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pH-responsive halochromic films based on carboxymethyl cellulose infused with anthocyanin or curcumin dye extracts for smart packaging applications
Hybrid Advances Pub Date : 2025-04-06 DOI: 10.1016/j.hybadv.2025.100476
Iftikhar Ahmed Channa , Jaweria Ashfaq , Maria Wasti , Abdul Ghaffar Memon , Muhammad Hasan , Muhammad Ali Shar , Abdulaziz AlHazaa , Athanasios Tiliakos
{"title":"pH-responsive halochromic films based on carboxymethyl cellulose infused with anthocyanin or curcumin dye extracts for smart packaging applications","authors":"Iftikhar Ahmed Channa ,&nbsp;Jaweria Ashfaq ,&nbsp;Maria Wasti ,&nbsp;Abdul Ghaffar Memon ,&nbsp;Muhammad Hasan ,&nbsp;Muhammad Ali Shar ,&nbsp;Abdulaziz AlHazaa ,&nbsp;Athanasios Tiliakos","doi":"10.1016/j.hybadv.2025.100476","DOIUrl":"10.1016/j.hybadv.2025.100476","url":null,"abstract":"<div><div>Spoilage of food results in the formation of various compounds (amines and ammonia, among others) that affect the pH levels of the produce. Smart biodegradable packaging materials that detect food expiration by changing color based on the pH in their interior provide an eco-friendly solution to the issue of product expiration monitoring by eliminating the plastic waste otherwise generated by conventional packaging. In this study, smart packaging films were developed from a Carboxymethyl Cellulose (CMC) | Agar gel matrix infused with curcumin, red cabbage or butterfly pea flower anthocyanins. Systematic comparative tests were performed on the obtained films focusing on their thermal stability, surface and mechanical properties, Water Vapor Transmission Rate (WVTR), halochromic response, and durability to environmental exposure. The dye-infused films displayed halochromic responses with distinct sensitivities to pH levels depending on their corresponding color indicator. Finally, based on detailed colorimetric and UV–Visual spectrometric evaluations, complete mappings of the halochromic responses of the anthocyanin-infused and curcumin-infused CMC-based films, offering precise correspondences to both CIELAB color space parameters and computed RGB values of dye color changes, were compiled to serve as convenient and readily available references for researchers working on related applications.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100476"},"PeriodicalIF":0.0,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100477
Irsa Tariq , Muhammad Zubair , Waheed Iqbal , Amin Badshah , Syed Mustansar Abbas , Ali Haider
{"title":"Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil","authors":"Irsa Tariq ,&nbsp;Muhammad Zubair ,&nbsp;Waheed Iqbal ,&nbsp;Amin Badshah ,&nbsp;Syed Mustansar Abbas ,&nbsp;Ali Haider","doi":"10.1016/j.hybadv.2025.100477","DOIUrl":"10.1016/j.hybadv.2025.100477","url":null,"abstract":"<div><div>The novelty of this work lies in the development of a bifunctional acid-base catalyst comprising tungsten oxide (WO<sub>3</sub>) supported on mesoporous MCM-41 and impregnated with alkaline earth metal oxides (Mg, Ca, Sr, Ba), which enables simultaneous esterification and transesterification for biodiesel production. The acidic and basic properties of the catalysts were quantitatively assessed through potentiometric titration, confirming the presence of both acid and basic sites, which are essential for the concurrent esterification of free fatty acids (FFAs) and transesterification of triglycerides. This bifunctionality is particularly advantageous for feedstocks with high FFA content, such as waste cooking oil, addressing a key challenge in biodiesel synthesis. The SrO-based catalyst demonstrated exceptional performance, achieving yields of 96 % for corn oil and 93 % for waste cooking oil, with minimal yield differences of 3 % attributed to the latter's impurities and higher FFA content. The study also provides detailed optimization of reaction conditions, revealing that waste cooking oil requires slightly harsher conditions (100 °C, 6 h, 20 mg catalyst) compared to corn oil (80 °C, 5 h, 10 mg catalyst), which is consistent with its complex composition. Comprehensive characterization (PXRD, SEM-EDX, BET/BJH) and validation through <sup>1</sup>H NMR spectroscopy (yields of 92 % and 91 % for corn and waste cooking oil, respectively) confirm the reliability of the results. Moreover, the biodiesel's physicochemical characteristics were examined thoroughly and contrasted with the ASTM biodiesel requirements. The outcomes demonstrated that the generated biodiesel's characteristics met the requirements of international standards.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100477"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143785784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst
Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100463
Carine Lannang Tsokeing , Sanchez Dave Mouafo Dongmo , Esther Judith Maffeu , Pierre Gerard Tchieta , Jean Duplex Wansi
{"title":"Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst","authors":"Carine Lannang Tsokeing ,&nbsp;Sanchez Dave Mouafo Dongmo ,&nbsp;Esther Judith Maffeu ,&nbsp;Pierre Gerard Tchieta ,&nbsp;Jean Duplex Wansi","doi":"10.1016/j.hybadv.2025.100463","DOIUrl":"10.1016/j.hybadv.2025.100463","url":null,"abstract":"<div><div>The present investigation sets out to describe the potential of magnetite (Fe<sub>3</sub>O<sub>4</sub>) impregnated bentonite (BE-Fe<sub>3</sub>O<sub>4</sub>) to assist in the Fenton process. Utilizing the Co-precipitation method, the BE-Fe<sub>3</sub>O<sub>4</sub> samples were developed as a catalyst for the degradation of RY-145 dye in an aqueous environment. The BE-Fe<sub>3</sub>O<sub>4</sub> were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The effects of solution pH, the concentration of H<sub>2</sub>O<sub>2</sub> solution, the mass of the catalyst, and the concentration of RY-145 dye on the degradation efficiency were evaluated for parametric optimization. The degradation of the dye was most favorable at an acid pH of 2, H<sub>2</sub>O<sub>2</sub> concentration of 1.5 mol/L, 100 mg of the catalyst and the initial RY-145 concentration of 100 mg/L. The pristine and modified clays were morphologically distinguishable, and XRD analyses confirmed the formation of Fe<sub>3</sub>O<sub>4</sub> particles. The minimum degradation percentage above 92 %, irrespective of the process conditions. RY-145 degradation dynamics on BE-Fe<sub>3</sub>O<sub>4</sub> followed second-order kinetic law. After five cycles of evaluation of BE-Fe<sub>3</sub>O<sub>4</sub>'s stability and efficiency, it was discovered that the material lost about 13 % of its efficiency. This research demonstrated that the catalyst obtained from BE-Fe<sub>3</sub>O<sub>4</sub> could be used in the treatment technology of wastewater containing RY-145 b y Fenton process.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100463"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the evolution of 5D and 6D printing: Current progress, challenges, technological innovations, and transformative biomedical applications 探索 5D 和 6D 打印的演变:当前的进展、挑战、技术创新和变革性生物医学应用
Hybrid Advances Pub Date : 2025-04-03 DOI: 10.1016/j.hybadv.2025.100470
Shrikant Dargude , Snehal Shinde , Swati Jagdale , Satish Polshettiwar , Amarjitsing Rajput
{"title":"Exploring the evolution of 5D and 6D printing: Current progress, challenges, technological innovations, and transformative biomedical applications","authors":"Shrikant Dargude ,&nbsp;Snehal Shinde ,&nbsp;Swati Jagdale ,&nbsp;Satish Polshettiwar ,&nbsp;Amarjitsing Rajput","doi":"10.1016/j.hybadv.2025.100470","DOIUrl":"10.1016/j.hybadv.2025.100470","url":null,"abstract":"<div><div>The evolution of additive manufacturing (AM) has led to the development of 4D printing, enabling 3D printed structures to dynamically alter shape in response to external stimuli, thereby improving mechanical properties and patient-specific applications. However, limitations persist in achieving complex geometry elements with high mechanical strength. To address these challenges, enhancement in the printing process and the use of multi-responsive smart materials are essential. The emergence of 5D printing, which combines additive and subtractive manufacturing, has advanced medical design by enhancing structural integrity and surface quality. As AM technology continues to evolve, 5D and 6D printing represent breakthroughs in biomedical engineering. By integrating the dynamic adaptability of 4D printing with the precision of 5D printing, 6D printing offers the potential for patient-specific interventions, particularly in biomedical applications. This review article evaluates the progress made in developing AM technologies, particularly 5D and 6D printing, highlighting the significant growth in healthcare due to the development of materials and technologies that respond to specific clinical demands.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100470"},"PeriodicalIF":0.0,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative Analysis of Silver and Titanium Oxide Hybrid Nanofluid in MHD Unsteady Flow Past an Accelerated Vertical Plate with Radiation Effects
Hybrid Advances Pub Date : 2025-04-01 DOI: 10.1016/j.hybadv.2025.100469
