Carbon Neutralization最新文献_第2页

Interfacial regulation engineering in anode-free rechargeable batteries 无阳极充电电池中的界面调节工程

Carbon Neutralization Pub Date : 2024-06-05 DOI: 10.1002/cnl2.144

Zhendong Hao, Liang Yan, Wenjie Li, Yuhan Zeng, Yuming Dai, Yuan Cong, Jia Ju, Baosen Zhang

{"title":"Interfacial regulation engineering in anode-free rechargeable batteries","authors":"Zhendong Hao, Liang Yan, Wenjie Li, Yuhan Zeng, Yuming Dai, Yuan Cong, Jia Ju, Baosen Zhang","doi":"10.1002/cnl2.144","DOIUrl":"10.1002/cnl2.144","url":null,"abstract":"Anode-free rechargeable batteries (AFRBs), equipped with bare collectors at the anode, are potential electrochemical energy storage technology attributed to their simplified cell configuration, high energy density, and cost reduction. Nevertheless, issues including insufficient Coulombic efficiency as well as the formation of the dendrites restrict their practical implementation. In recent years, various strategies have been proposed to overcome the critical issues of AFRBs. Among which, interfacial properties play key roles for achieving high stable AFRBs. In this review, an overview of AFRBs is discussed in the first part. Then, the main strategies based on interfacial regulation engineering toward high-performance AFRBs are summarized including designing of current collectors, introducing of surface coating layers, modification of electrolytes, separators engineering, cathode materials regulation, and so forth. In addition, some future perspectives for developing AFRBs are proposed. This review will create new avenues on constructing stable AFRBs for advanced energy storage devices.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.144","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141386308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Highly active air electrode catalysts for Zn-air batteries: Catalytic mechanism and active center from obfuscation to clearness 用于锌-空气电池的高活性空气电极催化剂：从模糊到清晰的催化机理和活性中心

Carbon Neutralization Pub Date : 2024-06-04 DOI: 10.1002/cnl2.133

Wenhui Deng, Zirui Song, Mingjun Jing, Tianjing Wu, Wenzhang Li, Guoqiang Zou

{"title":"Highly active air electrode catalysts for Zn-air batteries: Catalytic mechanism and active center from obfuscation to clearness","authors":"Wenhui Deng, Zirui Song, Mingjun Jing, Tianjing Wu, Wenzhang Li, Guoqiang Zou","doi":"10.1002/cnl2.133","DOIUrl":"10.1002/cnl2.133","url":null,"abstract":"Carbon-based materials have been found to accelerate the sluggish kinetic reaction and are largely subject to the overall Zn-air batteries (ZABs) property, while their full catalytic mechanism is still not excavated because of the indistinct internal structure and immature in-situ technology. Up to now, systematic methods have been utilized to study and design promising high-performance carbon-based catalysts. To resolve the real active units and catalytic mechanism, developing molecular catalyst is a significant strategy. Herein, the review will initiate to briefly introduce the working principle and composition of ZABs. An important statement is correspondingly provided about the typical structure and catalytic mechanisms for the air cathode material. It also presents the tremendous endeavors on the catalytic performance and stability of carbon-based material. Furthermore, combined with theoretical calculation, the self-defined active sites are analyzed to understand the catalytic character, where the molecular catalyst is subsequently summarized and discussed through highlighting the unambiguous and controllable structure, in the hope of surfacing the optimum catalyst. Building on the fundamental understanding of carbon-based and molecular catalysts, this review is expected to provide guidance and direction toward designing future mechanistic studies and ORR electrocatalysts.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.133","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141267788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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MXene materials: Pioneering sustainable energy storage solutions MXene 材料：开创可持续能源存储解决方案

Carbon Neutralization Pub Date : 2024-05-29 DOI: 10.1002/cnl2.135

Minghua Chen, Qi Fan, Ke Chen, Eva Majkova, Qing Huang, Kun Liang

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Mitigating voltage decay of O3-NaNi1/3Fe1/3Mn1/3O2 layered oxide cathode for sodium-ion batteries by incorporation of 5d metal tantalum 通过加入 5d 金属钽减缓钠离子电池 O3-NaNi1/3Fe1/3Mn1/3O2 层状氧化物阴极的电压衰减

Carbon Neutralization Pub Date : 2024-05-28 DOI: 10.1002/cnl2.136

Shuai Huang, Yuanyuan Sun, Tao Yuan, Haiying Che, Qinfeng Zheng, Yixiao Zhang, Pengzhi Li, Jian Qiu, Yuepeng Pang, Junhe Yang, Zi-Feng Ma, Shiyou Zheng

