Electrodeposition and Surface Treatment最新文献

筛选
英文 中文
Die elektrolytische abscheidung von zinnüberzügen aus pyrophosphatelektrolyten 这样一来,电解质就会分离细胞核锡层
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90030-8
B.A. Purin, I.A. Vitina
{"title":"Die elektrolytische abscheidung von zinnüberzügen aus pyrophosphatelektrolyten","authors":"B.A. Purin,&nbsp;I.A. Vitina","doi":"10.1016/0300-9416(73)90030-8","DOIUrl":"https://doi.org/10.1016/0300-9416(73)90030-8","url":null,"abstract":"<div><p>(1) Die kathodische Reduktion des Zinns wird sowohl durch die Bedingungen der Zufuhr und des Zerfalls des Zinn-Pyrophosphatkomplexes im Kathodenraum, als auch durch die Bildung des Hydroxids und der passivierenden Schicht bedingt.</p><p>Die Hauptrolle bei den Passivierungsvorgängen auf der Kathode spielt die Reduktion des Sn(IV) zum Sn(II), die mit der Bildung einer kompakten Zinnoxidschicht verbunden ist.</p><p>(2) Der Einfluβ der Konzentration der Sn<sup>4+</sup>-Ionen und einiger stabilisierender Zusätze zum Elektrolyt auf den Prozeβ der elektrolytischen Abscheidung von Zinn-Niederschlägen und die Stabilität des Elektrolyts während seiner Arbeit wurde untersucht. Es wird gezeigt, daβ Hydrazinhydrochlorid die Oxydation des Sn(II) wirksam unterdrückt; zusammen mit Gelatinehydrolysat läβt sich mit diesen Zusätzen eine hohe Einebnung (bis zu 100%) der Zinnoberfläche erzielen.</p><p>(3) Auf Grund der mitgeteilten Untersuchungsergebnisse wird ein hochleistungsfähiger Pyrophosphatelektrolyt zur elektrolytischen Verzinnung und Blechverzinnung empfohlen. Dieser Elektrolyt ist hydrolytisch stabil, oxydationsfest und gibt glänzende und halbglänzende porenfreie Zinnüberzüge in einem breiten Arbeitstemperaturbereich der Lösung.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 471-481"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90030-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92079763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of addition agents on the electrical resistivity of electrodeposited nickel 添加剂对电沉积镍电阻率的影响
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90027-8
P. Sibley , P.A. Brook
{"title":"The effect of addition agents on the electrical resistivity of electrodeposited nickel","authors":"P. Sibley ,&nbsp;P.A. Brook","doi":"10.1016/0300-9416(73)90027-8","DOIUrl":"10.1016/0300-9416(73)90027-8","url":null,"abstract":"<div><p>The effects of butynediol, coumarin, sodium naphthalenesulphonate, sodium benzenesulphonate and toluenesulphonamide on the electrical resistivity, mean grain diameter and hardness of nickel deposited from a Watts type solution are reported. The resistivity is dependent on type of addition, its concentration and the thickness of the deposit. The effect of thickness is that a very flat maximum is produced in between 10 and 20 μm. The absolute values of the resistivity vary from ≈70 μΩ-mm for deposits from a pure Watts bath to ≈120 μΩ-mm for deposits from baths containing coumarin.</p><p>The results are correlated with the size and active groups of the molecules through their adsorption-desorption behaviour. The adsorption of butynediol follows the Langmuir adsorption.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 439-448"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90027-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76066642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
A non-destructive optical technique for testing lacquered metal surfaces 一种检测涂漆金属表面的无损光学技术
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90028-X
J.P.G. Farr, J.M. Keen , M.D. Pettitt
{"title":"A non-destructive optical technique for testing lacquered metal surfaces","authors":"J.P.G. Farr,&nbsp;J.M. Keen ,&nbsp;M.D. Pettitt","doi":"10.1016/0300-9416(73)90028-X","DOIUrl":"10.1016/0300-9416(73)90028-X","url":null,"abstract":"<div><p>A simple non-destructive optical technique is described for testing lacquering on metal. A d.c. voltage is applied across a nematic liquid crystal layer sandwiched between the lacquered surface under investigation and a transparent conductive layer on a microscope slide. Current leakage across the nematic as the voltage is raised disturbs the molecular structure in the liquid crystal and causes dynamic optical displays viewed through the glass slide. Leakage occurs readily at pin-holes, less readily at physical or chemical heterogeneities in the lacquer. Examples are given of the application to defects in lacquer on tin-plate.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 449-455"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90028-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74230069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pulsating potential electrolysis in the deposition of copper 铜沉积中的脉冲电位电解
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90026-6
G. Savic-Maglić, A.R. Despić
