Carbon Neutralization最新文献_第2页

Front Cover: Carbon Neutralization, Volume 3, Issue 5, September 2024 封面：碳中和》，第 3 卷第 5 期，2024 年 9 月

Carbon Neutralization Pub Date : 2024-09-24 DOI: 10.1002/cnl2.172

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Recent progress in the synthesis and electrocatalytic application of MXene-based metal phosphide composites 基于 MXene 的金属磷化物复合材料的合成和电催化应用的最新进展

Carbon Neutralization Pub Date : 2024-09-23 DOI: 10.1002/cnl2.169

Hengjun Su, Chulong Jin, Xiaofeng Zhang, Zhixin Yu, Xiaojun Zeng

{"title":"Recent progress in the synthesis and electrocatalytic application of MXene-based metal phosphide composites","authors":"Hengjun Su, Chulong Jin, Xiaofeng Zhang, Zhixin Yu, Xiaojun Zeng","doi":"10.1002/cnl2.169","DOIUrl":"https://doi.org/10.1002/cnl2.169","url":null,"abstract":"In the domain of novel catalyst design and application, metal phosphides have attracted widespread interest due to their unique electronic structure and potential catalytic activity. Various types of supports that can effectively anchor metal phosphides have been reported, among which MXene have received significant attention due to their two-dimensional (2D) structure, adjustable composition, and composite variability. This work mainly aims to elucidate the preparation of novel MXene carriers and their unique roles in loading metal phosphides and participating in catalytic reactions. We will clarify the preparation strategy of MXene, the interaction between metal phosphides and MXene carriers, to explain the stabilization of metal phosphide active sites and the rational adjustment of electronic structure. In addition, we will comprehensively summarize recent research progress of MXene-based metal phosphide composites, with particular emphasis on advancements in the synergistic effect of heterostructures. Regarding applications, we review the utilization of MXene-based metal phosphide composites in electrocatalysis, including hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Finally, some fundamental challenges and prospects for the efficient electrocatalysis of MXene-based metal phosphide composites are introduced.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 6","pages":"1009-1035"},"PeriodicalIF":0.0,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.169","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Steric hindrance and orientation polarization by a zwitterionic additive to stabilize zinc metal anodes 用一种齐聚物添加剂稳定锌金属阳极的立体阻碍和取向极化作用

Carbon Neutralization Pub Date : 2024-09-18 DOI: 10.1002/cnl2.168

Lu Wang, Huaming Yu, Dongping Chen, Youliang Jin, Liangliang Jiang, Hanwei He, Gang Zhou, Zeqiang Xie, Yuejiao Chen

{"title":"Steric hindrance and orientation polarization by a zwitterionic additive to stabilize zinc metal anodes","authors":"Lu Wang, Huaming Yu, Dongping Chen, Youliang Jin, Liangliang Jiang, Hanwei He, Gang Zhou, Zeqiang Xie, Yuejiao Chen","doi":"10.1002/cnl2.168","DOIUrl":"https://doi.org/10.1002/cnl2.168","url":null,"abstract":"Zinc metal stands out as a promising anode material due to its exceptional theoretical capacity, impressive energy density, and low redox potential. However, challenges such as zinc dendrite growth, anode corrosion, and side reactions in aqueous electrolytes significantly impede the practical application of zinc metal anodes. Herein, 3-(1-pyridinio)-1-propanesulfonate (PPS) is introduced as a zwitterionic additive to achieve long-term and highly reversible Zn plating/stripping. Due to the orientation polarization with the force of electric field, PPS additive with π–π conjugated pyridinio cations and strong coordination ability of sulfonate anion tends to generate a dynamic adsorption layer and build a unique water–poor interface. PPS with steric hindrance effect and strong coordination ability can attract solvated Zn2+, thereby promoting the desolvation process. Moreover, by providing a large number of nucleation sites and inducing zinc ion flow, the preferred orientation of the (002) crystal plane can be achieved. Therefore, the interfacial electrochemical reduction kinetics is regulated and uniform zinc deposition is ensured. Owing to these advantages, the Zn//Zn symmetrical cell with PPS additive exhibits remarkable cycling stability exceeding 2340 h (1 mA cm−2 and 1 mA h cm−2). The Zn//V2O5 full cell also delivers stable cycling for up to 6000 cycles.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 6","pages":"996-1008"},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.168","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Uniform carbon coating and solid electrolyte interphase synergistically enhanced exceptional anodic K-ion storage properties of stable KTiOPO4 single crystals 均匀的碳涂层和固体电解质间相协同增强了稳定的 KTiOPO4 单晶的特殊阳极钾离子储存性能

