Next EnergyPub Date : 2024-09-10DOI: 10.1016/j.nxener.2024.100188
{"title":"Critical temperature-dependent adsorption selectivity of binary gas mixtures in slit pores: Insights from Gibbs ensemble Monte Carlo simulations","authors":"","doi":"10.1016/j.nxener.2024.100188","DOIUrl":"10.1016/j.nxener.2024.100188","url":null,"abstract":"<div><p>We conducted constant pressure Gibbs ensemble Monte Carlo molecular simulations to explore the adsorption separation of 3 binary gas mixtures: CH<sub>4</sub>/CO, C<sub>2</sub>F<sub>6</sub>/N<sub>2</sub>, and SO<sub>2</sub>/CO<sub>2</sub> within slit pores. Key findings indicate that CH<sub>4</sub>/CO, a mixture of 2 supercritical gases at room temperature, shows modest adsorption selectivity of around 4, even at elevated pressures of 20 MPa. In contrast, the C<sub>2</sub>F<sub>6</sub>/N<sub>2</sub> mixture, consisting of supercritical N<sub>2</sub> and C<sub>2</sub>F<sub>6</sub> near its critical temperature, exhibits significantly higher selectivity, reaching tens to hundreds. The SO<sub>2</sub>/CO<sub>2</sub> mixture, with both gases in a subcritical state at room temperature, displays intermediate selectivity between the other 2 systems. Our simulations revealed that the adsorption selectivity for CH<sub>4</sub>/CO and C<sub>2</sub>F<sub>6</sub>/N<sub>2</sub> mixtures displays distinct single- and double-peaked trends with varying pore widths under medium to high pressures, corresponding to monolayer and bilayer adsorption phenomena. The SO<sub>2</sub>/CO<sub>2</sub> system, however, presented a more intricate adsorption mechanism, potentially involving 3-layer molecular adsorption within the pores. Expanding our investigation to 276 mixtures, we discovered an important trend: a higher ratio of critical temperatures between mixture components correlates with increased adsorption selectivity and simplified separation processes. Intriguingly, when this ratio approaches unity, separation difficulty escalates. Additionally, we identified a significant linear relationship between adsorption selectivity and the ratio of adsorption heats at low pressures (0.1 MPa) for a pore width of 0.8 nm, underscoring the impact of thermodynamic properties on separation efficacy. These insights are crucial for the development of energy-efficient gas separation materials, which are vital for applications such as natural gas purification and carbon capture and storage, contributing to a sustainable energy future.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000930/pdfft?md5=9d40c8a9279634306cb44f9b73ce7697&pid=1-s2.0-S2949821X24000930-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-10DOI: 10.1016/j.nxener.2024.100190
{"title":"Enhancing 3G ETA solar cells with novel Bi2Se3 nanoparticles synthesized on TiO2: Impact of immersion cycles on PEC performance","authors":"","doi":"10.1016/j.nxener.2024.100190","DOIUrl":"10.1016/j.nxener.2024.100190","url":null,"abstract":"<div><p>The development of unexposed layer heterostructures by integrating metal chalcogenide semiconductors with metal oxide arrays offers a promising approach to enhance surface area, expand optical response, and improve charge kinetics key factors for achieving high-performance photoconversion devices. In this study, we introduce a facile, room-temperature chemical method using successive ionic layer adsorption and reaction (SILAR) to deposit Bi<sub>2</sub>Se<sub>3</sub> nanoparticles onto spin-coated TiO<sub>2</sub> arrays. We systematically explore the structural, optical, and surface morphological properties of the resulting TiO<sub>2</sub>/Bi<sub>2</sub>Se<sub>3</sub> heterostructures. Our findings reveal that the thin layer of Bi<sub>2</sub>Se<sub>3</sub> nanoparticles uniformly coats the porous TiO<sub>2</sub>, extending its optical response into the visible region. We also examine the charge kinetics and solar cell performance of devices constructed with an fluorine doped tin oxide (FTO)/TiO<sub>2</sub>/Bi<sub>2</sub>Se<sub>3</sub>/polysulfide/carbon-coated FTO sandwich-type architecture. Through comparative analysis, we assess the initial characterizations, charge kinetics, and photovoltaic performance of the TiO<sub>2</sub>/Bi<sub>2</sub>Se<sub>3</sub> heterostructures across different SILAR cycles. Our results demonstrate a significant enhancement in photocurrent for the bilayer TiO<sub>2</sub>/Bi<sub>2</sub>Se<sub>3</sub> architecture (0.55 mA/cm²) compared to bare TiO<sub>2</sub> (0.041 mA/cm²). This research highlights the potential of the proposed heterostructure to improve the efficiency of energy conversion devices.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000954/pdfft?md5=e3b3f92c047cb9bc158f3b85aea9e7b5&pid=1-s2.0-S2949821X24000954-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-07DOI: 10.1016/j.nxener.2024.100185
