Chinese Chemical Letters最新文献

Corrigendum to “The complexation of insulin with sodium N‐[8‐(2‐hydroxybenzoyl)amino]‐caprylate for enhanced oral delivery: Effects of concentration, ratio, and pH” [Chinese Chemical Letters 33 (2022) 1889-1894] “胰岛素与N‐[8‐（2‐羟基苯甲酰）氨基]‐辛酸钠络合增强口服给药：浓度、比例和pH值的影响”的更正[中国化学快报33 (2022)1889-1894]

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-06 DOI: 10.1016/j.cclet.2025.111316

Huixian Weng , Lefei Hu , Lei Hu , Yihan Zhou , Aohua Wang , Ning Wang , Wenzhe Li , Chunliu Zhu , Shiyan Guo , Miaorong Yu , Yong Gan

引用次数: 0

PVP decorated H3.78V6O13 microspheres assembled by nanosheets for aqueous zinc ion batteries at variable work temperature 用纳米片组装PVP修饰的H3.78V6O13微球用于变工作温度下的锌离子电池

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-01 DOI: 10.1016/j.cclet.2024.110185

Chunru Zhao , Yi Liu , Shilong Li , Xiang Wu , Jinghai Liu

引用次数: 0

Nature's revelation: Preparation of Graphene-based Biomimetic materials and its application prospects for water purification 大自然的启示：石墨烯仿生材料的制备及其在水净化中的应用前景

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-01 DOI: 10.1016/j.cclet.2024.110319

Huining Zhang , Baixiang Wang , Jianping Han , Shaofeng Wang , Xingmao Liu , Wenhui Niu , Zhongyu Shi , Zhiqiang Wei , Zhiguo Wu , Ying Zhu , Qi Guo

{"title":"Nature's revelation: Preparation of Graphene-based Biomimetic materials and its application prospects for water purification","authors":"Huining Zhang , Baixiang Wang , Jianping Han , Shaofeng Wang , Xingmao Liu , Wenhui Niu , Zhongyu Shi , Zhiqiang Wei , Zhiguo Wu , Ying Zhu , Qi Guo","doi":"10.1016/j.cclet.2024.110319","DOIUrl":"10.1016/j.cclet.2024.110319","url":null,"abstract":"<div><div>Pollutants contained in wastewater pose serious harm to the environment. Graphene-based water treatment materials show significant advantages in wastewater treatment. However, with the development of graphene-based materials, its progress in water treatment has reached a bottleneck. The challenge lies in effectively enhancing its performance in water treatment and ensuring its practicality. By employing biomimetic approaches, some exceptional properties and structures found in nature can be mimicked in graphene materials, effectively enhancing graphene's adsorption and mechanical properties. Current biomimetic methods include biomimetic mineralization, self-assembly, and templating. unfortunately, all of the above methods suffer from the disadvantages of complexity and poor bionic effect. Nevertheless, 3D printing, a form of additive manufacturing (AM) technology, offers integrated molding and excellent biomimetic performance in creating biomimetic materials. This paper will cover the following aspects: (1) An overview of objects suitable for bionics in terms of functional and structural aspects, along with their properties, and a discussion of various bionic objects combined with graphene materials in water treatment and related research; (2) a comparison of different methods for preparing graphene-based bionic materials; (3) an examination of the current drawbacks and limitations of graphene-based biomimetic materials; and (4) a conclusion and future prospects, exploring the potential of using 3D printing technology to produce graphene biomimetic materials. This review aims to serve as a guide for effectively leveraging natural inspirations to create graphene-based biomimetic materials and enhance graphene properties.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 6","pages":"Article 110319"},"PeriodicalIF":9.4,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144222603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

IFC - Editorial Board/ Publication info IFC -编辑委员会/出版信息

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-01 DOI: 10.1016/S1001-8417(25)00424-3

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Modulation of desolvation barriers and inhibition of lithium dendrites based on lithophilic electrolyte additives for lithium metal anode 锂金属阳极亲石电解质添加剂对锂枝晶脱溶障碍和抑制作用的调节

