Hybrid Advances最新文献_第2页

Effect of Al2O3 nanoparticle on mechanical properties of polyester/ glass-wool fiber reinforced polymer composites

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100472

Yohanes Abebe, Sivaprakasam Palani, Belete Sirahbizu

{"title":"Effect of Al2O3 nanoparticle on mechanical properties of polyester/ glass-wool fiber reinforced polymer composites","authors":"Yohanes Abebe, Sivaprakasam Palani, Belete Sirahbizu","doi":"10.1016/j.hybadv.2025.100472","DOIUrl":"10.1016/j.hybadv.2025.100472","url":null,"abstract":"<div><div>The need for strong, lightweight polymer composites constantly increases in the modern automobile, aviation, and defense sectors. Polyester resins are the predominant thermosetting polymers and are frequently utilized in various industries. E-glass fiber possesses significant qualities, including resistance to heat, chemicals, and moisture. Wool fibers were employed as reinforcement because of their accessibility and sustainability. A more comprehensive analysis is necessary to incorporate nanoparticles and the hybridization of different natural and synthetic fiber types, as seen in a composite composed of glass and wool fibers. In this research, polyester/wool-glass fiber with nano-alumina (Al<sub>2</sub>O<sub>3</sub>) particles at 2.0 wt% reinforced polymer composites (C0A-C5A) were made via hand layup and compression molding. The addition of Al<sub>2</sub>O<sub>3</sub> nanoparticles on wool-glass fiber reinforced composites and its effect on properties and morphology were characterized using mechanical testing and scanning electron microscopy (SEM) methods. The analysis of nanoparticle dispersion and the resulting modifications to the composite structure were performed using X-ray diffraction. Adding nano alumina enhanced the tensile strength by 55 %, compressive strength by 38 %, flexural strength by 109 % and impact strength by 47 %. The higher tensile strength of 99.39 MPa, compressive strength of 102.51 MPa, flexural strength of 135.22 MPa and impact strength of 380.34 kJ/m<sup>2</sup> were found in (C1A) glass fiber with nano alumina mixed composites. These nanocomposites can enhance the composites' tensile, compressive, flexural and impact strength and are preferred for structural application in automotive and construction industries.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100472"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication and characterization of formamidinium-based perovskite photovoltaic devices hybridized with decaphenylcyclopentasilane hole transport layers

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100473

Taiga Nasu , Takeo Oku , Atsushi Suzuki , Tomoharu Tachikawa , Sakiko Fukunishi

引用次数: 0

Performance of geopolymer mortar incorporating spent coffee grounds as a recycled building material: An experimental and predictive analysis

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100479

Ahmet Ferdi Şenol

{"title":"Performance of geopolymer mortar incorporating spent coffee grounds as a recycled building material: An experimental and predictive analysis","authors":"Ahmet Ferdi Şenol","doi":"10.1016/j.hybadv.2025.100479","DOIUrl":"10.1016/j.hybadv.2025.100479","url":null,"abstract":"<div><div>Spent coffee grounds ash (K) is investigated as a sustainable partial sand replacement (0 %, 5 %, 10 %, 15 %) in geopolymer mortars based on granulated blast furnace slag. This study assesses workability, mechanical performance, high-temperature resistance, and microstructure through experimental testing and statistical analysis. Key findings indicate that K content significantly influences workability, strength, and physical properties. Replacing sand with K reduced workability by up to 21 % due to its finer particle size and porosity. The K5 series, containing 5 % K, exhibited the highest compressive strength improvement, with gains of 8.9 % and 16.3 % at 7 and 28 days, respectively, compared to the control. However, higher K contents (10 %, 15 %) negatively impacted mechanical performance. At elevated temperatures, significant mass loss occurred up to 400 °C, after which it stabilized at 600 °C while maintaining structural integrity. Porosity and water absorption increased with K content, except in K5. Microstructural analysis revealed that the K5 series formed a dense, crack-minimal matrix, whereas K10 and K15 exhibited more microcracking and porosity. Statistical models confirmed that temperature had the greatest influence on compressive and flexural strengths, whereas K content significantly affected mass loss.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100479"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100477

Irsa Tariq , Muhammad Zubair , Waheed Iqbal , Amin Badshah , Syed Mustansar Abbas , Ali Haider

