Electrodeposition and Surface Treatment最新文献

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Conference announcements 会议公告
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90055-3
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引用次数: 0
Organic additives in zinc electroplating 电镀锌中的有机添加剂
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90048-6
K. Boto
{"title":"Organic additives in zinc electroplating","authors":"K. Boto","doi":"10.1016/0300-9416(75)90048-6","DOIUrl":"10.1016/0300-9416(75)90048-6","url":null,"abstract":"<div><p>The use of organic additives in zinc electroplating is reviewed with particular emphasis on the types of compounds used, the bath type for which they are most suited, and their function with respect to brightening and levelling action. Fundamental studies of the mode of action of these additives are also reviewed and comparisons are made with similar studies of nickel and copper electrodeposition. It is concluded that much more fundamental studies are required to fully explain the effects of additives. Further, the effect of codeposition of organic impurities on the corrosion resistance of electrodeposited zinc requires urgent study.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 77-95"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90048-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78921241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 57
Texture and morphology of nickel coatings deposited in the presence of surfactants 表面活性剂作用下镍镀层的结构和形貌
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90050-4
St. Rashkov, N. Atanasov
{"title":"Texture and morphology of nickel coatings deposited in the presence of surfactants","authors":"St. Rashkov,&nbsp;N. Atanasov","doi":"10.1016/0300-9416(75)90050-4","DOIUrl":"10.1016/0300-9416(75)90050-4","url":null,"abstract":"<div><p>The morphology and orientation texture of nickel coatings obtained from a Watts electrolyte in the presence of iodine ions, butyne-2-diol 1,4, formalin and phthalic anhydride over a wide current density and temperature interval were investigated. Electron diffraction measurements made it possible to determine the orientation axis at small thicknesses (from 1000 to 10,000 Å).</p><p>The 〈110〉 and 〈211〉 orientation axes observed in coatings obtained in the presence of iodine ions appear at a considerably later stage of the formation process of the coatings, whereas the addition of butyne-2-diol 1,4 leads to the formation of an oriented coating at a coating thickness of 1000 Å.</p><p>The morphology of coatings with a 〈211〉 orientation in the presence of iodine ions and butyne-2-diol 1,4 is completely different owing to the different growth mechanisms in the presence of one or another of the additives.</p><p>The presence or absence of the extra reflection on the electron diffraction patterns from coatings with a 〈211〉 orientation is thought to be connected with a different growth mechanism and therefore with a different morphology.</p><p>In the presence of formalin or phthalic anhydride the morphology of the nickel coating closely resembles that observed in the presence of iodine ions in the electrolyte.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 105-120"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90050-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80236279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Characterization of the corrosion or anodic oxidation products on zinc 锌表面腐蚀或阳极氧化产物的表征
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90052-8
G. Trabanelli, F. Zucchi, G. Brunoro, G. Gilli
{"title":"Characterization of the corrosion or anodic oxidation products on zinc","authors":"G. Trabanelli,&nbsp;F. Zucchi,&nbsp;G. Brunoro,&nbsp;G. Gilli","doi":"10.1016/0300-9416(75)90052-8","DOIUrl":"10.1016/0300-9416(75)90052-8","url":null,"abstract":"<div><p>The characteristics of surface products formed on zinc in slightly alkaline aqueous solutions have been studied. Measurements have been carried out on freely corroding zinc or on zinc galvanically coupled with iron, also in conditions of polarity reversal of the couple.</p><p>Experimental techniques such as photopotential measurements and X-ray diffraction have been applied. The photoelectrochemical measurements allowed the determination of the <em>n</em> or <em>p</em> semiconducting properties of the surface products.</p><p>It was shown that at high temperature or during the polarity reversal of the couple, <em>n</em>-ZnO was formed.</p><p>Analogous series of measurements were performed on zinc electrodes under conditions of anodic oxidation in borate buffer.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 129-138"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90052-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88823133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
X-ray line broadening in electrodeposited gold coatings 电沉积金镀层的x射线谱线展宽
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90053-X
L. Revay
{"title":"X-ray line broadening in electrodeposited gold coatings","authors":"L. Revay","doi":"10.1016/0300-9416(75)90053-X","DOIUrl":"10.1016/0300-9416(75)90053-X","url":null,"abstract":"<div><p>X-ray line broadening studies of electrodeposited gold coatings with different deposition variables and annealing treatments have been made. Dislocation densities estimated from X-ray data on domain size and lattice strains have been shown to increase with increasing cobalt content and deposition rate; an annealing treatment reduced the dislocation level in the deposits.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 139-144"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90053-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74648004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
A new method for the determination of stress-strain curves on thin electroplated layers 一种测定薄电镀层应力-应变曲线的新方法
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90054-1
Ch.J. Raub, J. Lendvay