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-01 DOI: 10.1016/j.cclet.2024.110669

Qian Wang , Dong Yang , Wenxing Xin , Yongqi Wang , Wenchang Han , Wengxiang Yan , Chunman Yang , Fei Wang , Yiyong Zhang , Ziyi Zhu , Xue Li

{"title":"Modulation of desolvation barriers and inhibition of lithium dendrites based on lithophilic electrolyte additives for lithium metal anode","authors":"Qian Wang , Dong Yang , Wenxing Xin , Yongqi Wang , Wenchang Han , Wengxiang Yan , Chunman Yang , Fei Wang , Yiyong Zhang , Ziyi Zhu , Xue Li","doi":"10.1016/j.cclet.2024.110669","DOIUrl":"10.1016/j.cclet.2024.110669","url":null,"abstract":"<div><div>Lithium metal has emerged as a highly promising anode material for enhancing the energy density of secondary batteries, attributed to its high theoretical specific capacity and low electrochemical potential. However, safety concerns related to lithium dendrite-induced short circuits and suboptimal electrochemical performance have impeded the commercial viability of lithium metal batteries. Current research efforts primarily focus on altering the solvated structure of Li<sup>+</sup> by modifying the current collector or introducing electrolyte additives to lower the nucleation barrier, expedite the desolvation process, and suppress the growth of lithium dendrites. Nevertheless, an integrated approach that combines the advantages of these two strategies remains elusive. In this study, we successfully employed metal-organic salt additives with lithophilic properties to accelerate the desolvation process, reduce the nucleation barrier of Li<sup>+</sup>, and modulate its solvated structure. This approach enhanced the inorganic compound content in the solid electrolyte interphase (SEI) on lithium foil surfaces, leading to stable Li<sup>+</sup> deposition and stripping. Specifically, Li||Cu cells demonstrated excellent cycle life and Coulombic efficiency (97.28% and 98.59%, respectively) at 0.5 mA/cm<sup>2</sup>@0.5 mAh/cm<sup>2</sup> and 1 mA/cm<sup>2</sup>@1 mAh/cm<sup>2</sup> for 410 and 240 cycles, respectively. Li||Li symmetrical cells showed no short circuit at 1 mA/cm<sup>2</sup>@1 mAh/cm<sup>2</sup> for 1150 h, and Li||LFP full cells retained 68.9% of their capacity (104.6 mAh/g) after 250 cycles at N/P (1.1:1.0) with a current density of 1 C.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 6","pages":"Article 110669"},"PeriodicalIF":9.4,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144222604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Indium-captured zirconium-porphyrin frameworks displaying rare multi-selectivity for catalytic transfer hydrogenation of aldehydes and ketones 铟捕获的锆卟啉框架对醛和酮的催化转移加氢具有罕见的多选择性

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-06-01 DOI: 10.1016/j.cclet.2024.110593

Hua Liu , Jian Zhao , Qi Li , Xiang-Yu Zhang , Zhi-Wei Zheng , Kun Huang , Da-Bin Qin , Bin Zhao

