Hybrid Advances最新文献

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Modeling of Marshall Stability of plastic-reinforced asphalt concrete using machine learning algorithms and SHAP 基于机器学习算法和SHAP的塑料增强沥青混凝土马歇尔稳定性建模
Hybrid Advances Pub Date : 2025-04-08 DOI: 10.1016/j.hybadv.2025.100483
Mahmudul Haque Jamil , Ravi Jagirdar , Abul Kashem , MD Nimar Ali , Dipongkar Deb
{"title":"Modeling of Marshall Stability of plastic-reinforced asphalt concrete using machine learning algorithms and SHAP","authors":"Mahmudul Haque Jamil ,&nbsp;Ravi Jagirdar ,&nbsp;Abul Kashem ,&nbsp;MD Nimar Ali ,&nbsp;Dipongkar Deb","doi":"10.1016/j.hybadv.2025.100483","DOIUrl":"10.1016/j.hybadv.2025.100483","url":null,"abstract":"<div><div>Pavement engineering has consistently emphasized the need to improve the performance and longevity of asphalt concrete, a critical material in road construction. This study focuses on the predicting the Marshall Stability of plastic-reinforced asphalt concrete using machine learning algorithms. Machine learning algorithms, including Random Forest (RF), Gradient Boosting, Extreme Gradient Boosting (XGB), and Bagging Regressor (BR) were employed to predict the Marshall Stability. The machine learning models were evaluated using six performance metrics, including coefficient of correlation (R), root mean square error (RMSE), mean absolute error (MAE), relative absolute error (RAE), root relative squared error (RRSE), mean absolute percentage error (MAPE), and scatter index (SI), to ensure robust and reliable predictions. Additionally, SHapley Additive exPlanations (SHAP) analysis was conducted to perform a parametric identifying the influence of input parameters on Marshall Stability. Specifically, the XGB model achieved the best R values of 0.95 for training and 0.84 for testing, indicating strong correlations between predicted and actual MS values. Furthermore, SHAP analysis was conducted for the XGB model, which highlighted the significant influence of plastic size and bitumen content on MS prediction. SHAP and machine learning models can be used to optimize the composition of plastic-reinforced asphalt concrete for enhanced performance and sustainability. This research will provide practical guidance for pavement engineers and policymakers in utilizing waste plastic for sustainable infrastructure development.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100483"},"PeriodicalIF":0.0,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comprehensive Review on plant and animal fiber reinforced composites: Experimental and theoretical approaches to interfacial strength optimization and potential applications 植物和动物纤维增强复合材料:界面强度优化的实验和理论方法及其潜在应用
Hybrid Advances Pub Date : 2025-04-07 DOI: 10.1016/j.hybadv.2025.100474
Olajesu Olanrewaju , Isiaka Oluwole Oladele , Samson Oluwagbenga Adelani
{"title":"A Comprehensive Review on plant and animal fiber reinforced composites: Experimental and theoretical approaches to interfacial strength optimization and potential applications","authors":"Olajesu Olanrewaju ,&nbsp;Isiaka Oluwole Oladele ,&nbsp;Samson Oluwagbenga Adelani","doi":"10.1016/j.hybadv.2025.100474","DOIUrl":"10.1016/j.hybadv.2025.100474","url":null,"abstract":"<div><div>Natural fiber-reinforced composites (NFRCs) have become vital in various engineering applications due to their exceptional properties and ease of manufacturing. Properties such as lightweight, sustainability, design flexibility, microstructure, durability, and advanced fabrication techniques have expanded their use across industries. Also, NFRCs are preferred because the extensive reliance on synthetic fibers presents significant challenges in recycling and waste management. Despite their excellent properties, NFRCs have three main challenges: fiber degradation, water degradation, and weak interfacial strength (incompatibility of fibers with the matrix). Consequently, research efforts have been directed at combating these challenges using different surface treatment techniques. However, research has been skewed towards experimental approaches for improving the interfacial strength in plant fiber polymer matrix composites (PMCs). Hence, there exists a dearth of information on the computational approaches for optimizing the interfacial properties of NFRCs. Hence, this review provides experimental and computational approaches (machine learning) for comprehensive optimizing strategies for different natural fibers (plant, animal, and microorganism) and matrices (polymers, metals, and ceramics). This review also highlights the importance of theoretical approaches and numerical modeling in analyzing and optimizing NFRCs. Finally, the review highlights recent advancements in NFRCs, their mechanical properties, potential applications, and future directions.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100474"},"PeriodicalIF":0.0,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143808245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