{"title":"A new method for the determination of stress-strain curves on thin electroplated layers","authors":"Ch.J. Raub,&nbsp;J. Lendvay","doi":"10.1016/0300-9416(75)90054-1","DOIUrl":"10.1016/0300-9416(75)90054-1","url":null,"abstract":"<div><p>Stress-strain curves are obtained for hard gold deposits electroplated onto soft gold wires. The strenth of the substrate wire is too low to contribute significantly to the behaviour of the composite specimens. The method avoids a number of possible artefacts and is useful for testing the quality of electrolytes and deposits. Application to other metals in anticipated.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 145-147"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90054-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83415896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrolytic aluminium-plating in fused salts based on chlorides 以氯化物为基础的熔盐中的电解镀铝
Electrodeposition and Surface Treatment Pub Date : 1975-03-01 DOI: 10.1016/0300-9416(75)90051-6
M. Paučírová, K. Matiašovský
{"title":"Electrolytic aluminium-plating in fused salts based on chlorides","authors":"M. Paučírová,&nbsp;K. Matiašovský","doi":"10.1016/0300-9416(75)90051-6","DOIUrl":"10.1016/0300-9416(75)90051-6","url":null,"abstract":"<div><p>Electrolytic aluminium-plating of iron bases in fused salts based on chlorides was investigated. As base electrolytes, the ternary AlCl<sub>3</sub>-NaCl- KCl mixtures containing 76–80 wt.% AlCl<sub>3</sub> and 20–24 wt.% of NaCl and KCl in the ratio of 1:1 were found to be the most effective. The quality of the deposited Al layer was further improved by an addition of 5 wt.% NaI. The best results were obtained in the temperature range 150–200°C with a cathodic current density of up to 7 A dm<sup>-2</sup>. Under these conditions, aluminum was deposited in the form of a fine-crystalline, silver-bright and non-porous layer.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 2","pages":"Pages 121-128"},"PeriodicalIF":0.0,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90051-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88984968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Molten salts in metal treating: Present uses and future trends 熔盐在金属处理中的应用现状及未来趋势
Electrodeposition and Surface Treatment Pub Date : 1975-01-01 DOI: 10.1016/0300-9416(75)90008-5
M. Galopin, J.S. Daniel
{"title":"Molten salts in metal treating: Present uses and future trends","authors":"M. Galopin,&nbsp;J.S. Daniel","doi":"10.1016/0300-9416(75)90008-5","DOIUrl":"10.1016/0300-9416(75)90008-5","url":null,"abstract":"<div><p>The uses of molten salt baths in metal treating applications such as heat treatment, cementation, cleaning, finishing and brazing are reviewed. The potential of some promising new applications is also assessed.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 1","pages":"Pages 1-31"},"PeriodicalIF":0.0,"publicationDate":"1975-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90008-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85856702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Die elektrolytische abscheidung von Kupferüberzü gen aus pyrophosphatelektrolyten 电解质对黄铁矿进行的铜沉淀
Electrodeposition and Surface Treatment Pub Date : 1975-01-01 DOI: 10.1016/0300-9416(75)90009-7
B.A. Purin, E.A. Ozola
{"title":"Die elektrolytische abscheidung von Kupferüberzü gen aus pyrophosphatelektrolyten","authors":"B.A. Purin,&nbsp;E.A. Ozola","doi":"10.1016/0300-9416(75)90009-7","DOIUrl":"10.1016/0300-9416(75)90009-7","url":null,"abstract":"<div><p></p><ul><li><span>1.</span><span><p>1. In copper pyrophosphate solutions in the range of pH 8 – 9, the copper electrode is reversible with respect to the free copper ions in the solution.</p></span></li><li><span>2.</span><span><p>2. At the cathode, the formation of a passive layer and the stepwise-reduction of the anionic copper pyrophosphate complex are most important. These phenomena determine the high cathodic polarisation and the finegrained structure of electroplated copper.</p></span></li><li><span>3.</span><span><p>3. The investigation of the electrochemical behaviour of an iron electrode in copper pyrophosphate plating solutions showed that the passive and active state of the electrode depends on the following: the concentrations of the principal components, the pH, and the presence of adducts in the solution. These factors must be taken into account for the production of adhering deposits in the electroplating of copper.</p></span></li><li><span>4.</span><span><p>4. A copper pyrophosphate electrolyte for bright copper plating on steel is described.</p></span></li></ul></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 1","pages":"Pages 33-43"},"PeriodicalIF":0.0,"publicationDate":"1975-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90009-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84933164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electro-affinage du cuivre: Influence des ions chlorure sur la cinetique de la reaction anodique 铜的电精炼:氯离子对阳极反应动力学的影响
Electrodeposition and Surface Treatment Pub Date : 1975-01-01 DOI: 10.1016/0300-9416(75)90010-3
R Galecio , J Guitton
{"title":"Electro-affinage du cuivre: Influence des ions chlorure sur la cinetique de la reaction anodique","authors":"R Galecio ,&nbsp;J Guitton","doi":"10.1016/0300-9416(75)90010-3","DOIUrl":"10.1016/0300-9416(75)90010-3","url":null,"abstract":"<div><p>The anodic dissolution of copper was studied in acid sulfate solution with concentrations and temperature as in the industry of electrolytic refining of copper. The effect of chloride ions in the phenomenon was studied, by using anodic and cathodic voltametry and potentiostatic methods. The results show that the mechanism of copper dissolution is not radically altered by the presence of chloride ions in the range of chloride concentrations and tension studied, but a cuprous chloride layer formed at the anode surface is confirmed causing a general decrease of anodic current density in voltametry. The observed phenomenon suggests a mechanism of copper oxidation via adsorbed phase.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"3 1","pages":"Pages 45-53"},"PeriodicalIF":0.0,"publicationDate":"1975-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(75)90010-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90488425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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