{"title":"Indium-captured zirconium-porphyrin frameworks displaying rare multi-selectivity for catalytic transfer hydrogenation of aldehydes and ketones","authors":"Hua Liu , Jian Zhao , Qi Li , Xiang-Yu Zhang , Zhi-Wei Zheng , Kun Huang , Da-Bin Qin , Bin Zhao","doi":"10.1016/j.cclet.2024.110593","DOIUrl":"10.1016/j.cclet.2024.110593","url":null,"abstract":"<div><div>Selective catalytic transfer hydrogenation (CTH) of carbonyl compounds to obtain specific alcohols holds significant importance across various fields. Achieving multiple selectivity in CTH is particularly crucial, but full of great challenge. Herein, a cationic In-captured Zr-porphyrin framework (<strong>1</strong>) with nanosized pores/cages was successfully constructed and showed high structure stability. Catalytic investigations revealed that <strong>1</strong> displayed highly multi-selective CTH of aldehydes and ketones containing both chemo- and size selectivity for the first time. The CTH of aldehydes and ketones exhibited remarkable reductive selectivity of 99% towards C<img>O bonds into CH<img>OH in the presence of -NO<sub>2</sub>, -CN and C<img>C groups. Through tuning the reaction conditions, <strong>1</strong> also exhibited highly selective reduction of 97% for -CHO groups in the simultaneous presence of -CHO and -COCH<sub>3</sub> groups in intra- and intermolecular settings. Remarkably, reductive selectivity towards -CHO group remained prominent among five concurrent unsaturated groups mentioned above. Additionally, the definite pore size of <strong>1</strong> facilitated volume control of substrates, enabling size selectivity. <strong>1</strong> as a heterogeneous catalyst was further confirmed by leaching tests, and maintained high activity even after being used for at least six cycles. Mechanistic studies have revealed that Zr<sub>6</sub>O<sub>8</sub> clusters served as the catalytic centers and the observed chemoselectivity mainly results from the synergistic effect of distinct metal sites within <strong>1</strong>. The heightened selectivity towards -CHO over -COCH<sub>3</sub> can be attributed to the easier realization of transfer hydrogenation processes for -CHO compared to -COCH<sub>3</sub>.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 6","pages":"Article 110593"},"PeriodicalIF":9.4,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144222606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The role of oceanic carbon pumps in Earth's climate system: Impact and feedback under climate change 海洋碳泵在地球气候系统中的作用：气候变化下的影响与反馈

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-05-16 DOI: 10.1016/j.cclet.2025.111300

Dongping Song , Tao Tu

引用次数: 0

Physicochemical design of magneto-responsive confined interfaces for manipulation of nonmagnetic liquids 操纵非磁性液体的磁响应受限界面的物理化学设计

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-04-28 DOI: 10.1016/j.cclet.2025.111206

Jing Liu , Ming Li , Jian Zhang , Xinyu Li , Yuqing Zheng , Xu Hou

{"title":"Physicochemical design of magneto-responsive confined interfaces for manipulation of nonmagnetic liquids","authors":"Jing Liu , Ming Li , Jian Zhang , Xinyu Li , Yuqing Zheng , Xu Hou","doi":"10.1016/j.cclet.2025.111206","DOIUrl":"10.1016/j.cclet.2025.111206","url":null,"abstract":"<div><div>Controllable liquid manipulation is of paramount scientific and technological importance in various fields, such as the chemical industry, biomedicine, and agricultural production. Magnetic actuation, characterized by rapid, contactless, and environmentally benign operation, has emerged as a promising approach for precise liquid control. However, conventional magnetic strategies typically govern droplet movement on open surfaces, facing limitations such as restricted liquid volumes, uncertain flow paths, and inevitable evaporation, thereby constraining their broader practical applications. Recently, a variety of magnetic-driven strategies have been developed to dynamically regulate liquids within enclosed spaces, especially through physicochemical mechanisms. These approaches provide efficient control over liquid behavior by leveraging magnetically induced chemical changes, structural deformations, and dragging motions, opening new opportunities for flexible and versatile fluid management. This review explores the design and mechanisms of magneto-responsive confined interfaces for the manipulation of nonmagnetic liquids, highlighting key advancements and potential applications including liquid valves, liquid mixing, liquid flow regulation, and liquid pumping. Finally, the existing challenges and future prospects in this field are presented.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 8","pages":"Article 111206"},"PeriodicalIF":9.4,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144229587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

IFC - Editorial Board/ Publication info IFC -编辑委员会/出版信息

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-04-25 DOI: 10.1016/S1001-8417(25)00285-2

引用次数: 0

Visible light-induced deuteration of arenes via thianthrenation 可见光诱导的硫代溴化芳烃的氘化

IF 9.4 1区化学

Chinese Chemical Letters Pub Date : 2025-04-23 DOI: 10.1016/j.cclet.2025.111255

Jia Peng , Guo-Ping Luo , Chao Wu , Congyang Wang

引用次数: 0