ChemistryOpen最新文献_第7页

Improved Synthesis of Dinuclear [M(μ-X)(η⁵-Cp*)X]₂ Precursors for Half-Sandwich Complexes (M=Rh or Ir; X=Br or I). 半夹心配合物[M(μ-X)(η - cp *)X]2前驱体的改进合成（M=Rh或Ir）X=Br或I)。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-03-03 DOI: 10.1002/open.202500026

Kamila Petrželová, Ondřej Bárta, Renata Héžová, Alžběta Andrýsková, Jan Hošek, Pavel Štarha

引用次数: 0

Efficient Regioselective Iodination of Pyrazole Derivatives Mediated by Cadmium(II) Acetate. 乙酸镉（II）介导的吡唑衍生物的高效区域选择性碘化。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-28 DOI: 10.1002/open.202400443

Nina G Hobosyan, Kristine V Balyan, Lusine A Movsisyan, Varduhi S Hovsepyan, Armen G Ayvazyan, Henrik A Panosyan, Hovhannes S Attaryan, Hmayak B Sargsyan, Haykanush R Pogosyan

{"title":"Efficient Regioselective Iodination of Pyrazole Derivatives Mediated by Cadmium(II) Acetate.","authors":"Nina G Hobosyan, Kristine V Balyan, Lusine A Movsisyan, Varduhi S Hovsepyan, Armen G Ayvazyan, Henrik A Panosyan, Hovhannes S Attaryan, Hmayak B Sargsyan, Haykanush R Pogosyan","doi":"10.1002/open.202400443","DOIUrl":"https://doi.org/10.1002/open.202400443","url":null,"abstract":"The present study focuses on the iodination of pyrazoles mediated by cadmium (II) acetate. The objects of research were compounds with pyrazole rings substituted by N-propargyl, C, N-alkyl groups. Depending on the molar ratios of the reagents effective ways of obtaining mono- and triiodo-substituted products with the participation of the propargylic fragment in DMSO were elucidated. Induced by the cadmium (II) acetate principles of electrophilic iodination of the C-4 position of the pyrazole ring containing electron-donating groups were revealed. The iodination of the pyrazole derivative with only propargylic substituent was found to target the CH-acidic center of the triple bond and to lead to the corresponding iodoalkyne. An iodo-substituted product with triple bond is more reactive and prone to further electrophilic iodination forming a triiodo-substituted derivative. The introduction of methyl groups in the pyrazole ring of derivatives with propargylic substituent contributed to the promotion of competitive iodination reactions due to the increase in nucleophilicity of the pyrazole ring. Dimerized pyrazole rings with carbon atoms in the 4-th position did not succeed in being iodinated by the mentioned way. Possible pathways for both triple bond and pyrazole ring iodination involving acetyl hypoiodite were proposed.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202400443"},"PeriodicalIF":2.5,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143522742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Node Modification of Metal-Organic Frameworks for Catalytic Applications. 金属-有机骨架的节点修饰催化应用。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-26 DOI: 10.1002/open.202400428

Mario Martos, Isidro M Pastor

{"title":"Node Modification of Metal-Organic Frameworks for Catalytic Applications.","authors":"Mario Martos, Isidro M Pastor","doi":"10.1002/open.202400428","DOIUrl":"https://doi.org/10.1002/open.202400428","url":null,"abstract":"Metal-organic frameworks (MOFs) have been a breakthrough in different fields of chemistry, not only due to the extensive possibilities regarding their synthesis, but also the ease of modulation of the structure's properties by chemical modification of linkers and nodes. The latter is particularly interesting in heterogeneous catalysis, as the newly inserted species may enhance, regulate, or straight enable new forms of catalysis unattainable by the pristine material. This acts in conjunction with the parent MOFs providing selectivity (e. g., by size exclusion) and protecting highly reactive catalytic species, offering increased stability and robustness to well-known catalytic systems. In this review, we compile the most relevant post-synthetic modification of the nodes of well-known MOFs of the last decade (2015-2024) and their application to heterogeneous catalysis. This review is divided into two main sections covering modifications involving metallic species and organic moieties, with sub-sections for each MOF on both. This way, we aim to provide a broad view of the state of the art while showcasing the expanded catalytic properties of the resulting materials.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202400428"},"PeriodicalIF":2.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143514827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrogen Storage and Release via Carbon Dioxide Hydrogenation to Formate Salts under High-Pressure Conditions with Ir Complex and Subsequent Formic Acid Dehydrogenation 高压条件下用Ir配合物将二氧化碳加氢生成甲酸盐并进行甲酸脱氢的储氢与释放。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-25 DOI: 10.1002/open.202500032

