Jihong Li , Zhenying Feng , Xiaokun Sheng , Keren Chen , Jingming Ran , Luyao Li , Lei Shi , Tongzhou Wang , Yida Deng
{"title":"平方米规模的镍基阳极:易于室温施工,实现高效的工业水电解","authors":"Jihong Li , Zhenying Feng , Xiaokun Sheng , Keren Chen , Jingming Ran , Luyao Li , Lei Shi , Tongzhou Wang , Yida Deng","doi":"10.1016/j.cclet.2025.111652","DOIUrl":null,"url":null,"abstract":"<div><div>The development of cost-effective and energy-efficient anode materials is essential for the advancement of industrial water electrolysis. Herein, we report a rapid, ambient-temperature method to prepare large-area nickel mesh electrodes (SFN/NM) <em>via</em> surface functionalization completed within 3 min, without relying on thermal treatments or noble metals. The as-prepared electrodes achieve a high current density of 100 mA/cm<sup>2</sup> at an overpotential of just 300 mV in 6 mol/L KOH, and exhibit remarkable stability over 1600 h of continuous operation. With comparable activity to commercial Raney nickel yet significantly lower processing and material costs (reduced by 50 %–70 %), this approach provides a practical solution for low-energy water splitting. Beyond its industrial relevance, the strategy offers a scalable model for engineering high-performance OER electrodes, inspiring future directions in electrocatalyst design.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 11","pages":"Article 111652"},"PeriodicalIF":8.9000,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Square-meter-scale nickel-based anode: Facile room-temperature construction for efficient industrial water electrolysis\",\"authors\":\"Jihong Li , Zhenying Feng , Xiaokun Sheng , Keren Chen , Jingming Ran , Luyao Li , Lei Shi , Tongzhou Wang , Yida Deng\",\"doi\":\"10.1016/j.cclet.2025.111652\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The development of cost-effective and energy-efficient anode materials is essential for the advancement of industrial water electrolysis. Herein, we report a rapid, ambient-temperature method to prepare large-area nickel mesh electrodes (SFN/NM) <em>via</em> surface functionalization completed within 3 min, without relying on thermal treatments or noble metals. The as-prepared electrodes achieve a high current density of 100 mA/cm<sup>2</sup> at an overpotential of just 300 mV in 6 mol/L KOH, and exhibit remarkable stability over 1600 h of continuous operation. With comparable activity to commercial Raney nickel yet significantly lower processing and material costs (reduced by 50 %–70 %), this approach provides a practical solution for low-energy water splitting. Beyond its industrial relevance, the strategy offers a scalable model for engineering high-performance OER electrodes, inspiring future directions in electrocatalyst design.</div></div>\",\"PeriodicalId\":10088,\"journal\":{\"name\":\"Chinese Chemical Letters\",\"volume\":\"36 11\",\"pages\":\"Article 111652\"},\"PeriodicalIF\":8.9000,\"publicationDate\":\"2025-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Chemical Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1001841725008320\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Chemical Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1001841725008320","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Square-meter-scale nickel-based anode: Facile room-temperature construction for efficient industrial water electrolysis
The development of cost-effective and energy-efficient anode materials is essential for the advancement of industrial water electrolysis. Herein, we report a rapid, ambient-temperature method to prepare large-area nickel mesh electrodes (SFN/NM) via surface functionalization completed within 3 min, without relying on thermal treatments or noble metals. The as-prepared electrodes achieve a high current density of 100 mA/cm2 at an overpotential of just 300 mV in 6 mol/L KOH, and exhibit remarkable stability over 1600 h of continuous operation. With comparable activity to commercial Raney nickel yet significantly lower processing and material costs (reduced by 50 %–70 %), this approach provides a practical solution for low-energy water splitting. Beyond its industrial relevance, the strategy offers a scalable model for engineering high-performance OER electrodes, inspiring future directions in electrocatalyst design.
期刊介绍:
Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.