Joseph Nicholaus Lutera , B. Shankar Goud , M.N. Raja Shekar
{"title":"Comparative Analysis of Silver and Titanium Oxide Hybrid Nanofluid in MHD Unsteady Flow Past an Accelerated Vertical Plate with Radiation Effects","authors":"Joseph Nicholaus Lutera ,&nbsp;B. Shankar Goud ,&nbsp;M.N. Raja Shekar","doi":"10.1016/j.hybadv.2025.100469","DOIUrl":"10.1016/j.hybadv.2025.100469","url":null,"abstract":"<div><div>The problem of MHD unsteady movement of the nanofluid past an accelerated perpendicular surface is investigated. Thermal radiation and electromagnetic field properties are taken into explanation of the hybrid nanofluid composed of Silver and Titanium dioxide nanoparticles. The nanoparticles offer an enhanced thermal conductivity property, a factor important in technological advancement including cooling, separation, nuclear reactors, solar energy and electronic devices. The study aims to analyze the characteristics of different nanofluids on the influence of dimensionless parameters for mass and heat transmission. The resultant nondimensionalized boundary problem is solved numerically by the finite difference technique employed to obtain the mathematical results of the partial differential equations. The results demonstrate a comparison of velocity and thermal energy profiles of Silver-water and Titanium dioxide-water nanofluids graphically. Silver particles portray greater impacts on the nanofluid flow rate than the Titanium dioxide particles. The temperature of silver water is greater than the temperature of Titanium dioxide water. The improvement of thermal radiation strength was observed to enhance the temperature and velocity profiles of the nanofluid. The study is crucial in decision-making, especially for the choice of efficient nanofluid in mass and heat transmission applications.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100469"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigations on effect of amine functionalised graphene nanoplatelets (f-GNPs) reinforcement on mechanical properties of epoxy resin
Hybrid Advances Pub Date : 2025-04-01 DOI: 10.1016/j.hybadv.2025.100443
Neerajkumar Wayzode , Mahendra L. Shelar , Vinod B. Suryawanshi
{"title":"Investigations on effect of amine functionalised graphene nanoplatelets (f-GNPs) reinforcement on mechanical properties of epoxy resin","authors":"Neerajkumar Wayzode ,&nbsp;Mahendra L. Shelar ,&nbsp;Vinod B. Suryawanshi","doi":"10.1016/j.hybadv.2025.100443","DOIUrl":"10.1016/j.hybadv.2025.100443","url":null,"abstract":"<div><div>Graphene nanoplatelets (f-GNPs) are emerging nanofillers with appealing attributes, such as strong compatibility with a wide range of polymers, exceptional overall strength, and cost-efficiency. This research examines the influence of varying weight fractions of functionalized graphene nanoplatelets (f-GNPs) on the mechanical properties of epoxy resin. Various weight fractions of f-GNPs namely 0.2%, 0.4%,0.6%,0.8%,1% and 5% are added to epoxy resin. Combination of ultra-sonication and magnetic stirring was used for dispersing f-GNPs in epoxy resin. f-GNPs reinforcement showed improvement in tensile strength on epoxy except for 1% and 5% weight fractions. Dispersion of f-GNPs is found to be superior at lower f-GNPs concentrations. The experimental results reveal that incorporating f-GNPs enhances the ultimate tensile strength of epoxy resin by 11.79%, 12.47%, 10.12%, and 13.31% at weight fractions of 0.2%, 0.4%, 0.6%, and 0.8%, respectively. This confirms the beneficial impact of amine-functionalized graphene nanoplatelets (f-GNPs) on epoxy resin. The highest improvement, 13.31%, was achieved at 0.8% f-GNPs, making it the optimal loading, which was subsequently utilized in the development of multiscale f-GNPs-reinforced Glass/Epoxy composites. This study also presents a detailed FTIR, LRS, XRD, TEM, SEM characterisation of amine functionalised graphene nanoplatelets (f-GNPs).</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100443"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Additive manufacturing in biomedical: Applications, challenges, and prospects 生物医学中的快速成型技术:应用、挑战和前景
Hybrid Advances Pub Date : 2025-03-31 DOI: 10.1016/j.hybadv.2025.100467
Md Hosne Mobarak , Abu Sofian Abid , Md Shahriar Munna , Mihir Dutta , Md Israfil Hossain Rimon