{"title":"Pulsating potential electrolysis in the deposition of copper","authors":"G. Savic-Maglić,&nbsp;A.R. Despić","doi":"10.1016/0300-9416(73)90026-6","DOIUrl":"10.1016/0300-9416(73)90026-6","url":null,"abstract":"<div><p>A very low impedance circuit was constructed in order to provide a pulsating cathodic potential for a copper electrode immersed in a copper sulphate solution of the type used in copper refining. The increase in surface roughness during a fixed period of plating was investigated as a function of the frequency of pulsation. It was established that the relative increase in surface roughness depended linearly on the square root of the reciprocal frequency. This is in accordance with the theory based on the model of amplification of surface roughness being a transport controlled phenomenon.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 429-438"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90026-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84646081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of ultrasonic agitation on some properties of electrodeposits 超声搅拌对镀层某些性能的影响
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90029-1
C.T. Walker, R. Walker
{"title":"Effect of ultrasonic agitation on some properties of electrodeposits","authors":"C.T. Walker,&nbsp;R. Walker","doi":"10.1016/0300-9416(73)90029-1","DOIUrl":"10.1016/0300-9416(73)90029-1","url":null,"abstract":"<div><p>This paper reviews the effect of ultrasonic agitation of the plating solution on the grain size, hardness, internal stress, porosity and brightness of electrodeposited metals. Generally, the hardness and brightness of electrodeposits are increased by ultrasonic agitation, whereas the porosity is decreased. Results from different sources for the effect of ultrasound on internal stress are conflicting, although coatings which are codeposited with hydrogen usually have a reduced internal stress. The influence of ultrasonic vibration on deposit grain size appears to be the controlling factor in most, if not all, property changes; dehydrogenation and the codeposition of extraneous particles, however, may also be important.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 457-469"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90029-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84406886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 55
Observations on the dissolution tests for sealing quality of anodic coatings on aluminium 铝阳极镀层密封质量的溶解试验观察
Electrodeposition and Surface Treatment Pub Date : 1973-07-01 DOI: 10.1016/0300-9416(73)90031-X
R. Lizarbe, S. Feliu
{"title":"Observations on the dissolution tests for sealing quality of anodic coatings on aluminium","authors":"R. Lizarbe,&nbsp;S. Feliu","doi":"10.1016/0300-9416(73)90031-X","DOIUrl":"10.1016/0300-9416(73)90031-X","url":null,"abstract":"<div><p>An approach is made towards a better understanding of the influence of some variables on the immersion tests currently in favour for determination of the sealing quality of anodic coatings on aluminium. The paper first discusses the dissolution mechanism of unsealed oxide coatings and that of coatings with different degrees of sealing. Data are then given which show the effects of the dissolved aluminium and of sodium acetate and acetic acid additions on the dissolving power of the so-called “acetic bath” as well as of sodium sulphite and sulphuric acid additions on the so-called “acidified sulphite bath”. The influence of a nitric acid pretreatment on the results obtained from both baths is also discussed. Finally, the effect of ageing on the oxide coating is commented upon.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 6","pages":"Pages 483-497"},"PeriodicalIF":0.0,"publicationDate":"1973-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90031-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78100072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electrochemical boriding of molybdenum in molten salts 熔盐中钼的电化学渗硼
Electrodeposition and Surface Treatment Pub Date : 1973-05-01 DOI: 10.1016/0300-9416(73)90025-4
A. Bonomi, H. Giess, C. Gentaz
{"title":"Electrochemical boriding of molybdenum in molten salts","authors":"A. Bonomi,&nbsp;H. Giess,&nbsp;C. Gentaz","doi":"10.1016/0300-9416(73)90025-4","DOIUrl":"10.1016/0300-9416(73)90025-4","url":null,"abstract":"<div><p>This work describes a study of the growth of a Mo<sub>2</sub>B<sub>5</sub> layer, obtained by diffusion of boron produced by cathodic reduction of KBF<sub>4</sub> on molybdenum metal in molten fluorides, at 830°C.</p><p>The growth of the Mo<sub>2</sub>B<sub>5</sub> layer has been studied by the galvanostatic method, and is controlled by diffusion of boron in the boride layer.</p><p>The experimental results show that boriding may occur with about 100% Faraday efficiency, and the calculated diffusion coefficient of boron in the surface layer is in agreement with the literature data obtained by chemical vapour boriding studies.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 5","pages":"Pages 419-427"},"PeriodicalIF":0.0,"publicationDate":"1973-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90025-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75140831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Elektrolumineszenzerscheinungen bei der anodisierung des aluminiums in chromsäure 一种病原光病变…就是都是铝造