Seo Ono, Dr. Ryoichi Kanega, Prof. Hajime Kawanami

{"title":"Hydrogen Storage and Release via Carbon Dioxide Hydrogenation to Formate Salts under High-Pressure Conditions with Ir Complex and Subsequent Formic Acid Dehydrogenation","authors":"Seo Ono, Dr. Ryoichi Kanega, Prof. Hajime Kawanami","doi":"10.1002/open.202500032","DOIUrl":"10.1002/open.202500032","url":null,"abstract":"To investigate the potential of formic acid (FA) as a hydrogen carrier, we examined hydrogen storage and production through formate salts generated via CO2 reduction under supercritical fluid conditions. Formate salts were synthesized using Cp*Ir homogeneous catalysts to reduce CO2 under supercritical conditions (CO2: 12 MPa; H2: 0.5 MPa; total 12.5 MPa), achieving turnover frequency (TOF) of 10,240 h−1 and a turnover number (TON) of 20,480 within 2 h at 50 °C. The maximum formate concentration reached 0.81 mol/L after 18 h. The resulting formate salt solution (0.81 mol/L) was subsequently converted into FA (0.50 mol/L) with a 96 % yield by exchange of the cation (K + to H +) using an ion exchange resin. FA was then dehydrogenated to regenerate hydrogen, achieving a FA conversion exceeding 98 %. This process yielded an overall hydrogen recovery rate of over 90 %. These findings demonstrate a viable method for hydrogen storage and regeneration using formate salts as an efficient hydrogen carrier for future energy applications.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":"14 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/open.202500032","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143490995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Machine Learning-Based High-Throughput Screening, Molecular Modeling and Quantum Chemical Analysis to Investigate Mycobacterium tuberculosis MetRS Inhibitors. 基于机器学习的高通量筛选、分子建模和量子化学分析，用于研究结核分枝杆菌 MetRS 抑制剂。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-25 DOI: 10.1002/open.202400460

Rajesh Maharjan, Kalpana Gyawali, Arjun Acharya, Madan Khanal, Kamal Khanal, Mohan Bahadur Kshetri, Madhav Prasad Ghimire, Tika Ram Lamichhane

{"title":"Machine Learning-Based High-Throughput Screening, Molecular Modeling and Quantum Chemical Analysis to Investigate Mycobacterium tuberculosis MetRS Inhibitors.","authors":"Rajesh Maharjan, Kalpana Gyawali, Arjun Acharya, Madan Khanal, Kamal Khanal, Mohan Bahadur Kshetri, Madhav Prasad Ghimire, Tika Ram Lamichhane","doi":"10.1002/open.202400460","DOIUrl":"https://doi.org/10.1002/open.202400460","url":null,"abstract":"The increasing drug resistance of Mycobacterium tuberculosis (Mtb) complicates its effective treatment and often leads to severe side effects. This research aims to pinpoint the potential drug candidates targeting Mtb methionyl-tRNA synthetase (MtbMetRS) using in silico techniques. Employing machine learning algorithms, including Random Forest, Extra Trees, and Nu-Support Vector, a voting classifier was built to screen 10 million molecules. A total of 590 molecules were filtered and analyzed for mutagenicity and other toxicities, resulting in 169 candidates for molecular docking. Among these, 1-[4-(1,3-benzodioxol-5-ylmethyl)piperazin-1-yl]-2-phenylsulfanylethanone (L1) and 1-ethyl-6-fluoro-4-oxo-7-(4-pentanoylpiperazin-1-yl)quinoline-3-carboxylic acid (L2) demonstrated strong binding affinities (-12.74 kcal/mol for L1 and -11.83 kcal/mol for L2) and favorable pharmacokinetic properties. MM/PBSA, DFT calculations, and LD50 values supported their stability, reactive nature, and safer toxicity profile, respectively. L1 and L2 are investigated as potential inhibitors of MtbMetRS; however, additional in vitro and in vivo investigations are necessary to confirm these findings.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202400460"},"PeriodicalIF":2.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143491002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Efficient Production and Isolation of 3-Acetamido-5-Acetylfuran from N-Acetyl-D-Glucosamine within Protic Ionic Liquids. 质子离子液体中n -乙酰- d -氨基葡萄糖高效生产- 3-乙酰氨基-5-乙酰呋喃

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-25 DOI: 10.1002/open.202500094