{"title":"Alkaline earth metal oxides supported on WO3@MCM-41; bifunctional catalysts for biodiesel production from corn and waste cooking oil","authors":"Irsa Tariq , Muhammad Zubair , Waheed Iqbal , Amin Badshah , Syed Mustansar Abbas , Ali Haider","doi":"10.1016/j.hybadv.2025.100477","DOIUrl":"10.1016/j.hybadv.2025.100477","url":null,"abstract":"<div><div>The novelty of this work lies in the development of a bifunctional acid-base catalyst comprising tungsten oxide (WO<sub>3</sub>) supported on mesoporous MCM-41 and impregnated with alkaline earth metal oxides (Mg, Ca, Sr, Ba), which enables simultaneous esterification and transesterification for biodiesel production. The acidic and basic properties of the catalysts were quantitatively assessed through potentiometric titration, confirming the presence of both acid and basic sites, which are essential for the concurrent esterification of free fatty acids (FFAs) and transesterification of triglycerides. This bifunctionality is particularly advantageous for feedstocks with high FFA content, such as waste cooking oil, addressing a key challenge in biodiesel synthesis. The SrO-based catalyst demonstrated exceptional performance, achieving yields of 96 % for corn oil and 93 % for waste cooking oil, with minimal yield differences of 3 % attributed to the latter's impurities and higher FFA content. The study also provides detailed optimization of reaction conditions, revealing that waste cooking oil requires slightly harsher conditions (100 °C, 6 h, 20 mg catalyst) compared to corn oil (80 °C, 5 h, 10 mg catalyst), which is consistent with its complex composition. Comprehensive characterization (PXRD, SEM-EDX, BET/BJH) and validation through <sup>1</sup>H NMR spectroscopy (yields of 92 % and 91 % for corn and waste cooking oil, respectively) confirm the reliability of the results. Moreover, the biodiesel's physicochemical characteristics were examined thoroughly and contrasted with the ASTM biodiesel requirements. The outcomes demonstrated that the generated biodiesel's characteristics met the requirements of international standards.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100477"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143785784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Carbon and glass fibre-reinforced hybrid composites in flexure

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100471

Chensong Dong

{"title":"Carbon and glass fibre-reinforced hybrid composites in flexure","authors":"Chensong Dong","doi":"10.1016/j.hybadv.2025.100471","DOIUrl":"10.1016/j.hybadv.2025.100471","url":null,"abstract":"<div><div>This study investigates the flexural behaviour of carbon and glass fibre-reinforced hybrid composites using a finite element analysis (FEA)-based approach. Hybrid composites combine the strengths of different fibre types to enhance material performance, with carbon and glass fibres being selected for their distinct mechanical properties. The primary objective is to evaluate the flexural strength and failure mechanisms of these composites, focusing on the effects of hybrid layups and the interlaminar stresses that can lead to delamination. Nine different layups of hybrid composites, varying in the number of glass/epoxy plies, were analysed under three-point bending conditions. The study considers two predominant failure modes: microbuckling and delamination. Results show that delamination is the most likely failure mode, particularly at higher interlaminar shear stresses, while microbuckling is less critical in comparison. The predicted flexural strengths, based on delamination criteria, align closely with experimental data, with relative differences less than 2 %, demonstrating the significant influence of stacking sequence on hybrid composite performance. The findings highlight the complex interplay of fibre types and stacking sequences, providing valuable insights into the design and optimization of carbon and glass fibre-reinforced hybrid composites for engineering applications.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100471"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143808241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst

Hybrid Advances Pub Date : 2025-04-04 DOI: 10.1016/j.hybadv.2025.100463

Carine Lannang Tsokeing , Sanchez Dave Mouafo Dongmo , Esther Judith Maffeu , Pierre Gerard Tchieta , Jean Duplex Wansi