{"title":"Mitigating voltage decay of O3-NaNi1/3Fe1/3Mn1/3O2 layered oxide cathode for sodium-ion batteries by incorporation of 5d metal tantalum","authors":"Shuai Huang, Yuanyuan Sun, Tao Yuan, Haiying Che, Qinfeng Zheng, Yixiao Zhang, Pengzhi Li, Jian Qiu, Yuepeng Pang, Junhe Yang, Zi-Feng Ma, Shiyou Zheng","doi":"10.1002/cnl2.136","DOIUrl":"https://doi.org/10.1002/cnl2.136","url":null,"abstract":"The cycling stability of O3-type NaNi1/3Fe1/3Mn1/3O2 (NFM) as a commercial cathode material for sodium ion batteries (SIBs) is still a challenge. In this study, the Ni/Fe/Mn elements are replaced successfully with tantalum (Ta) in the NFM lattice, which generated additional delocalized electrons and enhanced the binding ability between the transition metal and oxygen, resulting in suppressed lattice distortion during charging and discharging. This caused significant mitigation of voltage decay and improved cycle stability within the potential range of 2.0–4.2 V. The optimized Na(Ni1/3Fe1/3Mn1/3)0.97Ta0.03O2 sample achieved a reversible capacity of 162.6 mAh g−1 at a current rate of 0.1 C and 73.2 mAh g−1 at a high rate of 10 C. Additionally, the average charge/discharge potential retention reached 98% after 100 cycles, significantly mitigating the voltage decay. This work demonstrates a significant contribution towards the practical utilization of NFM cathodes in the SIBs energy storage field.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.136","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141968245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Front Cover: Carbon Neutralization, Volume 3, Issue 3, May 2024 封面：碳中和》，第 3 卷第 3 期，2024 年 5 月

Carbon Neutralization Pub Date : 2024-05-27 DOI: 10.1002/cnl2.149

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Inside Front Cover Image: Carbon Neutralization, Volume 3, Issue 3, May 2024 封面内页图片：碳中和》，第 3 卷第 3 期，2024 年 5 月

Carbon Neutralization Pub Date : 2024-05-27 DOI: 10.1002/cnl2.150

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Back Cover Image: Carbon Neutralization, Volume 3, Issue 3, May 2024 封底图片：碳中和》，第 3 卷第 3 期，2024 年 5 月

Carbon Neutralization Pub Date : 2024-05-27 DOI: 10.1002/cnl2.151

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Covalent organic framework-derived Fe, Co-nitrogen codoped carbon as a bifunctional electrocatalyst for rechargeable efficient Zn–air batteries 源于共价有机框架的铁、氮共掺碳作为双功能电催化剂用于可充电高效锌-空气电池

Carbon Neutralization Pub Date : 2024-05-27 DOI: 10.1002/cnl2.145

Zhanpeng Chen, Jiabi Jiang, Mingjun Jing, Yansong Bai, Xiaoyan Zhang, Wenhui Deng, Yufeng Wu, Fang Chen, Mingguang Yi, Meixia Yang, Xinkai Xu, Tianjing Wu, Yang Zhang, Xianyou Wang

{"title":"Covalent organic framework-derived Fe, Co-nitrogen codoped carbon as a bifunctional electrocatalyst for rechargeable efficient Zn–air batteries","authors":"Zhanpeng Chen, Jiabi Jiang, Mingjun Jing, Yansong Bai, Xiaoyan Zhang, Wenhui Deng, Yufeng Wu, Fang Chen, Mingguang Yi, Meixia Yang, Xinkai Xu, Tianjing Wu, Yang Zhang, Xianyou Wang","doi":"10.1002/cnl2.145","DOIUrl":"https://doi.org/10.1002/cnl2.145","url":null,"abstract":"The development of cathode materials with controllable physicochemical structures and explicit catalytic sites is important in rechargeable Zn–air batteries (ZABs). Covalent organic frameworks (COFs) have garnered increasing attention owing to their facile synthesis methods, ordered pore structure, and selectivity of functional groups. However, the sluggish kinetics of oxygen evolution reaction (OER) or oxygen reduction reaction (ORR) inhibit their practical applications in ZABs. Herein, nucleophilic substitution is adopted to synthesize pyridine bi-triazine covalent organic framework (denoted as O-COF), and meanwhile, ionothermal conversion synthesis is employed to load MOx (M=Fe, Co) onto carbon nanosheet (named as FeCo@NC) to modulate the electronic structure. The Fe, Co-N codoped carbon material possesses a large portion of pyridinic N and M-N, high graphitization, and a larger BET surface area. An outstanding bifunctional activity has been exhibited in FeCo@NC, which provides a small voltage at 10 mA cm−2 for OER (E10 = 1.67 V) and a remarkable half-wave voltage for ORR (E1/2 = 0.86 V). More impressively, when assembling ZABs, it displays notable rate performance, significant specific capacity (783.9 mAh gZn−1), and satisfactory long-term endurance. This method of regulating covalent organic framework and ionothermal synthesis can be extended to design diverse catalysts.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.145","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Hybrid catalyst-assisted synthesis of multifunctional carbon derived from Camellia shell for high-performance sodium-ion batteries and sodium-ion hybrid capacitors 混合催化剂辅助合成提取自山茶壳的多功能碳，用于高性能钠离子电池和钠离子混合电容器