Emma L Matthewman, Jonathan Sperry, Cameron C Weber

{"title":"Efficient Production and Isolation of 3-Acetamido-5-Acetylfuran from N-Acetyl-D-Glucosamine within Protic Ionic Liquids.","authors":"Emma L Matthewman, Jonathan Sperry, Cameron C Weber","doi":"10.1002/open.202500094","DOIUrl":"https://doi.org/10.1002/open.202500094","url":null,"abstract":"The transformation of chitin and its monomer N-acetylglucosamine (NAG) to high-value organonitrogen chemicals has attracted increasing interest, with 3-acetamido-5-acetylfuran (3A5AF) proposed as a versatile platform chemical. The preparation of 3A5AF from NAG has relied on high boiling organic solvents, ionic liquids (ILs) or deep eutectic solvents (DES). While these methods have met with some success, the isolation of 3A5AF and recycling of the solvent remains problematic for non-IL methods whereas most IL methods utilize inherently expensive aprotic ILs with substantial environmental footprints. This study details the preparation of 3A5AF in more cost-effective chloride-based protic ILs (PILs) with lower synthetic footprints than conventional ILs. Maximum yields of 42.5 %, 51.5 % and 57.0 % of 3A5AF were afforded in 1,8-diazabicyclo[5.4.0]undec-7-ene chloride ([DBU]Cl), tripropylammonium chloride ([TPA]Cl) and tributylammonium chloride ([TBA]Cl) respectively with 2 eq. B(OH)3 at 150 °C. The 3A5AF formed was readily isolated by simple solvent extraction, avoiding column chromatography, with selected systems displaying good recyclability and scalability. E-factor calculations revealed that the PIL methodology produced substantially less waste than approaches for the production of 3A5AF from molecular solvents and DES, highlighting that PILs are suitable solvents for the sustainable production of 3A5AF.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202500094"},"PeriodicalIF":2.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143490993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Improving the OER Activity of Titania Via Doping and Adlayers 通过掺杂和添加剂提高二氧化钛OER活性。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-25 DOI: 10.1002/open.202400085

Anna Gomer, Prof. Dr. Thomas Bredow

{"title":"Improving the OER Activity of Titania Via Doping and Adlayers","authors":"Anna Gomer, Prof. Dr. Thomas Bredow","doi":"10.1002/open.202400085","DOIUrl":"10.1002/open.202400085","url":null,"abstract":"The oxygen evolution reaction (OER) was investigated theoretically on modified rutile(110) surfaces at density functional theory level in search for inexpensive but active catalyst materials required for water electrolysis. Ti substitution by Nb in rutile and furthermore adding adlayers of transition metal (TM) oxides, with TM<math></math>\u0000Ir, Ru and Rh, substantially improves titania OER activity. The catalytic activity was assessed by the overpotential of the OER which was calculated from adsorption energies of the intermediates M−O, M−OH and M−OOH. Different reaction mechanisms were suggested depending on the presence or absence of M−OOH. Materials with iridium dioxide in the top layer have similar overpotentials, both as adlayer on (doped) <math></math>\u0000 and as pure <math></math>\u0000. Thus, the percentage of this expensive and scarce element can be drastically reduced without deteriorating the activity. A monolayer of <math></math>\u0000 on rutile <math></math>\u0000 has an even lower overpotential compared to pure <math></math>\u0000. In addition, <math></math>\u0000 and <math></math>\u0000:<math></math>\u0000 were identified as catalysts with higher OER activity than <math></math>\u0000.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":"14 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/open.202400085","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143490998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Utilization of Pulsed Current-Electro Fenton Technology for the Treatment of Wastewater from Industrial Processes. 脉冲电流-电Fenton技术在工业废水处理中的应用。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-21 DOI: 10.1002/open.202400505

Perumal Asaithambi, Abdelrahman O Ezzat, Firomsa Bidira, Mamuye Busier Yesuf, Omar H Abd-Elkader, Arun Thirumurugan, N M Hariharan, Hamad A Al-Lohedan, Abudukeremu Kadier

{"title":"Utilization of Pulsed Current-Electro Fenton Technology for the Treatment of Wastewater from Industrial Processes.","authors":"Perumal Asaithambi, Abdelrahman O Ezzat, Firomsa Bidira, Mamuye Busier Yesuf, Omar H Abd-Elkader, Arun Thirumurugan, N M Hariharan, Hamad A Al-Lohedan, Abudukeremu Kadier","doi":"10.1002/open.202400505","DOIUrl":"https://doi.org/10.1002/open.202400505","url":null,"abstract":"In recent years, there has been a rise in the use of electrochemical and advanced oxidation methods to treat the industrial wastewater. The efficiency of several approaches for treating industrial wastewater, including hydrogen peroxide (H2O2), electro-Fenton (EF) and pulsed-electro-Fenton (PEF) processes were all investigated. In evaluation to the H2O2, EF, and PEF technologies, the results showed that the PEF process produced 100 % total color and 98 % chemcial oxygen demand (COD) removal efficiency with a low consumption of power of 3.4 kWhrm-3. The experimental parameters comprised the following: COD - 2500 mg L-1, pH - 3, H2O2 - 300 mg L-1, distance between electrode - 0.75 cm, current - 0.40 A, cycle of pulse duty - 0.75, combination of electrode - Fe/Fe, stirring speed - 500 rpm and treatment duration (TD) - 125 min. It was demonstrated that increasing the TD, current, and H2O2 while lowering the COD content improved the COD elimination efficiency while employing a iron (Fe/Fe) electrode combination with wastewater pH of 3. The efficiency of the EF process has been reduced in comparison to the PEF process because of the development of an impermeable oxide layer on the cathode and the oxidation-induced corrosion on the anode. Consequently, experimental results have indicated that the PEF could be a more promising technology than the EF method for eliminating pollutants from wastewater with reduced power consumption and process efficiency.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202400505"},"PeriodicalIF":2.5,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143467219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effects of the Central Unit Structure, Lateral Substitution and Symmetry on the Mesomorphic Behavior of Some Bent-Core Azoester Derivatives. 中心单元结构、侧向取代和对称性对某些双核偶氮酯衍生物介形行为的影响。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-21 DOI: 10.1002/open.202400454