Electrodeposition and Surface Treatment Pub Date : 1973-05-01 DOI: 10.1016/0300-9416(73)90020-5
P. Csokán
{"title":"Elektrolumineszenzerscheinungen bei der anodisierung des aluminiums in chromsäure","authors":"P. Csokán","doi":"10.1016/0300-9416(73)90020-5","DOIUrl":"10.1016/0300-9416(73)90020-5","url":null,"abstract":"<div><p>Es wurden Untersuchungen zwecks Feststellung der Bedingungen des Auftretens von Elektrolumineszenzerscheinungen beim Anodisieren des Aluminiums durchgeführt. Die in verdünnten, kalten Chromsäurelösungen ermittelten Ergebnisse bestätigen, daβ Funkenentladungs- und Glimmerscheinungen nicht nur bei der Formierung der Oxidsperrschichten in oxidnichtlösenden Elektrolyten auftreten, sondern — im Gegensatz zur bisherigen Auffassung — bei Anwendung bestimmter Versuchsbedingungen auch in den oxidlösenden Elektrolyten hervorgerufen werden können.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 5","pages":"Pages 349-358"},"PeriodicalIF":0.0,"publicationDate":"1973-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90020-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87600992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Corrosion tests of stainless steel X6 Cr Mo 17 and of microcracked chromium surface layers by electrochemical techniques 不锈钢X6 Cr Mo 17及微裂纹铬表面层的电化学腐蚀试验
Electrodeposition and Surface Treatment Pub Date : 1973-05-01 DOI: 10.1016/0300-9416(73)90023-0
F. Stricker, J. Brauner
{"title":"Corrosion tests of stainless steel X6 Cr Mo 17 and of microcracked chromium surface layers by electrochemical techniques","authors":"F. Stricker,&nbsp;J. Brauner","doi":"10.1016/0300-9416(73)90023-0","DOIUrl":"10.1016/0300-9416(73)90023-0","url":null,"abstract":"<div><p>Electrode potential- and current density-time curves in dilute sulphuric acid and in 3% NaCl solution were measured in order to compare the corrosion resistance of microcracked chromium layers and of X6 Cr Mo 17 steel. The surface potentials of the two materials were registered in another series of trials in weak acid alcoholic solution. The results allowed the following conclusions to be drawn: </p><ul><li><span>1.</span><span><p>1. The X6 Cr Mo 17 steel has the better corrosion resistance in weak sulphuric acid; this means that it is the better suited for an industrial atmosphere.</p></span></li><li><span>2.</span><span><p>2. In solutions with chlorine ions a more or less superficial attack on the microcracked chromium layer can be observed, but the pitting of the X6 Cr Mo 17 steel is to be expected.</p></span></li><li><span>3.</span><span><p>3. In electrolytes the production of local cells on the microcracked chromium layer is to be expected and for that reason some local corrosion, too; there is no pitting, however. The corresponding differences of potential were not observed with the X6 Cr Mo 17 steel. Therefore the steel must react more advantageously.</p></span></li></ul><p>Accelerated corrosion tests completed the trials and brought results which agree with these conclusions.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 5","pages":"Pages 395-404"},"PeriodicalIF":0.0,"publicationDate":"1973-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90023-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84747739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Anodic oxidation of aluminium in sulphuric acid under potentiostatic conditions 恒电位条件下铝在硫酸中的阳极氧化
Electrodeposition and Surface Treatment Pub Date : 1973-05-01 DOI: 10.1016/0300-9416(73)90024-2
T. Muramaki, H.R. Khan, Ch.J. Raub
{"title":"Anodic oxidation of aluminium in sulphuric acid under potentiostatic conditions","authors":"T. Muramaki,&nbsp;H.R. Khan,&nbsp;Ch.J. Raub","doi":"10.1016/0300-9416(73)90024-2","DOIUrl":"10.1016/0300-9416(73)90024-2","url":null,"abstract":"<div><p>The behaviour of the current and impedance have been investigated at low potentials and temperatures by means of a potentiostatic technique for the initial anodic oxidation of aluminium in sulphuric acid. A linear relationship between the reciprocal capacitance and the oxide over potential was obtained and found to be independent of temperature. However, the resistance of the oxide films was temperature dependent. It increases with increasing electrical field. A deviation from an exponential relationship between the current and the potential was found at lower potentials. The experimental data obtained indicate that the initial growth of the pores of the oxide films depends on the applied electrical field strength. A deviation from the empirical exponential relationship between the ionic current and the electrical field strength for the barrier type film is a characteristic of the porous type film in the region of low oxide over potentials.</p></div>","PeriodicalId":100399,"journal":{"name":"Electrodeposition and Surface Treatment","volume":"1 5","pages":"Pages 405-418"},"PeriodicalIF":0.0,"publicationDate":"1973-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9416(73)90024-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84166950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信