pH-responsive halochromic films based on carboxymethyl cellulose infused with anthocyanin or curcumin dye extracts for smart packaging applications ph响应的基于羧甲基纤维素注入花青素或姜黄素染料提取物的智能包装应用的变色膜
Hybrid Advances Pub Date : 2025-04-06 DOI: 10.1016/j.hybadv.2025.100476
Iftikhar Ahmed Channa , Jaweria Ashfaq , Maria Wasti , Abdul Ghaffar Memon , Muhammad Hasan , Muhammad Ali Shar , Abdulaziz AlHazaa , Athanasios Tiliakos
{"title":"pH-responsive halochromic films based on carboxymethyl cellulose infused with anthocyanin or curcumin dye extracts for smart packaging applications","authors":"Iftikhar Ahmed Channa ,&nbsp;Jaweria Ashfaq ,&nbsp;Maria Wasti ,&nbsp;Abdul Ghaffar Memon ,&nbsp;Muhammad Hasan ,&nbsp;Muhammad Ali Shar ,&nbsp;Abdulaziz AlHazaa ,&nbsp;Athanasios Tiliakos","doi":"10.1016/j.hybadv.2025.100476","DOIUrl":"10.1016/j.hybadv.2025.100476","url":null,"abstract":"<div><div>Spoilage of food results in the formation of various compounds (amines and ammonia, among others) that affect the pH levels of the produce. Smart biodegradable packaging materials that detect food expiration by changing color based on the pH in their interior provide an eco-friendly solution to the issue of product expiration monitoring by eliminating the plastic waste otherwise generated by conventional packaging. In this study, smart packaging films were developed from a Carboxymethyl Cellulose (CMC) | Agar gel matrix infused with curcumin, red cabbage or butterfly pea flower anthocyanins. Systematic comparative tests were performed on the obtained films focusing on their thermal stability, surface and mechanical properties, Water Vapor Transmission Rate (WVTR), halochromic response, and durability to environmental exposure. The dye-infused films displayed halochromic responses with distinct sensitivities to pH levels depending on their corresponding color indicator. Finally, based on detailed colorimetric and UV–Visual spectrometric evaluations, complete mappings of the halochromic responses of the anthocyanin-infused and curcumin-infused CMC-based films, offering precise correspondences to both CIELAB color space parameters and computed RGB values of dye color changes, were compiled to serve as convenient and readily available references for researchers working on related applications.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100476"},"PeriodicalIF":0.0,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties of concrete containing crumb rubber as partial replacement of fine Aggregate—A review 含橡胶屑部分替代细骨料混凝土的性能研究进展
Hybrid Advances Pub Date : 2025-04-06 DOI: 10.1016/j.hybadv.2025.100481
Naila Hisbani , Nasir Shafiq , Muhammad Alamgeer Shams , Syed Ahmad Farhan , Muhammad Zahid
{"title":"Properties of concrete containing crumb rubber as partial replacement of fine Aggregate—A review","authors":"Naila Hisbani ,&nbsp;Nasir Shafiq ,&nbsp;Muhammad Alamgeer Shams ,&nbsp;Syed Ahmad Farhan ,&nbsp;Muhammad Zahid","doi":"10.1016/j.hybadv.2025.100481","DOIUrl":"10.1016/j.hybadv.2025.100481","url":null,"abstract":"<div><div>The rapid expansion of the global population and industrialization has resulted in more individuals relying on public and private transportation. Consequently, the rise in personal and commercial vehicle use has significantly contributed to the growing accumulation of scrap tires. Landfilling of waste tires in open mounds causes issues such as the spread of mosquito-borne diseases and landscape degradation. On the other hand, open burning of the tires is difficult as the subsequent fire extinguishing consumes many resources. Furthermore, there are concerns regarding fire safety and releasing harmful toxic gases into the air. Besides, the tire waste construction industry uses a lot of natural resources, such as sand, which are depleting. To avoid the depletion or scarcity of these natural resources, it is necessary to use alternative materials instead of sand. Indeed, methods to reuse or recycle tire waste must be devised. Research has started to explore the potential of using tire waste in the crumb rubber form, which is a waste product derived from the recycling of tires, as a partial substitute for fine aggregate in concrete. This review study aims to find the effect of crumb rubber (CR) in normal concrete as a partial replacement for sand. The study's objective is to provide a baseline for the effect of CR on normal concrete to provide a pathway for future studies working on rubber concrete to mitigate the limitations of the use of CR in concrete. A systematic meta-analysis is performed on the experimental facts from different studies to develop a model for optimizing the use of CR in concrete. The regression model adopted showed a good variation with the input data. The study finds that adding CR to concrete leads to a loss in its mechanical properties when crumb rubber is used. Despite the decrease in strength, rubberized concrete demonstrates enhanced durability characteristics, such as greater resistance to acid attack and chloride ion penetration, making it well-suited for environments with high chlorine exposure. This article provides an overview of the use of crumb rubber as an alternative substitute for fine aggregate in concrete and reviews the normal concrete's properties based on the research findings thus far.