{"title":"Additive manufacturing in biomedical: Applications, challenges, and prospects","authors":"Md Hosne Mobarak ,&nbsp;Abu Sofian Abid ,&nbsp;Md Shahriar Munna ,&nbsp;Mihir Dutta ,&nbsp;Md Israfil Hossain Rimon","doi":"10.1016/j.hybadv.2025.100467","DOIUrl":"10.1016/j.hybadv.2025.100467","url":null,"abstract":"<div><div>Additive Manufacturing (AM), also called 3D printing, has introduced revolutionary advancements across multiple industries, particularly impacting the biomedical field. This technology facilitates the production of intricate, patient-specific medical devices, such as implants, prosthetics, and surgical models, with unparalleled precision and customization. These capabilities have facilitated personalized medicine, enabling therapies customized to particular patient requirements and anatomical characteristics, improving clinical outcomes and patient satisfaction. Nevertheless, numerous obstacles continue to impede the comprehensive integration of AM into conventional healthcare. Critical concerns encompass the biocompatibility and longevity of additive manufacturing materials, rigorous regulatory and safety standards, and the substantial expenses linked to the development and production of additive manufacturing medical devices. Confronting these problems necessitates continuous research and development to formulate better biocompatible materials, enhance additive manufacturing methods, and facilitate regulatory approval procedures. This study will offer a comprehensive overview of the applications, constraints, and future potential of additive manufacturing in biomedicine, highlighting its contribution to personalized healthcare solutions and enhanced patient outcomes through innovation.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100467"},"PeriodicalIF":0.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of a hybrid reduced graphene oxide functionalized ZnO/ZnCo2O4 nanocomposite for electrochemical energy storage
Hybrid Advances Pub Date : 2025-03-31 DOI: 10.1016/j.hybadv.2025.100466
Subrata Maity , Arpita Dutta , Kartik Tantubay , Bapan Bairy , Sayani Saha , Sourav Bhowmick , Supriya Mondal , Abu Jahid Akhtar , Moni Baskey (Sen)
{"title":"Fabrication of a hybrid reduced graphene oxide functionalized ZnO/ZnCo2O4 nanocomposite for electrochemical energy storage","authors":"Subrata Maity ,&nbsp;Arpita Dutta ,&nbsp;Kartik Tantubay ,&nbsp;Bapan Bairy ,&nbsp;Sayani Saha ,&nbsp;Sourav Bhowmick ,&nbsp;Supriya Mondal ,&nbsp;Abu Jahid Akhtar ,&nbsp;Moni Baskey (Sen)","doi":"10.1016/j.hybadv.2025.100466","DOIUrl":"10.1016/j.hybadv.2025.100466","url":null,"abstract":"<div><div>Recent advancements have positioned supercapacitors as one of the most promising energy storage technologies in modern innovation. A primary focus of research to enhance their performance lies in developing and characterizing advanced electrode materials with high conductivity and energy density. In this study, reduced graphene oxide based hybrid ZnO/ZnCo<sub>2</sub>O<sub>4</sub> nanocomposite was synthesized via a simple reflux method. The successful formation of the nanocomposite was confirmed through various characterization techniques, including X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), Ultraviolet–visible (UV–Vis), Scanning Electron Spectroscopy (SEM) and Transmission Electron Spectroscopy (TEM) studies. The surface area of the nanocomposite was analyzed by Brunauer–Emmett–Teller (BET) study. The electrochemical properties of the synthesized nanocomposite were assessed using cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) tests in a two-electrode configuration with 1 M KOH as the electrolyte. The results revealed a high specific capacitance of 646 F/g at 1 A/g and excellent cyclic stability, retaining 84.8 % of its initial capacitance even after 4000 cycles. The device also demonstrated impressive specific energy and power, achieving 50.28 Wh/kg and 2999 W/kg respectively. Additionally, charge storage mechanisms were investigated using the Trasatti plot, which indicated a balanced contribution from electric double-layer capacitance (EDLC, 51.45 %) and pseudo capacitance (CPC, 48.55 %). These results highlight the ZnO/ZnCo<sub>2</sub>O<sub>4</sub>-rGO nanocomposite as a highly promising material for energy storage applications, offering optimized total capacitance through the combined contributions of EDLC and pseudo capacitance.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100466"},"PeriodicalIF":0.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of atmospheric moisture interaction on modified copper surfaces using thermoelectric cooling
Hybrid Advances Pub Date : 2025-03-28 DOI: 10.1016/j.hybadv.2025.100465
C. Pownraj , A. Valan Arasu , B. Prabhu , Suresh Sethu