Catalina-Ionica Ciobanu, Elena-Luiza Epure, Laurentiu Soroaga, Aurel Simion, Gabriela Lisa, Irina Carlescu

{"title":"Effects of the Central Unit Structure, Lateral Substitution and Symmetry on the Mesomorphic Behavior of Some Bent-Core Azoester Derivatives.","authors":"Catalina-Ionica Ciobanu, Elena-Luiza Epure, Laurentiu Soroaga, Aurel Simion, Gabriela Lisa, Irina Carlescu","doi":"10.1002/open.202400454","DOIUrl":"https://doi.org/10.1002/open.202400454","url":null,"abstract":"We report here the synthesis and characterization of some new bent-core asymmetric compounds derived from resorcinol whose thermal behavior has been analyzed by comparison with their analogs derived from 1,3-disubstituted benzene and 2,7-dihydroxynaphthalene containing azoester aromatic units and alkyl chain end. The asymmetric structures contain 4-(4-alkyloxyphenylazo)-benzoyl and 4-methoxy-benzoyl or 3-bromo-4-methoxy-benzoyl as side arms. The investigations have been carried out to reach a better understanding of the structure-properties relationship in such bent-shaped compounds. We observed that a change in molecular structure like the nature of the central core, the symmetry of the structure or the presence of polar lateral substituent influence not only liquid crystalline properties, but also the thermal behavior. The thermogravimetric analysis showed that the bent-core derivatives have a good thermal stability since the degradation of the compounds begins over the isotropization temperature. Theoretical calculations were performed to elucidate the behavior of the compounds. These can assist us in designing new molecules that exhibit specific mesomorphic properties.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202400454"},"PeriodicalIF":2.5,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143467217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

B,N-Doped Activated Carbon-Based Electrodes from Potato Peels for Energy Storage Applications 马铃薯皮B， n掺杂活性炭基储能电极。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-02-19 DOI: 10.1002/open.202400527

Dr. Jan Willem Straten, Dr. Muhammad-Jamal Alhnidi, Ghassan Alchoumari, Krishna Sangam, Prof. Dr. Andrea Kruse

{"title":"B,N-Doped Activated Carbon-Based Electrodes from Potato Peels for Energy Storage Applications","authors":"Dr. Jan Willem Straten, Dr. Muhammad-Jamal Alhnidi, Ghassan Alchoumari, Krishna Sangam, Prof. Dr. Andrea Kruse","doi":"10.1002/open.202400527","DOIUrl":"10.1002/open.202400527","url":null,"abstract":"Potato peels (PPs) as waste biomass were selected as the biobased carbon source for this study, using urea as N precursor and boron trioxide as B precursor for the “in situ doping” via hydrothermal carbonization (HTC). During HTC, the feedstocks decompose over a wide range of complex chemical degradation mechanisms that finally form single B- and N- as well as B,N-co-doped hydrochars (HCs). Upon chemical ZnCl2 activation, the single B-doped activated carbon (AC) possessed a maximum B content of 0.2 wt%, whereas co-doped B,N-AC had the highest N content of 5.7 wt% with a B content of 0.1 wt%. The influence of single and B,N-co-doping on the physical-chemical material properties of the AC electrodes was analyzed and compared, in combination with its effect on the electrochemical performance for energy storage application. Compared to pristine AC derived from PPs, the B-doped and B,N-co-doped AC depicted increased electrical conductivity (EC) values of 50.3 S ⋅ m−1 and 34.0 S ⋅ m−1, respectively. In addition, the B,N-co-doped AC unveiled the highest average specific capacitances of 51.7 F ⋅ g−1 at 100 mV ⋅ s−1 and of 71.9 F ⋅ g−1 at 5 mV ⋅ s−1 outperforming the specific capacitance values of the reference material AC from peat.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":"14 3","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/open.202400527","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143457079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0