{"title":"Enhancing photovoltaic systems: A comprehensive review of cooling, concentration, spectral splitting, and tracking techniques","authors":"","doi":"10.1016/j.nxener.2024.100185","DOIUrl":"10.1016/j.nxener.2024.100185","url":null,"abstract":"<div><p>As the demand for renewable energy sources continues to rise, the integration of solar photovoltaic technology has emerged as a promising solution. But since these panels benefit from only about 15–20% of the radiation falling on them, the current trend has been towards improving the performance of these panels and raising their efficiency to benefit from the greatest possible amount of solar radiation. In this regard, this review presents a thorough examination of the latest advancements in enhancing photovoltaic (PV) systems, with a focus on cooling techniques, concentration methods, spectral splitting filtering, and tracking systems. A comprehensive analysis of both passive and active cooling technologies was presented, where cooling improves the efficiency of the panel to up to 25%, in addition to the possibility of integrating PV modules with thermal collectors to exploit the wasted heat in what is known as Photovoltaic/thermal systems (PV/T). Additionally, the study explores various types of concentrated PV (CPV) systems, such as flat concentrators, compound parabolic concentrators, and Fresnel lenses, which can lead to 10% increase in the panel efficiency. The paper also introduces the concept of spectral splitting filtering, covering reflective and absorptive methods to optimize solar energy utilization, which is considered a new technology cooling method. Furthermore, it delves into tracking systems for PV modules which can cause an increase in efficiency about 20%. The novelty of this review lies in its up-to-date coverage of the latest research and advancements in PV system enhancement. There are several studies that deal with a specific modification to improve the performance of the PV panel, while this study provides a comprehensive overview of the state-of-the-art techniques including four different types of modern modifications and analyzes them extensively to reach the best possible configuration, as this review aims to contribute to the continued development of effective and sustainable photovoltaic systems.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000905/pdfft?md5=b1104aace7ede852e942705971868bb0&pid=1-s2.0-S2949821X24000905-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-06DOI: 10.1016/j.nxener.2024.100187
{"title":"Improving the efficiency of kesterite solar cells using semi-ellipsoidal nanostructures","authors":"","doi":"10.1016/j.nxener.2024.100187","DOIUrl":"10.1016/j.nxener.2024.100187","url":null,"abstract":"<div><p>The use of kesterite materials in photovoltaic solar cells holds great promise due to their abundance, non-toxic nature, cost-effectiveness, and excellent optoelectronic properties. However, the power conversion efficiency of kesterite solar cells remains considerably below the Shockley-Queisser limit efficiency. This underscores the need for continuous development of new cell designs to maximize kesterite's potential for solar energy conversion. In this study, we presented a novel design for a kesterite solar cell incorporating semi-ellipsoidal nanostructures into the active layer to overcome its limitations and achieve higher efficiencies. Comprehensive simulations were conducted to study the effect of these nanostructures on solar cell performance. An extensive parametric study was also performed to identify the design parameters for the best performance. The results revealed that the presence of nanostructures significantly enhances power conversion efficiency, reaching a remarkable 17.6%, overcoming many challenging obstacles facing kesterite solar cells and making them more competitive in the ever-expanding solar cell market.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000929/pdfft?md5=a1ed85c10ebf80e7a60d4afb8f88c32e&pid=1-s2.0-S2949821X24000929-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-05DOI: 10.1016/j.nxener.2024.100189
