mechanism in degrading TC solution","authors":"Xuying Duan , Fucheng Yu , Ruobing Jiang , Jinlong Ren , Jielin Zhang , Chenchen Feng , Cuixia Li , Kechao Hu , Xiaogang Hou","doi":"10.1016/j.coco.2024.102156","DOIUrl":"10.1016/j.coco.2024.102156","url":null,"abstract":"<div><div>The synthesis of high-performance photocatalysts represents a pivotal aspect of research into photocatalytic degradation technology. In order to address this need, a novel ZnO/MgAl-LDH/FeOOH ternary composite photocatalyst has been synthesized via a multi-step process involving the hydrothermal, calcination and ultrasonic-assisted wet impregnation methods. The ternary composite photocatalyst was observed to demonstrate effective separation of photogenerated carriers in photocatalysis, following a Type-II and S-scheme linked carrier migration mechanism. An examination of the photocatalytic characteristics of the composite photocatalyst in the degradation of a tetracycline (TC) solution revealed that the reduction of •O<sub>2</sub><sub><sup>-</sup></sub> radicals and the oxidation of •OH radicals resulted in the effective degradation of the TC solution. The degradation efficiency of the TC solution under the photocatalysis of the ternary composite photocatalyst was observed to be 1.54, 1.11 and 3.15 times that of the single-component samples of ZnO, MgAl-LDH and FeOOH, respectively, in 30 min. Moreover, the degradation pathway of TC molecules under the photocatalysis of the composite has been elucidated. The research findings provide a foundation for further investigation into this composite photocatalyst.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102156"},"PeriodicalIF":6.5,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yingxin Liu , Minhua Jiang , Junying Hu , Zixuan Guo , Jian Liu , Xinxin Fu , Li Liu , Shaohua Jiang
{"title":"Polypyrrole-bound carbon nanotube conductive polysulfone membranes for self-cleaning of fouling","authors":"Yingxin Liu , Minhua Jiang , Junying Hu , Zixuan Guo , Jian Liu , Xinxin Fu , Li Liu , Shaohua Jiang","doi":"10.1016/j.coco.2024.102155","DOIUrl":"10.1016/j.coco.2024.102155","url":null,"abstract":"<div><div>A novel conductive membrane, polypyrrole carbon nanotubes polysulfone (PPy-CNT-PSF), was successfully synthesized using the membrane phase infiltration in-situ polymerization method (MPIP). The resulting PPy-CNT-PSF, utilized as an anode in the electrochemical filtration reactor, exhibited a chain-like morphology of PPy extending from within to the exterior of the PSF membrane, effectively anchoring the CNT layer on its surface and establishing a stable conductive network with a surface resistance of 0.142 ± 0.052 kΩ/cm. Its electrical conductivity surpasses that of most conductive membranes derived from pyrrole (Py). Furthermore, the structural integrity of this conductive membrane remained intact following exposure to chlorine. Cyclic voltammetry (CV) analysis revealed a subtle redox peak with no significant alteration in surface structure after 50 CV cycles. This reaction can be attributed to a Fenton-like reaction process due to Fe presence detected by EDX on the surface. Current-time curves under constant potential further confirmed that the PPy-CNT-PSF conductive membrane possesses both a stable conductive network and favorable electrode stability. Additionally, self-cleaning occurred when voltage was applied during electrochemical experiments utilizing a conductive membrane anode paired with a Ti cathode due to electrostatic repulsive forces. At an applied voltage of 20 V, removal efficiency and flux restoration achieved values of 97.63 % and 100 %, respectively. This straightforward yet effective approach is believed to hold promise for fabricating conductive membranes characterized by structural stability and electrode reliability for practical applications aimed at mitigating membrane fouling.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102155"},"PeriodicalIF":6.5,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shanmugam Logesh, Yi Wen Cheah, Keen Hoe Ho, Brindha K. Rajan, Clara Cher Lin Tan, Andi Haris, Chen Wang