Carbon Neutralization Pub Date : 2024-09-18 DOI: 10.1002/cnl2.167

Ling Bai, Su Jin, Qian Liu, Wenjuan Xu, Ziquan Li, Zhen-Dong Huang

{"title":"Uniform carbon coating and solid electrolyte interphase synergistically enhanced exceptional anodic K-ion storage properties of stable KTiOPO4 single crystals","authors":"Ling Bai, Su Jin, Qian Liu, Wenjuan Xu, Ziquan Li, Zhen-Dong Huang","doi":"10.1002/cnl2.167","DOIUrl":"https://doi.org/10.1002/cnl2.167","url":null,"abstract":"Searching for low-cost, high-capacity, high-power, high-stability, high-tap-density, and inherently safe materials for developing cheap, safe, and high-performance batteries has always been a research hotspot. Herein, an inherently safe, low-cost, and low-strain KTiOPO4 (KTOP) submicron single crystals with a uniform thin layer carbon coating are developed using a ball-mill assisted solid-state method. Uniform solid electrolyte interphase, carbon coating, and inherently stable structure synergistically help compact KTOP submicron single crystals achieve an exceptional anodic K-ion storage performance. The carbon-coated KTOP single crystals obtained under the carbonization temperature of 400°C (KTOP-C-400) can deliver an exceptional potassium ion storage performance of 253.3, 224.0, 175.5, and 131.1 mA h g−1 at the current density of 100, 200, 500, and 1000 mA g−1, respectively, in the electrolyte of 5 M potassium bis(fluorosulfonyl)imide (KFSI) in DIGLYME electrolytes. Even after being cycled at 1000 mA g−1 for 1000 cycles, the capacity was maintained at 182.5 mA h g−1 with a coulombic efficiency of 99.9%.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 6","pages":"1131-1139"},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.167","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A novel design for conversion and storage of solar thermal energy into electrical energy using a solar thermoelectric device-coupled supercapacitor 利用太阳能热电装置耦合超级电容器将太阳热能转化为电能并加以储存的新型设计

Carbon Neutralization Pub Date : 2024-08-30 DOI: 10.1002/cnl2.166

Pengjun Ma, Yan Wang, Xu Zhang, Junwei Lang, Juan Yang, Tongtong Yu, Liqiang Chai, Bingjun Yang, Yanan Deng, Xianfeng Fan, Joonho Bae

{"title":"A novel design for conversion and storage of solar thermal energy into electrical energy using a solar thermoelectric device-coupled supercapacitor","authors":"Pengjun Ma, Yan Wang, Xu Zhang, Junwei Lang, Juan Yang, Tongtong Yu, Liqiang Chai, Bingjun Yang, Yanan Deng, Xianfeng Fan, Joonho Bae","doi":"10.1002/cnl2.166","DOIUrl":"https://doi.org/10.1002/cnl2.166","url":null,"abstract":"The conversion of solar-thermal (ST) power into electrical power along with its efficient storage represents a crucial and effective approach to address the energy crisis. The thermoelectric (TE) generator can absorb ST power and transform it into electrical energy, making it a highly viable technology to achieve photo-thermal conversion (PTC). However, the practical application of the pristine TE generator devices on a larger scale is still facing several challenges. On the one hand, the pristine TE generator device has low inherent PTC efficiency, thereby leading to low power conversion. On the other hand, such solar-thermoelectric (STE) conversion does not provide the functionality of electric energy storage. Herein, an effective strategy has been proposed that employs a CoAl2O4 PTC coating to decorate the pristine TE generator for developing the STE generator device with the remarkable STE performance and then coupling this device with a supercapacitor (SC) for effective storage power. In comparison to the pristine TE generator, the developed STE device exhibited considerable enhancement in both the open-circuit voltage (Voc) and its maximum power density, displaying more than a 4- and 15-fold improvement, respectively. In addition, the feasibility of coupling this solar-driven STE generator device in series with a SC for ST conversion and storage was verified, and the working mechanism has been elucidated. This work presents a promising approach to effectively convert and store clean solar power into electrical energy, enabling practical applications of STE generator devices in conjunction with other electrochemical energy storage devices.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 5","pages":"781-797"},"PeriodicalIF":0.0,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.166","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142316913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Insight into rechargeable batteries in extreme environment for deep space exploration 深入了解极端环境下的充电电池，促进深空探索