{"title":"Correlation of acoustic emission signatures with electrochemical and mechanical behavior in Li-ion batteries: A comprehensive method for in-operando acoustic emission analysis","authors":"","doi":"10.1016/j.nxener.2024.100189","DOIUrl":"10.1016/j.nxener.2024.100189","url":null,"abstract":"<div><p>As the demand for high-performance and long-lasting batteries continues to escalate, understanding the degradation mechanisms of Li-ion batteries (LIBs) has become a pressing concern. In this study, we employed the acoustic emission (AE) technique to detect and quantify the internal changes occurring within LIBs during the degradation processes. Our goal was to propose a comprehensive method to categorize the AE data and correlate them with different battery events, which has not yet been properly established in the state of the art. Two commercial pouch cells at different levels of degradation were monitored using the AE technique during their cycling, and the changes in their electrochemical and mechanical behavior were analyzed. A thorough investigation of the AE hits enabled us to identify 4 distinct AE types in terms of frequency, which could reflect multiple battery degradation events, including intercalation-induced stress, gas generation, and particle/electrode cracking. Our proposed approach was compared with the conventional methods presented in past studies, demonstrating its compatibility in explaining different battery phenomena and the coupled behavior of those phenomena. Overall, this work offers a new approach to <em>in-operando</em> AE analysis of LIBs, which helps further development of the AE technique as a real-time and nondestructive diagnostic tool for LIBs.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000942/pdfft?md5=3b775895fa6a479553ab288a91328a8d&pid=1-s2.0-S2949821X24000942-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-05DOI: 10.1016/j.nxener.2024.100183
{"title":"In situ electrochemical redox tuning of MXene-Co-MOF to MXene/TiO2@Co3O4 nanosheet with enhanced activity and stability","authors":"","doi":"10.1016/j.nxener.2024.100183","DOIUrl":"10.1016/j.nxener.2024.100183","url":null,"abstract":"<div><p>Supercapacitors have witnessed significant development in recent years due to their high power density, fast charging rate, and excellent cycle stability, which can be used in wearable devices, electric wheel loader, and other energy storage systems for needing high discharge rate. Designing a simple synthetic protocol to simultaneously produce electrode materials with high activity and stability is a significant challenge for high-performance supercapacitors. Herein, we developed an one-step <em>in situ</em> electrochemical oxidation method to develop MXene/TiO<sub>2</sub>@Co<sub>3</sub>O<sub>4</sub> nanosheets at room temperature and neutral solution from their corresponding MXene-Co-MOF. The dual role of <em>in-situ</em> electrochemical oxidation reaction was presented: (1) the electrochemical oxidation reaction facilitates the decomposition of Co<sub>3</sub>(HHTP)<sub>2</sub> MOF to Co<sub>3</sub>O<sub>4</sub> and the transformation of the part of MXene to TiO<sub>2</sub>; (2) the electrochemical oxidation reaction enhances the Faradaic activity of electrode materials by forming more active sites on weak crystalline MXene/TiO<sub>2</sub>@Co<sub>3</sub>O<sub>4</sub>. The electrochemically tuned MXene/TiO<sub>2</sub>@Co<sub>3</sub>O<sub>4</sub> nanosheets grown directly on the Ni foam electrodes exhibit high specific capacitance of up to 2403 F g<sup>−1</sup> at current density of 1 A g<sup>−1</sup>. When assembled into an asymmetric supercapacitors (ASC) device, the MXene/TiO<sub>2</sub>@Co<sub>3</sub>O<sub>4</sub>//AC device obtains a high energy density of 55.8 Wh kg<sup>−1</sup> at a power density of 799.7 W kg<sup>−1</sup> and appears 78.6% retention after 5000 cycles stability test. The improved activities are attributed to the introduction of oxygen vacancies, more active sites with poor-crystalline phase. This work provides a promising <em>in situ</em> electrochemistry strategy to develop electrode materials alternatives for supercapacitor applications.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000887/pdfft?md5=43bd87a7a2c7650b0c54e8bc43482583&pid=1-s2.0-S2949821X24000887-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142135928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-03DOI: 10.1016/j.nxener.2024.100186