{"title":"Flexural behaviours and heterogeneous interface fracture in overmoulded multi-material thermoplastic composites","authors":"Shanmugam Logesh, Yi Wen Cheah, Keen Hoe Ho, Brindha K. Rajan, Clara Cher Lin Tan, Andi Haris, Chen Wang","doi":"10.1016/j.coco.2024.102152","DOIUrl":"10.1016/j.coco.2024.102152","url":null,"abstract":"<div><div>The development of lightweight multi-material composites is imperative to meet the demands of the aerospace and automotive industries. Thermoplastic-based multi-material composites represent a novel approach, wherein two or more distinct composite materials are combined to create a hybrid material with enhanced performance characteristics. However, varying failure modes across multi-scale interfaces in the composites affect their mechanical performance in a complex manner. In this study, multi-material composites were manufactured through overmoulding of virgin polycarbonate (VP) and short-fibre reinforced polycarbonate (SFP) on continuous fibre-reinforced thermoplastic polycarbonate (CFRTP) laminate to assess behaviours of heterogeneous interfaces and structural performance under flexural loading. In the compression overmoulding process, the consolidation of thermoplastics creates interdiffusion of polymer chains across the multi-material interfaces. The multi-material composites successfully demonstrated enhanced flexural properties compared to single material constituent such as VP, SFP, and CFRTP. Benchmarking with CFRTP composite laminates, results revealed that overmoulding SFP on CFRTP results in 319 % higher flexural strength and 36 % higher of flexural modulus. VP/CFRTP composite offered 103 % more flexural strain and 175 % more specific energy absorption during fracture. Strategic optimization of the neutral axis (NA) and integration of high modulus materials in multi-material systems contributed to such performance enhancements. Failure analysis conducted using optical microscope and scanning electron microscopy (SEM) revealed progressive heterogeneous interface fracture and crack propagation in the CFRTP laminate layer. Results indicated that control of interface failure modes need to be considered in multi-material structure design to achieve desired flexural strength.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102152"},"PeriodicalIF":6.5,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fushuai Wang, Xinhui Geng, Chi Zhang, Qiang Gao, Liancai Xun, Wuju Wang, Xinghong Zhang, Ping Hu
{"title":"Study of microscale heat transfer in UHTCMCs based on deep learning and finite element analysis","authors":"Fushuai Wang, Xinhui Geng, Chi Zhang, Qiang Gao, Liancai Xun, Wuju Wang, Xinghong Zhang, Ping Hu","doi":"10.1016/j.coco.2024.102150","DOIUrl":"10.1016/j.coco.2024.102150","url":null,"abstract":"<div><div>The microstructure of ultra-high temperature ceramic matrix composites (UHTCMCs) is extremely complex, making it particularly challenging to conduct precise heat transfer analysis that accurately reflects the material's true structural features due to their heterogeneous multiphase characteristics. In this study, we propose a heat transfer model that combines deep learning with finite element analysis, which is used for feature extraction and heat transfer analysis of the microstructure of ultra-high temperature ceramic matrix composites, allowing for the calculation of effective thermal conductivity to predict the material's macroscopic thermal conductivity. Microstructural feature recognition is achieved by segmenting the phase structure of ultra-high temperature ceramic matrix composites using the BSE/EDS images, through the construction of the Unet deep learning model. Additionally, the structural mapping mesh method is employed to convert the actual structural information of the reactive material into a finite element mesh model for a detailed analysis of its micro-scale heat transfer characteristics. The macroscopic thermal conductivities of the materials are obtained by statistically calculating the thermal conductivities of the microscopic sections, showing consistency with the thermal conductivities from the theoretical model and the experiment. This study effectively reveals the heat transfer characteristics from the complex microstructure of UHTCMCs.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"52 ","pages":"Article 102150"},"PeriodicalIF":6.5,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}