Carbon Neutralization Pub Date : 2024-08-30 DOI: 10.1002/cnl2.164

Yi He, Wenxu Shang, Peng Tan

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Binder-induced inorganic-rich solid electrolyte interphase and physicochemical dual cross-linked network for high-performance SiOx anode 用于高性能氧化硅阳极的粘合剂诱导富无机固体电解质间相和物理化学双交联网络

Carbon Neutralization Pub Date : 2024-08-22 DOI: 10.1002/cnl2.158

Gang Wu, Yuanhang Gao, Zheng Weng, Zhicheng Zheng, Wenqiang Fan, Anqiang Pan, Ning Zhang, Xiaohe Liu, Renzhi Ma, Gen Chen

{"title":"Binder-induced inorganic-rich solid electrolyte interphase and physicochemical dual cross-linked network for high-performance SiOx anode","authors":"Gang Wu, Yuanhang Gao, Zheng Weng, Zhicheng Zheng, Wenqiang Fan, Anqiang Pan, Ning Zhang, Xiaohe Liu, Renzhi Ma, Gen Chen","doi":"10.1002/cnl2.158","DOIUrl":"https://doi.org/10.1002/cnl2.158","url":null,"abstract":"Silicon oxide (SiOx) is heralded as the forefront anode material for high-energy density lithium-ion batteries, owing to its exceptional specific capacity. Nevertheless, the traditional combination of polyacrylic acid binder and acetylene black conductive carbon continues to struggle with the immense stress induced by the repetitive volume expansion and contraction processes. Here we report a high ionic conductivity, sulfonyl fluoro-containing binder for SiOx anode via free radical copolymerization reaction between perfluoro (4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride and acrylic acid. The electrode fabrication process incorporated amino-functionalized carbon nanotubes (CNT-NH2) as the conductive agent. A three-dimensional conductive network structure is constructed through physical and chemical double cross-linking interactions between the -COOH and -SO2F functional groups of PAF0.1 binder, the -NH2 groups of CNT-NH2, and the -OH groups on the surface of SiOx, including hydrogen bonds and covalent bonds. In addition, the binder induces the formation of a solid electrolyte interphase (SEI) rich in inorganic components such as Li2O, Li2SO3, Li2CO3, and LiF. Benefiting from the synergistic effects of the physically and chemically double cross-linked three-dimensional conductive network constructed by the PAF0.1 binder and CNT-NH2, coupled with the rich-inorganic SEI, the SiOx anode delivers exceptional rate performance, cycle stability, and lithium-ion diffusion dynamics.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 5","pages":"857-872"},"PeriodicalIF":0.0,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.158","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142316856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Integral morphology and structure design of poly (heptazine imide) for efficient utilization of visible light generated charge carriers in proton reduction reactions 在质子还原反应中高效利用可见光产生的电荷载流子的聚（庚嗪亚胺）整体形态和结构设计

Carbon Neutralization Pub Date : 2024-08-22 DOI: 10.1002/cnl2.154

Boyin Zhai, Jiarui He, Hongguan Li, Xinglong Li, Suvonkul Nurmanov, Olim Ruzimuradov, Ping Niu, Sangeun Chun, Shulan Wang, Li Li