{"title":"Study of the degradation of RY-145 b y the fenton process using a prepared magnetic bentonite as heterogeneous catalyst","authors":"Carine Lannang Tsokeing , Sanchez Dave Mouafo Dongmo , Esther Judith Maffeu , Pierre Gerard Tchieta , Jean Duplex Wansi","doi":"10.1016/j.hybadv.2025.100463","DOIUrl":"10.1016/j.hybadv.2025.100463","url":null,"abstract":"<div><div>The present investigation sets out to describe the potential of magnetite (Fe<sub>3</sub>O<sub>4</sub>) impregnated bentonite (BE-Fe<sub>3</sub>O<sub>4</sub>) to assist in the Fenton process. Utilizing the Co-precipitation method, the BE-Fe<sub>3</sub>O<sub>4</sub> samples were developed as a catalyst for the degradation of RY-145 dye in an aqueous environment. The BE-Fe<sub>3</sub>O<sub>4</sub> were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The effects of solution pH, the concentration of H<sub>2</sub>O<sub>2</sub> solution, the mass of the catalyst, and the concentration of RY-145 dye on the degradation efficiency were evaluated for parametric optimization. The degradation of the dye was most favorable at an acid pH of 2, H<sub>2</sub>O<sub>2</sub> concentration of 1.5 mol/L, 100 mg of the catalyst and the initial RY-145 concentration of 100 mg/L. The pristine and modified clays were morphologically distinguishable, and XRD analyses confirmed the formation of Fe<sub>3</sub>O<sub>4</sub> particles. The minimum degradation percentage above 92 %, irrespective of the process conditions. RY-145 degradation dynamics on BE-Fe<sub>3</sub>O<sub>4</sub> followed second-order kinetic law. After five cycles of evaluation of BE-Fe<sub>3</sub>O<sub>4</sub>'s stability and efficiency, it was discovered that the material lost about 13 % of its efficiency. This research demonstrated that the catalyst obtained from BE-Fe<sub>3</sub>O<sub>4</sub> could be used in the treatment technology of wastewater containing RY-145 b y Fenton process.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100463"},"PeriodicalIF":0.0,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Exploring the evolution of 5D and 6D printing: Current progress, challenges, technological innovations, and transformative biomedical applications 探索 5D 和 6D 打印的演变：当前的进展、挑战、技术创新和变革性生物医学应用

Hybrid Advances Pub Date : 2025-04-03 DOI: 10.1016/j.hybadv.2025.100470

Shrikant Dargude , Snehal Shinde , Swati Jagdale , Satish Polshettiwar , Amarjitsing Rajput

{"title":"Exploring the evolution of 5D and 6D printing: Current progress, challenges, technological innovations, and transformative biomedical applications","authors":"Shrikant Dargude , Snehal Shinde , Swati Jagdale , Satish Polshettiwar , Amarjitsing Rajput","doi":"10.1016/j.hybadv.2025.100470","DOIUrl":"10.1016/j.hybadv.2025.100470","url":null,"abstract":"<div><div>The evolution of additive manufacturing (AM) has led to the development of 4D printing, enabling 3D printed structures to dynamically alter shape in response to external stimuli, thereby improving mechanical properties and patient-specific applications. However, limitations persist in achieving complex geometry elements with high mechanical strength. To address these challenges, enhancement in the printing process and the use of multi-responsive smart materials are essential. The emergence of 5D printing, which combines additive and subtractive manufacturing, has advanced medical design by enhancing structural integrity and surface quality. As AM technology continues to evolve, 5D and 6D printing represent breakthroughs in biomedical engineering. By integrating the dynamic adaptability of 4D printing with the precision of 5D printing, 6D printing offers the potential for patient-specific interventions, particularly in biomedical applications. This review article evaluates the progress made in developing AM technologies, particularly 5D and 6D printing, highlighting the significant growth in healthcare due to the development of materials and technologies that respond to specific clinical demands.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100470"},"PeriodicalIF":0.0,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative Analysis of Silver and Titanium Oxide Hybrid Nanofluid in MHD Unsteady Flow Past an Accelerated Vertical Plate with Radiation Effects

Hybrid Advances Pub Date : 2025-04-01 DOI: 10.1016/j.hybadv.2025.100469

Joseph Nicholaus Lutera , B. Shankar Goud , M.N. Raja Shekar

{"title":"Comparative Analysis of Silver and Titanium Oxide Hybrid Nanofluid in MHD Unsteady Flow Past an Accelerated Vertical Plate with Radiation Effects","authors":"Joseph Nicholaus Lutera , B. Shankar Goud , M.N. Raja Shekar","doi":"10.1016/j.hybadv.2025.100469","DOIUrl":"10.1016/j.hybadv.2025.100469","url":null,"abstract":"<div><div>The problem of MHD unsteady movement of the nanofluid past an accelerated perpendicular surface is investigated. Thermal radiation and electromagnetic field properties are taken into explanation of the hybrid nanofluid composed of Silver and Titanium dioxide nanoparticles. The nanoparticles offer an enhanced thermal conductivity property, a factor important in technological advancement including cooling, separation, nuclear reactors, solar energy and electronic devices. The study aims to analyze the characteristics of different nanofluids on the influence of dimensionless parameters for mass and heat transmission. The resultant nondimensionalized boundary problem is solved numerically by the finite difference technique employed to obtain the mathematical results of the partial differential equations. The results demonstrate a comparison of velocity and thermal energy profiles of Silver-water and Titanium dioxide-water nanofluids graphically. Silver particles portray greater impacts on the nanofluid flow rate than the Titanium dioxide particles. The temperature of silver water is greater than the temperature of Titanium dioxide water. The improvement of thermal radiation strength was observed to enhance the temperature and velocity profiles of the nanofluid. The study is crucial in decision-making, especially for the choice of efficient nanofluid in mass and heat transmission applications.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100469"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigations on effect of amine functionalised graphene nanoplatelets (f-GNPs) reinforcement on mechanical properties of epoxy resin