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100481"},"PeriodicalIF":0.0,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influences of homogenous and heterogenous dopants on structural, electric, and thermodynamic properties of the gallium arsenide (GaAs) nanodot: A DFT study 均相和非均相掺杂剂对砷化镓纳米点结构、电学和热力学性质的影响:DFT研究
Hybrid Advances Pub Date : 2025-04-05 DOI: 10.1016/j.hybadv.2025.100482
Aoly Ur Rahman , D.M. Saaduzzaman , Syed Mahedi Hasan , Md Kabir Uddin Sikder
{"title":"Influences of homogenous and heterogenous dopants on structural, electric, and thermodynamic properties of the gallium arsenide (GaAs) nanodot: A DFT study","authors":"Aoly Ur Rahman ,&nbsp;D.M. Saaduzzaman ,&nbsp;Syed Mahedi Hasan ,&nbsp;Md Kabir Uddin Sikder","doi":"10.1016/j.hybadv.2025.100482","DOIUrl":"10.1016/j.hybadv.2025.100482","url":null,"abstract":"<div><div>In recent times, low-dimensional semiconducting materials have drawn the attention of researchers due to their wide range of applicability in technological sectors. Among different semiconducting materials, gallium arsenide (GaAs) is the second most prominent materials for developing devices due to its direct band gap and high electron mobility. In this work, the geometric, electronic, and thermodynamic properties of the GaAs nanodot after consecutive doping with homogenous transition metals (Ir–Ir) and heterogeneous transition metals (Ir–Ru &amp; Ir–Pd) have been investigated. The investigation has been performed by employing density functional theory (DFT) with B3LYP hybrid functional using LanL2DZ basis set. The investigation reveals that the GaAs nanodot gains more stability (−98 eV ∼ −468 eV for doped clusters and −21 eV for the pristine cluster) and becomes efficient which is confirmed by studying binding energy and bond lengths in the heterogeneous doping process rather than the sequential homogenous doping process. Moreover, the infrared (IR) spectra analysis confirms that all structures might be found naturally in a stable and true energy minima, except Ga<sub>2</sub>As<sub>2</sub>Ir<sub>2</sub>Ru<sub>2</sub><sub>,</sub> because of the presence of imaginary frequency. Also, the band gap (1.2 eV–2 eV for all doped structures) exhibits a suitable semiconducting nature of the doped structures. The thermodynamic properties show that both homogenous and heterogenous doping techniques cause thermodynamic stability to the GaAs nanodot as well as make them more feasible. Finally, considering all the physicochemical properties it has been concluded that for GaAs nanodot, the heterogenous atom doping process is more efficient than the homogenous atom doping when the dopant number is the same.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100482"},"PeriodicalIF":0.0,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Al2O3 nanoparticle on mechanical properties of polyester/ glass-wool fiber reinforced polymer composites 纳米Al2O3颗粒对聚酯/玻璃棉纤维增强聚合物复合材料力学性能的影响
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100472
Yohanes Abebe, Sivaprakasam Palani, Belete Sirahbizu
{"title":"Effect of Al2O3 nanoparticle on mechanical properties of polyester/ glass-wool fiber reinforced polymer composites","authors":"Yohanes Abebe,&nbsp;Sivaprakasam Palani,&nbsp;Belete Sirahbizu","doi":"10.1016/j.hybadv.2025.100472","DOIUrl":"10.1016/j.hybadv.2025.100472","url":null,"abstract":"<div><div>The need for strong, lightweight polymer composites constantly increases in the modern automobile, aviation, and defense sectors. Polyester resins are the predominant thermosetting polymers and are frequently utilized in various industries. E-glass fiber possesses significant qualities, including resistance to heat, chemicals, and moisture. Wool fibers were employed as reinforcement because of their accessibility and sustainability. A more comprehensive analysis is necessary to incorporate nanoparticles and the hybridization of different natural and synthetic fiber types, as seen in a composite composed of glass and wool fibers. In this research, polyester/wool-glass fiber with nano-alumina (Al<sub>2</sub>O<sub>3</sub>) particles at 2.0 wt% reinforced polymer composites (C0A-C5A) were made via hand layup and compression molding. The addition of Al<sub>2</sub>O<sub>3</sub> nanoparticles on wool-glass fiber reinforced composites and its effect on properties and morphology were characterized using mechanical testing and scanning electron microscopy (SEM) methods. The analysis of nanoparticle dispersion and the resulting modifications to the composite structure were performed using X-ray diffraction. Adding nano alumina enhanced the tensile strength by 55 %, compressive strength by 38 %, flexural strength by 109 % and impact strength by 47 %. The higher tensile strength of 99.39 MPa, compressive strength of 102.51 MPa, flexural strength of 135.22 MPa and impact strength of 380.34 kJ/m<sup>2</sup> were found in (C1A) glass fiber with nano alumina mixed composites. These nanocomposites can enhance the composites' tensile, compressive, flexural and impact strength and are preferred for structural application in automotive and construction industries.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100472"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and characterization of formamidinium-based perovskite photovoltaic devices hybridized with decaphenylcyclopentasilane hole transport layers 十苯基环五硅烷空穴传输层杂化甲脒基钙钛矿光伏器件的制备与表征
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100473
Taiga Nasu , Takeo Oku , Atsushi Suzuki , Tomoharu Tachikawa , Sakiko Fukunishi
{"title":"Fabrication and characterization of formamidinium-based perovskite photovoltaic devices hybridized with decaphenylcyclopentasilane hole transport layers","authors":"Taiga Nasu ,&nbsp;Takeo Oku ,&nbsp;Atsushi Suzuki ,&nbsp;Tomoharu Tachikawa ,&nbsp;Sakiko Fukunishi","doi":"10.1016/j.hybadv.2025.100473","DOIUrl":"10.1016/j.hybadv.2025.100473","url":null,"abstract":"<div><div>Double-stacked formamidinium-based perovskite photovoltaic devices with different bandgaps were fabricated using decaphenylcyclopentasilane (DPPS) as the hole-transport layer, and their photovoltaic properties were evaluated. Perovskite/DPPS hybridized thin films were fabricated under a high temperature of 190 °C. The DPPS layer functioned as a protective layer and the efficiencies of the DPPS-based devices were maintained even after one year. Optical and microstructural analyses were performed to investigate the microstructure and properties of the DPPS, and its crystallization was observed after annealing. The crystal growth of the perovskite layer was enhanced in the thicker region of the crystallized DPPS film, which suggests that the suppression of CH<sub>3</sub>NH<sub>3</sub> desorption by DPPS improved the quality of the perovskite films.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100473"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143808244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of geopolymer mortar incorporating spent coffee grounds as a recycled building material: An experimental and predictive analysis 以废咖啡渣为再生建筑材料的地聚合物砂浆的性能:实验与预测分析
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100479
Ahmet Ferdi Şenol
{"title":"Performance of geopolymer mortar incorporating spent coffee grounds as a recycled building material: An experimental and predictive analysis","authors":"Ahmet Ferdi Şenol","doi":"10.1016/j.hybadv.2025.100479","DOIUrl":"10.1016/j.hybadv.2025.100479","url":null,"abstract":"<div><div>Spent coffee grounds ash (K) is investigated as a sustainable partial sand replacement (0 %, 5 %, 10 %, 15 %) in geopolymer mortars based on granulated blast furnace slag. This study assesses workability, mechanical performance, high-temperature resistance, and microstructure through experimental testing and statistical analysis. Key findings indicate that K content significantly influences workability, strength, and physical properties. Replacing sand with K reduced workability by up to 21 % due to its finer particle size and porosity. The K5 series, containing 5 % K, exhibited the highest compressive strength improvement, with gains of 8.9 % and 16.3 % at 7 and 28 days, respectively, compared to the control. However, higher K contents (10 %, 15 %) negatively impacted mechanical performance. At elevated temperatures, significant mass loss occurred up to 400 °C, after which it stabilized at 600 °C while maintaining structural integrity. Porosity and water absorption increased with K content, except in K5. Microstructural analysis revealed that the K5 series formed a dense, crack-minimal matrix, whereas K10 and K15 exhibited more microcracking and porosity. Statistical models confirmed that temperature had the greatest influence on compressive and flexural strengths, whereas K content significantly affected mass loss.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100479"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil WO3@MCM-41负载的碱土金属氧化物;玉米和废食用油制备生物柴油的双功能催化剂