{"title":"Thermal runaway process in lithium-ion batteries: A review","authors":"","doi":"10.1016/j.nxener.2024.100186","DOIUrl":"10.1016/j.nxener.2024.100186","url":null,"abstract":"<div><p>Climate change and global warming represent critical challenges for the 21st century, partly attributable to the combustion of fossil fuels. The adoption of alternative energy sources presents viable solutions to mitigate these challenges. Among the strategies to address climate change, lithium-ion batteries (LIBs) have emerged as increasingly important. However, the advancement of LIB technology is hindered by the phenomenon of thermal runaway (TR), which constitutes the primary failure mechanism of LIBs, potentially leading severe fires and explosions. This review provides a comprehensive understanding of the TR mechanisms in LIBs, which vary significantly depending on the battery’s materials. Extensive research has been conducted on the component materials of LIBs, the causes triggering TR, and the mechanisms underlying TR in laboratory settings. Yet, further research to fully understand and mitigate TR is necessary as it is a highly complex process that is readily influenced by both external conditions and internal reactions. For LIBs composed of different materials, the processes and mechanisms underlying TR exhibit significant variations. Therefore, this review emphasizes the need to study various battery cells to gain a comprehensive understanding of the TR mechanisms. The focus of this review lies in elucidating the diverse TR mechanisms, preventive methods, and highlighting recent key progresses in research aimed at improving the safety of LIBs. Finally, this review concludes with recommendations for future research and development on the safety of LIBs, emphasizing the need for a more coherent view of TR mechanisms and LIB safety.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000917/pdfft?md5=a009dfce313becd08f0e8e52154c7330&pid=1-s2.0-S2949821X24000917-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142128284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-03DOI: 10.1016/j.nxener.2024.100184
{"title":"Coordination unsaturated structure of titanium sulfate promoting the carbon chain growth for dimethyl ether oxidation","authors":"","doi":"10.1016/j.nxener.2024.100184","DOIUrl":"10.1016/j.nxener.2024.100184","url":null,"abstract":"<div><p>Polyoxymethylene dimethyl ethers (DMM<sub><em>x</em></sub>, CH<sub>3</sub>O(CH<sub>2</sub>O)<sub><em>x</em></sub>CH<sub>3</sub>, <em>x</em> = 1–8) are appealing oxygenated chemicals with potential applications mainly used as sustainable fuels and solvents. The growth of longer C-O chain for direct oxidation of dimethyl ether (DME) to DMM<sub><em>x</em></sub> is especially important, but the construction of the acid sites with different strengths and matched redox sites faces great difficulties. Herein, the gradient acidity and enhanced oxidizability have been successfully created by regulating coordination structure of titanium sulfate (Ti(SO<sub>4</sub>)<sub><em>x</em></sub>). The formation of a higher proportion of weak-medium acid sites and appropriate redox sites over a Ti(SO<sub>4</sub>)<sub><em>x</em></sub>/activated carbon (AC) catalyst with nitrogen treatment significantly promotes the synthesis of larger molecules, with DMM<sub>2–3</sub> selectivity up to 42.2%. Combined with the characterizations, designed experiments and theoretical calculations, the configurations of Ti(SO<sub>4</sub>)<sub><em>x</em></sub> and their local chemical environment are revealed. The different distortions of Ti(SO<sub>4</sub>)<sub><em>x</em></sub> structure in nitrogen atmosphere result in the various coordination unsaturated Ti atoms located at the center of polyhedral, which is the main reason for the gradient acidity distribution and enhanced oxidative property.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000899/pdfft?md5=2df4a2d9b14b0c6b9d0654993da3b4d7&pid=1-s2.0-S2949821X24000899-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142128288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-09-03DOI: 10.1016/j.nxener.2024.100182