Hybrid Advances Pub Date : 2025-04-01 DOI: 10.1016/j.hybadv.2025.100443

Neerajkumar Wayzode , Mahendra L. Shelar , Vinod B. Suryawanshi

{"title":"Investigations on effect of amine functionalised graphene nanoplatelets (f-GNPs) reinforcement on mechanical properties of epoxy resin","authors":"Neerajkumar Wayzode , Mahendra L. Shelar , Vinod B. Suryawanshi","doi":"10.1016/j.hybadv.2025.100443","DOIUrl":"10.1016/j.hybadv.2025.100443","url":null,"abstract":"<div><div>Graphene nanoplatelets (f-GNPs) are emerging nanofillers with appealing attributes, such as strong compatibility with a wide range of polymers, exceptional overall strength, and cost-efficiency. This research examines the influence of varying weight fractions of functionalized graphene nanoplatelets (f-GNPs) on the mechanical properties of epoxy resin. Various weight fractions of f-GNPs namely 0.2%, 0.4%,0.6%,0.8%,1% and 5% are added to epoxy resin. Combination of ultra-sonication and magnetic stirring was used for dispersing f-GNPs in epoxy resin. f-GNPs reinforcement showed improvement in tensile strength on epoxy except for 1% and 5% weight fractions. Dispersion of f-GNPs is found to be superior at lower f-GNPs concentrations. The experimental results reveal that incorporating f-GNPs enhances the ultimate tensile strength of epoxy resin by 11.79%, 12.47%, 10.12%, and 13.31% at weight fractions of 0.2%, 0.4%, 0.6%, and 0.8%, respectively. This confirms the beneficial impact of amine-functionalized graphene nanoplatelets (f-GNPs) on epoxy resin. The highest improvement, 13.31%, was achieved at 0.8% f-GNPs, making it the optimal loading, which was subsequently utilized in the development of multiscale f-GNPs-reinforced Glass/Epoxy composites. This study also presents a detailed FTIR, LRS, XRD, TEM, SEM characterisation of amine functionalised graphene nanoplatelets (f-GNPs).</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100443"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Additive manufacturing in biomedical: Applications, challenges, and prospects 生物医学中的快速成型技术：应用、挑战和前景

Hybrid Advances Pub Date : 2025-03-31 DOI: 10.1016/j.hybadv.2025.100467

Md Hosne Mobarak , Abu Sofian Abid , Md Shahriar Munna , Mihir Dutta , Md Israfil Hossain Rimon

{"title":"Additive manufacturing in biomedical: Applications, challenges, and prospects","authors":"Md Hosne Mobarak , Abu Sofian Abid , Md Shahriar Munna , Mihir Dutta , Md Israfil Hossain Rimon","doi":"10.1016/j.hybadv.2025.100467","DOIUrl":"10.1016/j.hybadv.2025.100467","url":null,"abstract":"<div><div>Additive Manufacturing (AM), also called 3D printing, has introduced revolutionary advancements across multiple industries, particularly impacting the biomedical field. This technology facilitates the production of intricate, patient-specific medical devices, such as implants, prosthetics, and surgical models, with unparalleled precision and customization. These capabilities have facilitated personalized medicine, enabling therapies customized to particular patient requirements and anatomical characteristics, improving clinical outcomes and patient satisfaction. Nevertheless, numerous obstacles continue to impede the comprehensive integration of AM into conventional healthcare. Critical concerns encompass the biocompatibility and longevity of additive manufacturing materials, rigorous regulatory and safety standards, and the substantial expenses linked to the development and production of additive manufacturing medical devices. Confronting these problems necessitates continuous research and development to formulate better biocompatible materials, enhance additive manufacturing methods, and facilitate regulatory approval procedures. This study will offer a comprehensive overview of the applications, constraints, and future potential of additive manufacturing in biomedicine, highlighting its contribution to personalized healthcare solutions and enhanced patient outcomes through innovation.</div></div>","PeriodicalId":100614,"journal":{"name":"Hybrid Advances","volume":"10 ","pages":"Article 100467"},"PeriodicalIF":0.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0