Carbon Neutralization Pub Date : 2024-05-23 DOI: 10.1002/cnl2.146

Hanshu Mao, Sisi Yang, Yingjun Yang, Jinyue Yang, Guizhi Yuan, Mingtao Zheng, Hang Hu, Yeru Liang, Xiaoyuan Yu

{"title":"Hybrid catalyst-assisted synthesis of multifunctional carbon derived from Camellia shell for high-performance sodium-ion batteries and sodium-ion hybrid capacitors","authors":"Hanshu Mao, Sisi Yang, Yingjun Yang, Jinyue Yang, Guizhi Yuan, Mingtao Zheng, Hang Hu, Yeru Liang, Xiaoyuan Yu","doi":"10.1002/cnl2.146","DOIUrl":"10.1002/cnl2.146","url":null,"abstract":"Biomass-derived carbon as energy storage materials have gradually attracted widespread attention due to their low cost, sustainability, and inherent structural advantages. Herein, hard carbon (H-1200) and porous carbon (PC-800) for sodium-ion batteries (SIBs), sodium-ion capacitors (SICs) half cells and sodium-ion hybrid capacitors (SIHCs) have been synthesized from the same biomass precursor of Camellia shells through different treatments. H-1200 synthesized by directly high-temperature carbonization possesses a rational graphitic layer structure and plentiful heteroatoms. When applied as anode for SIBs, it exhibits a reversible capacity of 365.5 mAh g–1 at 25 mA g–1 and capacity retention 89.0% after 400 cycles at 200 mA g–1. Additionally, PC-800 prepared by catalytic carbonization of K2C2O4/CaC2O4 hybrid catalyst has a sophisticated porous structure and a high surface area of 2186.9 m2 g–1. When employed as a cathode for SICs, it delivers a maximum capacity 104.2 mAh g–1 at 100 mA g–1 and 35.0 mAh g–1 at 5 A g–1. Furthermore, the all carbon assembled SIHC (H-1200||PC-800) using H-1200 as anode and PC-800 as cathode, features a broad output voltage range (0.01 ~ 4.1 V), high energy density of 161.5 Wh kg–1, power density of 12896.1 W kg–1, and superior capacity retention of 90.32% after 10000 cycles at 10 A g–1. This research result provide a new horizon for constructing low-cost and large-scale production of biomass derived carbon for energy storage materials.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.146","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141104342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Multiscale modeling for enhanced battery health analysis: Pathways to longevity 用于增强电池健康分析的多尺度建模：长寿之路

Carbon Neutralization Pub Date : 2024-05-15 DOI: 10.1002/cnl2.124

Kaiyi Yang, Lisheng Zhang, Wentao Wang, Chengwu Long, Shichun Yang, Tao Zhu, Xinhua Liu

{"title":"Multiscale modeling for enhanced battery health analysis: Pathways to longevity","authors":"Kaiyi Yang, Lisheng Zhang, Wentao Wang, Chengwu Long, Shichun Yang, Tao Zhu, Xinhua Liu","doi":"10.1002/cnl2.124","DOIUrl":"10.1002/cnl2.124","url":null,"abstract":"The issues of health assessment and lifespan prediction have always been prominent challenges in the large-scale application of lithium-ion batteries (LIBs). This paper reviews the multiscale modeling techniques and their applications in battery health analysis, including atomic scale computational chemistry, particle scale reaction simulations, electrode scale structural models, macroscale electrochemical models, and data-driven models at the system level. Multiscale modeling offers a profound insight into material behavior and the aging process of batteries, thereby providing a valuable reference for both estimation and management strategies of battery state of health. To extend the battery lifespan, the utilization of artificial intelligence for material discovery and manufacturing process optimization, the implementation of end-cloud collaborative battery management systems, and the design of a multiscale simulation integration platform are considered. A management framework aimed at extending battery life is further proposed. This framework offers a promising roadmap for addressing health analysis challenges in LIBs, ultimately leading to more reliable, efficient, and durable solutions for next-generation batteries.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.124","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140977117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0