{"title":"Performance optimization of a novel perovskite solar cell with power conversion efficiency exceeding 37% based on methylammonium tin iodide","authors":"","doi":"10.1016/j.nxener.2024.100182","DOIUrl":"10.1016/j.nxener.2024.100182","url":null,"abstract":"<div><p>The development of highly efficient lead-free solar cells is essential for sustainable energy production in the face of depleting fossil fuel resources and the negative effects of climate change. Perovskite solar cells (PSCs) containing lead pose considerable environmental and public health hazards, in addition to thermal stability and longevity challenges. Here, a novel lead-free solar cell design of the configuration, ITO/PC<sub>61</sub>BM/CH<sub>3</sub>NH<sub>3</sub>SnI<sub>3</sub>/PEDOT:PSS/Mo, is investigated for improved light harvesting capabilities, enhanced device performance, and better operational efficiency under various temperature conditions. The optimal thickness of the light-absorbing layer, CH<sub>3</sub>NH<sub>3</sub>SnI<sub>3</sub>, was found to be 1000 nm for maximum quantum efficiency (QE). Further, the temperature tolerance of the solar cell was evaluated using Mott-Schottky (MS) capacitance analysis and showed that the model cell retains about 95% of its power at 400 K, demonstrating excellent thermal stability and robust performance. The solar cell also shows promising electrical output parameters, including a short-circuit current density (J<sub>sc</sub>) of 34.84 mA/cm², open-circuit voltage (V<sub>oc</sub>) of 1.5226 V, Fill factor (FF) of 71.04%, and an impressive power conversion efficiency (PCE) of 37.66% at 300 K. The effect of buffer layers such as CdS, ZnS, ZnSe, and V<sub>2</sub>O<sub>5</sub> on the electrical outcomes of the model cell structure has been critically examined. Additionally, parasitic resistances and doping characteristics on the operational performance of the cell have been explored in detail. This work therefore, provides remarkable insights in the field of solar energy harvesting, offering potential sustainable energy generation solutions, supporting de-carbonization of the environment and climate change mitigation efforts towards an energy sustainable future.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X24000875/pdfft?md5=b250283501ac5e12171ecab7eeaa7d7e&pid=1-s2.0-S2949821X24000875-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142128285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Next EnergyPub Date : 2024-08-31DOI: 10.1016/j.nxener.2024.100179
{"title":"Environmentally friendly production of petroleum systems with high CO2 content","authors":"","doi":"10.1016/j.nxener.2024.100179","DOIUrl":"10.1016/j.nxener.2024.100179","url":null,"abstract":"<div><p>Natural gas hydrates represents a huge source of energy. At the same time substantial leakages of natural gas from hydrates contributes significantly to climate changes. One of the most important reasons for these natural gas fluxes is leakage of seawater in to the hydrates from seafloor, through fracture systems. Hydrate dissociates if surrounding seawater is less than hydrate stability limit. Another interesting aspect of natural gas hydrates is the potential for safe CO<sub>2</sub> storage. These different aspects of hydrates in natural sediments put demands on thermodynamic models. In addition to accurate description of pressure temperature hydrate stability there also a need to describe hydrate dissociation in concentration gradients towards surrounding water or surrounding gas as two examples. In this work we present new experimental data and an extensive thermodynamic model for hydrate. In contrast to conventional thermodynamic models for hydrate the model is consistent since all thermodynamic properties are derived from the Gibbs free energy. In this work we examine mixtures of CH<sub>4</sub>, C<sub>2</sub>H<sub>6</sub>, N<sub>2</sub>, CO<sub>2</sub> from the China Sea and some synthetic mixtures, using this model. Maximum CO<sub>2</sub> content in these mixtures are 60 mol% and the rest is dominated by CH<sub>4</sub>. Agreement between experimental data and model calculations are generally good and average deviations are below 5.5% for all the systems and conditions examined. Another aspect of the model is the ability for incorporation of effects of mineral surfaces. Specifically it is illustrated that adsorption of water on rust dominates liquid water drop out from gas as compared to water dew-point. Production of natural gas with such high CO<sub>2</sub> content requires a strategy for CO<sub>2</sub> separation and storage. It is proposed that the CH<sub>4</sub> is separated from the C<sub>2</sub>H<sub>6</sub>, CO<sub>2</sub> and N<sub>2</sub> and cracked to H<sub>2</sub> and CO<sub>2</sub> using steam. Thermodynamic analysis indicates a significant potential for safe CO<sub>2</sub> storage in natural gas hydrate and H<sub>2</sub> as the only export product.</p></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949821X2400084X/pdfft?md5=266f79a863d4e1ecd73da3f5956a0086&pid=1-s2.0-S2949821X2400084X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142098526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}