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100477
Irsa Tariq , Muhammad Zubair , Waheed Iqbal , Amin Badshah , Syed Mustansar Abbas , Ali Haider
{"title":"Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil","authors":"Irsa Tariq ,&nbsp;Muhammad Zubair ,&nbsp;Waheed Iqbal ,&nbsp;Amin Badshah ,&nbsp;Syed Mustansar Abbas ,&nbsp;Ali Haider","doi":"10.1016/j.hybadv.2025.100477","DOIUrl":"10.1016/j.hybadv.2025.100477","url":null,"abstract":"<div><div>The novelty of this work lies in the development of a bifunctional acid-base catalyst comprising tungsten oxide (WO<sub>3</sub>) supported on mesoporous MCM-41 and impregnated with alkaline earth metal oxides (Mg, Ca, Sr, Ba), which enables simultaneous esterification and transesterification for biodiesel production. The acidic and basic properties of the catalysts were quantitatively assessed through potentiometric titration, confirming the presence of both acid and basic sites, which are essential for the concurrent esterification of free fatty acids (FFAs) and transesterification of triglycerides. This bifunctionality is particularly advantageous for feedstocks with high FFA content, such as waste cooking oil, addressing a key challenge in biodiesel synthesis. The SrO-based catalyst demonstrated exceptional performance, achieving yields of 96 % for corn oil and 93 % for waste cooking oil, with minimal yield differences of 3 % attributed to the latter's impurities and higher FFA content. The study also provides detailed optimization of reaction conditions, revealing that waste cooking oil requires slightly harsher conditions (100 °C, 6 h, 20 mg catalyst) compared to corn oil (80 °C, 5 h, 10 mg catalyst), which is consistent with its complex composition. Comprehensive characterization (PXRD, SEM-EDX, BET/BJH) and validation through <sup>1</sup>H NMR spectroscopy (yields of 92 % and 91 % for corn and waste cooking oil, respectively) confirm the reliability of the results. Moreover, the biodiesel's physicochemical characteristics were examined thoroughly and contrasted with the ASTM biodiesel requirements. The outcomes demonstrated that the generated biodiesel's characteristics met the requirements of international standards.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100477"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143785784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst 制备的磁性膨润土作为非均相催化剂,fenton法降解ry - 145b的研究
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100463
Carine Lannang Tsokeing , Sanchez Dave Mouafo Dongmo , Esther Judith Maffeu , Pierre Gerard Tchieta , Jean Duplex Wansi
{"title":"Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst","authors":"Carine Lannang Tsokeing ,&nbsp;Sanchez Dave Mouafo Dongmo ,&nbsp;Esther Judith Maffeu ,&nbsp;Pierre Gerard Tchieta ,&nbsp;Jean Duplex Wansi","doi":"10.1016/j.hybadv.2025.100463","DOIUrl":"10.1016/j.hybadv.2025.100463","url":null,"abstract":"<div><div>The present investigation sets out to describe the potential of magnetite (Fe<sub>3</sub>O<sub>4</sub>) impregnated bentonite (BE-Fe<sub>3</sub>O<sub>4</sub>) to assist in the Fenton process. Utilizing the Co-precipitation method, the BE-Fe<sub>3</sub>O<sub>4</sub> samples were developed as a catalyst for the degradation of RY-145 dye in an aqueous environment. The BE-Fe<sub>3</sub>O<sub>4</sub> were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The effects of solution pH, the concentration of H<sub>2</sub>O<sub>2</sub> solution, the mass of the catalyst, and the concentration of RY-145 dye on the degradation efficiency were evaluated for parametric optimization. The degradation of the dye was most favorable at an acid pH of 2, H<sub>2</sub>O<sub>2</sub> concentration of 1.5 mol/L, 100 mg of the catalyst and the initial RY-145 concentration of 100 mg/L. The pristine and modified clays were morphologically distinguishable, and XRD analyses confirmed the formation of Fe<sub>3</sub>O<sub>4</sub> particles. The minimum degradation percentage above 92 %, irrespective of the process conditions. RY-145 degradation dynamics on BE-Fe<sub>3</sub>O<sub>4</sub> followed second-order kinetic law. After five cycles of evaluation of BE-Fe<sub>3</sub>O<sub>4</sub>'s stability and efficiency, it was discovered that the material lost about 13 % of its efficiency. This research demonstrated that the catalyst obtained from BE-Fe<sub>3</sub>O<sub>4</sub> could be used in the treatment technology of wastewater containing RY-145 b y Fenton process.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100463"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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