{"title":"Integral morphology and structure design of poly (heptazine imide) for efficient utilization of visible light generated charge carriers in proton reduction reactions","authors":"Boyin Zhai, Jiarui He, Hongguan Li, Xinglong Li, Suvonkul Nurmanov, Olim Ruzimuradov, Ping Niu, Sangeun Chun, Shulan Wang, Li Li","doi":"10.1002/cnl2.154","DOIUrl":"https://doi.org/10.1002/cnl2.154","url":null,"abstract":"Sufficient utilization of visible-light generated charge carriers in proton reduction reactions is of great significance for the development of effective solar-fuel technologies. Achieving simultaneous bulk rapid transfer and surface efficient extraction of charge carriers is still very challenging. Herein, it is found for the first time ammonium persulfate (APS) can significantly influence polymerization processes of C3N4 (CN) from melamine to poly (heptazine imide) (PHI) under the simultaneous oxygen doping and etching effect of SO42−. PHI with high crystallinity, porous structure, and in-situ oxygen doping was therefore obtained through one-step APS-assisted salt strategy. Benefiting from sufficient visible-light absorption and upshifted conduction band originating from regulated electronic structure and optimized morphology through APS modification, the as-prepared PHI achieved a H2 evolution activity of 3274.23 μmol h−1 g−1 (λ  > 420 nm), which is appropriately 148 and 19 times that of conventional and crystalline CN. This work opens up new opportunities for efficient photocatalysis.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 5","pages":"888-903"},"PeriodicalIF":0.0,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.154","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142316632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

MXene ink printing of high-performance micro-supercapacitors MXene 油墨印刷高性能微型超级电容器

Carbon Neutralization Pub Date : 2024-08-22 DOI: 10.1002/cnl2.165

Yitong Wang, Yuhua Wang

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Layered oxide cathodes: A comprehensive review of characteristics, research, and development in lithium and sodium ion batteries 层状氧化物阴极：锂离子和钠离子电池的特性、研究和发展综述

Carbon Neutralization Pub Date : 2024-08-19 DOI: 10.1002/cnl2.162

Zhengwei Xu, Kangwei Song, Xinyue Chang, Li Li, Weicheng Zhang, Yixun Xue, Jiahui Zhang, Dewu Lin, Zheyuan Liu, Qian Wang, Yan Yu, Chengkai Yang

{"title":"Layered oxide cathodes: A comprehensive review of characteristics, research, and development in lithium and sodium ion batteries","authors":"Zhengwei Xu, Kangwei Song, Xinyue Chang, Li Li, Weicheng Zhang, Yixun Xue, Jiahui Zhang, Dewu Lin, Zheyuan Liu, Qian Wang, Yan Yu, Chengkai Yang","doi":"10.1002/cnl2.162","DOIUrl":"https://doi.org/10.1002/cnl2.162","url":null,"abstract":"Layered oxide materials are widely used in the field of energy storage and conversion due to their high specific energy, high efficiency, long cycle life, and high safety. Herein, We summarize the latest research progress in the field of layered metal oxide cathode materials from three aspects: challenges faced, failure mechanisms, and modification methods. We also compare the characteristics of lithium-based layered oxides and sodium-based layered oxides, and predict future development directions. The layered oxide cathode materials for sodium-ion batteries and lithium-ion batteries exhibit overall structural and operational similarities. There are also some differences, such as lattice parameters and application extent. Sodium-ion battery cathode materials need to explore new materials and address structural instability issues, while lithium-ion batteries require finding alternative materials and improving production efficiency. Future challenges for both types of materials include enhancing capacity and cycle performance, elucidating deep mechanisms, reducing costs, and improving resource sustainability. Future development should focus on balancing cycle stability and charge cut-off voltage to meet the growing demand for battery applications.","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"3 5","pages":"832-856"},"PeriodicalIF":0.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.162","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142316788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0