{"title":"Investigation of atmospheric moisture interaction on modified copper surfaces using thermoelectric cooling","authors":"C. Pownraj ,&nbsp;A. Valan Arasu ,&nbsp;B. Prabhu ,&nbsp;Suresh Sethu","doi":"10.1016/j.hybadv.2025.100465","DOIUrl":"10.1016/j.hybadv.2025.100465","url":null,"abstract":"<div><div>Atmospheric moisture extraction is crucial for rectifying two key challenges: 1) reducing atmospheric temperature through greenhouse gas effects and 2) alleviating drinking water scarcity. Various methods for extracting atmospheric moisture, such as condensation, porous metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hygroscopic aerogels, have been explored to address this issue. In this study, four types of copper surfaces (bare, treated, SA-modified, and AA-SA-modified) were prepared using a solution immersion method. These surfaces were characterized using field-emission scanning electron microscopy with energy-dispersive X-ray spectroscopy (FE-SEM with EDAX), X-ray Diffraction (XRD), Attenuated Total Reflectance Infrared Spectroscopy (ATR-IR), and contact angle measurements. Water droplet absorption experiments were conducted at an atmospheric relative humidity variation of 50–53 % with laboratory and condensation surface temperature variations of 29.9–31 °C and 9–9.6 °C, respectively, using a Peltier thermoelectric cooling setup. The absorption tests were performed at 15-minute intervals (over four cycles) using simple tissue paper as the absorbent. The AA-SA-modified copper surface exhibited the highest atmospheric moisture interaction (36.36 %) during the first 15 min compared to the other surfaces owing to its optimal surface energy. Additionally, the shapes of the water droplets and their absorption mechanisms on the AA-SA-modified surface were analyzed. Overall, this study demonstrates that the AA-SA-modified copper surface has significant potential for atmospheric moisture extraction under various humidity conditions.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100465"},"PeriodicalIF":0.0,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143738569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing layer configuration and material selection to enhance CIGS solar cell performance through computational simulation
Hybrid Advances Pub Date : 2025-03-27 DOI: 10.1016/j.hybadv.2025.100460
Sawrab Sikder , Md. Kamrul Hasan , Hayati Mamur , Mohammad Ruhul Amin Bhuiyan
{"title":"Optimizing layer configuration and material selection to enhance CIGS solar cell performance through computational simulation","authors":"Sawrab Sikder ,&nbsp;Md. Kamrul Hasan ,&nbsp;Hayati Mamur ,&nbsp;Mohammad Ruhul Amin Bhuiyan","doi":"10.1016/j.hybadv.2025.100460","DOIUrl":"10.1016/j.hybadv.2025.100460","url":null,"abstract":"<div><div>The increasing demand for renewable energy has driven research into advanced photovoltaic (PV) technologies for solar cells (SCs). Copper indium gallium selenide (CIGS) SCs present numerous benefits, such as high absorption efficiency, compatibility with flexible substrates, and potential for cost-effective production. This study utilizes SCAPS-1D software to optimize a CIGS-based SC structure featuring a novel Al/ZnO/ZnMnO/CIGS/Cu<sub>2</sub>O/Ni configuration. We systematically optimized key parameters, including material selection, layer thickness, doping concentrations, series and shunt resistances, and temperature, to enhance device performance. Our results demonstrate that an optimal configuration with a 3000 nm thick CIGS absorber layer, a 50 nm thick zinc oxide (ZnO) window layer, zinc manganese oxide (ZnMnO) buffer layers, and a 10 nm thick cuprous oxide (Cu<sub>2</sub>O) electron-reflecting hole transport layer (ER-HTL) achieves an impressive open-circuit voltage (V<sub>OC</sub>) of 1.0112 V, a short-circuit current density (J<sub>SC</sub>) of 38.80 mA/cm<sup>2</sup>, a fill factor (FF) of 81.13 %, and a power conversion efficiency (PCE) of 31.84 % under AM1.5G solar spectra. By minimizing series resistance and maximizing shunt resistance, we reduced resistive losses, voltage drop, and current leakage, thus enhancing overall device performance. Additionally, the device exhibited a remarkable quantum efficiency (QE) of approximately 95.54 % within the visible wavelength range. These findings contribute to a deeper understanding of CIGS solar cells and guide future research aimed at optimizing materials and designs to improve efficiency and stability, ultimately advancing affordable solar energy solutions.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100460"},"PeriodicalIF":0.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143726284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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